PL448397A1 - N,N-diphenyl-2-aminosumane and method of obtaining it - Google Patents

N,N-diphenyl-2-aminosumane and method of obtaining it

Info

Publication number
PL448397A1
PL448397A1 PL448397A PL44839724A PL448397A1 PL 448397 A1 PL448397 A1 PL 448397A1 PL 448397 A PL448397 A PL 448397A PL 44839724 A PL44839724 A PL 44839724A PL 448397 A1 PL448397 A1 PL 448397A1
Authority
PL
Poland
Prior art keywords
diphenyl
aminosumane
obtaining
tricyclopenta
jkl
Prior art date
Application number
PL448397A
Other languages
Polish (pl)
Inventor
Artur Kasprzak
Jakub Cyniak
Original Assignee
Politechnika Warszawska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Warszawska filed Critical Politechnika Warszawska
Priority to PL448397A priority Critical patent/PL448397A1/en
Publication of PL448397A1 publication Critical patent/PL448397A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/62—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with more than three condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Przedmiotem wynalazku jest N,N-difenylo-2-aminosumanen o nazwie systematycznej N,N-difenylo-4,7-dihydro-1H-tricyklopenta[def,jkl,pqr]trifenyleno-2-amina o wzorze 1. Kolejnym przedmiotem wynalazku jest sposób otrzymywania N,N-difenylo-2-aminosumanenu o nazwie systematycznej N,N-difenylo-4,7-dihydro-1H-tricyklopenta[def,jkl,pqr]trifenyleno-2-amina o wzorze 1, charakteryzujący się tym, że przygotowuje się mieszaninę 2-halogenosumanenu, jodku miedzi(I), liganda oraz zasady w rozpuszczalniku organicznym w stosunku molowym 1:1:(0,2 do 2,0):2, następnie mieszaninę reakcyjną ogrzewa się przez 24 godziny w temperaturze wrzenia w atmosferze gazu obojętnego, po czym do mieszaniny dodaje się 1M roztwór kwasu solnego, a uzyskany osad wydziela się z mieszaniny reakcyjnej na drodze ekstrakcji, a czysty produkt wyodrębnia się na drodze chromatografii kolumnowej.The subject of the invention is N,N-diphenyl-2-aminosumane with the systematic name N,N-diphenyl-4,7-dihydro-1H-tricyclopenta[def,jkl,pqr]triphenylene-2-amine of the formula 1. Another subject of the invention is a method for obtaining N,N-diphenyl-2-aminosumane with the systematic name N,N-diphenyl-4,7-dihydro-1H-tricyclopenta[def,jkl,pqr]triphenylene-2-amine of the formula 1, characterized in that a mixture of 2-halogenosumane, copper(I) iodide, ligand and base in an organic solvent in a molar ratio of 1:1:(0.2 to 2.0):2 is prepared, then the reaction mixture is heated for 24 hours at reflux temperature in an inert gas atmosphere, after which a 1M solution of hydrochloric acid, the obtained precipitate is separated from the reaction mixture by extraction and the pure product is isolated by column chromatography.

PL448397A 2024-04-24 2024-04-24 N,N-diphenyl-2-aminosumane and method of obtaining it PL448397A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL448397A PL448397A1 (en) 2024-04-24 2024-04-24 N,N-diphenyl-2-aminosumane and method of obtaining it

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL448397A PL448397A1 (en) 2024-04-24 2024-04-24 N,N-diphenyl-2-aminosumane and method of obtaining it

Publications (1)

Publication Number Publication Date
PL448397A1 true PL448397A1 (en) 2024-10-21

Family

ID=93155075

Family Applications (1)

Application Number Title Priority Date Filing Date
PL448397A PL448397A1 (en) 2024-04-24 2024-04-24 N,N-diphenyl-2-aminosumane and method of obtaining it

Country Status (1)

Country Link
PL (1) PL448397A1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1604949A2 (en) * 2003-01-31 2005-12-14 Nippon Shokubai Co., Ltd. Sumanene and process for production thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1604949A2 (en) * 2003-01-31 2005-12-14 Nippon Shokubai Co., Ltd. Sumanene and process for production thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DOMINIKA UFNAL ET AL.: "Organic & Biomolecular Chemistry, issue 25, 2024, p.1-10 https://www.researchgate.net/publication/380609522_Sumanene-carbazole_conjugate_with_push-pull_structure_and_its_chemoreceptor_application", SUMANENE–CARBAZOLE CONJUGATE WITH PUSH–PULL STRUCTURE AND ITS CHEMORECEPTOR APPLICATION *
SHAKEEL ALVI AND RASHID ALI: "Beilstein J. Org. Chem. 2020, 16, 2212–2259, https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-16-186.pdf", SYNTHETIC APPROACHES TO BOWL-SHAPED Π-CONJUGATED SUMANENE AND ITS CONGENERS *

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