PL3307B1 - The method of making the mass for carving models from gypsum debris and furnace waste. - Google Patents
The method of making the mass for carving models from gypsum debris and furnace waste. Download PDFInfo
- Publication number
- PL3307B1 PL3307B1 PL3307A PL330721A PL3307B1 PL 3307 B1 PL3307 B1 PL 3307B1 PL 3307 A PL3307 A PL 3307A PL 330721 A PL330721 A PL 330721A PL 3307 B1 PL3307 B1 PL 3307B1
- Authority
- PL
- Poland
- Prior art keywords
- lime
- gypsum
- models
- debris
- carbonic acid
- Prior art date
Links
- 239000010440 gypsum Substances 0.000 title claims description 8
- 229910052602 gypsum Inorganic materials 0.000 title claims description 8
- 239000002699 waste material Substances 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 15
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 15
- 239000004571 lime Substances 0.000 claims description 15
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 8
- 238000002485 combustion reaction Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000010304 firing Methods 0.000 claims 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 150000004760 silicates Chemical class 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000011398 Portland cement Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- -1 silicic acid silicates Chemical class 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical class [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 241000405217 Viola <butterfly> Species 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Description
Podstawa sposobu wyrobu maisy do mo¬ deli rzezbiarskich, bedacego przedlmibtem wynalazku nilniejszeglo, jest to, ze istnieja¬ ce w gruzie gjjpsowym krzemiany glinu i kwlasu krzemowego najdaja sile wybornie do przygotowlaniia zajprawy bez dodawania srodka wijacego. Podlug wynalazku ni¬ niejszego przediewszystkiem przed lub pod¬ czas spalania w zwyklym piecu nagroma¬ dza sile z gruzem gilpsowym mielone wiaprio, zawierajace kwas weglowy talk, ze przy dlznalabiii ciepla spalania' sie gruzu, wy¬ dziela si^ kwiais weglowy z zawierajacego go wapna i powlsitaje wialpno zrace, Wów- ctzais gasi sile powstaljace z tej mieszaniny zuzle zapomoca wody lub pary wodnej, przez co wapno zrace przechodzi w wo- dziian wapnia. Cieplo pozostiale w zuzlu wraz z ciepfem powstalem przy przemianie wapna zracego w wodzian wapnia dziala rugujaoo na krzemiany glinu i kwalsu knze- mowego i powioduje to, ze wodzilam wiapnia i krzemiany wstepuja w zwiajzek chemicz¬ ny, co wlasnie jest niadzwyozialj pozadane przy tworzeniu sile zaprawy.Podi wzgledem ekonomiczinosci1 sposób niniejiszy posiiadto wliiele istotnych korzysci, a mianiowifcie: spalanie wapna w (Specjal¬ nym piecu przy stosowaniu wegla, drzewa lub koksu odpada. Przez wymgówanile i zuzytkowanie wchodzacych w sklaid gruzu gipsowego krzemianów glinu i krzemionki, tworzy sie produkt, który w polaczeniu z portlandcementem nadzwyczaj jest podob¬ ny do tego ostatnfego i wlasciwosci ma pra¬ wie równoznaczne. Zuzle gruzu gipsowegoskladaja sie mam) wiecej z 13% glkioziie- mu, 14% tlenku zelaza,, 2% potasu, 58% kwasu krzemowego, 1 % kwasu snarczamiego i 12% wiapmal, wówczas gdy ceaitent isklada sale z 58% wapna, 1,3% soli gorzkich, 9,2% glilnoziiemu, 5% tlenku zelaza,, 1% potasu, 1% sodto, 24% llcwiasu krzemowego, 2% kwasu weglowego i 0,5% kwasu salarczanego.Wlasciiwfoscil zuzli gruzu gipsowego i ce¬ mentu sa wiec prawie jednakowe, brak tyl¬ ko obficie zawartego w cemencie wtopna.Przez mieszanie ziizla gSpsoweglo z1 walpnem zawierajacem kwas weglowy, które przy spalaniu sie zamienia w w&pno zrace, nai- ^|1iera ód tfcgo\ brakujacego sklladtóka; nah * -stepnie latwo wspólreagujace krzemiany glitnu i krzemionki, wskutek przebiegu za- rowego i gaszacego, przechodza w polacze¬ niu z wlalpneni w trujdinio wspólreagujace, przez co zapewwiioneiriJ sa trwalosc i spój¬ nosc tak otrzymanej suchej zaprawy.Inne wykonanie sposobu tego polega na tern, ze gazy paleniskowe pieca do spala¬ nia gruzuN,gjip«oiMBgo, ukiemwalftezostaja do specjalnej komory, polaczonej z piecem, która jest pralwie do polowy napelniona wiaipnein, zawieraj acem kwas weglowy; Wskutek powyzszego gazy spalinowe, któ¬ re podlug doswiadczen opuszczaja paleni¬ sko przy 800—1000°, wspólnie z dziala¬ niem ciagu wyrugowuja kwas weglowy z zawierajacego go wapnia, przeistaczajac go w wapno zrace. Gdy db tego wapna do¬ dac zuzli gipsowych i np, zemlec ralzem, to otrzyma sile doskonala sucha zaprawe do modelowaniiaj, która jest* niemal równo¬ znaczna z cementem portlandzkim, gdyz jak pokazuje doswiadczenie polaczenie o- trzymanego ostatecznego produktu jest równie dobre jak polaczenie z portllandce- menrtern.Gazy powstajace ptfzy spalaniu sie wafp- na|, zawierajacegjo kwas weglowy, moga byc dalej zuzytkowane w sposób dowolny; z powodu swej wielkiej zaiwartoscil kwasu wleglowego w szczególnosci nadaja sile do utrwalania kamieni i cegiel Wszelkich ro- diztail PLThe basis of the method of producing maisy for carving models, which is the forerunner of the invention, is the fact that the aluminum and silicic acid