PL15971B3 - A method of protecting textile goods, fur, hair, feathers and similar materials from pests. - Google Patents
A method of protecting textile goods, fur, hair, feathers and similar materials from pests. Download PDFInfo
- Publication number
- PL15971B3 PL15971B3 PL15971A PL1597129A PL15971B3 PL 15971 B3 PL15971 B3 PL 15971B3 PL 15971 A PL15971 A PL 15971A PL 1597129 A PL1597129 A PL 1597129A PL 15971 B3 PL15971 B3 PL 15971B3
- Authority
- PL
- Poland
- Prior art keywords
- feathers
- pests
- fur
- hair
- similar materials
- Prior art date
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- 239000000463 material Substances 0.000 title claims description 7
- 241000607479 Yersinia pestis Species 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- 210000003746 feather Anatomy 0.000 title claims description 3
- 239000004753 textile Substances 0.000 title claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 150000004780 naphthols Chemical class 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 239000007859 condensation product Substances 0.000 description 5
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- YPNZJHFXFVLXSE-UHFFFAOYSA-N 2-chloro-6-methylphenol Chemical compound CC1=CC=CC(Cl)=C1O YPNZJHFXFVLXSE-UHFFFAOYSA-N 0.000 description 2
- HORNXRXVQWOLPJ-UHFFFAOYSA-N 3-chlorophenol Chemical compound OC1=CC=CC(Cl)=C1 HORNXRXVQWOLPJ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000003223 protective agent Substances 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- HOLHYSJJBXSLMV-UHFFFAOYSA-N 2,6-dichlorophenol Chemical compound OC1=C(Cl)C=CC=C1Cl HOLHYSJJBXSLMV-UHFFFAOYSA-N 0.000 description 1
- GZFGOTFRPZRKDS-UHFFFAOYSA-N 4-bromophenol Chemical compound OC1=CC=C(Br)C=C1 GZFGOTFRPZRKDS-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Description
Najdluzszy czas trwania patentu do 22 marca 1943 r« W patencie Nr 10094 ochrania sie spo¬ sób zabezpieczania towarów wlókienni¬ czych, futer, wlosia, piór i materjalów po¬ dobnych od szkodników, który to sposób polega na tern, ze towar traktuje sie pro¬ duktami kondensacji otrzymanemi z alde¬ hydów zapomoca p-chlorofenolu lub p-bro- mofenolu lub ich pochodnych zawierajacych obojetne podstawniki.Wykryto obecnie, ze tak samo jak zwiazki przytoczone w patencie Nr 10094 nadaja sie, jako srodki zabezpieczajace od moli odziezowych i szkodników podobnych, równiez inne zwiazki oksy-dwu lub trójary- lometanowe, które otrzymuje sie w kwasach lub podobnie dzialajacych srodowiskach zapomoca kondensacji aldehydów z innemi niz przytoczone w patencie glównym feno¬ lami, jak równiez z naftolami lub ich po- chodnemi zawierajacemi obojetne podstaw¬ niki. Stopien dzialania poszczególnych sub- stancyj zalezy zarówno od ich budowy jak i sposobu uzycia. Nowe te srodki zabezpie¬ czajace od moli mozna stosowac w taki sam sposób, jak to podano w patencie glównym.Przyklad. 100 kg materjalu przeznaczo¬ nego do uodpornienia przeciwko molom traktuje sie zaleznie od sposdbu barwienia 1—5 kg produktu kondensacji kwasu ben- zaldehydo-o-sulfonowego zapomoca 2 cza-steczek molowych 3-ehlloro-4-iarezolu(Ctiz: : OH : Cl = 1 : 4 ; 3) w roztworze wodnym, •dodajac *£wentuahkfe barwnika mogacego jednoczesnie ciagnac ze srodkiem ochron¬ nym. W razie potrzeby mozna dodac odpo¬ wiedniej soli lulb zasady lub odpowiedniego kwasu. Materjal w ten sposób obrobiony jest odjporny przeciwko molom.Tak samo jalk wymieniona substancja zachowuja sie np. produkty kondensacji o- trzymane z kwasu ibenzaldehydo-o-sulfo- nowego i 6-chloro-2-lkrezolu (CH3 : OH : :Cl= 1:2:6), m-chlorofenolu, p-krezolu, fenolu lub produkty kondensacji aldehydu mrówkowego otrzymane zapomoca : 2,6- dwuchlorofenolu, 6-chloro-2-krezolu, m- chlorofenolu, p-kreziólu, 4-chloro-./-naftolu.Nierozpuszczalne lub trudnorozpuszczal- ne w wodzie produkty kondensacji rozpu¬ szcza sie najlepiej badz w scisle wymaga¬ nej ilosci amonjaku lub zasady hub w od¬ powiednim rozpuszczalniku organicznym i roztwory te stosuje sie w sposób podany w przykladach I lub II patentu Nr 10094 badz substancje te rozdziela na materjale podlegajacym zabezpieczeniu w inny spo¬ sób, np. jako proszek, lub rozdziela sie w srodku emulgujacym. PLThe longest term of the patent until March 22, 1943. Patent No. 10094 protects a method of protecting textile goods, fur, hair, feathers and similar materials from pests, which is based on the fact that the goods are treated proactively. Condensation products obtained from aldehydes using p-chlorophenol or p-bromophenol or their derivatives containing inert substituents. It has now been found that, as well as the compounds mentioned in patent No. 10094, are suitable as protective agents against moths and similar pests , also other oxy-di or trarylmethane compounds, which are obtained in acids or similarly acting environments by the condensation of aldehydes with phenols other than those mentioned in the main patent, as well as with naphthols or their derivatives containing inert substituents. The degree of action of individual substances depends both on their structure and the way of use. These new mothproofing agents can be used in the same way as stated in the main patent. 100 kg of the material intended for resistance to moths is treated, depending on the dyeing method, 1-5 kg of the benzaldehyde-sulfonic acid condensation product with 2 molar molecules of 3-ehlloro-4-iaresol (Ctiz:: OH: Cl = 1: 4; 3) in an aqueous solution, • adding a fan of a dye that can simultaneously drag with the protective agent. If necessary, a suitable salt or base or a suitable acid may be added. The material thus treated is resistant to moths. The same applies as for the substance mentioned, for example, condensation products obtained from ibenzaldehyde-o-sulfonic acid and 6-chloro-2-cresol (CH3: OH: Cl = 1) : 2: 6), m-chlorophenol, p-cresol, phenol or formaldehyde condensation products obtained with: 2,6-dichlorophenol, 6-chloro-2-cresol, m-chlorophenol, p-cresol, 4-chloro. Naphthol. The water-insoluble or sparingly soluble condensation products dissolve best or in the strictly required amount of ammonia or a hub base in a suitable organic solvent, and these solutions are used as described in Examples 1 or 2 of Patent No. 10094 or these substances are distributed on the material to be protected in some other way, for example as a powder, or they are distributed in an emulsifying agent. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL15971B3 true PL15971B3 (en) | 1932-04-30 |
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