OA17727A - Construction panel having improved fixing strengh and method for the manufacture thereof. - Google Patents
Construction panel having improved fixing strengh and method for the manufacture thereof. Download PDFInfo
- Publication number
- OA17727A OA17727A OA1201500464 OA17727A OA 17727 A OA17727 A OA 17727A OA 1201500464 OA1201500464 OA 1201500464 OA 17727 A OA17727 A OA 17727A
- Authority
- OA
- OAPI
- Prior art keywords
- fibres
- starch
- plasterboard
- gypsum
- amount
- Prior art date
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- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 238000010276 construction Methods 0.000 title 1
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 64
- 239000010440 gypsum Substances 0.000 claims abstract description 64
- 239000000654 additive Substances 0.000 claims abstract description 17
- 230000000996 additive Effects 0.000 claims abstract description 17
- 239000011159 matrix material Substances 0.000 claims abstract description 13
- 229920002472 Starch Polymers 0.000 claims description 92
- 235000019698 starch Nutrition 0.000 claims description 92
- 239000008107 starch Substances 0.000 claims description 83
- 239000002002 slurry Substances 0.000 claims description 29
- 239000003365 glass fiber Substances 0.000 claims description 24
- 239000000835 fiber Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 17
- 230000001617 migratory Effects 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 229920003043 Cellulose fiber Polymers 0.000 claims description 7
- -1 Bakélite Polymers 0.000 claims description 6
- 229920000126 Latex Polymers 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 6
- 229920001353 Dextrin Polymers 0.000 claims description 5
- 239000004375 Dextrin Substances 0.000 claims description 5
- 229920000881 Modified starch Polymers 0.000 claims description 5
- 235000019425 dextrin Nutrition 0.000 claims description 5
- 239000002023 wood Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 239000004627 regenerated cellulose Substances 0.000 claims description 3
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims description 2
- 229920001225 Polyester resin Polymers 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- 229920002522 Wood fibre Polymers 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 150000002148 esters Chemical group 0.000 claims description 2
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 2
- 239000011152 fibreglass Substances 0.000 claims description 2
- 229920001903 high density polyethylene Polymers 0.000 claims description 2
- 239000004700 high-density polyethylene Substances 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 235000010981 methylcellulose Nutrition 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- 229920002225 poly(styrene-co-butadiene) Polymers 0.000 claims description 2
- 229920001888 polyacrylic acid Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 16
- 235000013339 cereals Nutrition 0.000 description 10
- 239000011120 plywood Substances 0.000 description 8
- 229920002261 Corn starch Polymers 0.000 description 7
- 235000019759 Maize starch Nutrition 0.000 description 7
- ASCUXPQGEXGEMJ-GPLGTHOPSA-N [(2R,3S,4S,5R,6S)-3,4,5-triacetyloxy-6-[[(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(4-methylanilino)oxan-2-yl]methoxy]oxan-2-yl]methyl acetate Chemical compound CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H](COC(=O)C)O[C@@H]1OC[C@@H]1[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](NC=2C=CC(C)=CC=2)O1 ASCUXPQGEXGEMJ-GPLGTHOPSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 240000008042 Zea mays Species 0.000 description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 238000005192 partition Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920000433 Lyocell Polymers 0.000 description 3
- 235000005822 corn Nutrition 0.000 description 3
- 235000005824 corn Nutrition 0.000 description 3
- 230000001965 increased Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000000717 retained Effects 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910021487 silica fume Inorganic materials 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 230000037250 Clearance Effects 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 240000001016 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 240000000359 Triticum dicoccon Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 230000035512 clearance Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
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- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 239000000789 fastener Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
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- 230000005012 migration Effects 0.000 description 1
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- 238000006011 modification reaction Methods 0.000 description 1
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- 229920005615 natural polymer Polymers 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
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- 238000000518 rheometry Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
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Abstract
A plasterboard comprises a gypsum matrix having fibres embedded therein. The plasterboard optionally has a backing lamina attached to one of the faces thereof. The gypsum matrix of the plasterboard optionally comprises a polymetric additive.
