PL408588A1 - New metal ligand with the formula [Mn(L)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]X<sub>2</sub> and method for obtaining it and the MOF network, built using the new metal ligand and method for obtaining it - Google Patents
New metal ligand with the formula [Mn(L)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]X<sub>2</sub> and method for obtaining it and the MOF network, built using the new metal ligand and method for obtaining itInfo
- Publication number
- PL408588A1 PL408588A1 PL408588A PL40858814A PL408588A1 PL 408588 A1 PL408588 A1 PL 408588A1 PL 408588 A PL408588 A PL 408588A PL 40858814 A PL40858814 A PL 40858814A PL 408588 A1 PL408588 A1 PL 408588A1
- Authority
- PL
- Poland
- Prior art keywords
- sub
- obtaining
- formula
- new metal
- metal ligand
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000003446 ligand Substances 0.000 title 2
- 239000002184 metal Substances 0.000 title 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 5
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 abstract 3
- FKNQCJSGGFJEIZ-UHFFFAOYSA-N 4-methylpyridine Chemical compound CC1=CC=NC=C1 FKNQCJSGGFJEIZ-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000005580 one pot reaction Methods 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- -1 4-picolinium aldehyde Chemical class 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000006482 condensation reaction Methods 0.000 abstract 1
- 150000007857 hydrazones Chemical class 0.000 abstract 1
- ABMDIECEEGFXNC-UHFFFAOYSA-N n-ethylpropanamide Chemical compound CCNC(=O)CC ABMDIECEEGFXNC-UHFFFAOYSA-N 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 238000007039 two-step reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Metaloligand o wzorze [Mn(L)2(H2O)4]X2, zawiera kation Mn2+, obojętną cząsteczkę hydrazonu (L) pochodzącego od hydrazydu kwasu izonikotynowego i aldehydu 4-pikolinowego wzorze 1 oraz anion (X) kompensujący dodatni ładunek kationu Mn2+. Sposób otrzymywania nowego metaloliganda o wzorze [Mn(L)2(H2O)4]X2, przebiega w reakcji jednoetapowej lub dwuetapowej. W reakcji jednoetapowej hydrazyd kwasu izonikotynowego i aldehyd 4-pikolinowy poddaje się kondensacji w rozpuszczalniku, który został wybrany spośród alkoholi C1-8, roztworów wodnych alkoholi C1-8, mieszanin wody, alkoholu C1-8 i N,N'-dimetyloformamidu (DMF) lub mieszanin wody, alkoholu C1-8 i N,N'-dietyloformamidu (DEF). W reakcji dwuetapowej, w pierwszym etapie prowadzi się reakcję kondensacji hydrazydu kwasu izonikotynowego i aldehydu 4-pikolinowego na drodze mechanochemicznej, bez udziału lub z małym udziałem rozpuszczalnika. Sposób otrzymywania sieci MOF polega na tym, że metaloligand o wzorze [Mn(L)2(H2O)4]X2, poddaje się reakcji z Zn(NO3)2 x 4H2O, kwasem tereftalowym i DMF.The metalloligand of formula [Mn (L) 2 (H2O) 4] X2 contains a Mn2 + cation, a neutral hydrazone (L) molecule derived from isonicotinic acid hydrazide and 4-picolinium aldehyde formula 1, and an anion (X) compensating for the positive charge of the Mn2 + cation. The method of obtaining a new metalloligand of formula [Mn (L) 2 (H2O) 4] X2 takes place in a one-step or two-step reaction. In a one-step reaction, isonicotinic acid hydrazide and 4-picoline aldehyde are condensed in a solvent that is selected from C1-8 alcohols, aqueous solutions of C1-8 alcohols, mixtures of water, C1-8 alcohol and N, N'-dimethylformamide (DMF) or mixtures of water, C1-8 alcohol and N, N'-diethylformamide (DEF). In the two-stage reaction, in the first stage the condensation reaction of isonicotinic acid hydrazide and 4-picolinic aldehyde is carried out mechanochemically, without or with little solvent. The method of obtaining the MOF network is that the metalloligand of formula [Mn (L) 2 (H2O) 4] X2 is reacted with Zn (NO3) 2 x 4H2O, terephthalic acid and DMF.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL408588A PL408588A1 (en) | 2014-06-17 | 2014-06-17 | New metal ligand with the formula [Mn(L)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]X<sub>2</sub> and method for obtaining it and the MOF network, built using the new metal ligand and method for obtaining it |
PCT/PL2015/050024 WO2015194981A1 (en) | 2014-06-17 | 2015-06-17 | New metalloligand, a metal-organic framework (mof) comprising thereof and a method for its preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL408588A PL408588A1 (en) | 2014-06-17 | 2014-06-17 | New metal ligand with the formula [Mn(L)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]X<sub>2</sub> and method for obtaining it and the MOF network, built using the new metal ligand and method for obtaining it |
Publications (1)
Publication Number | Publication Date |
---|---|
PL408588A1 true PL408588A1 (en) | 2015-12-21 |
Family
ID=53761468
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL408588A PL408588A1 (en) | 2014-06-17 | 2014-06-17 | New metal ligand with the formula [Mn(L)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]X<sub>2</sub> and method for obtaining it and the MOF network, built using the new metal ligand and method for obtaining it |
Country Status (2)
Country | Link |
---|---|
PL (1) | PL408588A1 (en) |
WO (1) | WO2015194981A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107011525B (en) * | 2017-03-08 | 2020-03-31 | 宁波大学 | Zinc metal organic framework material and preparation method and application thereof |
CN109731611A (en) * | 2019-01-17 | 2019-05-10 | 中山大学 | A kind of composite material and preparation method and application based on Photoactive metal-organic coordination Molecular Ring and carbonitride |
CN113461965B (en) * | 2021-08-10 | 2022-07-08 | 蚌埠医学院 | Novel metal organic framework compound and preparation method and application thereof |
CN114196032B (en) * | 2021-10-22 | 2023-09-15 | 广东工业大学 | Tetrathiol functionalized UiO-66 type metal organic framework material and preparation method and application thereof |
-
2014
- 2014-06-17 PL PL408588A patent/PL408588A1/en unknown
-
2015
- 2015-06-17 WO PCT/PL2015/050024 patent/WO2015194981A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2015194981A1 (en) | 2015-12-23 |
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