PL14765B1 - A way to protect magnesium and its alloys from being bitten by heating baths made of salt alloys. - Google Patents

A way to protect magnesium and its alloys from being bitten by heating baths made of salt alloys. Download PDF

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Publication number
PL14765B1
PL14765B1 PL14765A PL1476530A PL14765B1 PL 14765 B1 PL14765 B1 PL 14765B1 PL 14765 A PL14765 A PL 14765A PL 1476530 A PL1476530 A PL 1476530A PL 14765 B1 PL14765 B1 PL 14765B1
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PL
Poland
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alloys
bitten
salt
way
heating baths
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Application number
PL14765A
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Polish (pl)
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Publication of PL14765B1 publication Critical patent/PL14765B1/en

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Znanym srodkiem do traktowania me¬ tali zapomoca ogrzewania w celu uszlachet¬ nienia ich i t d. sa stopy soli, zwlaszcza stopy saletrowe topiace sie przy niskiej temperaturze, do których zanurza sie me¬ tale przez pewien okres czasu, poczem, odpowiednio do danych warunków, naste¬ puje ochladzanie powolne lub nagle i u- wainianie metali od przyczepionego stopu soli* Doswiadczenia, wykonane w tym kie¬ runku z magnezem, wzglednie ze stopami magnezu (zwlaszcza w postaci blachy) w kapielach saletrowych przy 350 — 400°C, daly wprawdzie pozadane wyniki pod wzgledem fizycznym, jednak z drugiej stro¬ ny wykazaly ze blacha zostala, nawet po krótkotrwalem zetknieciu sie ze stopem saletry, znacznie nagryziona. Nagryzanie wykazuje zmniejszenie sie wagi, wahajace sie, zaleznie od dlugosci trwania doswiad¬ czenia, np. pomiedzy 2,1 a 7,5 g/m2 na go¬ dzine.Doswiadczenia wykazaly, ze przez do¬ datek chromianów potasowcowych, dwu¬ chromianów potasówcowych i fluorków po- tasowcowych do stopu saletry, a to juz w stezeniu niskiem, wyno&zaoem np. 1 — 2%, zapobiega sie zupelnie nagryzaniu, praw¬ dopodobnie przez tworzenie warstwy o- chronnej na metalu, wzglednie na stopie.Dodatek fluorków, wzglednie chromia-nów potasowcowych, stosowano juz w celu unikniecia dzialania nagryzajacego stopów soltkifetfilfetalf <£lesfcie]W pierwszym rzedzie na zelazo i stal. Ze wzgledu jednak na to, ze magnez i jego stopy ulegaja nagryzaniu juz przy zwyklych temperaturach w wiek¬ szym stopniu anizeli metale ciezkie, nie- spodziewanem jest, iz stosunkowo bardzo maly dodatek fluorków i chromianów po¬ tasowcowych do stopów soli zapobiega na¬ gryzaniu metali.Dane podane ponizej uwidoczniaja wy¬ niki, osiagniete zapomoca niniejszego spo¬ sobu.Przyklad I. Czas trwania dzialania po 5 minut, Sklad stopu soli: K N 03 K N 03 + 2% K2CrO± K N 03 + 2% K2Cr207 nagryzanie w g/m2 na godzine — 3,42 + 0 + 0,6 Przyklad II. Czas trwania dzialania po 30 minut.Sklad stopu soli: K N 03 K N 03 + 2% NaF K N 03 + 1% KHF2+KF K N 03 + 2% Lit nagryzanie w g/m2 na godzine — 2,6 + 2,0 + 1,6 + 2,6 Powiekszenie wagi metalu odpowiada tworzeniu sie cienkiej, nierozpuszczalnej w wodzie warstwy ochronnej. PLA known means of treating metals by means of heating in order to refine them, and so on, are salt alloys, especially nitrate alloys melting at low temperature, into which the metals are immersed for a certain period of time, then, depending on the given conditions, there is a slow or sudden cooling and making the metals away from the adhered salt alloy. Experiments made in this direction with magnesium, or with magnesium alloys (especially in the form of sheet metal) in saltpetre baths at 350-400 ° C, Physically desirable results, however, on the other hand, showed that the sheet was, even after brief contact with the nitrate alloy, significantly bitten. Biting shows a decrease in weight, which varies, depending on the duration of the experiment, e.g., between 2.1 and 7.5 g / m2 per hour. Experiments have shown that by the addition of potassium chromate, potassium dichromate and phosphorus fluorides for nitrate alloy, and this already in a low concentration, e.g. 1 - 2%, is completely prevented from biting, possibly by creating a protective layer on the metal or on the alloy. - Potassium carbonates, have already been used to avoid the caustic effect of soltkifetfilfetalf <£ lesfcie] In the first row on iron and steel. However, since magnesium and its alloys burn more at ordinary temperatures than heavy metals, it is surprising that the relatively very little addition of fluorides and postcarbon chromates to the salt alloys prevents metal sticking to metals. The data given below show the results obtained with this method. Example I. Duration of action after 5 minutes, Composition of salt alloy: KN 03 KN 03 + 2% K2CrO ± KN 03 + 2% K2Cr207 bite in g / m2 per hour - 3.42 + 0 + 0.6. Example II. Duration of action 30 minutes. Salt alloy composition: KN 03 KN 03 + 2% NaF KN 03 + 1% KHF2 + KF KN 03 + 2% Lit bite in g / m2 per hour - 2.6 + 2.0 + 1, 6 + 2.6 Increasing the weight of the metal corresponds to the formation of a thin, water-insoluble protective layer. PL

Claims (1)

1. Zastrzezenie patentowe. Sposób zabezpieczania magnezu i jego stopów od nagryzania przez kapiele ogrze¬ wajace ze stopionych soli, zwlaszcza ze stopionych soli saletrowych, znamienny tern, ze do tych stopionych soli dodaje sie chromiany lub dwuchromiany lub flu¬ orki potasowcowe, np. w ilosci od 1 do 2%. I. G. Fair ben indu strie A k t i e n g e s e 11 s c h a f t. Zastepca: Dr. inz. M. Kryzan, rzecznik patentowy. Druk L. Boguslawskiego 1 Ski, Warszawa. PL1. Patent claim. A method of preventing magnesium and its alloys from being bitten by molten salt heating baths, in particular molten nitrate salts, characterized by adding chromates or dichromates or potassium fluorides to these molten salts, for example in an amount from 1 to 2 %. I. G. Fair ben indu strie A k t i e n g e s e 11 s c h a f t. Deputy: Dr. inz. M. Kryzan, patent attorney. Print by L. Boguslawskiego 1 Ski, Warsaw. PL
PL14765A 1930-11-21 A way to protect magnesium and its alloys from being bitten by heating baths made of salt alloys. PL14765B1 (en)

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PL14765B1 true PL14765B1 (en) 1931-11-30

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