PL24006B1 - - Google Patents
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- Publication number
- PL24006B1 PL24006B1 PL24006A PL2400633A PL24006B1 PL 24006 B1 PL24006 B1 PL 24006B1 PL 24006 A PL24006 A PL 24006A PL 2400633 A PL2400633 A PL 2400633A PL 24006 B1 PL24006 B1 PL 24006B1
- Authority
- PL
- Poland
- Prior art keywords
- rubber
- weight
- parts
- milk
- oil
- Prior art date
Links
- 239000008267 milk Substances 0.000 claims description 11
- 210000004080 milk Anatomy 0.000 claims description 11
- 235000013336 milk Nutrition 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 7
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 239000004902 Softening Agent Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- 230000035943 smell Effects 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- UBLAMKHIFZBBSS-UHFFFAOYSA-N 3-Methylbutyl pentanoate Chemical compound CCCCC(=O)OCCC(C)C UBLAMKHIFZBBSS-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- 241000206575 Chondrus crispus Species 0.000 description 1
- 241000102542 Kara Species 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000003205 diastolic effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 239000011297 pine tar Substances 0.000 description 1
- 229940068124 pine tar Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
Do wyrobu kleiiw przy uzyciu kauczuku stosowano dotychczas cementy kauczuko¬ we albo zwykle lub stezone mleczko kau¬ czukowe.Stwierdzono, ze takie kleiwa moga byc znacznie ulepszone, jezeli do ich wyrobu z&mia&t cementów kauczukowych albo zwyklego lub stezonego mleczka kauczu¬ kowego zastosuje sie tak zwane smietan¬ kowe mleczko kauczukowe. Pod wyraze¬ niem „smietankowe mleczko kauczukowe" nalezy rozumiec plywajaca po wierzchu i zawierajaca czastki kauczuku warstewke mleczka kauczukowego, która oddziela sie od dolnej warstwy rozpuszczalnych w wo¬ dzie, niekauczukowych skladników mlecz¬ ka, jezeli mleczko kauczukowe zada sie srodkiem ulatwiajacym wydzielenie sie smietanki, jak np. pektyna, guma Ka- raya'ska, sluzem wodorostów morskich, mchem irlandzkim, mchem islandzkim i t. d.Ewentualnie mozna stosowac mleczko kau¬ czukowe po kilkakrotnej takiej obróbce zbierania smietanki.Otrzymywanie kleiwa wedlug wynalaz¬ ku niniejszego odbywa sie w ten sposób, ze smietankowe mleczko kauczukowe miesza sie ze srodkiem rozmiekczajacym kauczuk.Ewentualnie do mieszaniny tej mozna do¬ dac równiez lotnego, nierozpuszczalnego w wodzie rozpuszczalnika organicznego w po¬ staci emulsji.Mleczko kauczukowe moze byc kwasne, zasadowe lub obojetne, a w razie zyczenia moga byc dodane do niego równiez srodki wulkanizujace lub materialy wypelniajace.Gdy mieszanina posiada {niepozadany za¬ pach, a mianowicie, gdy pachnie np. amo¬ niakiem, mozna dodac substancji aroma¬ tycznej dla zamaskowania zapachu amo¬ niaku, Wynalazek niniejszy moze byc wyko¬ nany tytulem przykladu w sposób naste¬ pujacy.Do 100 czesci wagowych kauczuku w postaci smiietankowcgo mleczka kauczuko¬ wego dodaje sie 20 — 40 czesci wagowych oleju zywicznego w postaci emulsji, 30 — 200 czesci wagowych emulsji czterochlorku wegla* (skladajacej isde z 60 czesci wago¬ wych czterochlorku wegla, 38 czesci, wa¬ gowych wody, 1 czesci wagoiwej kleju i 1 czesci wagowej olejanu sodowego) i 2 — 5 czesci wagowych oleju diziiegcilogaultowego.Zastosowanie dziegciu gaultowego nie jest konieczne i ma na celu tylko polepszenie zapachu. Gdy stosuje sie jednoczesnie ma¬ terial wypelniajacy, to mozna dodac do powyzszej mieszaniny np. kredy w ilosci np. 50 — 100 czesci wagowych. v Wytwarzanie wspomnianej emulsji ole¬ ju zywicznego moze odbywac sie np. w ten sposób, ze mieszanine 100 czesci wagowych oleju zywicznego i 30 — 40 czesci wago¬ wych 29%-owego roztworu