Description
The présent invention relates to panels for use in building construction and the manufacture thereof. In particular, the présent invention relates to panels for providing partitions to which items such as sinks, télévisions, or radiators may be affixed.
Light-weight panels such as plasterboard (e.g. gypsum plasterboard), polystyrène board and fibreboard are commonly used to provide partitions within buildings. Their advantages for this application include the fact that they are light and quick to install.
However, in certain cases, such light-weight panels may hâve the drawback that they are not strong enough to support fixtures (e.g. sinks, télévisions, radiators, fire extinguishers, shelves and any other item that requires attachment to the panel). In such cases, the weight ofthe fixture may cause thefixing means (e.g. screws) to be pulled out ofthe panel, such that the fixture falls away from the partition.
Typically, this problem has been addressed by providing plywood sheets to increase the fixing strength ofthe panel. In this case, the plywood sheet is provided on the side ofthe panel opposite to that on which the fixture is to be located. The plywood sheet may provide increased strength for retaining one or more fixing means (e.g. screws) employed to secure the fixture to the panel. Typically, the plywood sheet is positioned within the partition framework, and the plasterboard then fixed to the plywood, so that it lies outsidè the partition . framework.
As an alternative, métal support means may be provided. These may comprise fixing plates, channels, straps, or métal fasteners. As is the case for plywood sheets, the métal support means are generally positioned on the side of the panel opposite that to which the fixture is to be secured, and act to receive and secure fixing means, e.g. fixing screws, that are used to attach the fixture to the panel.
Both these arrangements hâve the disadvantage that they require the panels and the additional supporting components to be affixed to each other on-site. Moreover, when métal support means are used, a plurality of such support means may be needed to support the full set of fixing means required to secure the fixture to the panel. Thus, the installation process may be time-consuming and expensive.
Furthermore, the addition of métal support means or plywood sheets increases the weight and thickness of the partition, and/or results in a réduction in cavity wall space. In general, the plywood itself must be eut to size on site, thus increasing the time required for installation and possibly leading to the release of dust and potentially harmful components.
Therefore, there is a need to provide improved panels that are able to retain fixing means and support fixtures, and that do not require time-consuming installation processes.
It has been found that by providing a panel comprising a substrate board having a polymerbased lamina secured to one of its faces, an improvement in the ability of the panel to retain fixing means may be achieved. However, such panels may be susceptible to screw overtightening, whereby even a small additional rotation of a screw after peak tightening torque has been achieved may resuit in stripping of the inner surface of the screw hole, with the resuit that the screw is no longer retained in the panel. As a resuit, it may be difficult to insert screw fixings into the panel in a reliable and reproducible manner.
It has been found that, in the case where the substrate board is a gypsum plasterboard, this problem may be reduced by selecting a plasterboard that includes at least a fibre additive.
Therefore, in a first aspect, the présent invention may provide a panel comprising a plasterboard, the plasterboard having a backing lamina attached to one ofthefaces thereof, the plasterboard comprising a gypsum matrix having fibres embedded therein, in an amount of at least 1 wt% relative to the gypsum.
Preferably, the lamina is a polymer-based lamina, typically comprising substantially a material selected from the group comprising: PVC, HDPE, Nylon, polycarbonate, Bakélite, polypropylene, acetal, and fibreglass.
Typically, the lamina has a thickness of at least 1 mm. In general, the lamina is glued to the plasterboard, e.g. by means of a polymer-based glue, such as an acrylic glue.
Preferably, the gypsum matrix further comprises a starch additive in an amount of at least 1 wt% relative to the gypsum, preferably 2 wt%, more preferably 2.5 wt%.
