PL17486B1 - A method of obtaining easily water-soluble organic substances, containing phosphorus, from plants and seeds, especially oily, or their marc. - Google Patents
A method of obtaining easily water-soluble organic substances, containing phosphorus, from plants and seeds, especially oily, or their marc. Download PDFInfo
- Publication number
- PL17486B1 PL17486B1 PL17486A PL1748631A PL17486B1 PL 17486 B1 PL17486 B1 PL 17486B1 PL 17486 A PL17486 A PL 17486A PL 1748631 A PL1748631 A PL 1748631A PL 17486 B1 PL17486 B1 PL 17486B1
- Authority
- PL
- Poland
- Prior art keywords
- acid
- seeds
- plants
- marc
- organic substances
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title description 3
- 239000011574 phosphorus Substances 0.000 title description 3
- 229910052698 phosphorus Inorganic materials 0.000 title description 3
- 239000000126 substance Substances 0.000 title description 2
- 239000002253 acid Substances 0.000 claims description 12
- 238000000605 extraction Methods 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 229940043430 calcium compound Drugs 0.000 claims description 4
- 150000001674 calcium compounds Chemical class 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 159000000007 calcium salts Chemical class 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Description
Znany jest z pat. Nr 11053 sposób o- trzymywania substancyj organicznych, za¬ wierajacych fosfor, z roslin i nasion olei¬ stych, który polega na tern, ze kwasny plyn otrzymany z ekstrakcji surowca roslinne¬ go doprowadza sie do odczynu zasadowego przy pomocy lugu np. sodowego, wapienne¬ go lub innego i przez to samo juz powodu¬ je sie stracenie osadu, który zawiera prze¬ waznie sole kwasu inozytofosforowego trudno rozpuszczalne w wodzie. Produkt ten moze byc uzywany bezposrednio po oczyszczeniu lub po zamianie na produkt latworozpuszczalny w wodzie wedlug pa¬ tentu Nr 14185. Trzeba bylo zatem w celu otrzymania latwo rozpuszczalnego produk¬ tu przeprowadzac dwa procesy najpierw wedlug patentu Nr 11053, a nastepnie we¬ dlug patentu Nr 14185.Otrzymanie latworozpuszczalnego w wodzie produktu, skladajacego sie glównie z soli wapniowej kwasu inozytofosforowe¬ go, udaje sie sposobem wedlug wynalazku droga prostsza i wygodniejsza, a mianowi¬ cie w ten sposób, ze kwasny plyn otrzyma¬ ny z ekstrakcji surowca roslinnego sposo¬ bem zwyklym zadaje sie taka iloscia ja¬ kiegokolwiek zwiazku wapnia, np. tlenku wapnia, weglanu wapnia, soli wapniowej kwasu organicznego, która nie wystarcza do calkowitego zobojetnienia plynu poeks¬ trakcyjnego, a przy której pomimo utrzy-mania kwasnego odczynu plynu poekstrak- * cyjnego powstaje osad soli kwasu inozyto- n fosforowego o t&kim skladzie, ze zamiana na kwasna rozpuszczalna sól moze byc wy¬ konana bezposrednio i bez jakichkolwiek innych zabiegów dodatkowych, jedynie przez rozpuszczenie osadu w kwasie mine¬ ralnym i stracenie alkoholem w znany spo¬ sób.Sposób wedlug patentu austrjackiego Nr 122654 jest analogiczny prawie ze spo¬ sobem wedlug pat. pol. Nr 11053 z ta tylko róznica, ze stosuje nie lug wapienny, jak w pat, Nr 11053, ale weglan wapnia, co pro¬ wadzi jednak w kazdym z tych przypad¬ ków 4° otrzymania nierozpuszczalnej soli wapniowej kwasu inozytofosforowego, wy¬ magajacej oczyszczania przed zamiana na rozpuszczalna sól, a wiec czynnosci, której sposobem wedlug niniejszego wynalazku wlasnie sie unika.Sposób uproszczonej pracy jest zna¬ mienny tern, ze przez zadanie plynu poeks¬ trakcyjnego taka iloscia zwiazku wapnia, która nie wystarcza do calkowitego zobo¬ jetnienia jego kwasowosci, uzyskuje sie moznosc bezposredniej zamiany osadu o- trzymanego w postaci nierozpuszczalnej soli wapniowej kwasu inozytofosforowego na sól rozpuszczalna sposobem znanym.Dotychczas nie przeprowadzano tej prze¬ miany na sól rozpuszczalna bezposrednio, a zadawano miedzy innemi i lugiem wa¬ piennym plyn poekstrakcyjny do odczynu zasadowego, a wiec zobojetniano calkowi¬ cie. Wymagalo to oczyszczania otrzyma¬ nej soli wapniowej i dopiero wówczas moz¬ na bylo zamieniac na sól rozpuszczalna.To oczyszczanie staje sie zbednem przy stosowaniu sposobu wedlug wynalazku i na tern polega postep techniczny wynalazku, nie mówiac juz o oszczednosci w ilosciach stosowanych zwiazków wapnia do niecal¬ kowitego zobojetniania zadawanego niemi kwasnego plynu otrzymanego z ekstrakcji.Przyklad. 