PL4641B1 - A method of deoxidizing metals and protecting them against oxidation. - Google Patents

A method of deoxidizing metals and protecting them against oxidation. Download PDF

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Publication number
PL4641B1
PL4641B1 PL4641A PL464125A PL4641B1 PL 4641 B1 PL4641 B1 PL 4641B1 PL 4641 A PL4641 A PL 4641A PL 464125 A PL464125 A PL 464125A PL 4641 B1 PL4641 B1 PL 4641B1
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PL
Poland
Prior art keywords
protecting
metals
metal
carbon
against oxidation
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Application number
PL4641A
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Polish (pl)
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Publication of PL4641B1 publication Critical patent/PL4641B1/en

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Wynalazek dotyczy sposobu ochrania¬ nia plynnych metali lub stopów, zachowu¬ jacych sie obojetnie wzgledem wegla, od dostepu tlenu powietrza i utleniania me¬ tali.Metale posiadajace wlasnosc utleniania sie w stanie plynnym i rozpuszczania pozo¬ stalych tlenków, sa bardzo trudne do za¬ bezpieczenia od dzialania tlenu powietrza.Metody stosowane dotychczas w wyzej wspomnianym celu polegaja na tern, ze na plynny metal dziala sie gazami opalowymi, którym nadano wlasnosci redukcyjne, albo tez dodaje sie do stapianego metalu inne metale lub metaloidy, jak np. P,Mg,Al,Zn, któne maja silne powinowactwo do tlenu.Metod tych nie mozna jednak zawsze stosowac.Metali lub stopów o niskiej temperatu¬ rze parowania nie mozna stapiac w otwar¬ tych naczyniach o duzej powierzchni, po¬ trzebnej wtedy, gdy na stapiany metal ma¬ ja dzialac redukcyjne gazy. Dodawanie re¬ dukcyjnych skladników wymienionych po¬ wyzej, jest takze czasem niemozliwe, mia¬ nowicie wtedy, gdy przerabiane metale lub stopy musza byc bardzo czyste, Jezeli sie uzywa takich domieszek redukcyjnych, to nie mozna ich ilosci tak uregulowac, aby pewna ich ilosc nie weszla w sklad stopu, wplywajac szkodliwie na jego wlasnosci mechaniczne. Ochrona metalu od utlenia¬ nia zapomcca wegla drzewnego jest rów¬ niez niewystarczajaca i moze byc powodem wprowadzenia do stopu niepozadanych skladników, bo jak wiadomo, w porach we-gla drzewnego moze byc zawarty oprócz innych dal, np. wodoru, takze wolny tlen.Wi^c przy uzyciu wegla drzewnego wpro¬ wadza sie do stopu wlasnie ten tak bardzo niepozadany tlen, nie mówiac juz o wodo¬ rze, który w pewnych wypadkach moze byc równiez szkodliwy, W mysl wynalazku osiaga sie nieza¬ wodna ochrone metalu (obojetnego wzgle¬ dem wegla) od utleniania, przez mieszanie plynnego metalu i pokrycie jego powierzch¬ ni warstwa sadzy lub wegla o wlasnosciach podobnych.Sadza jest jak wiadomo czystym we¬ glem, bardzo rozdrobnionym. Rozdrobnie¬ nie takie, obok czystosci, jest niemozliwe do osiagniecia mechanicznymi srodkami na¬ wet w przyblizeniu, a dla samego procesu ma ogromnie znaczenie. Gdy sie sadze mie¬ sza z plynnym metalem, to wszystkie jego czasteczki moga sie zetknac z redukcyjnie dzialajacemi czasteczkami sadzy, wskutek czego redukcja jest bardzo energiczna i me¬ tal nie moze zanieczyszczac sie obcemi do¬ mieszkami.Zapomoca mieszania sadzy z metalem osiaga sie bardzo dokladna nedukcje, któ¬ ra staje sie jeszcze dokladniejsza jezeli po¬ wierzchnie plynnego metalu pokryc warst¬ wa sadzy i ogrzac metal do temperatury najkorzystniejszej dla redukc/jl. Mala zdol¬ nosc sadzy-do przewodzenia ciepla, umozli¬ wia, pozadane podniesienie temperatury plynnego metalu, przyczem warstwa sadzy, pokrywajac powierzchnie metalu luzna i po¬ rowata, lecz gesta warstwa, uniemozliwia dostep tlenu do metalu, chroniac go od u- tlenienia, które przy wyzszej temperaturze byloby tern gwaltowniejsze.Równoczesnie, nienagrzewajaca sie war¬ stwa sadzy, nie przepuszcza par metalu, bo chlodzi jie