amoniaku go¬ tuje sie w ciagu kilku minut, Otrzymany w ten sposób rezyniani amonowy dziala ja¬ ko stabilizator emuls ji.Zamiast oleju zywicznego mozna stoso¬ wac jakikolwiek inny znamy srodek zmiek¬ czajacy kauczuk, jak np. smole sosnowa, smole jodlowa albo kumarom. Tak samo za¬ miast czterochlorku wegla mozna stosowac benzen, nafte lub solwent-nafte albo inny trudlnopalny produkt destylacji smoly w postaci emulsji. Zamiast oleju gaultowego mozna stosowac równiez terpineol, aldehyd anyzowy, alkohol fenylo-etylowy, salicylan metylu albo olejek lawendowy i t. d.Kleiwo wedlug- wynalazku niniejszego posiada szeroki zakres zastosowania, a mianowicie do wyrobu obuwia, opon i wo- góle do wyrobu przedmiotów kauczuko¬ wych. Przy porównaniu z innymi kleiwami kleiwo to wykazuje cenniejsze wlasciwo¬ sci, zwlaszcza pod wzgledem wiekszej sily klejenia i odpornosci na wilgoc. PLUntil now, rubber cements or ordinary or concentrated rubber milk have been used for the production of adhesives using rubber. It has been found that such adhesives can be significantly improved if they are made of rubber cements or ordinary or concentrated rubber milk by so-called creamy rubber milk. By the expression "creamy gum milk" is to be understood a layer of rubber milk floating on the top and containing particles of rubber, which separates from the lower layer of water-soluble, non-rubber milk components, if the rubber milk is asked to release the cream with a release agent. such as, for example, pectin, Kara's gum, seaweed mucus, Irish moss, Icelandic moss, and so on. Alternatively, rubbery milk may be used after collecting the cream in such a way several times. that the creamy rubber milk is mixed with the rubber softener. Optionally, the mixture can also be mixed with a volatile, water-insoluble organic solvent in the form of an emulsion. The rubber milk can be acidic, alkaline or neutral, and can be added if desired. to it, also vulcanizing agents or filling materials the mixture has an undesirable odor, namely when it smells of e.g. ammonia, an aromatic substance may be added to mask the smell of ammonia, the present invention may be implemented by the title of an example as follows. 20 - 40 parts by weight of a resin oil in the form of an emulsion, 30 - 200 parts by weight of an emulsion of carbon tetrachloride (consisting of 60 parts by weight of carbon tetrachloride, 38 parts by weight of water) are added. , 1 part by weight of glue and 1 part by weight of sodium oleate) and 2 - 5 parts by weight of diastolic oil. The use of gault tar is not necessary and is only intended to improve the odor. If a filler material is used simultaneously, for example, chalk may be added to the above mixture in an amount of, for example, 50-100 parts by weight. The preparation of the said resin-oil emulsion can take place, for example, in that a mixture of 100 parts by weight of resin oil and 30-40 parts by weight of 29% ammonia solution is boiled within a few minutes. the ammonium-resin process acts as an emulsion stabilizer. Instead of resin oil, any other known rubber softener, such as pine tar, fir tar or coumarom, may be used. Likewise, instead of carbon tetrachloride, benzene, kerosene or solvent-kerosene or other flame retardant emulsion product may be used. Instead of gault oil, it is also possible to use terpineol, anisaldehyde, phenyl ethyl alcohol, methyl salicylate or lavender oil, and so on. . Compared to other adhesives, this adhesive exhibits more valuable properties, particularly in terms of greater adhesive strength and resistance to moisture. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL24006B1 true PL24006B1 (en) | 1936-11-30 |
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