PL409042A1 - Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines i N-phosphonomethyl glycine and method to produce them - Google Patents
Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines i N-phosphonomethyl glycine and method to produce themInfo
- Publication number
- PL409042A1 PL409042A1 PL409042A PL40904214A PL409042A1 PL 409042 A1 PL409042 A1 PL 409042A1 PL 409042 A PL409042 A PL 409042A PL 40904214 A PL40904214 A PL 40904214A PL 409042 A1 PL409042 A1 PL 409042A1
- Authority
- PL
- Poland
- Prior art keywords
- phosphonomethylglycine
- fragment
- fragments
- polyampholyte
- diaminopropane
- Prior art date
Links
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract 6
- HZCDANOFLILNSA-UHFFFAOYSA-N Dimethyl hydrogen phosphite Chemical class COP(=O)OC HZCDANOFLILNSA-UHFFFAOYSA-N 0.000 title 1
- 239000012634 fragment Substances 0.000 abstract 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- 229920001281 polyalkylene Polymers 0.000 abstract 5
- 229920000768 polyamine Polymers 0.000 abstract 5
- GOJNABIZVJCYFL-UHFFFAOYSA-N dimethylphosphinic acid Chemical compound CP(C)(O)=O GOJNABIZVJCYFL-UHFFFAOYSA-N 0.000 abstract 4
- OTBHHUPVCYLGQO-UHFFFAOYSA-N 1,7-diamino-4-aza-heptane Natural products NCCCNCCCN OTBHHUPVCYLGQO-UHFFFAOYSA-N 0.000 abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 abstract 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 abstract 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 abstract 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 abstract 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 abstract 1
- RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 abstract 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- 239000005700 Putrescine Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- MRNZSTMRDWRNNR-UHFFFAOYSA-N bis(hexamethylene)triamine Chemical compound NCCCCCCNCCCCCCN MRNZSTMRDWRNNR-UHFFFAOYSA-N 0.000 abstract 1
- SSJXIUAHEKJCMH-UHFFFAOYSA-N cyclohexane-1,2-diamine Chemical compound NC1CCCCC1N SSJXIUAHEKJCMH-UHFFFAOYSA-N 0.000 abstract 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 1
- DTSDBGVDESRKKD-UHFFFAOYSA-N n'-(2-aminoethyl)propane-1,3-diamine Chemical compound NCCCNCCN DTSDBGVDESRKKD-UHFFFAOYSA-N 0.000 abstract 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Abstract
Wynalazek dotyczy poliamfolitów pochodnych kwasu dimetylofosfinowego, polialkilenopoliamin i N-fosfonometyloglicyny o wzorze ogólnym I, w którym A oznacza fragment struktury kwasu dimetylofosfinowego, x oznacza liczbę takich fragmentów w poliamfolicie, natomiast B oznacza fragment struktury polialkilenopoliaminy, w którym n i p mogą być takie same lub różne i oznaczają liczby całkowite od 2 do 12, natomiast q jest liczbą struktur aminopolialkenowych i wynosi od 2 do 6, y oznacza liczbę fragmentów poliaminopolialkenowych w polimerze, natomiast C oznacza fragment struktury N-fosfonometyloglicyny, a z oznacza liczbę takich fragmentów w poliamfolicie, przy czym wolne miejsca fragmentu A mogą się wiązać tylko z wolnymi miejscami we fragmencie B i C. Wynalazek ujawnia również sposób wytwarzania poliamfolitów pochodnych kwasu dimetylofosfinowego, polialkilenopoliamin i N-fosfonometyloglicyny, o wzorze ogólnym I, który polega na tym, że w pierwszym etapie jedną część molową kwasu fosfinowego poddaje się reakcji z co najmniej jedną częścią molową formaldehydu i co najmniej dwiema częściami molowymi grup -NH-, na które składa się suma grup -NH- pochodzących od polialkiłenopoliaminy wybranej z grupy zawierającej: 1,2-diaminoetan, 1,3-diaminopropan, 1,4-diaminobutan, 1,5-diaminopentan, 1,6-diaminoheksan, 2-metylo-1,5-diaminopentan, 1,2-diaminocykloheksan, bis(heksametyleno)triaminę, dietylenotriaminę, N-(3 -aminopropylo) -1,3 -diaminopropan, N-(2 -aminoetylo) -1,3 -diaminopropan, N,N' -bis(3-aminopropylo)etylenodiaminę, trietylenotetraminę, tetraetylenopentaminę i pentaetylenoheksaminę, i grup -NH- pochodzących od N-fosfonometyloglicyny, a reakcję prowadzi się w temperaturze 273-373K, w wodzie, aż do przereagowania substratów i utworzenia się poliamfolitu zawierającego fragmenty strukturalne kwasu dimetylofosfinowego, polialkilenopoliaminy i N-fosfonometyloglicyny, który w trzecim etapie poddaje się dosieciowaniu co najmniej 0,5 części molowej formaldehydu.The invention relates to polyampholytes derived from dimethylphosphinic acid, polyalkylene polyamines and N-phosphonomethylglycine of the general formula I, in which A is a fragment of the structure of dimethylphosphinic acid, x is the number of such fragments in the polyampholyte, and B is a fragment of the polyalkylene polyamine structure, in which n and p may be the same or different and denote integers from 2 to 12, while q is the number of aminopolyalkene structures and ranges from 2 to 6, y denotes the number of polyaminopolyalkene fragments in the polymer, while C denotes a fragment of the N-phosphonomethylglycine structure, and z denotes the number of such fragments in polyampholyte, where the free the sites of fragment A can only bind to free sites in fragment B and C. The invention also discloses a method for preparing polyampholytes derivatives of dimethylphosphinic acid, polyalkylene polyamines and N-phosphonomethylglycine, with the general formula I, which consists in the fact that in the first step one mole part of the acid phosphine is reacted with at least one mole part of formaldehyde and at least two mole parts of -NH- groups, which consist of the sum of -NH- groups derived from a polyalkylene polyamine selected from the group containing: 1,2-diaminoethane, 1,3-diaminopropane , 1,4-diaminobutane, 1,5-diaminopentane, 1,6-diaminohexane, 2-methyl-1,5-diaminopentane, 1,2-diaminocyclohexane, bis(hexamethylene)triamine, diethylenetriamine, N-(3-aminopropyl) -1,3-diaminopropane, N-(2-aminoethyl)-1,3-diaminopropane, N,N'-bis(3-aminopropyl)ethylenediamine, triethylenetetramine, tetraethylenepentamine and pentaethylenehexamine, and -NH- groups derived from N-phosphonomethylglycine , and the reaction is carried out at a temperature of 273-373K in water until the reactants are reacted and a polyampholyte is formed containing structural fragments of dimethylphosphinic acid, polyalkylene polyamine and N-phosphonomethylglycine, which is cross-linked with at least 0.5 mole of formaldehyde in the third stage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL409042A PL223386B1 (en) | 2014-07-31 | 2014-07-31 | Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines i N-phosphonomethyl glycine and method to produce them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL409042A PL223386B1 (en) | 2014-07-31 | 2014-07-31 | Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines i N-phosphonomethyl glycine and method to produce them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL409042A1 true PL409042A1 (en) | 2015-03-02 |
| PL223386B1 PL223386B1 (en) | 2016-10-31 |
Family
ID=52574573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL409042A PL223386B1 (en) | 2014-07-31 | 2014-07-31 | Polyampholites derivatives of dimethylphosphonic acid, polyalkyenepolyamines i N-phosphonomethyl glycine and method to produce them |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL223386B1 (en) |
-
2014
- 2014-07-31 PL PL409042A patent/PL223386B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL223386B1 (en) | 2016-10-31 |
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