PL422165A1 - Nanostructural polymer composite material with polymeric fleece backing with strengthening phase in the form of composite ceramic nano-wires and method for producing it - Google Patents
Nanostructural polymer composite material with polymeric fleece backing with strengthening phase in the form of composite ceramic nano-wires and method for producing itInfo
- Publication number
- PL422165A1 PL422165A1 PL422165A PL42216517A PL422165A1 PL 422165 A1 PL422165 A1 PL 422165A1 PL 422165 A PL422165 A PL 422165A PL 42216517 A PL42216517 A PL 42216517A PL 422165 A1 PL422165 A1 PL 422165A1
- Authority
- PL
- Poland
- Prior art keywords
- polymer
- composite material
- bi2o3
- tio2
- sio2
- Prior art date
Links
Landscapes
- Nonwoven Fabrics (AREA)
- Inorganic Fibers (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
Przedmiotem zgłoszenia jest nanostrukturalny materiał kompozytowy o osnowie polimerowej z fazą wzmacniającą, którą stanowią nanodruty ceramiczne; TiO2, SiO2, Bi2O3 charakteryzuje się tym, że fazę wzmacniającą stanowią ceramiczne nanodrutu kompozytowe takie jak TiO2 i/lub SiO2 i/lub Bi2O3 o stężeniu masowym w zakresie od 2% do 65%, średnicy 10 do 600 nm i długości do 5 µm w stosunku do osnowy, którą stanowi polimer PVA lub PMMA lub PAN lub PVP. Zgłoszenie obejmuje też sposób wytwarzania materiału kompozytowego o osnowie polimerowej z fazą wzmacniającą, który polega na tym, że do rozpuszczalnika w postaci n,n-dimetyloformamidu (DMF) lub wody (H2O) lub etanolu (EtOH) wprowadza się nanodruty kompozytowe takie jak: TiO2 i/lub SiO2 i/lub Bi2O3 o stężeniu masowym w stosunku do polimeru w zakresie od 2% do 65%, następnie mieszaninę poddaję się procesowi sonikacji w czasie od 0,5 do 3 h, stale uzupełniając odparowujący rozpuszczalnik, do tak przygotowanej mieszaniny dodaje się polimer poli(alkohol winylowy) (PVA) lub poli(metakrylan metylu) (PMMA) poliakrylonitryl (PAN) lub poli(winylopirolidon) (PVP) i poddaje się mechanicznemu mieszaniu mieszadłem mechanicznym w czasie od 2 do 72 godzin, po czym poddaje się procesowi elektroprzędzenia w polu elektrostatycznym przy zastosowaniu odległości pomiędzy elektrodami w zakresie 7,5 - 25 cm, różnicy potencjałów pomiędzy elektrodami 5 - 30 kV oraz szybkości podawania roztworu równej 0,5 - 5 ml/h, a następnie suszy w temperaturze pokojowej od 2 do 48 h.The subject of the application is a nanostructured composite material with a polymer matrix with a reinforcing phase, which are ceramic nanowires; TiO2, SiO2, Bi2O3 is characterized in that the reinforcing phase is ceramic composite nanowires such as TiO2 and / or SiO2 and / or Bi2O3 with a mass concentration in the range of 2% to 65%, diameter 10 to 600 nm and length up to 5 µm in relative to the matrix, which is a PVA or PMMA or PAN or PVP polymer. The application also includes a method of producing a polymer matrix composite material with a reinforcing phase, which consists in introducing composite nanowires such as TiO2 into the solvent in the form of n, n-dimethylformamide (DMF) or water (H2O) or ethanol (EtOH) and / or SiO2 and / or Bi2O3 with a mass concentration in relation to the polymer in the range of 2% to 65%, then the mixture is subjected to sonication process for 0.5 to 3 hours, constantly supplementing the evaporating solvent, to this mixture is added poly (vinyl alcohol) (PVA) or poly (methyl methacrylate) (PMMA) polyacrylonitrile (PAN) or poly (vinylpyrrolidone) (PVP) polymer and mechanically mixing with a mechanical stirrer for 2 to 72 hours, and then subjected to electrospinning process in the electrostatic field using the distance between the electrodes in the range 7.5 - 25 cm, the potential difference between the electrodes 5 - 30 kV and the speed of giving a solution equal to 0.5 - 5 ml / h, and then dried at room temperature from 2 to 48 h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL422165A PL233451B1 (en) | 2017-07-10 | 2017-07-10 | Nanostructural polymer composite material with polymeric fleece backing with strengthening phase in the form of composite ceramic nano-wires and method for producing it |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL422165A PL233451B1 (en) | 2017-07-10 | 2017-07-10 | Nanostructural polymer composite material with polymeric fleece backing with strengthening phase in the form of composite ceramic nano-wires and method for producing it |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL422165A1 true PL422165A1 (en) | 2019-01-14 |