Typically, the fibres are présent in an amount of at least 2 wt% relative to the gypsum, preferably 2.5 wt%
In general, the fibres are selected from a group comprising glass fibres, wood fibres, fibres derived from wood, and mixtures thereof. In certain embodiments, however, the fibres may be synthetic polymer fibres.
For example, the fibres may be regenerated cellulose fibres, such as lyocell, that are manufactured from dissolved wood pulp. In this case, the fibres typically hâve one or more of the following properties:
• an average length that is greater than 0.1 mm, preferably greater than 0.2 mm;
• an average length that is less than 0.5 mm, preferably less than 0.4 mm;
• an average diameter that is less than 20 micron, preferably less than 15 micron.
In certain embodiments, the fibres may be présent within the plasterboard in the form of particles of agglomerated fibres, for example, paper particles and/or wood particles (for example, fine sawdust particles). In general, these particles are irregular in shape. The particles typically hâve one or more ofthe following properties.· • their maximum dimension is preferably greater than 0.5 mm, preferably greater than mm, more preferably greater than 1.5 mm;
• their maximum dimension is less than 3 mm, preferably less than 2.5 mm;
» the average length of the fibres within the particles is greater than 1 mm;
» the average length of the fibres within the particles is less than 15 mm;
• the average diameter of the fibres within the particles is greater than 1 micron, preferably greater than 5 micron;
• the average diameter of the fibres within the particles is less than 50 micron, preferably less than 30 micron.
The fibres follow a convoluted path such that they are contained within the boundaries ofthe particle.
In the case that the fibres are glass fibres, the fibres may hâve one or more ofthe following properties:
• an average length greater than 10 mm, preferably greater than 15 mm;
• an average length less than 50 mm, preferably less than 30 mm;
• an average diameter greater than 20 micron, preferably greater than 30 micron;
• an average diameter less than 80 micron, preferably less than 70 micron.
Preferably, the starch comprises a non-migratory starch, that is, a starch compound that is retained within the core of the plasterboard and does not migrate to the board surface. Such starches are distinguished from migratory starches, which typically migrate to the surface of the plasterboard and serve the purpose of improving the bonding of the plasterboard core to the paperfacing. However, the plasterboard may additionally comprise such migratory starches.
Non-migratory starches may be provided in a number of different ways, as is weil-known in the art. For example, the starch may comprise dextrin, as described in US7708847, which is hereby incorporated by reference.
In other cases, the starch may be a pre-gelatinised starch.
In certain embodiments, the starch may be selected to hâve a low viscosity (e.g. a Brookfield viscosity of less than 60 cps) at a température of less than 60°C, and a much higher viscosity (e.g. a Brookfield viscosity of over 10000 cps) at a température of 70°C. Such starches are described in e.g. US8252110, which is hereby incorporated by reference. These starches hâve a rheology that is strongly temperature-dependent: it is thought that, at low températures, the starch may be dispersed in the core in order to penetrate into the inter-crystalline spaces. As soon as the température is above 60°C, the viscosity of the starch increases rapidly up to a very high level to ensure that the starch actually remains in the core and does not migrate to the core/facing interface.
In certain embodiments, the starch is a substituted starch, such as described in US7048794, which is hereby incorporated by reference. Substituted starches are starch dérivatives that hâve been chemically reacted to replace one or more of the hydroxyl functional groups. Typically, the process involves éthérification or estérification of a starch or modified starch which appends ether or ester linkages along the starch polymer backbone. This process is distinct from other modifications typically made to starches such as oxidization, acidthinning, cross-linking, and pre-gelatinisation, although such processes may also be applied to the starch, prior to or after substitution with one or more types of functionalities.
It is thought that substituted starches act as efficient binders for the inorganic phase of plasterboards, e.g. gypsum, thus increasing the core strength of the plasterboard. Preferably, the starch is insoluble in cold water, but dissolves at a higher processing température during forming, setting, ordrying ofthe plasterboard. This is thought to limit excessive migration ofthe starch, so that it remains in the plasterboard core, to provide a binderforthe gypsum crystals.
