PL68550B3 - - Google Patents

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Publication number
PL68550B3
PL68550B3 PL13233969A PL13233969A PL68550B3 PL 68550 B3 PL68550 B3 PL 68550B3 PL 13233969 A PL13233969 A PL 13233969A PL 13233969 A PL13233969 A PL 13233969A PL 68550 B3 PL68550 B3 PL 68550B3
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PL
Poland
Prior art keywords
hal
dihalo
amino
general formula
amide
Prior art date
Application number
PL13233969A
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Polish (pl)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to PL13233969A priority Critical patent/PL68550B3/pl
Publication of PL68550B3 publication Critical patent/PL68550B3/pl

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Description

Wytworzony z dwumetyloamidu kwasu 4-amino-3,5-dwubromofenyloglikolowego w sposób analogiczny do podanego w przykladzie III. 25 PL PLPrepared from 4-amino-3,5-dibromophenylglycolic acid dimethylamide in a manner analogous to example III. 25 PL PL

Claims (2)

1. Zastrzezenia patentowe 1. Sposób wytwarzania amino-dwuchlorowco-fe- nyloetyloamin o wzorze ogólnym 2, w którym pod¬ stawniki Hal sa takie same lub rózne i oznaczaja 30 atomy bromu lub chloru, a podstawniki R4 i R5, które sa takie same lub rózne, oznaczaja atomy wodoru, o prostym lub rozgalezionym lancuchu nizsze reszty alkilowe, reszty alkenylowe, alkiny- lowe, hydroksyalkilowe, alkoksyalkilowe, dwualki- 35 loaminoalkilowe, cykloalkilowe, fenylowe, benzy¬ lowe lub adamantylowe, albo lacznie z atomem azotu tworza pierscien pirolidynowy, piperydyno- wy, piperazynowy, morfolinowy, szesciometyleno- iminowy lub kamfidynowy, ewentualnie podsta- 40 wiony nizszymi resztami alkilowymi, jak równiez ich fizjologicznie dopuszczalnych soli addycyjnych z nieorganicznymi lub organicznymi kwasami, po¬ legajacy na redukcji amidu kwasu amino-dwu- chlorowco-fenyloglioksalowego lub amidu kwasu 45 amino-dwuchlorowco-fenyloglikolowego za pomoca kompleksowego wodorku metali alkalicznych, we¬ dlug patentu nr 65976, znamienny tym, ze jako substrat stosuje sie amid kwasu fenyloglioksalo- wego o wzorze ogólnym 3 lub amid kwasu feny- so loglikolowego o wzorze ogólnym 4, w których to wzorach Hal, R4 i R6 maja wyzej podane znacze¬ nie.1. Claims 1. A method for the preparation of the amino-dihalo-phenylethylamines of general formula II, in which Hal are the same or different and represent bromine or chlorine, and R4 and R5, which are the same or miscellaneous, denote hydrogen atoms, straight or branched chain, lower alkyl residues, alkenyl, alkynyl, hydroxyalkyl, alkoxyalkyl, dialkylaminoalkyl, cycloalkyl, phenyl, benzene or adamantyl residues, or in combination with a pyrrolidine nitrogen atom, piperidine, piperazine, morpholine, hexamethylenimine or camphidine, optionally substituted with lower alkyl residues, as well as their physiologically acceptable addition salts with inorganic or organic acids, by reduction of the amino dihalo phenylglyoxyl amide or amide of 45-amino-dihalo-phenylglycolic acid by means of an alkali metal hydride complex, according to the patent No. 65,976, characterized in that the starting material is a phenylglyoxylic acid amide of the general formula III or a phenylglycolic acid amide of the general formula IV, in which the formulas Hal, R4 and R6 have the meaning given above. 2. Sposób wedlug zastrz. 1, znamienny tym, ze redukcje prowadzi sie za pomoca wodorku lito- 55 wo-glinowego w bezwodnym obojetnym rozpusz¬ czalniku.KI. 12ql/02 68 550 MKP C07c 87/28 Hal Hal OH H d I I /"' CH-C-NV I \D H NH0 WZÓR1 Hal ?H V /R. C—C-N H H Rs WZÓR 2 WZÓR 3 OH O .R I II / * CH—C—N WZÓR 4 PL PL2. The method according to claim A process as claimed in claim 1, characterized in that the reductions are carried out with lithium aluminum hydride in an anhydrous, inert solvent. 12ql / 02 68 550 MKP C07c 87/28 Hal Hal OH H d II / "'CH-C-NV I \ DH NH0 PATTERN1 Hal? HV / R. C — CN HH Rs PATTERN 2 MODEL 3 OH O .RI II / * CH — C — N MODEL 4 PL PL
PL13233969A 1969-03-14 1969-03-14 PL68550B3 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL13233969A PL68550B3 (en) 1969-03-14 1969-03-14

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL13233969A PL68550B3 (en) 1969-03-14 1969-03-14

Publications (1)

Publication Number Publication Date
PL68550B3 true PL68550B3 (en) 1973-02-28

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Application Number Title Priority Date Filing Date
PL13233969A PL68550B3 (en) 1969-03-14 1969-03-14

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PL (1) PL68550B3 (en)

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