PL203591B1 - Method of modification of the properties of metals and alloys in a liquid state - Google Patents
Method of modification of the properties of metals and alloys in a liquid stateInfo
- Publication number
- PL203591B1 PL203591B1 PL354382A PL35438202A PL203591B1 PL 203591 B1 PL203591 B1 PL 203591B1 PL 354382 A PL354382 A PL 354382A PL 35438202 A PL35438202 A PL 35438202A PL 203591 B1 PL203591 B1 PL 203591B1
- Authority
- PL
- Poland
- Prior art keywords
- alloys
- metals
- properties
- liquid state
- modification
- Prior art date
Links
- 229910045601 alloy Inorganic materials 0.000 title claims description 14
- 239000000956 alloy Substances 0.000 title claims description 14
- 229910052751 metal Inorganic materials 0.000 title claims description 8
- 239000002184 metal Substances 0.000 title claims description 8
- 150000002739 metals Chemical class 0.000 title claims description 4
- 239000007788 liquid Substances 0.000 title claims description 3
- 230000004048 modification Effects 0.000 title description 2
- 238000006011 modification reaction Methods 0.000 title description 2
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N oxygen atom Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- CBENFWSGALASAD-UHFFFAOYSA-N ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- YZCKVEUIGOORGS-UHFFFAOYSA-N hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
Description
Opis wynalazku Przedmiotem wynalazku jest sposób metalurgicznej obróbki metali i stopów w stanie ciek lym. Znane s a sposoby modyfikacji np. stopów za pomoc a: sodu, fosforu, boru, tytanu lub zwi azków chemicznych w postaci gazowej. Sposób wed lug wynalazku polega na tym, ze przez obróbk e na drodze jonizacji, gazów ko- rzystnie tlenu do postaci-odpowiednio: trójatomowego lub atomowego tlenu i wprowadza si e do k apieli metalowej, przy czym na skutek wysokiej aktywno sci gazy te reaguj ac w metalu lub stopie daj a zwi az- ki, które umacniaj a zakrzep ly stop. Sposób pozwala na popraw e w lasno sci mechanicznych np. twardo sci i wytrzyma lo sci. Poza czystymi gazami jednosk ladnikowymi korzystne jest tak ze stosowanie aktywowanego powietrza. Sposób charakteryzuje si e fizycznymi i/lub chemicznymi reakcjami mi edzy ciek lymi metalami lub stopami a aktywnymi, alotropowymi odmianami gazów jak np.: ozon, atomowy azot, atomowy wo- dór i inne lub mieszaninami zawieraj acymi podobne gazy, gdzie produktami reakcji s a fazy lub zwi azki umacniaj ace metale i stopy tj. wymuszaj ace wzrost ich twardo sci i/lub wytrzyma lo sci. P r z y k l a d 1. 2 kg stopu AM-5 z dodatkiem 0,4% Ti i 0,03% B po stopieniu w piecu indukcyjnym i przegrzaniu do temperatury 1000°C przedmuchuje si e powietrzem przetworzonym w generatorze ozonu o wydaj- no sci do 0,056 mg O 3 /s w czasie 200 s, przy ci snieniu 25 Pa i przep lywie 3 • 10 3 m 3 /s. Stop odlewa si e do kokili. P r z y k l a d 2. 2 kg stopu AK-12 5 z dodatkiem 0,3% Ti i 0,03% B po stopieniu w piecu indukcyjnym i prze- grzaniu do temperatury 900° przedmuchuje si e powietrzem przetworzonym w generatorze ozonu o wydajno sci do 0,056 mgO 3 /s w czasie 240 s, przy ci snieniu 0,1 MPa i przep lywie 12,5 • 10 -3 m 3 /s. Stop odlewa si e do formy piaskowej. PLDescription of the invention The present invention relates to a method of metallurgical treatment of metals and alloys in a liquid state. There are known methods of modification of, for example, alloys with: sodium, phosphorus, boron, titanium or chemical compounds in gaseous form. The method according to the invention consists in the fact that by treatment by means of ionization, gases, preferably oxygen, to the form, respectively: tratomic or atomic oxygen, are introduced into the metal bath, and due to the high activity of these gases, they react in the metal or alloy they give rise to compounds that strengthen the clotted alloy. The method allows for the improvement of mechanical properties, e.g. hardness and strength. In addition to pure single-component gases, it is also advantageous to use activated air. The method is characterized by physical and / or chemical reactions between liquid metals or alloys and active, allotropic forms of gases, such as ozone, atomic nitrogen, atomic hydrogen and others, or mixtures containing similar gases, where the reaction products are phases or compounds strengthening metals and alloys, i.e. forcing an increase in their hardness and / or strength. Example 1. 