The substituted starch may comprise hydroxyethylated, hydroxypropylated, and/or acetylated starch. Preferably, the starch is a hydroxyethylated starch.
The starch may be derived from e.g. potato, tapioca, or corn. Preferably, the starch is derived from corn.
In a second aspect, the présent invention may provide a plasterboard comprising a gypsum matrix, the gypsum matrix having fibres embedded therein, the fibres being présent in an amount of at least 1 wt% relative to the gypsum, the gypsum matrix further comprising a polymeric additive, the polymeric additive being présent in an amount of at least 1 wt% relative to the gypsum.
Preferably, the fibres are présent in an amount of at least 3 wt% relative to the gypsum, more preferably at least 4 wt%, most preferably at least 4.5 wt%. Preferably, the polymeric additive is présent in an amount of at least 3 wt% relative to the gypsum, more preferably at least 4 wt%, most preferably at least 4.5 wt%. It is thought that these relatively high levels of fibre and polymeric additive may provide the plasterboard with sufficient ability to retain fixing means that no backing lamina is required.
By omitting a backing lamina, it may be possible to provide a panel having adéquate fixing strength at a relatively lower cost, due to reduced raw material costs and greater ease of manufacture. Additionally, the panel may be easier to recycle, since the requirement to separate the lamina from the plasterboard may be avoided.
Typically the polymeric additive is selected from group comprising polyvinyl acetate, poly vinyl acetate-ethylene co-polymer, polyvinyl pyrrolidone crosslinked with polystyrène sulfonate, polyvinyl alcohol, methyl cellulose, hydroxyethyl methyl cellulose, styrenebutadiene copolymer latex, acrylic ester latex, acrylic copolymer latex, polyester resin, epoxy resin, polymethyl méthacrylate, polyacrylic acid, cationic starch, ethylated starch, dextrin and mixtures thereof.
In general, the polymeric additive is a starch.
Preferably, in the case that the starch is présent at a level of at least 3 wt% relative to the gypsum, the starch is a migratory starch. Surprisingly, it has been found that at these relatively high starch contents, even a migratory starch will be retained within the plasterboard core in sufficient amounts so as to enhance the fixing strength of the plasterboard. At the same time, the migratory starch may aid in improving the bonding of the plasterboard core to a paperfacing (if used), so that there is no need to include multiple starch varieties within the plasterboard.
In the case that the starch is présent at a level of at least 3 wt% relative to the gypsum, it is generally preferred that the starch is a native starch, rather than a pre-gelatinised starch. At these relatively high starch levels, pre-gelatinised starch is considered to impart excessive viscosity to the gypsum slurry.
Typically, the starch may be derived from e.g. wheat, corn, maize, or rice. At starch levels of 3 wt% or more relative to the gypsum, potato starch is less preferred, since its relatively large grain size is considered to hâve a deleterious effect on water distribution within the gypsum slurry.
Preferably, the fibres are glass fibres.
Preferably, in the case that the fibres are présent at a level of at least 3 wt% relative to the gypsum, the fibre length is less than 10 mm, more preferably less than 8 mm. It is thought . that longer fibres are difficult to process in these relatively large amounts within a gypsum slurry. Typically, the fibre length is greater than 4 mm.
Typically, the fibre diameter is in the range 5-50 micron, preferably 10-30 micron, more preferably 10-20 micron.
In certain embodiments, the fibres may be organic fibres, e.g. natural polymer fibres, such as those derived from wood, or synthetic polymer fibres.
In certain embodiments, the plasterboard may contain silicone oil or wax and/or a biocide.
In general, the plasterboard has paperfacings. However, in certain cases, the plasterboard may hâve a mat partially or fully embedded at its surface, for example, a glass fibre mat, which may be pre-coated. Additionally or alternatively, the plasterboard may hâve a thermoplastic coating or a polymeric film (such as polyester) on one or more of its faces.
