PL138627B1 - An alloy of improved resistance against thermal fatigue,especially for rotary furnace construction - Google Patents

An alloy of improved resistance against thermal fatigue,especially for rotary furnace construction Download PDF

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Publication number
PL138627B1
PL138627B1 PL23981182A PL23981182A PL138627B1 PL 138627 B1 PL138627 B1 PL 138627B1 PL 23981182 A PL23981182 A PL 23981182A PL 23981182 A PL23981182 A PL 23981182A PL 138627 B1 PL138627 B1 PL 138627B1
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Poland
Prior art keywords
alloy
weight
resistance against
thermal fatigue
improved resistance
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PL23981182A
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Polish (pl)
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PL239811A1 (en
Inventor
Andrzej Weronski
Slawomir Szewczyk
Krzysztof Skrzydlo
Wojciech Budzynski
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Lubelska Polt
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Priority to PL23981182A priority Critical patent/PL138627B1/en
Publication of PL239811A1 publication Critical patent/PL239811A1/en
Publication of PL138627B1 publication Critical patent/PL138627B1/en

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Przedmiotem wynalazku jest stop o podwyzszo¬ nej odpornosci na zmeczenie cieplne, zwlaszcza do budowy pieców obrotowych, zwlaszcza segmentów plaszcza (carg) pieców do wypalania klinkieru.Dotychczas najczesciej stosowana do tego celu stal weglowa w gatunku ST3S posiada stosunkowo niska wytrzymalosc i wykazuje silna sklonnosc do starzenia po zgniocie, co powoduje nawet dzie¬ sieciokrotne obnizenie udarnosci materialu po pró¬ bie przyspieszonego starzenia Najbardziej zblizo¬ nym skladem do stopu bedacego przedmiotem wy¬ nalazku sa stale kotlowe w gatunku ST36K, ST41K, i ST44K, o skladzie chemicznym zawierajacym wa¬ gowo: mangan minimum 0,55%, krzem 0,15—0,35%, siarke maksimum 0,045%, forfor maksimum 0,045%, chrom maksimum 0,30%, nikiel maksimum 0,30%, miedz maksimum 0,30%, aluminium minimum 0,02% i odpowiednio dla wymienionych gatunków stali wegiel: 0,08—0,16%, 0,12—0,20% i 0,14^0,22% reszta zelazo.Celem wynalazku jest uzyskanie podwyzszenia trwalosci segmentów plaszcza pieców obrotowych do wypalania klinkieru, Cel ten osiagnieto poprzez opracowanie stopu, którego istota polega na tym, ze stop o skladzie wagowym: C = 0,08—0,22%, Mn nie mniej niz 0,55%, Si = 0,15—0,35%, S nie wiecej niz 0,045%, P nie wiecej niz 0,045%, Cr nie wiecej niz 0,30%, Ni nie wiecej niz 0,30%, Cu nie wiecej niz 0,30%, 10 u 2 Al nie mniej niz 0,02%, reszta zelazo, zawiera Nb w ilosci wagowej 0,03—0,40%.Korzystnym skutkiem wynalazku jest to, ze po¬ zwala na zwiekszenie w stopniu nieoczekiwanym odpornosci na zmeczenie cieplne stali, o ponad 70% w stosunku do materialów dotychczas stosowanych.Umozliwi ta podwyzszenie trwalosci segmentów plaszcza pieców obrotowych i wydatnie skróci czas przestoju pieca spowodowany okresowymi remon¬ tami.Podczas dlugotrwalych badan stwierdzono, ze wprowadzenie do stali dodatku niobu w ilosci jak wyzej umozliwilo podwyzszenie granicy plastycz¬ nosci o okolo 80 MPa w stosunku do stali ST3S i zapewnilo utrzymanie wysokiej wartosci Re do temperatury 450°C. Ponadto zastosowanie mikro- dodatku Nb wydatnie ograniczylo sklonnosc stali do starzenia po zgniocie. Korzystny wplyw dodatku niobu na wlasnosci wytrzymalosciowe stali jest wynikiem jego duzego powinowactwa chemicznego do wegla i azotu, co sprawia, ze wegliki i wegliko- -azotki niobu sa bardzo trwale. Zwiazanie przez niob miedzywezlowych atomów azotu w znacznym stopniu ograniczylo efekty starzenia stali po zgnio¬ cie. Z drugiej strony utworzenie stabilnych wegli¬ ków i wegliko-azotków niobu o, duzym stopniu dyspersji hamuje rozrost austenitu, co z kolei ula¬ twia uzyskanie drobnoziarnistej struktury wtórnej.W efekcie uzyskano wyrazny wzrost granicy pla¬ stycznosci stali. 138 6273 133.827 4 Przyklad. Wykonana wytop stali o nastepu¬ jacym skladzie chemicznym: wegiel 0,10% wagowo, mangan 0,67% wagowo, krzem 0,26% wagowo, fo¬ sfor 0,012% wagowo, siarka 0,010% wagowo, chrom 0,03% wagowo, nikiel 0,11% wagowo, miedz 0,03% wagowo, aluminium 0,06% wagowo, niob 0,064% wagowo, reszta zelazo. Z wlewka po przekuciu wykonano droga obróbki mechanicznej próbki o wymiarach 0 180/120x30 mm do modelowania badan zmeczenia cieplnego. W stanie normalizoa* waa&m ppófoki modelowe uzyskane z tego materia¬ lu posiadaly odpornosc na zmeczenie cieplne wy- wynoszaca srednio 1450 cykli^ przy; sredniej; tiow* losci dotychczas stosowanego* materialu w gatunku ST3S wynoszacej 840 cykli.Zastrzezenie patentowe Stop o podwyzszonej odpornosci na zmeczenie cieplne, zwlaszcza da budowy pieców obrotowych, o skladzie wagpwym: C = 0,08—0,022%,, Mn nie mniej mzr 0;55%, Si = 0,15—0,35%, S nie wiecej niz 0,045%, P nie wiecej niz 0,045%, Cr nie wiecej niz 0,3G%; Al nie mniej niz 0,02%, reszta zelazo, zna¬ mienny tym, ze zawiera Nb w ilosci wagowej 0,03—0,40%. 