PL4809B1 - A method of producing a binder for the production of briquettes. - Google Patents
A method of producing a binder for the production of briquettes. Download PDFInfo
- Publication number
- PL4809B1 PL4809B1 PL4809A PL480924A PL4809B1 PL 4809 B1 PL4809 B1 PL 4809B1 PL 4809 A PL4809 A PL 4809A PL 480924 A PL480924 A PL 480924A PL 4809 B1 PL4809 B1 PL 4809B1
- Authority
- PL
- Poland
- Prior art keywords
- tar
- resin
- binder
- mixture
- resin material
- Prior art date
Links
- 239000011230 binding agent Substances 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims 6
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 239000003208 petroleum Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- -1 alkaline earth metal salts Chemical class 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims 2
- 239000000057 synthetic resin Substances 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 239000010779 crude oil Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 239000011269 tar Substances 0.000 description 13
- 239000003245 coal Substances 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011286 gas tar Substances 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011279 mineral tar Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Description
Do wyrobu brykietowi i sztucznie wy¬ twarzanych bryl kulistych z wegla uzywa¬ no dotychczas smoly pogazowej, kleju, zy¬ wicy badz materjalów podobnych.Spoiwo ze smoly jest bezsprzecznie najlepsze, gdyz nie przepuszcza wody, jest wytrzymale w ogniu, a nie zawierajac mi¬ neralów, daje malo popiolu.Spoiwo z kleju, którego wytwarzanie nie jest niczem ograniczone, ma wade, ze nie wytrzymuje dzialania wody i zczasem plesnieje. Poza tern daje duzo popiolu, gdyz do tego spoiwa* w celu zwiekszenia spoi¬ stosci, dodaje sie gips.Próbowano ulzywac, jako spoiwa, zywic, ale uzyciu ich w wiekszej ilosci stoi na przeszkodzie wysoka cena. Dotyczy to równiez zywic otrzymywanych ze smoly naftowej.Poza tern uzycie samej smoly naftowej, która jest wprawdzie tania i nie ma wieksze¬ go zastosowania, jest nieodpowiednie, gdyz wtekutek lepkosci nie da sie ona dobrze rozdrobnic.Wedlug wynalazku niniejszego, uzywa sie jako spoiwa do paliwa zazwyczaj sta¬ lego (wegla, trocin, korka i podobnydh ma¬ terjalów) mieszaniny smoly mineralmej od¬ wodnionej, pozbawionej olejów, z zywicami mineralnemi, roslinnemi lub syntetyczinemi, badz tylko z nieoczyszczona smola nafto¬ wa, niie pozbawiona zywic, Gdy mieszani¬ na jest wytwo-rzonaT pozadane jest wlac ja do zimnej wody, przez co staje sie ona ziar¬ nista i bardzo twarda. Spoiwo w ten spo¬ sób otrzymane ma takiez zalety jak smola pogazowa, ale jest tansze.Spoiwo to mozna mieszac w jakikolwiekodpowiedni sposób. Jezeli jeisit ono ziarni¬ ste, to lepiej sie rozmiesza w drobnym we¬ glu badz innejm paliwie. Nie trzeba go rów¬ niez uprzednio mlec, co jest konieczne przy uzyciu smoly zwyczajnej.Spoiwo przygotowuje sie ze smoly ^ któ¬ ra, w celu usuniecia oleju, odwadnia sie i destyluje przy niskiem cisnieniu (przy ci¬ snieniu slupa rteci od 5 do 6 cn^) oraz przy temperaturze od 150° do 200°C.Destylujac gmole przy niskiem olsnie¬ niu zapobiega sie pyrogenizacji jak rów¬ niez gromadzeniu sie weglanu w spoiwie; poza tern przy takiej destylacji uzywa sie mniej wegla.Pózniejj dodaje sie do smoly zywice rozpuszczona badz nieoczyszczona smole naftowa.Na 100 kilogramów smoly mozna dodac równiez, naprzyklad, od 50 do 100 kilo¬ gramów simoly naiftowej oraz od 5 do 10 kg zywiicy. Zywice, a wskutek tego i spoi¬ wo, otrzymuja wieksza twardosc, jezeli zmydli sie zawarte w nich wolne kwasy, dodajac niedulzo soli alkalicznych badz ziem alkalicznych, mianowicie, magnezje palona, wapno palone badz sól kuchenna w przyblizeniu w stosunku 1 : 100. Po zmy- dleniu zywicy, smola staje sie bardziej plynna i topnieje pfrzy nizlsizej tempera¬ turze.Gdy mieszanina jest roztopiona, wstrza¬ sa sie ja mechaniczmie badz w inny spo¬ sób, aby stala sie bardziej jednolita. Spoi¬ wo wlewa sie wtedy do form badz do zim¬ nej wody.W ostatnim wypadiku doprowadza sie spoiwo do rozpylacza skad scieka ono cienkiemi strumieniami do zhnnej wody, w której staje sie ziarniste.Oczywiste, ze w zakresie wynalazku mozna do spoiwa dodac smole z wegla ka- mietajnego, smole stearynowa, smole bawel¬ niana, smole zywiczna, bitum, asfalt badz materjaly podobne. PLSo far, coal tar, glue, resin or similar materials have been used for the production of briquettes and artificially produced spherical lumps of coal. Nerals, gives little ash. The binder of the glue, the production of which is not limited