PL439643A1 - Porphyrin-sugar hybrids and their synthesis - Google Patents

Porphyrin-sugar hybrids and their synthesis

Info

Publication number
PL439643A1
PL439643A1 PL439643A PL43964321A PL439643A1 PL 439643 A1 PL439643 A1 PL 439643A1 PL 439643 A PL439643 A PL 439643A PL 43964321 A PL43964321 A PL 43964321A PL 439643 A1 PL439643 A1 PL 439643A1
Authority
PL
Poland
Prior art keywords
porphyrin
general formula
sugar
hybrids
synthesis
Prior art date
Application number
PL439643A
Other languages
Polish (pl)
Other versions
PL244591B1 (en
Inventor
Maciej Malinowski
Dariusz Baran
Bartosz Godlewski
Stanisław Ostrowski
Original Assignee
Politechnika Warszawska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Warszawska filed Critical Politechnika Warszawska
Priority to PL439643A priority Critical patent/PL244591B1/en
Publication of PL439643A1 publication Critical patent/PL439643A1/en
Publication of PL244591B1 publication Critical patent/PL244591B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/22—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains four or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/16—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Przedmiotem zgłoszenia jest hybryda porfirynowo-cukrowa o wzorze ogólnym I zawierająca ugrupowanie porfirynowe i 2-etynyloglikalowe. Przedmiotem zgłoszenia jest również sposób syntezy hybrydy porfirynowo-cukrowej o wzorze ogólnym I obejmujący a) reakcję pochodnej 2-etynyloglikalowej z porfiryną w mieszaninie rozpuszczalnika organicznego i trietyloaminy, w obecności źródła jonów fluorkowych i katalizatora palladowego oraz ligandu fosfinowego z otrzymaniem związku o wzorze ogólnym II; b) reakcję związku o wzorze ogólnym II otrzymanego w etapie a) z węglanem metalu prowadzoną w mieszaninie rozpuszczalników z otrzymaniem hybrydy porfirynowo-cukrowej o wzorze ogólnym I.The subject of the application is a porphyrin-sugar hybrid of the general formula I comprising a porphyrin and a 2-ethynylglycal moiety. The application also relates to a method of synthesizing a porphyrin-sugar hybrid of general formula I comprising a) reacting a 2-ethynylglycal derivative with a porphyrin in a mixture of an organic solvent and triethylamine in the presence of a fluoride ion source and a palladium catalyst and a phosphine ligand to obtain a compound of general formula II; b) reacting the compound of general formula II obtained in step a) with a metal carbonate carried out in a mixture of solvents to obtain a porphyrin-sugar hybrid of general formula I.

PL439643A 2021-11-25 2021-11-25 Porphyrin-sugar hybrids and method of their synthesis PL244591B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL439643A PL244591B1 (en) 2021-11-25 2021-11-25 Porphyrin-sugar hybrids and method of their synthesis

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL439643A PL244591B1 (en) 2021-11-25 2021-11-25 Porphyrin-sugar hybrids and method of their synthesis

Publications (2)

Publication Number Publication Date
PL439643A1 true PL439643A1 (en) 2023-05-29
PL244591B1 PL244591B1 (en) 2024-02-12

Family

ID=86548326

Family Applications (1)

Application Number Title Priority Date Filing Date
PL439643A PL244591B1 (en) 2021-11-25 2021-11-25 Porphyrin-sugar hybrids and method of their synthesis

Country Status (1)

Country Link
PL (1) PL244591B1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL451782A1 (en) * 2025-04-11 2025-12-08 Politechnika Warszawska Trans-A2B2 glycoporphyrins and their method of preparation

Also Published As

Publication number Publication date
PL244591B1 (en) 2024-02-12

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