PL411767A1 - Method for obtaining fluorocarbofunctional silsesquioxanes - Google Patents

Method for obtaining fluorocarbofunctional silsesquioxanes

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Publication number
PL411767A1
PL411767A1 PL411767A PL41176715A PL411767A1 PL 411767 A1 PL411767 A1 PL 411767A1 PL 411767 A PL411767 A PL 411767A PL 41176715 A PL41176715 A PL 41176715A PL 411767 A1 PL411767 A1 PL 411767A1
Authority
PL
Poland
Prior art keywords
obtaining
fluorocarbofunctional
hcf2
silsesquioxanes
hydrosilsesquioxanes
Prior art date
Application number
PL411767A
Other languages
Polish (pl)
Other versions
PL225992B1 (en
Inventor
Hieronim Maciejewski
Joanna Karasiewicz
Michał Dutkiewicz
Original Assignee
Uniwersytet Im. Adama Mickiewicza W Poznaniu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uniwersytet Im. Adama Mickiewicza W Poznaniu filed Critical Uniwersytet Im. Adama Mickiewicza W Poznaniu
Priority to PL411767A priority Critical patent/PL225992B1/en
Publication of PL411767A1 publication Critical patent/PL411767A1/en
Publication of PL225992B1 publication Critical patent/PL225992B1/en

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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicon Polymers (AREA)

Abstract

Przedmiotem wynalazku jest sposób otrzymywania fluorokarbofunkcyjnych silseskwioksanów klatkowych o ogólnym wzorze 1, w którym podstawniki R są takie same i oznaczają grupę C6F5O-, lub C6F5OSi(CH3)2O-, lub HCF2(CF2)n(CH2)mOSi(CH 3)2O-, lub HCF2(CF2)n(CH2)mO-, w których n = 1 - 12, a m = 1 - 4, polegający na reakcji dehydrogenującego sililowania hydroksylowych pochodnych organicznych, zawierających ugrupowania fluoroalkilowe lub arylowe wodorosilseskwioksanami w obecności heterogenicznego katalizatora palladowego, naniesionego na powierzchnię kopolimeru styrenu i diwinylobenzenu (SDB).The subject of the invention is a method for obtaining fluorocarbofunctional cage silsesquioxanes of the general formula 1, in which the R substituents are the same and represent the group C6F5O-, or C6F5OSi(CH3)2O-, or HCF2(CF2)n(CH2)mOSi(CH 3)2O- , or HCF2(CF2)n(CH2)mO-, in which n = 1 - 12 and m = 1 - 4, consisting in the reaction of dehydrogenating silylation of hydroxyl organic derivatives containing fluoroalkyl or aryl groups with hydrosilsesquioxanes in the presence of a heterogeneous palladium catalyst, applied to styrene-divinylbenzene (SDB) copolymer surface.

PL411767A 2015-03-30 2015-03-30 Method for obtaining fluorocarbofunctional silsesquioxanes PL225992B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL411767A PL225992B1 (en) 2015-03-30 2015-03-30 Method for obtaining fluorocarbofunctional silsesquioxanes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL411767A PL225992B1 (en) 2015-03-30 2015-03-30 Method for obtaining fluorocarbofunctional silsesquioxanes

Publications (2)

Publication Number Publication Date
PL411767A1 true PL411767A1 (en) 2015-11-09
PL225992B1 PL225992B1 (en) 2017-06-30

Family

ID=54364872

Family Applications (1)

Application Number Title Priority Date Filing Date
PL411767A PL225992B1 (en) 2015-03-30 2015-03-30 Method for obtaining fluorocarbofunctional silsesquioxanes

Country Status (1)

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PL (1) PL225992B1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021085482A1 (en) * 2019-10-31 2021-05-06 国立研究開発法人産業技術総合研究所 Compound and method for producing same

Also Published As

Publication number Publication date
PL225992B1 (en) 2017-06-30

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