silicates present in the gjps rubble are the most powerful force for preparation of the season without adding a binder. According to the present invention, first of all, before or during combustion in an ordinary furnace, ground viola, containing carbonic acid, talc is accumulated with gilps debris, so that when the debris is burned with heat for a long time, carbon sour is released from lime-containing lime. and it generates the heat of the zest, so ctzais extinguishes the forces that arise from this mixture badly with the help of water or steam, which causes the lime to disappear into calcium hydrate. The heat remaining in the slag together with the heat formed during the conversion of the roughened lime into calcium hydrate acts rugujaoo on the silicates of aluminum and knizemic acid and causes that the limescale and silicates are absorbed into the chemical compound, which is in fact unfavorable for the formation of the mortar. In terms of economy, this method has many important advantages, namely: burning lime in a (special furnace when using coal, wood or coke is eliminated. Due to the necessity and use of the aluminum silicates and silicates contained in the gypsum debris, which form the product, in combination with portland cement it is remarkably similar to the last one and its properties are almost equivalent. Bad gypsum debris consists of more than 13% glucose, 14% iron oxide, 2% potassium, 58% silicic acid, 1 % snarczami acid and 12% wiapmal, when the ceaitent is composed of chambers with 58% lime, 1.3% bitter salts, 9.2% algae, 5% iron oxide, 1% potassium, 1% sodium, 24% silicic acid, 2% carbonic acid and 0.5% salaric acid. The properties of gypsum debris and cement are almost the same, only the cement is not abundantly contained in the cement. z1 walpnem containing carbonic acid, which, when burned, turns into & nourish, nai- ^ | 1ier tfcgo \ missing compound; Then, the easily reacting silicates of alumina and silica, due to the slack and quenching behavior, transform in conjunction with the liquid into a co-reacting principle, thus ensuring durability and consistency of the dry mortar thus obtained. Another embodiment of this method is also, the combustion gases of the debris combustion furnace, gjip oiMBgo, are deposited into a special chamber connected to the furnace, which is half filled with waxnein containing carbonic acid; As a result of the above, the exhaust gases, which, in the course of the experiment, leave the combustion chamber at 800-1000 °, together with the continuous action to drive the carbonic acid out of the calcium it contains, transforming it into a calcified lime. When the lime is added to the gypsum slurry and, for example, grinded with rime, it will get a strength of an excellent dry modeling mortar, which is almost equivalent to Portland cement, because the experience shows that the joint of the final product obtained is as good as the joint. from portllandce- menrtern. The gases produced by the combustion of wafer | containing carbonic acid can be further used freely; due to their high content of fatty acid, they are especially strong for fixing stones and bricks of all kinds PL
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL3307B1 true PL3307B1 (en) | 1925-12-31 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6137850B2 (en) | Hydraulic composition | |
| EG25326A (en) | Geopolymeric cement based on fly ash and harmless to use. | |
| ES2918899T3 (en) | Fly ash manufacturing method | |
| KR20230035965A (en) | Covering material using mixture of solid refuse fuel and coal ash for stabilizing ground | |
| PL3307B1 (en) | The method of making the mass for carving models from gypsum debris and furnace waste. | |
| Kozlova et al. | Physicochemical aspects of natural and forced carbonization of cement systems | |
| JP2000119077A (en) | Production of lightweight foamed concrete | |
| Luxán et al. | Ancient XVI century mortar from the Dominican Republic: its characteristics, microstructure and additives | |
| SU1535861A1 (en) | Concrete mix for lining a gas intake shaft | |
| JP2023028440A (en) | Cement admixture and cement composition | |
| SU981585A1 (en) | Plugging material | |
| SU392027A1 (en) | RAW MIXTURE | |
| US2049882A (en) | Building tile | |
| CN113372070B (en) | Self-compacting concrete for floor heating protective layer and preparation method thereof | |
| JPS59128239A (en) | Manufacture of specific cement using coal ash | |
| SU808418A1 (en) | Binder | |
| Malipatil et al. | Geopolymer concrete for railway sleepers | |
| SU578278A1 (en) | Complex addition to silica-concrete mix | |
| SU1255605A1 (en) | Concrete composition | |
| RU2004102567A (en) | FIRE-RESISTANT CONCRETE MIX | |
| JP2023028439A (en) | Cement admixture and cement composition | |
| CN121063884A (en) | A self-curing low-carbon concrete for flue and chimney and its construction method | |
| SU1038311A1 (en) | Concrete mix | |
| PL15896B1 (en) | A method of making boton resistant to sea water. | |
| PL5420B1 (en) | A method of producing cement with high initial strength. |