2 kg of AM-5 alloy with the addition of 0.4% Ti and 0.03% B, after melting in an induction furnace and superheating to 1000 ° C, are blown with air processed in an ozone generator with a capacity of 0.056 mg O 3 / s during 200 s, at a pressure of 25 Pa and a flow rate of 3 • 10 3 m 3 / s. The alloy is poured into the die. Example 2. 2 kg of AK-12 alloy 5 with the addition of 0.3% Ti and 0.03% B, after melting in an induction furnace and heating to 900 ° C, are blown with air processed in an ozone generator with a capacity of 0.056 mgO 3 / s during 240 s, at a pressure of 0.1 MPa and a flow of 12.5 • 10 -3 m 3 / s. The alloy is poured into a sand mold. PL
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL354382A PL203591B1 (en) | 2002-06-10 | Method of modification of the properties of metals and alloys in a liquid state |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL354382A PL203591B1 (en) | 2002-06-10 | Method of modification of the properties of metals and alloys in a liquid state |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL354382A1 PL354382A1 (en) | 2003-12-15 |
| PL203591B1 true PL203591B1 (en) | 2009-10-30 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Sibum | Titanium and Titanium Alloys—From Raw Material to Semi‐finished Products | |
| IT8203505A1 (en) | FERROLEGA FOR THE INOCULATION TREATMENT OF SPHERICAL GRAPHITE CAST IRONS | |
| ES2230308T3 (en) | ALLOY STEEL WITH NITROGEN, SPRAY COMPACT STEEL, PROCEDURE FOR REDUCTION AND COMPOSITE MATERIAL MANUFACTURED OF THE INDICATED STEEL. | |
| PL203591B1 (en) | Method of modification of the properties of metals and alloys in a liquid state | |
| US6896846B1 (en) | Synthesis of orthopaedic implant materials | |
| Aponbiede et al. | The effect of chloride salts on the mechanical properties of gray cast iron | |
| Golubtsov et al. | Improving wheel steel by means of barium-based modifiers | |
| SU1668404A1 (en) | Modifying mixture | |
| JPS63183151A (en) | Low-expansion cast iron having excellent machinability | |
| Timofeev et al. | Production of tool steels at BMZ | |
| Gulyga et al. | Modeling the metal temperature dynamics on route. | |
| Zheng et al. | New high nitrogen wear and corrosion resistant steels from powder metallurgical process | |
| Dower et al. | Toughness of Powder Metallurgy Forgings as a Function of Processing Route | |
| Golub et al. | Physicochemical grounds for the substitution of nitrogen for argon during out-of-furnace treatment of high-carbon steel | |
| JP2005509739A5 (en) | ||
| Katunin et al. | Improvement in quality of production of rails from steel made in electric furnace | |
| JP2004300508A5 (en) | ||
| Varahraam et al. | A Method of Magnesium Treatment for Producing Gravity-diecast Ductile Iron | |
| Calderon | Inter-particle connections development during sintering of Cr-Mo-alloyed steel powder in N2/H2 atmosphere | |
| Kostyakov et al. | Production processes of quality metal in electric furnaces with plasma heating | |
| UA29301A (en) | Method for carbonic ferrotitanium production | |
| Kimstach et al. | The graphitizing inoculation of hypereutectoid steel | |
| Tsai | The study of HH sub 2 heat resistance large castings | |
| Neuer | Means and process for the calcium treatment of steel | |
| Bavajtsev et al. | Prediction of explosion possibility for exothermic mixtures using calculations of their combustion specific heat |