PL29403B1 - - Google Patents
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- Publication number
- PL29403B1 PL29403B1 PL29403A PL2940337A PL29403B1 PL 29403 B1 PL29403 B1 PL 29403B1 PL 29403 A PL29403 A PL 29403A PL 2940337 A PL2940337 A PL 2940337A PL 29403 B1 PL29403 B1 PL 29403B1
- Authority
- PL
- Poland
- Prior art keywords
- incendiary
- acid
- composition
- production
- diazotriazylcarbonic
- Prior art date
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- 239000002253 acid Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009527 percussion Methods 0.000 claims description 3
- 230000002964 excitative effect Effects 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 239000000463 material Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- -1 antimonyl sulfide Chemical compound 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- 229910021346 calcium silicide Inorganic materials 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 150000004905 tetrazines Chemical class 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006193 diazotization reaction Methods 0.000 description 1
- JZCYIPYIBOLETF-UHFFFAOYSA-N dinitroso carbonate Chemical compound O=NOC(=O)ON=O JZCYIPYIBOLETF-UHFFFAOYSA-N 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- WETZJIOEDGMBMA-UHFFFAOYSA-L lead styphnate Chemical compound [Pb+2].[O-]C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C([O-])=C1[N+]([O-])=O WETZJIOEDGMBMA-UHFFFAOYSA-L 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- MHWLNQBTOIYJJP-UHFFFAOYSA-N mercury difulminate Chemical compound [O-][N+]#C[Hg]C#[N+][O-] MHWLNQBTOIYJJP-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 description 1
Description
Do wytwarzania nie nagryzajacych mas zapalajacych, stosowanych do wyro¬ bu kapiszonów, srodków zapalajacych, amunicji malokalibrowej, zwlaszcza nie zawierajacych rteci lub innych mas zapa¬ lajacych, stosuje sie dotychczas zwlasz¬ cza tetrazyny, które dodawane w malych ilosciach do zwyklej masy zapalajacej, np. do trójnitrorezorcynianu olowiu, stanowia wybitny srodek uczulajacy.Okazalo sie obecnie, ze w celu zwiek¬ szenia czulosci mas zapalajacych poza te- trazynami mozna stosowac takze inne zwiazki zawierajace duzo azotu, przy czym otrzymuje sie takie same wyniki.Wedlug wynalazku jako pobudzajacy srodek zapalajacy stosuje sie znany kwas dwuazotrójazylokarbonowy, który otrzy¬ muje sie przez dwuazowanie kwasu ami- diotrójazylokarbonowego.Jako material wyjsciowy sluzy kwas amidotrój azylokarbonowy H JT H2N - Cx N- C C O OH, z którego w wyniku traktowania kwa¬ sem azotawym powstaje prawie ilosciowo kwas dwuazotrójazylokarbonowy.Kwas dwuazotrójazylokarbonowy sta¬ nowi przy wyrobie mas zapalajacych ma¬ terial nieznany, który w tych masach mo¬ ze zastapic stosowany zwykle piorunian rteci lub podobny material wybuchowy.Najodpowiedniejsze stosunki skladni¬ ków masy zapalajacej z dodatkiem mate¬ rialu wedlug wynalazku sa nastepujace: styfnianu olowiu kwasu dwuazotrój- azylokarbonowego siarczku antymonu dwutlenku olowiu azotanu baru krzemku wapnia 30 _ 60% 1 — 10% do 10% do 4% 20 — 50% do 10%.Do wyrobu kapiszonów najodpowied¬ niejszy sklad jest np. nastepujacy: styfnianu olowiu 30% kwasu dwuazotrójazylo- karbonowego 5% siarczku antymonu 10% dwutlenku olowiu 5% azotanu baru 45% krzemku wapnia 5%.Kwas dwu;azotrójazylokarbonowy po¬ wieksza znacznie wrazliwosc masy zapa¬ lajacej na uderzenie, jesli w malych ilos¬ ciach jest dodany do wlasciwych materia¬ lów masy zapalajacej, np. do trójnitrore- zorcynianu olowiu, baru lub podobnego materialu. PLFor the production of non-scratching incendiary compositions for percussion caps, incendiary agents, malocaliber ammunition, especially without mercury or other incendiary masses, hitherto especially tetrazines have been used, which are added in small amounts to ordinary incendiary mass, e.g. It is an outstanding sensitizing agent to lead trinitroreorcinate. It has now turned out that in order to increase the sensitivity of incendiary masses, besides tetrazines, other compounds containing a lot of nitrogen can also be used, with the same results being obtained. the known diazotriazylcarbonic acid is used, which is obtained by diazotization of the amino-triazylcarbic acid. The starting material is amidotriazylcarbonic acid H JT H2N - Cx N-CCO OH, from which, by treatment with nitrous acid, almost quantitatively is formed diitric acid. Diazotriazylcarbonic acid is an ignition material in the production of containing an unknown material, which in these masses can replace the commonly used mercury fulminate or a similar explosive. The most suitable ratios of the components of the incendiary mass with the addition of the material according to the invention are as follows: lead styphate, dinitrasyl sulfide, antimonyl sulfide, antimony barium nitrate calcium silicide 30-60% 1 - 10% to 10% to 4% 20 - 50% to 10%. For the production of percussion caps, the most suitable composition is, for example: lead styphate 30% dinitrosyl carbonic acid 5% antimony sulphide 10% lead dioxide 5% barium nitrate 45% calcium silicide 5% diacid triazylcarbonic acid considerably increases the sensitivity of the fire mass to an impact, if it is added in small amounts to suitable materials of the flame material, e.g. Lead trinitroresorcinate, barium or the like. PL
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL29403B1 true PL29403B1 (en) | 1940-12-31 |
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