In a third aspect, the présent invention may provide a method of manufacturing a plasterboard according to the second aspect ofthe invention, comprising the step of adding starch to a gypsum slurry, wherein the grain size ofthe starch is less than 40 micron.
Preferably, the grain size ofthe starch is less than 30 micron. It is thoughtthat a large starch grain size results in an uneven water distribution within the slurry, such that more water is required overall.
In a fourth aspect, the présent invention may provide a method of manufacturing a plasterboard according to the second aspect ofthe invention, comprising the steps of adding starch and fibre to a gypsum slurry, shaping the slurry to form a plasterboard and drying the plasterboard at a température in the range 140-180°C.
The plasterboard manufactured through the methods ofthe third orfourth aspects ofthe invention may hâve one or more ofthe optional features ofthe plasterboard according to the second aspect ofthe invention.
The invention will now be described by way of example with reference to the following Figures in which:
Figure 1 is a schematic graph of torque against rotation angle.
Figure 2 is a schematic graph of torque against rotation angle for Example 1 and Comparative Examples 1 and 2.
Examples 1-3
Gypsum plasterboards were prepared from the compositions described below. A 2mm sheet of PVC was glued to one face of each plasterboard using Aquagrip 29860 glue.
Example 1
A gypsum plasterboard was prepared from a slurry containing stucco and desulphogypsum (DSG), the DSG being présent in an amount of 31 wt% relative to the stucco. The slurry additionally contained the following ingrédients:
• ethylated starch in an amount of 2.9 wt% relative to the amount of stucco and DSG (the starch is available from Grain Processing Corporation under the trade name Coatmaster K57F);
• glass fibre in an amount of 3.2 wt% relative to the amount of stucco and DSG.
Example 2
A gypsum plasterboard was prepared from a slurry containing stucco and desulphogypsum (DSG), the DSG being présent in an amount of 31wt% relative to the stucco. The slurry additionally contained the following ingrédients:
• glass fibre in an amount of 0.46 wt% relative to the stucco and DSG;
o 0.85 wt% Collofilm 120 starch;
» ethylated starch in an amount of 2.9 wt% relative to the amount of stucco and DSG (the starch is available from Grain Processing Corporation under the trade name Coatmaster K57F);
» Cellulose fibre in an amount of 3.7 wt% relative to the amount of stucco and DSG (the cellulose fibre is available from Lenzing under the trade name Tencel FCP
10/300/M. The fibres hâve an average length of 0.3 mm, measured via MORFI fibre analysis, and a diameter of 10 micron).
Example 3
A gypsum plasterboard was prepared from a slurry containing stucco and desulphogypsum (DSG), the DSG being présent in an amount of 31 wt% relative to the stucco. The slurry additional contained the following ingrédients:
• glass fibre in an amount of 0.46 wt% relative to the stucco and DSG;
• 0.85 wt% Collofilm 120 starch;
• ethylated starch in an amount of 4.4 wt% relative to the amount of stucco and DSG (the starch is available from Grain Processing Corporation under the trade name Coatmaster K57F);
® Cellulose fibre in an amount of 5.5 wt% relative to the amount of stucco and DSG (the cellulose fibre is available from Lenzing under the trade name Tencel FCP 10/300/M. The fibres hâve an average length of 0.3 mm, measured via MORFI fibre analysis, and a diameter of 10 micron).
Examples 4-12
Gypsum plasterboards were prepared from the compositions described below.
Example 4
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
• stucco;
® glass fibre in an amount of 5 wt% relative to the stucco, the fibre length being about 6mm;
® acid hydrolysed maize starch (from Tate & Lyle) in an amount of 5 wt% relative to the stucco.
The average screw pull-out strength, measured on four samples, was 617N.
