PL3281B1 - A method of making glass with great strength. - Google Patents

A method of making glass with great strength. Download PDF

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Publication number
PL3281B1
PL3281B1 PL3281A PL328123A PL3281B1 PL 3281 B1 PL3281 B1 PL 3281B1 PL 3281 A PL3281 A PL 3281A PL 328123 A PL328123 A PL 328123A PL 3281 B1 PL3281 B1 PL 3281B1
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PL
Poland
Prior art keywords
glass
great strength
making glass
great
produced
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Application number
PL3281A
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Polish (pl)
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Publication of PL3281B1 publication Critical patent/PL3281B1/en

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Wyauailaizjek nitaitejszy dotyczy wyrobu szkllaii nadajacego sie w szczególnosci do pnac chemicznych i wyrózniajacegjo sie ma¬ lym wspólczynnikiem rozszerzalnosci, trud¬ no topliwoscia i odpornoscia na wplywy chemiczne, to jest na dzialalnie wody, kwa¬ sów i alkaljów, jak równiez nadzwyczajna twardoscia. Zarazem szklo to nie jest tak kruche, jak inne szklo twarde. W przeci¬ wienstwie do szkla twardego i tlukacego sie, szklo wyrabiane w mysl wytualazku ni- nilejisiziego wykalztuje wielka elastycznosc, wskutek czego w razie pekniecia szkla na¬ czynie nie roizpaida] isile na dlnofone kawalki, lecz peiknilecile to moznai zatopic. Obecnie tylko szklo kwarcowe posiadaj wlasciwosci podoibnie do szkla nSnalejsziegoi, lecz szklo to musi byc wytwarzane w piecach elek¬ trycznych, co utrudnia bardzo ksztaltowa¬ nie wyrabianych zen przedmiotów. Szkte stanowiace przedmiot wtyrialatzku niniejsze¬ go mozna wytwarzac w zwyklych piecach szklarskich o temperaturze, rozumie sie, wyzszej, a przedmioty mozna ksztaltowac wydmuchiwaniem. Zruane juz sa szkla) wy~ trzymale na dzialanie mechaniczne, lecz wlasciwosc te osiaga sie njp. ochladzaniem w oleju lufo stalpiatnilem dwóch giatunków szkla 01 rozmaitym Sfpólczynniku rozszerzal¬ nosci (sizklbi Durex'a) lub podlofonemi sizczegiólnemii sposobami. Przeciwnie, ga¬ tunki wyzszie sizkla wytworzonego w spo¬ sób niniiejsizy wykazuja te wlasciwosc bez^ posrednio, dzieki swemu sklaldowl.Zaluwa&ono, ze wbrew Wszelkim prze¬ widywaniem, dodajac pierwiastki gjrupykrzemowfej, np. cyrkon lub tytan, i jedno¬ czesnie zmniejszajac ilosc alkalljów, otrzy¬ muje sie szklo, które posiada! wielka twar¬ dosc, nie jest laimiliwe i wykazuje znaczna sipo&tosc i wielka wytrzymalosc na ude¬ rzenia. Spólczynnik rozszerzalnosci tego szkla wynosi 3 a = (143 — 145) X 10"7, a wytrzymalosc nai sciskanie 101 kg niai mim2. Pomiajdtb szklo to jest dobrym prze¬ wodnikiem ciepla, wskutek czego naczynia nagrzewaja sie natychmiast, dlzieki czemu niema potrzeby wyrabiac naczynia i apara¬ ty tak^iiepkjift. jak ze szkla zwyklego, w^- ról*^^w|^ ji t§t bardizo laitlwy, & przgdmio- ty z tego szkla sa maisywniejsKe ii trwalsze.Mozna je bez obawy pekniecia magrzewac wprost na ognili w slanie próznym i gwal¬ townie oziebiac, np. zanurzaljac do zimniej wody.Sklajd tego szkla znamionuje mailal za¬ wartosc alkalljów, nieobecnosc waipmia ii me¬ tali najjcizeseiej go zastepujacych np. baru, cynku, olowiu, al ponadto wieksza czesc kwasu krzemowego jest zastapiona kwafsem bornym, ai mmiejisze jego ilosci tlenkiem cyrkonu i tytanu.W celu otrzymania nowego szkla poistle- puje sie w spolsób zwykly, t. j. miesza siie dokladnie ciala wyjsciowe, uprzednio siproisizkowaine, i otrzymualna mase, statpia si$.Prizedmioty wyrabiane z tej stopionej ma¬ sy ksztaltuje sie zapomolca wydmuchiwania lub podobnego dzialania.Tytulem przykladu podac moznia na¬ stepujacy sklad przyblizony mieszaniny: Piasku 60—70% Kwiajsu bornego 15—30% Weglanu potasowego 1—2% Weglanu sodowego 3—6% Kaoliny 2^6% Miki 0--4% Zr02 1^-3 Jg Ti02 ' 1—3% Szklo to posiada) w przyblizeniu naste¬ pujacy sfcl&d czasteczkowy: 70SiO2. 20B2Os. 3RO. y2 A/203. 2R02 (R oznalcza) sód lub potais, R' metale grupy krzemu nip. tytaln lulb cyrkon).Szklo w ten sposób otrzymane przewyz¬ sza swemi zaletami chemicznemi, termicz nemi i mechalnilcznemi wszelkiego rodzaju szkla znane dlotychczas i nadaje sie szcze¬ gólnie do analiz, gdyz nie zawiera baru, cynku, wapnia ani cial,, które moglyby przejsc do roztworu. Nagpzewainie tprzez czas dluzszy nowe szklo w przeciwienstwie do szkla kwarcowego rate ulega nagryzaniu, jak zwykle szklo krzemowe. Jako przy¬ klad odpornosci tego szkla .mozna' przyto¬ czyc fakt nalstepujacy: w njalczyniu z tego szkla mozna roztopic lug sodlofwy i potem natychmilaJst pograzyc je wraz z lugiem stopionym do wody zimnej i naczynie nie peknie. PLThe explanation of the rivet is a glass and glass product