PL17364B1 - A way to separate minerals by swimming. - Google Patents

A way to separate minerals by swimming.

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Publication number
PL17364B1
PL17364B1 PL17364A PL1736431A PL17364B1 PL 17364 B1 PL17364 B1 PL 17364B1 PL 17364 A PL17364 A PL 17364A PL 1736431 A PL1736431 A PL 1736431A PL 17364 B1 PL17364 B1 PL 17364B1
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PL
Poland
Prior art keywords
minerals
swimming
interaction
saturated
way
Prior art date
Application number
PL17364A
Other languages
Polish (pl)
Filing date
Publication date
Application filed filed Critical
Publication of PL17364B1 publication Critical patent/PL17364B1/en

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Description

Jest rzecza znana, ze rozmaite minera¬ ly daja sie oddzielic od siebie przez wsply¬ wanie. Wedlug tego sposobu rozdzielania zawiesza sie mineraly w wodzie z dodat¬ kiem rozmaitych odczynników chemicznych i olejów i wytwarza piane, unoszaca jeden lub wiecej mineralów. Znamienna cecha wsplywania jest stosowanie wody, jako o- srodka, w którym sie wytwarza piane i za¬ wiesza mineraly.Niniejszy wynalazek umozliwia prze¬ prowadzenie wsplywania mineralów, roz¬ puszczalnych w wodzie, lub tez prowadze¬ nie wsplywania w warunkach zupelnie in¬ nych pod wzgledem stosowanej cieczy i dla¬ tego przez rozszerzenie stosowalnosci i wy¬ konania przedstawia znaczne korzysci tech¬ niczne. rl'" ""T"'".Doswiadczenia wykazaly, ze jest rze¬ cza mozliwa zastosowanie wsplywania do mineralów, rozpuszczalnych w wodzie, ta¬ kich jak sól kuchenna, sole potasowe, ma- gnezjowe i inne w celu oddzielania ich od siebie, wzglednie wydzielania ilu, towarzy¬ szacego tym mineralom.Wsplywanie daje sie w tym przypadku przeprowadzic, jezeli sie uzyje jako osrod¬ ka, w którym sie zawiesza te mineraly, na¬ syconych roztworów odpowiednich soli, wszystkich albo ich czesci, a to w celu nie¬ rozpuszczalna tych mineralów w wodzie w czasie wykonywania wsplywania. Ponie¬ waz przy wsplywaniu powstaja pewne straty w osrodku plynnym, mozna doda¬ wac do nasyconego roztworu nieco wody, przez co ten roztwór jest niecalkowicie na-sycony i dopiero dosyca sie w czasie wyko¬ nywania wsplywania. Zreszta wsplywanie przeprowadzi sie w sposób znany przez dodatek chemikaljów, srodków pienia¬ cych w nasyconych roztworach solnych i olejów, wynoszacych tylko pewne skladni¬ ki mineralne. Ponizej zamieszczone przy¬ klady przedstawiaja wyniki stosowania ni¬ niejszego sposobu.Przyklad L Tak zwany zubr solny, skladajacy sie z soli kuchennej, ilu i ma¬ lej ilosci towarzyszacych mineralów jak anhydrytu, soli potasowych i magnezjo- wych zmielono w mlynie kulowym na ziar¬ na ponizej 0,2 mm srednicy w ilosci 1 kg.Pyl ten zadano szescioma litrami solanki i poddano wsplywaniu w roztworze kwa¬ snym z dodatkiem terpentyny. Po kilka- krotnem powtórzeniu wsplywania udalo sie w pianie wydzielic cala ilosc ilu i otrzy¬ mano w ten sposób czysta sól kuchenna, za¬ wierajaca w sobie nierozpuszczalny an¬ hydryt. Wydatek byl okolo 700 g, ilosc wsplynietego ilu wynosila 270 g a straty 30 g.Przyklad II. Sywinit ilasty po zmiele¬ niu na ziarno okolo 0.2 mm zadano szescio¬ krotna iloscia roztworu nasyconego soli ku¬ chennej i chlorku potasowego w zwyczaj¬ nej temperaturze. Poddano te zawiesine wsplywaniu terpentyna i frakcja ksylolo- wa z mazi pogazowej. W pianie znajdowal sie il i czesc soli kuchennej, która byla z ilem przerosnieta, o stosunkowo bardzo nieznacznej ilosci chlorku potasowego. Na¬ tomiast osad w roztworze zawieral wzbo¬ gacony sylwin, a nieznaczne ilosci ilu soli kuchennej i anhydrytu. Male ilosci soli magnezjowych przeszly do roztworu. Wy¬ dajnosc tego procesu liczac na skladnik wartosciowy chlorek potasu byla okolo 70%, a produkt koncowy, otrzymany przez filtracje, byl wzbogacony w stosunku do surowca, zawierajacego 20% KC1, na pro¬ dukt, zawierajacy okolo 35% KCl. PLIt is known that different minerals can be separated from each other by interaction. According to this method of separation, the minerals are suspended in water with the addition of a variety of chemicals and oils, and a foam is produced which carries one or more of the minerals. A characteristic feature of the interaction is the use of water as a medium for producing foams and suspending the minerals. The present invention makes it possible to carry out the interaction of water-soluble minerals, or to conduct the interaction under completely different conditions. with regard to the liquid used, and therefore, by expanding the applicability and the execution, it presents considerable technical advantages. rl "" "" T "" ". Experience has shown that it is quite possible to apply the treatment of water-soluble minerals such as table salt, potassium, magnesium and other salts to separate them from each other. relative separation of how many accompanying these minerals can be carried out by using as a medium in which to suspend these minerals, saturated solutions of the corresponding salts, all or part of them, in order not to These minerals are soluble in water during the swimming-time. Since some losses occur in the liquid medium during the swimming, you can add a little water to the saturated solution, so that the solution is not completely saturated and only saturates over time. Moreover, the interaction will be carried out in a manner known by the addition of chemicals, foaming agents in saturated salt solutions and oils, which contain only certain minerals. y show the results of the present method. Example L The so-called salt cone, consisting of table salt, how many and small amounts of accompanying minerals such as anhydrite, potassium and magnesia salts were ground in a ball mill for grains below 0, 2 mm in diameter, in the amount of 1 kg. This dust was treated with six liters of brine and coalesced in an acidic solution with the addition of turpentine. After repeating the interaction several times, it was possible to separate the entire quantity in the foam, and thus a pure table salt was obtained, containing an insoluble anhydrite. The expenditure was about 700 g, the amount of the combined amount was 270 g and the loss was 30 g. Example II. The clay sivinite, after grinding to grain of about 0.2 mm, was treated with a six-fold amount of a solution of saturated kitchen salt and potassium chloride at the usual temperature. The suspension was also subjected to the interaction of turpentine and the xylol fraction from the gaseous fluid. The foam contained an abundance and a portion of table salt, which was too much overgrown, with a relatively very small amount of potassium chloride. The sediment in the solution, on the other hand, contained enriched silicium, and slight amounts of table salt and anhydrite. Small amounts of the magnesia salt passed into solution. The efficiency of this process, based on the value component potassium chloride, was about 70%, and the final product, obtained by filtration, was enriched with respect to the raw material containing 20% KCl, for the product containing about 35% KCl. PL