Example 5
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
« stucco;
« glass fibre in an amount of 5 wt% relative to the stucco, the fibre length being about 6mm;
• ethylated starch in an amount of 5 wt% relative to the amount of stucco (the starch is available from Grain Processing Corporation under the trade name Coatmaster K57F).
The average screw pull-out strength, measured on four samples, was 773N.
Example 6
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
® stucco;
• glass fibre in an amount of 5 wt% relative to the stucco, the fibre length being about 6mm;
• dextrin in an amount of 5 wt% relative to the stucco.
The average screw pull-out strength, measured on four samples, was 579N.
Example 7
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
® stucco;
• glass fibre in an amount of 5 wt% relative to the stucco, the fibre length being about 6mm;
• maize starch in an amount of 5 wt% relative to the stucco (this is a migratory starch).
The average screw pull-out strength, measured on four samples, was 569N.
Example 8
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
• stucco;
• glass fibre in an amount of 5 wt% relative to the stucco, the fibre length being about 6mm;
• acid hydrolysed maize starch (from Tate & Lyle) in an amount of 5 wt% relative to the stucco;
• microsilica in an amount of 20 kg/m3.
The average screw pull-out strength, measured on four samples, was 653N.
Example 9
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
• stucco; · » glass fibre in an amount of 5 wt% relative to the stucco, the fibre length being about 6mm;
» ethylated starch in an amount of 5 wt% relative to the amount of stucco (the starch is available from Grain Processing Corporation under the trade name Coatmaster K57F);
® microsilica in an amount of 20 kg/m3.
The average screw pull-out strength, measured on four samples, was 706N.
Example 10
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
• stucco;
• glass fibre in an amount of 5 wt% relative to the stucco, the fibre length being about 6mm;
• acid hydrolysed maize starch (from Tate & Lyle) in an amount of 5 wt% relative to the stucco;
« silicone oil in an amount of 1 wt% relative to the stucco.
The average screw pull-out strength, measured on four samples, was 541 N.
Example 11
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
• stucco;
• glass fibre in an amount of 3 wt% relative to the stucco, the fibre length being about 6 mm;
» acid hydrolysed maize starch (from Tate & Lyle) in an amount of 3 wt% relative to the stucco.
Example 12
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
<» stucco;
« glass fibre in an amount of 4 wt% relative to the stucco, the fibre length being about 6 mm;
• polyvinyl acetate in an amount of 5 wt% relative to the stucco.
Comparative examples 1-2
Gypsum plasterboards were prepared from the compositions described below. A 2mm sheet of PVC was glued to one face of each plasterboard using Aquagrip 29860 glue.
Comparative example 1
A gypsum plasterboard was prepared from a slurry containing stucco and desulphogypsum (DSG), the DSG being présent in an amount of 31 wt% relative to the stucco. The slurry additionally contained the following ingrédients:
• glass fibre in an amount of 0.46 wt% relative to the stucco and DSG;
» 0.85 wt% Collofilm 120 starch.
Comparative example 2
A gypsum plasterboard was prepared from a slurry containing stucco and desulphogypsum (DSG), the DSG being présent in an amount of 31 wt% relative to the stucco. The slurry additionally contained the following ingrédients:
• glass fibre in an amount of 0.46 wt% relative to the stucco and DSG;
• 0.85 wt% Collofilm 120 starch;
• ethylated starch in an amount of 2.9 wt% relative to the amount of stucco and DSG (the starch is available from Grain Processing Corporation under the trade name Coatmaster K57F).
Comparative examples 3-4
Gypsum plasterboards were prepared from the compositions described below.
Comparative example 3
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
• stucco;
• glass fibre in an amount of 2 wt% relative to the stucco, the fibre length being about 6mm;
• acid hydrolysed maize starch (from Tate & Lyle) in an amount of 5 wt% relative to the stucco;
The average screw pull-out strength, measured on four samples, was 458N.