i skrapla. PLThe invention relates to a method of protecting liquid metals or alloys which behave indifferently to carbon from the access of air oxygen and the oxidation of metals. Metals having the property of oxidizing in a liquid state and dissolving residual oxides are very difficult to form. protection from the action of air oxygen. The methods used so far for the above-mentioned purpose consist in the fact that the molten metal is treated with fuel gases, which have been given reducing properties, or other metals or metalloids, such as P, Mg, are added to the molten metal, Al, Zn, which have a strong affinity for oxygen. These methods, however, cannot always be used. Metals or alloys with a low evaporation temperature cannot be fused in open vessels with a large surface area, needed when the metal to be fused is ¬ I work reducing gases. The addition of the reducing components mentioned above is also sometimes impossible, namely when the processed metals or alloys must be very pure, If such reducing admixtures are used, their amount cannot be regulated so that a certain amount does not became part of the alloy, adversely affecting its mechanical properties. The protection of the metal from oxidation by means of charcoal is also insufficient and may be the reason for introducing undesirable components into the alloy, because as it is known, in the pores of charcoal, apart from other minerals, e.g. hydrogen, also free oxygen may be present. With the use of charcoal, this very undesirable oxygen is introduced into the alloy, not to mention hydrogen, which in some cases may also be harmful. According to the invention, a reliable protection of the metal (inert relative to carbon) from oxidation, by mixing the molten metal and covering its surface with a layer of soot or carbon with similar properties. Carbon black is known to be pure, finely divided coal. Such fragmentation, apart from purity, is impossible to achieve by mechanical means, even approximately, and is of great importance for the process itself. When carbon black is mixed with a liquid metal, all its particles may come into contact with the reducing soot particles, so that the reduction is very vigorous and the metal cannot contaminate with foreign substances. a precise reduction, which becomes even more accurate if the surfaces of the molten metal are covered with a layer of soot and the metal is heated to the temperature most favorable for the reduction. The low ability of soot to conduct heat enables the desired increase of the temperature of the molten metal, with a layer of soot covering the surface of the metal, loose and rough, but dense, preventing oxygen from reaching the metal, protecting it from oxidation, which would be more violent at a higher temperature. At the same time, the non-heating layer of soot does not let the metal vapor pass through, because it cools and condenses. PL

Claims (1)

1. Zastrzezenie patentowe. Sposób odtleniania metali, obojetnych wzgledem wegla i ochraniania ich od utle¬ niania, znamienny tern, ze plynny metal miesza sie z sadzami i pokrywa gesta war¬ stwa sadzy lub wegla sproszkowanego o podobnych wlasnosciach. Emil Heuse. Zastepca: M. Kryzan, rzecznik patentowy. Druk l Boguslawskiego Warszawa. PL1. Patent claim. A method of deoxidizing carbon-neutral metals and protecting them from oxidation, characterized by the fact that the molten metal is mixed with the soot and covered with a dense layer of carbon black or powdered carbon with similar properties. Emil Heuse. Deputy: M. Kryzan, patent attorney. Print and Boguslawski Warsaw. PL
PL4641A 1925-06-10 A method of deoxidizing metals and protecting them against oxidation. PL4641B1 (en)

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PL4641B1 true PL4641B1 (en) 1926-05-31

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