PL402384A1 - New bifunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides - Google Patents
New bifunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicidesInfo
- Publication number
- PL402384A1 PL402384A1 PL402384A PL40238413A PL402384A1 PL 402384 A1 PL402384 A1 PL 402384A1 PL 402384 A PL402384 A PL 402384A PL 40238413 A PL40238413 A PL 40238413A PL 402384 A1 PL402384 A1 PL 402384A1
- Authority
- PL
- Poland
- Prior art keywords
- diallyldimethylammonium
- ionic liquids
- herbicides
- preparation
- herbicidal
- Prior art date
Links
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 title abstract 5
- 230000002363 herbicidal effect Effects 0.000 title abstract 5
- 230000001588 bifunctional effect Effects 0.000 title abstract 4
- 239000002608 ionic liquid Substances 0.000 title abstract 4
- 239000004009 herbicide Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 150000001450 anions Chemical class 0.000 abstract 2
- SMYMJHWAQXWPDB-UHFFFAOYSA-M (2,4,5-trichlorophenoxy)acetate Chemical compound [O-]C(=O)COC1=CC(Cl)=C(Cl)C=C1Cl SMYMJHWAQXWPDB-UHFFFAOYSA-M 0.000 abstract 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-M (2,4-dichlorophenoxy)acetate Chemical compound [O-]C(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-M 0.000 abstract 1
- WNTGYJSOUMFZEP-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-UHFFFAOYSA-N 0.000 abstract 1
- YIVXMZJTEQBPQO-UHFFFAOYSA-M 4-(2,4-dichlorophenoxy)butanoate Chemical compound [O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl YIVXMZJTEQBPQO-UHFFFAOYSA-M 0.000 abstract 1
- LLWADFLAOKUBDR-UHFFFAOYSA-M 4-(4-chloro-2-methylphenoxy)butanoate Chemical compound CC1=CC(Cl)=CC=C1OCCCC([O-])=O LLWADFLAOKUBDR-UHFFFAOYSA-M 0.000 abstract 1
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem wynalazku są nowe dwufunkcyjne Poli(diallilodimetyloamoniowe herbicydowe ciecze jonowe), sposób ich otrzymywania oraz zastosowanie jako herbicydów do ochrony roślin. Nowe dwufunkcyjne poli(diallilodimetyloamoniowe herbicydowe ciecze jonowe) są to związki o wzorze ogólnym 1 gdzie A- oznacza anion herbicydowy. Sposób ich otrzymywania polega na tym, że poli(diallilodimetyloamoniowy wodorotlenek) rozpuszcza się w metanolu, a następnie poddaje się reakcji zobojętniania w stosunku molowym 1:1 roztworem o stężeniu co najmniej 1%, zawierającym mieszaninę kwasów w dowolnych stosunkach molowych będących źródłem anionów: (4-chloro-2-metylofenoksy)octanowego, lub (2,4-dichlorofenoksy)octanowego, lub (4-chloro-2-metylofenoksy)propionianowego, lub 4-(2,4-dichlorofenoksy)-butanianowego, lub (2,4,5-trichlorofenoksy)octanowego, lub 4-(4-chloro-2-metylofenoksy)butanianowego. Wynalazek obejmuje również zastosowanie dwufunkcyjnych poli(diallilodimetyloamoniowych herbicydowych cieczy jonowych), w postaci czystej, lub w postaci roztworów wodnych, lub alkoholowych, lub wodno-alkoholowych o stężeniu substancji czynnej od 0,1% do 50%, jako herbicydy do ochrony roślin.The subject of the invention are new bifunctional poly(diallyldimethylammonium herbicidal ionic liquids), a method of their preparation and use as herbicides for plant protection. The new bifunctional poly(diallyldimethylammonium herbicidal ionic liquids) are compounds of the general formula 1 where A- is a herbicidal anion. The method of their preparation consists in the fact that poly(diallyldimethylammonium hydroxide) is dissolved in methanol and then neutralized in a molar ratio of 1:1 with a solution with a concentration of at least 1%, containing a mixture of acids in any molar ratios that are a source of anions: ( 4-chloro-2-methylphenoxy)acetate or (2,4-dichlorophenoxy)acetate or (4-chloro-2-methylphenoxy)propanoate or 4-(2,4-dichlorophenoxy)butanoate or (2,4 ,5-trichlorophenoxy)acetate, or 4-(4-chloro-2-methylphenoxy)butanoate. The invention also includes the use of bifunctional poly(diallyldimethylammonium herbicidal ionic liquids), in pure form or in the form of aqueous or alcoholic or aqueous-alcoholic solutions with an active ingredient concentration of 0.1% to 50%, as herbicides for plant protection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL402384A PL224025B1 (en) | 2013-01-08 | 2013-01-08 | New bifunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL402384A PL224025B1 (en) | 2013-01-08 | 2013-01-08 | New bifunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL402384A1 true PL402384A1 (en) | 2014-07-21 |
| PL224025B1 PL224025B1 (en) | 2016-11-30 |
Family
ID=51179254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL402384A PL224025B1 (en) | 2013-01-08 | 2013-01-08 | New bifunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL224025B1 (en) |
-
2013
- 2013-01-08 PL PL402384A patent/PL224025B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL224025B1 (en) | 2016-11-30 |
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