Comparative example 4
A gypsum plasterboard was prepared from a slurry containing the following ingrédients:
« stucco;
• glass fibre in an amount of 2 wt% relative to the stucco, the fibre length being about 6mm;
• acid hydrolysed maize starch (from Tate & Lyle) in an amount of 5 wt% relative to the stucco;
• silicone oil in an amount of 1 wt% relative to the stucco.
The average screw pull-out strength, measured on four samples, was 41 ON.
Comparative Example 5
Comparative Example 5 is a gypsum fibreboard comprising paper fibres bound by a calcium sulphate binder (Rigidur board from British Gypsum).
Quantification of résistance to overtightening
To quantify the résistance to overtightening ofthe panels ofthe Examples 1-3 and Comparative Examples 1 and 2, a graph of torque against rotation angle was plotted for a screw being inserted into each panel. The screw was a No. 10 woodscrew having a length of 50 mm and a diameter of 5 mm. An example of such a graph is shown in Figure 1.
The area below the curve was then calculated between the rotation angle of zéro (corresponding to peak torque) and 7.85 radians. This area is considered to give an indication ofthe work done in tightening the screw after peaktorque has been attained. It is thought that the greater the work done after peak torque has been attained, the lower the risk of overtightening the screw and stripping material from the inner surface ofthe screw hole.
The peak torque was also measured for each board. The results are set out in Table 1:
Table 1
Example | Work done (J) | Peak torque (Nm) |
Example 1 | 23.5 | 3.5 |
Example 2 | 29.7 | 4.6 |
Example 3 | 32.4 | 4.9 |
Comparative Example 1 | 18.7 | 3.2 |
Comparative Example 2 | 21.0 | 3.3 |
Figure 2 shows a graph of torque against rotation angle for a screw being inserted into a panel according to Example 1 and Comparative Examples 1 and 2 respectively. This shows that the panel of Example 1 retains a higher torque (after peak torque has been attained) than the panels of the Comparative Examples. This is considered to indicate an improved ability of the panel to withstand stripping of a screw hole formed therein.
Impact tests
To quantify the impact résistance of plasterboard, a 500g steel bail having a diameter of 50 mm is dropped down a vertical 6 m pipe onto 200 mm x 200 mm sample of the board. The sample is supported in a horizontal orientation on the rim of a drainage hopper. The drainage hopper is generally cylindrical and is positioned such that its longitudinal axis coïncides with that of the pipe. The internai diameter of the drainage hopper is 115 mm and the external diameter is 122 mm. There is at least 40 mm clearance between the top of the hopper and the bottom of the pipe.
The depth of the indent produced in the board sample is measured and the results are set out in Table 2:
Table 2
Example | Impact depth (mm) |
Example 4 | 5.8 |
Example 11 | 2.7 |
Example 12 | 3.1 |
Comparative Example 1 | 11.3 |
Comparative Example 5 | 9.3 |
Claims (27)
1. A panel comprising a plasterboard, the plasterboard having a backing lamina attached to one of the faces thereof, the plasterboard comprising a gypsum matrix having fibres embedded therein in an amount of at least 1 wt% relative to the gypsum.
2. A panel according to claim 1, wherein the gypsum matrix further comprises a starch additive, the starch additive being présent in an amount of at least 1 wt% relative to the gypsum.
3. A panel according to claim 2, wherein the starch additive is présent in the gypsum matrix of the plasterboard in an amount of at least 2 wt% relative to the gypsum.
4. A panel according to any one of the preceding claims, wherein the fibres are présent in the gypsum matrix of the plasterboard in an amount of at least 2 wt% relative to the gypsum.
5. A panel according to any one of the preceding claims, in which the fibres are selected from a group comprising glass fibres, wood fibres, fibres derived from wood (such as regenerated cellulose fibres), and mixtures thereof.