that is particularly suitable for chemical swelling and is distinguished by its low expansion coefficient, fusibility difficulty and resistance to chemical influences, that is, to the action of water, acid and alkali, as well as extraordinary hardness. At the same time, this glass is not as brittle as other hard glass. Unlike hard and shattering glass, glass produced in accordance with the invention of Nilejisizi will have great flexibility, so that if the glass breaks, the vessel will not break down and forcefully to the long-phono pieces, but it can be sunk a little longer. At present, only quartz glass has properties similar to that of nSnalejsziegoi glass, but this glass must be produced in electric furnaces, which makes it very difficult to shape zen-made objects. The piece constituting the subject of this plug can be produced in ordinary glass furnaces with a temperature, that is to say, higher, and the articles can be formed by blowing. The glass is already broken) is resistant to mechanical action, but this property is achieved, for example. cooling in oil or cooling two glass filaments 01 by various expansion factors (Durex sizklbi) or by various methods. On the contrary, the higher species of silicon dioxide produced by the low-level exhibit these properties directly, thanks to their composition. It has been contaminated, against all foresight, by adding group elements of silico-aph, e.g. zircon or titanium, and simultaneously reducing the number of alkali. , you get the glass you own! great hardness, it is not laymilish and shows considerable poisonousness and great impact resistance. The expansion coefficient of this glass is 3 a = (143 - 145) X 10 "7, and the compressive strength is 101 kg n1 and mm2. Apart from that, this glass is a good heat conductor, as a result of which the dishes heat up immediately, so there is no need to knead the dishes. and devices as well as those made of ordinary glass, in a ^ - role * ^^ in | ^ ji t§t bardizo laitlwy, & blasts made of this glass are maisive and more durable. They can be without fear of cracking by heating directly on they fired in empty slides and rapidly cooled, e.g. by immersing them in cold water. The glass composition is characterized by the mailal content of alkali, the absence of waipmia, and metals most closely replacing it, e.g. barium, zinc, lead, and, moreover, most of silicic acid it is replaced with boric acid, and even smaller amounts with zircon and titanium oxide. In order to obtain a new glass, the usual way is used, i.e. the initial bodies are mixed thoroughly, and the resulting mass is degraded. Prizedmio These are made of this molten mass and are shaped without blowing or the like. For example, the following composition can be given: Sand 60-70% Boricine 15-30% Potassium carbonate 1-2% Sodium carbonate 3-6% Kaolins 2 ^ 6% Mica 0-4% ZrO2 1 ^ -3 Jg TiO2 '1-3% This glass has approximately the following molecular sfcl & d: 70 SiO2. 20B2Os. 3RO. y2 A / 203. 2R02 (R represents) sodium or potais, R 'silicon metals n and p. The glass obtained in this way has the chemical, thermal and mechanical advantages of all types of glass known so far and is particularly suitable for analyzes because it does not contain barium, zinc, calcium or any bodies that could pass through into the solution. For a longer time, the new glass, unlike rate quartz glass, undergoes biting, as usually silicon glass. As an example of the resistance of this glass, the following fact can be given: in a glass of this glass, it is possible to melt the slurry of soda and then it is immediately threatened with the melted liquor into cold water and the vessel will not break. PL

Claims (1)

1. Zastrzezenie patentowe. Sposób wyrobu szkla o wielkiej wy¬ trzymalosci, znamienny term, ze uzywa sile mieszalnine zialwieriaijaca 60—70% kwasu krzemowego, 15—30% kwasu bornego, li— 2% weglanu potialsowegfl, 3—6% wleglanu sodowego, 2—6% kaoliny, 0—4% miki i 1—3% tlenków grupy krzemowe\ (Zr, Ti)* V a c 1 a v Hora k. Zastepca: M. Skrzypkowski, rzecznik patentowy. Druk L. Boguslawskiego, Warszawa. / PL1. Patent claim. A method of producing glass with high strength, characterized by the fact that it uses a strong mixing of 60-70% silicic acid, 15-30% boric acid, 1-2% potassium carbonate, 3-6% sodium carbonate, 2-6% kaolin , 0-4% mica and 1-3% oxides of silicon groups (Zr, Ti) * V ac 1 av Hora near. Deputy: M. Skrzypkowski, patent attorney. Print by L. Boguslawski, Warsaw. / PL
PL3281A 1923-01-30 A method of making glass with great strength. PL3281B1 (en)

Publications (1)

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PL3281B1 true PL3281B1 (en) 1925-12-31

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