Claims (1)

1. Zastrzezenie patentowe. Sposób rozdzielania mineralów przez wsplywanie, znamienny tern, ze wsplywa¬ nie przeprowadza sie w roztworach nasy¬ conych lub prawie nasyconych solami wzglednie skladnikami soli i to takiemi, które stoja w równowadze ze wszystkimi lub czescia mineralów poddanemi wsply¬ waniu, wzglednie w roztworach nasyco¬ nych, w których mineraly nie sa rozpu¬ szczalne, lub tylko bardzo wolno rozpu¬ szczalne. Spólka Akcyjna Eksploatacji Soli Potasowych. Druk L. Boguslawskiego i Ski, Warszawa, PL1. Patent claim. A method of separating minerals by swimming, characterized by the fact that the interaction is carried out in solutions which are saturated or nearly saturated with salts or with salt components, and those which are in equilibrium with all or parts of the minerals subjected to interaction, or in saturated solutions substances in which the minerals are not soluble or only very slowly dissolving. Joint stock company for the exploitation of potassium salts. Print by L. Boguslawski and Ski, Warsaw, PL
PL17364A 1931-01-09 A way to separate minerals by swimming. PL17364B1 (en)

Publications (1)

Publication Number Publication Date
PL17364B1 true PL17364B1 (en) 1932-11-30

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