100 kg kuchu konopnego ekstrahuje sie kilkakrotnie w obecnosci for¬ maliny zapomoca 1% -owego kwasu octo¬ wego, stosujac kwasu tego ogólem 700 kg.Otrzymany plyn poekstrakcyjny zadaje sie 5,6 kg tlenku wapnia i 15 kg octanu wapnia i powstaly osad soli kwasu inozy¬ tofosforowego w znany sposób rozpuszcza sie w potrzebnej do rozpuszczenia ilosci kwasu solnego, roztwór odbarwia sie we¬ glem i przesacz straca zapomoca alkoholu lub acetonu. PLHe is known from Pat. No. 11053 method of preserving phosphorus-containing organic substances from plants and oilseeds, which consists in the fact that the acidic liquid obtained from the extraction of plant raw material is made alkaline with the use of a slurry, e.g. soda, lime Or any other, and thereby already causes the loss of the precipitate, which usually contains salts of inositophosphoric acid which are sparingly soluble in water. This product can be used immediately after cleaning or after conversion to a water-soluble product according to the patent No. 14185. It was therefore necessary to carry out two processes in order to obtain a readily soluble product, first according to patent No. 11053 and then according to patent No. 14185. Obtaining a water-soluble product, consisting mainly of the calcium salt of inositophosphoric acid, is easier and more convenient according to the invention, namely that the acidic liquid obtained from the extraction of the vegetable raw material by the method of the invention is the usual amount of any calcium compound, e.g. calcium oxide, calcium carbonate, calcium salt of an organic acid, is not sufficient to completely neutralize the extraction fluid and which, despite the acidity of the extraction fluid, produces a precipitate of phosphoric inositon salt of the same composition that replacement with an acid soluble salt may It is applied directly and without any other additional treatment, only by dissolving the precipitate in mineral acid and dissolving it with alcohol in a known manner. The method according to Austrian patent No. 122654 is almost analogous to the method according to US Pat. half. No. 11053 with the only difference that it uses not limestone, as in US Pat. No. 11053, but calcium carbonate, which, however, in each of these cases results in a 4 ° insoluble calcium salt of inositophosphoric acid, requiring purification before conversion to a soluble salt, an activity that is precisely avoided according to the present invention. The method of simplified work is significant in that, by applying an amount of calcium compound that is not sufficient to completely deplete its acidity, the direct conversion of the sludge obtained in the form of an insoluble calcium salt of inositophosphoric acid into a soluble salt is obtained by the known method. Hitherto this conversion has not been carried out into a directly soluble salt, and the post-extraction liquid was added to an alkaline pH, So it was completely darkened. This required purification of the obtained calcium salt, and only then could it be converted into a soluble salt. This purification becomes unnecessary in the application of the method according to the invention and this is the technical progress of the invention, not to mention savings in the amounts of calcium compounds used down to some ¬ complete neutralization of the silky acidic liquid obtained from the extraction. 100 kg of hemp gruel are extracted several times in the presence of formrin with 1% acetic acid, using a total of 700 kg of the acid. The resulting extraction fluid is mixed with 5.6 kg of calcium oxide and 15 kg of calcium acetate and the resulting acid salt precipitate is Phosphorus inositol is dissolved in a known manner in the amount of hydrochloric acid required to dissolve, the solution becomes discolored with carbon and the filtrate is lost with alcohol or acetone. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL17486B1 true PL17486B1 (en) | 1932-12-31 |
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