PL421951A1 - New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, applications of complex compounds of europium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials - Google Patents
New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, applications of complex compounds of europium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materialsInfo
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- PL421951A1 PL421951A1 PL421951A PL42195117A PL421951A1 PL 421951 A1 PL421951 A1 PL 421951A1 PL 421951 A PL421951 A PL 421951A PL 42195117 A PL42195117 A PL 42195117A PL 421951 A1 PL421951 A1 PL 421951A1
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- new
- europium
- iii
- complex compounds
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Abstract
Zgłoszenie dotyczy nowych systemów fotoinicjujących do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej tiol-en i hybrydowej nowych związków kompleksowych europu(III), sposobów ich wytwarzania zastosowań związków kompleksowych europu(III), nowych luminescencyjnych sond molekularnych do monitorowania procesów polimeryzacji oraz nowych luminescencyjnych sensorów molekularnych do badań materiałów powłokowych. Nowe systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej, zawierające sole oniowe i ko-inicjator, charakteryzują się tym, że zawierają co najmniej jedną sól oniową wybraną spośród następujących: sole jodoniowe wybrane spośród heksafluorofosforanu difenylojodoniowego, heksafluoroantymonianu difenylojodoniowego, heksafluorofosforanu 4-metylo-4'-izopropylodifenylojodoniowego, heksafluorofosforanu 4,4'-dimetylodifenylojodoniowego, tetrakis pentafluorofenyloboranu 4-metylo-4'-izopropylodifenylojodoniowego; sole sulfoniowe wybrane spośród heksafluorofosforanu trifenylo-sulfoniowego i heksafluoroantymonianu trifenylosulfoniowego; oraz co najmniej jeden ko-inicjator wybrany z grupy związków kompleksowych europu(III) o wzorze ogólnym (1), w którym R1 oznacza podstawnik wybrany spośród następujących: grupa fenylowa, grupa 4-fluorofenylowa, grupa 4-metylofenylowa, grupa 4-cyjanofenylowa, grupa 2-tienylowa, grupa 2-furylowa; R2 oznacza podstawnik wybrany spośród następujących: grupa butylowa, grupa oktylowa, grupa fenylowa.The application concerns new photoinitiation systems for photoinitiated cationic, radical thiol-hybrid and hybrid polymerization processes of new europium (III) complex compounds, methods of their production, applications of europium (III) complex compounds, new luminescent molecular probes for monitoring polymerization processes and new luminescent molecular sensors for coating materials testing. New photoinitiation systems for photoinitiated cationic, radical, thiol-hybrid and hybrid polymerization processes, containing onium salts and a co-initiator, are characterized by containing at least one onium salt selected from the following: iodonium salts selected from diphenyl iodonium hexafluorophosphate, dipheliodonium hexafluoroanthonate 4-methyl-4'-isopropyl diphenyl iodonium hexafluorophosphate, 4,4'-dimethyldiphenyl iodonium hexafluorophosphate, 4-methyl-4'-isopropyl diphenyl iodonium pentafluorophenyl borate tetrakis; sulfonium salts selected from triphenyl sulfonium hexafluorophosphate and triphenyl sulfonium hexafluoroantimonate; and at least one co-initiator selected from the group of europium (III) complex compounds of general formula (1), wherein R1 is a substituent selected from the following: phenyl group, 4-fluorophenyl group, 4-methylphenyl group, 4-cyanophenyl group, 2-thienyl group, 2-furyl group; R2 is a substituent selected from the following: butyl group, octyl group, phenyl group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL421951A PL244891B1 (en) | 2017-06-20 | 2017-06-20 | New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, applications of complex compounds of europium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL421951A PL244891B1 (en) | 2017-06-20 | 2017-06-20 | New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, applications of complex compounds of europium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL421951A1 true PL421951A1 (en) | 2019-01-02 |
| PL244891B1 PL244891B1 (en) | 2024-03-25 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL421951A PL244891B1 (en) | 2017-06-20 | 2017-06-20 | New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, applications of complex compounds of europium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials |
Country Status (1)
| Country | Link |
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| PL (1) | PL244891B1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004067914A (en) * | 2002-08-08 | 2004-03-04 | Nippon Kayaku Co Ltd | Ink composition |
| EP1492173A2 (en) * | 2003-06-24 | 2004-12-29 | Kabushiki Kaisha Toshiba | Light emitting device containing a rare earth complex as luminescent medium |
| CN102898971A (en) * | 2012-10-29 | 2013-01-30 | 常州大学 | Rare-earth light conversion agent and preparation method and application thereof |
| WO2015113114A1 (en) * | 2014-01-31 | 2015-08-06 | Newsouth Innovations Pty Limited | Process for preparing a polymer |
| WO2015157149A1 (en) * | 2014-04-07 | 2015-10-15 | Dow Global Technologies Llc | Regulation of a controlled radical polymerization of acrylates by light |
-
2017
- 2017-06-20 PL PL421951A patent/PL244891B1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004067914A (en) * | 2002-08-08 | 2004-03-04 | Nippon Kayaku Co Ltd | Ink composition |
| EP1492173A2 (en) * | 2003-06-24 | 2004-12-29 | Kabushiki Kaisha Toshiba | Light emitting device containing a rare earth complex as luminescent medium |
| CN102898971A (en) * | 2012-10-29 | 2013-01-30 | 常州大学 | Rare-earth light conversion agent and preparation method and application thereof |
| WO2015113114A1 (en) * | 2014-01-31 | 2015-08-06 | Newsouth Innovations Pty Limited | Process for preparing a polymer |
| WO2015157149A1 (en) * | 2014-04-07 | 2015-10-15 | Dow Global Technologies Llc | Regulation of a controlled radical polymerization of acrylates by light |
Non-Patent Citations (3)
| Title |
|---|
| M. A. CAREY, C. V. BANKS, "SYNERG1C SOLVENT EXTRACTION OF EUROPIUM(ILL) INTO MIXTURES OF 2-THENOYL-TRIFLUOROACETONE WITH VARIOUS ALKYLPHOSPHINE OXIDES" J. INORG NUCL. CHEM. 1969. VOL. 31, 1969 * |
| M. A. CAREY, C. V. BANKS, "SYNERG1C SOLVENT EXTRACTION OF EUROPIUM(ILL) INTO MIXTURES OF 2-THENOYL-TRIFLUOROACETONE WITH VARIOUS ALKYLPHOSPHINE OXIDES" J. INORG NUCL. CHEM. 1969. VOL. 31, ABSTRACT, 1969 * |
| OHASHI KOUSABURO ET AL., "EMISSLON PROPERTIES OF A TERNARY COMPLEXES OF EUROPIUM (III)-BETA-DIKETONE-TRIOCTYLPHOSPHINE OXIDE. ANALYTICAL SCIENCES" ANAL.SCI. 1990, ABSTRACT, 1990 * |
Also Published As
| Publication number | Publication date |
|---|---|
| PL244891B1 (en) | 2024-03-25 |
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