in any way, has the disadvantage that it does not withstand the action of water and molds over time. In addition to the ground, it gives a lot of ash, because gypsum is added to this binder to increase the cohesion. Attempts have been made to reduce the amount of resin as a binder, but using more of them is prevented by a high price. This also applies to resins obtained from petroleum tar. Apart from the use of petroleum tar itself, which is cheap and has no major application, is unsuitable, because due to its viscosity, it cannot be finely divided. In the present invention, it is used as a binder for Usually solid fuels (coal, sawdust, cork and similar materials) mixtures of dehydrated, oil-free mineral tar with mineral resins, vegetable or synthetic, or only with unpurified petroleum tar, not without resin, when mixed If it is made, it is desirable to pour it into cold water, which makes it grainy and very hard. The binder thus obtained has the same advantages as gas tar, but is cheaper. The binder can be mixed in any suitable manner. If it is granular, it will better distribute in fine wool or other fuel. It does not need to be milled beforehand, which is necessary with common tar. The binder is prepared from the tar which, to remove the oil, is dehydrated and distilled under low pressure (with a mercury pressure of 5 to 6 cn2) and at a temperature of 150 ° to 200 ° C. By distilling crash bars at low glare, pyrogenization is prevented as well as carbon build-up in the binder; outside the ground, less carbon is used in this distillation. Later, dissolved or unrefined petroleum tar is added to the tar. For 100 kg of tar, you can also add, for example, 50 to 100 kg of naift simola and 5 to 10 kg of resin. The resins, and thus the binder, obtain greater hardness when the free acids they contain are washed out by adding non-alkaline or alkaline earth salts, namely, burnt magnesia, quicklime or table salt in an approximately 1: 100 ratio. After the saponification of the resin, the tar becomes more fluid and melts at lower temperatures. When the mixture is molten, it is shaken mechanically or otherwise to make it more uniform. The binder is then poured into molds or into cold water. In the latter case, the binder is fed to a sprayer, from which it drips in thin streams into good water, where it becomes granular. Of course, within the scope of the invention, tar with hard coal, stearic tar, cotton tar, resin tar, bitumen, asphalt or the like. PL
Claims (6)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL4809B1 true PL4809B1 (en) | 1926-06-30 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0422753B1 (en) | Process for preparing a particular mixture having hydrophobic properties | |
| DE1594815B2 (en) | PROCESS FOR COATING POWDERY TO GRAINY SOLIDS WITH BITUMINOES BINDING AGENTS | |
| DE2010263A1 (en) | Process for the production of foam glass | |
| PL4809B1 (en) | A method of producing a binder for the production of briquettes. | |
| GB317496A (en) | An improved cold asphalt and application thereof | |
| US2738287A (en) | Structural elements and process of forming the same | |
| US2310095A (en) | Production of lignite briquettes | |
| US1603961A (en) | Process for the production of briquetted fuel with asphaltic bitumens as binders | |
| US1167373A (en) | Process for solidifying emulsion products. | |
| DE406191C (en) | Process for the recovery of domestic and commercial waste, incineration residues or similar waste | |
| US1872135A (en) | Fuel briquette | |
| DE398578C (en) | Process for the production of silica raw material, silica stones u. like | |
| DE853415C (en) | Method of preventing excessive dust formation when burning cement in rotary kilns | |
| DE393332C (en) | Method for producing a fuel saving mass | |
| DE1919750A1 (en) | Sintering flue dust on grids | |
| DE557374C (en) | Process for the production of bituminous masses, especially for road construction purposes | |
| SU36382A1 (en) | The method of producing peat coke | |
| GB190902461A (en) | Improvements in or relating to the Construction of Roads and a Composition therefor. | |
| Šedina et al. | Alternative Micro-Milled Binders in Cold Recycling Technologies | |
| DE945499C (en) | Process for the production of masses containing pitch | |
| US830086A (en) | Artificial fuel. | |
| DE446775C (en) | Process for the production of bituminous masses for road construction purposes | |
| US2906633A (en) | Bituminous roadmaking material | |
| AT126133B (en) | Process for the production of a waterproof building material. | |
| US60830A (en) | John f |