| PL233451B1 PL233451B1 (en) | 2019-10-31 |
Family
ID=64958894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL422165A PL233451B1 (en) | 2017-07-10 | 2017-07-10 | Nanostructural polymer composite material with polymeric fleece backing with strengthening phase in the form of composite ceramic nano-wires and method for producing it |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL233451B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111468176A (en) * | 2020-05-15 | 2020-07-31 | 山东师范大学 | Composite catalyst and preparation method and application thereof |
-
2017
- 2017-07-10 PL PL422165A patent/PL233451B1/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111468176A (en) * | 2020-05-15 | 2020-07-31 | 山东师范大学 | Composite catalyst and preparation method and application thereof |
| CN111468176B (en) * | 2020-05-15 | 2022-04-15 | 山东师范大学 | Composite catalyst and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| PL233451B1 (en) | 2019-10-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Zhou et al. | Silkworm-based silk fibers by electrospinning | |
| Zhao et al. | Human skin-like, robust waterproof, and highly breathable fibrous membranes with short perfluorobutyl chains for eco-friendly protective textiles | |
| Porter et al. | Biomimetic materials by freeze casting | |
| Chapartegui et al. | Analysis of the conditions to manufacture a MWCNT buckypaper/benzoxazine nanocomposite | |
| JP2016000817A5 (en) | Composition based on PTFE, mixed powder, and molding material | |
| WO2009002858A3 (en) | Stimuli responsive nanofibers | |
| Hancock et al. | Anisotropic material synthesis by capillary flow in a fluid stripe | |
| Huang et al. | Durable superhydrophobic materials enabled by abrasion-triggered roughness regeneration | |
| Kucharska et al. | Fabrication and characterization of chitosan microspheres agglomerated scaffolds for bone tissue engineering | |
| RU2007110505A (en) | PROPPHANT AND METHOD OF ITS MANUFACTURE | |
| PL422165A1 (en) | Nanostructural polymer composite material with polymeric fleece backing with strengthening phase in the form of composite ceramic nano-wires and method for producing it | |
| FR2960878B1 (en) | NOVEL AQUEOUS STABLE DISPERSIONS OF HIGH-PERFORMANCE THERMOPLASTIC POLYMER NANOPARTICLES AND THEIR USE AS FILM AGENTS | |
| CN107675281B (en) | Preparation method of PVP/PAN nano composite fiber | |
| Gao et al. | Mechanical behavior of a terpolymer-based pH-and temperature-responsive hydrogel | |
| Xu et al. | Electrospun nanoscale bent fibrous membrane with controllable porous structure and hydrophilic modification for high-efficiency oil-water separation, particle/bacterial filtration and antibacterial applications | |
| Zhao et al. | A poly (allylamine hydrochloride)/poly (styrene sulfonate) microcapsule-coated cotton fabric for stimulus-responsive textiles | |
| TW201938857A (en) | Natural polymeric nanofiber and manufacturing method thereof | |
| Kurimoto et al. | Fibrous materials | |
| CN109382002A (en) | A kind of intelligent switch film and preparation method thereof based on nanogel | |
| JP2006249622A (en) | Photo-responsive stretchable fiber | |
| Nasir et al. | Preliminary study of trong clay-HA bone scaffold fabrication using solvent casting/particulate leaching method and indirect 3D-printing technique | |
| JP6704915B2 (en) | Method of making a molded functional cellulosic article for release of an active ingredient of interest | |
| PL416931A1 (en) | Nanostructural fibrous polymer matrix composite material with reinforcing phase and method for producing it | |
| CN110016108A (en) | A kind of antibacterial polymer lotion and antibacterial bacteriological protection stick cellulose-based fiber and fabric | |
| PL410580A1 (en) | Nanostructural polymer composite material with reinforcing phase and method for producing it |