5 10L OZGraf. Z.P. Dz-WO, z. 466 (95+15) 10.86 Cena 100 ii PLThe subject of the invention is an alloy with higher resistance to heat fatigue, especially for the construction of rotary kilns, especially shell segments (carg) of clinker kilns. Until now, the most commonly used for this purpose carbon steel of the ST3S grade has relatively low strength and shows a strong tendency to aging after crushing, which causes even a tenfold reduction in the impact strength of the material after an accelerated aging test. The most similar composition to the alloy being the subject of the invention are boiler steels of the grades ST36K, ST41K, and ST44K, with a chemical composition containing weight : manganese minimum 0.55%, silicon 0.15-0.35%, sulfur maximum 0.045%, phosphorus maximum 0.045%, chromium maximum 0.30%, nickel maximum 0.30%, copper maximum 0.30%, aluminum minimum 0.02% and, respectively, for the above-mentioned steel grades: carbon: 0.08-0.16%, 0.12-0.20% and 0.14 ^ 0.22% the rest of the iron. The aim of the invention is to increase the durability of the mantle segments rotary kilns for burning clinker, This goal was achieved by developing an alloy, the essence of which is that the alloy has the following weight composition: C = 0.08-0.22%, Mn not less than 0.55%, Si = 0.15-0 , 35%, S no more than 0.045%, P no more than 0.045%, Cr no more than 0.30%, Ni no more than 0.30%, Cu no more than 0.30%, 10 u 2 Al no less than 0.02%, the remainder iron contains Nb in an amount by weight of 0.03-0.40%. A favorable effect of the invention is that it allows to increase unexpectedly the heat fatigue resistance of steel by more than 70% in This will make it possible to increase the durability of the mantle segments of rotary kilns and significantly reduce the downtime of the furnace caused by periodic repairs. During long-term studies it was found that the introduction of niobium in the amount above allowed to increase the yield strength by about 80 MPa in relation to ST3S steel and ensured the maintenance of high Re value up to the temperature of 450 ° C. Moreover, the application of the micro-additive of Nb significantly reduced the tendency of the steel to aging after working out. The beneficial effect of niobium addition on the strength properties of steel is the result of its high chemical affinity for carbon and nitrogen, which makes the carbons and carbons of niobium very durable. The binding of interstitial nitrogen atoms by niobium significantly reduced the effects of aging of the steel after crushing. On the other hand, the formation of stable carbides and niobium carbonitrides with a high degree of dispersion inhibits the growth of austenite, which in turn facilitates the obtaining of a fine-grained secondary structure. As a result, a significant increase in the yield limit of the steel was obtained. 138 6273 133.827 4 Ex. Steel smelting made of the following chemical composition: carbon 0.10% by weight, manganese 0.67% by weight, silicon 0.26% by weight, phosphorus 0.012% by weight, sulfur 0.010% by weight, chromium 0.03% by weight, Nickel 0.11% by weight, copper 0.03% by weight, aluminum 0.06% by weight, niobium 0.064% by weight, the rest iron. After forging, the ingot was used for machining a sample with dimensions of 0 180/120 x 30 mm for modeling heat fatigue tests. In the normalized state, the model half-shells obtained from this material had a thermal fatigue resistance of 1,450 cycles on average; medium; The fate of the material used so far in the ST3S grade, amounting to 840 cycles. Patent claim An alloy with increased resistance to heat fatigue, especially due to the construction of rotary kilns, with a weight composition: C = 0.08-0.022%, Mn not less mfr 0; 55%, Si = 0.15-0.35%, S not more than 0.045%, P not more than 0.045%, Cr not more than 0.3G%; Al not less than 0.02%, the remainder is iron, characterized in that it contains Nb in an amount by weight of 0.03-0.40%. 5 10L OZGraf. Z.P. Dz-WO, issue 466 (95 + 15) 10.86 Price 100 II PL