6. A panel according to claim 5, wherein the fibres are regenerated cellulose fibres and further wherein the average length of the fibres lies in the range 0.1-0.5 mm and / or the average diameter of the fibres is below 20 micron.
7. A panel according to any one of claims 1-6, wherein the fibres are présent within the board in the form of particles of agglomerated fibres, such as paper particles or wood particles.
8. A panel according to claim 7, wherein the maximum dimension ofthe particles is in the range 0.5-3 mm and / orthe average length ofthe fibres within the particles is in the range 1-15 mm and / orthe average diameter ofthe fibres within the particles is in the range 1-50 micron.
9. A panel according to claim 5, wherein the fibres are glass fibres and further wherein the average length ofthe fibres lies in the range 10-50 mm and / orthe average diameter of the fibres lies in the range 5-50 micron.
10. A panel according to claim 5, wherein the fibres are glass fibres and further wherein the average length ofthe fibres lies in the range 10-50 mm and / or the average diameter of the fibres lies in the range 20-80 micron.
11. A panel according to any one of claims 2-10, wherein the starch is a non-migratory starch.
12. A panel according to claim 11, wherein the starch is selected from the group comprising: dextrin, pre-gelatinised starch, substituted starch, and starch having a Brookfield viscosity of less than 60 cps at a température below 60°C and a Brookfield viscosity greater than 10,000 cps at a température of 70°C.
13. A panel according to claim 11 or 12, wherein the starch is a substituted starch and the substituent group is an ether substituent group or an ester substituent group.
14. A panel according to any one ofthe preceding claims, wherein the lamina comprises substantially a material selected from the group comprising: PVC, HDPE, Nylon, polycarbonate, Bakélite, polypropylene, acetal, and fibreglass.
15. A panel according to any one ofthe preceding daims, wherein the lamina has a thickness of at least 1 mm.
16. A plasterboard comprising a gypsum matrix having fibres embedded therein in an amount of at least 1 wt% relative to the gypsum, the gypsum matrix further comprising a polymeric additive, the polymeric additive being présent in an amount of at least 1 wt% relative to the gypsum.
17. A plasterboard according to claim 16, wherein the fibres are présent in an amount of at least 3 wt% relative to the gypsum, and the polymeric additive is présent in an amount of at least 3 wt% relative to the gypsum.
18. A plasterboard according to claim 16 or claim 17, wherein the polymeric additive is selected from group comprising polyvinyl acetate, poly vinyl acetate-ethylene co-polymer, polyvinyl pyrrolidone crosslinked with polystyrène sulfonate, polyvinyl alcohol, methyl cellulose, hydroxyethyl methyl cellulose, styrenebutadiene copolymer latex, acrylic ester latex, acrylic copolymer latex, polyester resin, epoxy resin, polymethyl méthacrylate, polyacrylic acid, cationic starch, ethylated starch, dextrin and mixtures thereof.
19. A plasterboard according to any one of daims 16 to 18, wherein the polymeric additive is a starch.
20. A plasterboard according to claim 19, wherein the starch is a migratory starch.
21. A plasterboard according to claim 19, wherein the starch is an acid-thinned starch.
22. A plasterboard according to any one of daims 19-21, wherein the starch is a native starch.
23. A plasterboard according to any one of claims 16 to 22, wherein the fibres are glass fibres.
5
24. A plasterboard according to claim 23, wherein the fibres are 4-10 mm long.
25. A plasterboard according to claim 23 or claim 24, wherein the fibre diameter is in the range 5-50 micron.
10
26. A method of manufacturing a plasterboard according to any one of claims 19-22, comprising the step of adding starch to a gypsum slurry, wherein the grain size ofthe starch is less than 40 micron.
27. A method of manufacturing a plasterboard according to any one of claims 19-22,
15 wherein the plasterboard is dried at a température in the range 140-180°C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1309058.4 | 2013-05-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
OA17727A true OA17727A (en) | 2017-10-26 |
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