Claims (1)

1. Zastrzezenie patentowe Stop o podwyzszonej odpornosci na zmeczenie cieplne, zwlaszcza da budowy pieców obrotowych, o skladzie wagpwym: C = 0,08—0,022%,, Mn nie mniej mzr 0;55%, Si = 0,15—0,35%, S nie wiecej niz 0,045%, P nie wiecej niz 0,045%, Cr nie wiecej niz 0,3G%; Al nie mniej niz 0,02%, reszta zelazo, zna¬ mienny tym, ze zawiera Nb w ilosci wagowej 0,03—0,40%. 5 10L OZGraf. Z.P. Dz-WO, z. 466 (95+15) 10.86 Cena 100 ii PL1. Patent claim An alloy with increased resistance to heat fatigue, especially for the construction of rotary furnaces, with a weight composition: C = 0.08-0.022%, Mn not less mzr 0; 55%, Si = 0.15-0.35 %, S not more than 0.045%, P not more than 0.045%, Cr not more than 0.3G%; Al not less than 0.02%, the remainder is iron, characterized in that it contains Nb in an amount by weight of 0.03-0.40%. 5 10L OZGraf. Z.P. Dz-WO, issue 466 (95 + 15) 10.86 Price 100 II PL
PL23981182A 1982-12-27 1982-12-27 An alloy of improved resistance against thermal fatigue,especially for rotary furnace construction PL138627B1 (en)

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PL23981182A PL138627B1 (en) 1982-12-27 1982-12-27 An alloy of improved resistance against thermal fatigue,especially for rotary furnace construction

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PL23981182A PL138627B1 (en) 1982-12-27 1982-12-27 An alloy of improved resistance against thermal fatigue,especially for rotary furnace construction

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PL138627B1 true PL138627B1 (en) 1986-10-31

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