OA17226A - Threaded joint for steel pipe. - Google Patents
Threaded joint for steel pipe. Download PDFInfo
- Publication number
- OA17226A OA17226A OA1201400528 OA17226A OA 17226 A OA17226 A OA 17226A OA 1201400528 OA1201400528 OA 1201400528 OA 17226 A OA17226 A OA 17226A
- Authority
- OA
- OAPI
- Prior art keywords
- coating film
- resin coating
- ultraviolet ray
- threaded joint
- steel pipe
- Prior art date
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 65
- 239000010959 steel Substances 0.000 title claims abstract description 65
- 238000000576 coating method Methods 0.000 claims abstract description 243
- 239000011248 coating agent Substances 0.000 claims abstract description 241
- 229920005989 resin Polymers 0.000 claims abstract description 98
- 239000011347 resin Substances 0.000 claims abstract description 98
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 65
- 229920002050 silicone resin Polymers 0.000 claims abstract description 64
- 239000003086 colorant Substances 0.000 claims description 3
- 239000002184 metal Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 53
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 48
- 230000001050 lubricating Effects 0.000 description 28
- 239000003921 oil Substances 0.000 description 28
- 239000007787 solid Substances 0.000 description 19
- 230000001965 increased Effects 0.000 description 13
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- 239000007921 spray Substances 0.000 description 11
- 239000004925 Acrylic resin Substances 0.000 description 10
- 229920000178 Acrylic resin Polymers 0.000 description 10
- 239000004519 grease Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000007747 plating Methods 0.000 description 9
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- 238000010168 coupling process Methods 0.000 description 8
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- -1 zinc-iron Chemical compound 0.000 description 7
- 239000000314 lubricant Substances 0.000 description 6
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- 230000002829 reduced Effects 0.000 description 6
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- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- 230000000149 penetrating Effects 0.000 description 5
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- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
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- 239000003999 initiator Substances 0.000 description 4
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
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- 239000001993 wax Substances 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
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- 238000005755 formation reaction Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N HF Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 210000001503 Joints Anatomy 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N Molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 206010067482 No adverse event Diseases 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229940056345 Tums Drugs 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000007739 conversion coating Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 231100000078 corrosive Toxicity 0.000 description 2
- 231100001010 corrosive Toxicity 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000001747 exhibiting Effects 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004923 Acrylic lacquer Substances 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 206010018987 Haemorrhage Diseases 0.000 description 1
- 210000000088 Lip Anatomy 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004698 Polyethylene (PE) Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 210000002356 Skeleton Anatomy 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N Tungsten(IV) sulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H Zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000005296 abrasive Methods 0.000 description 1
- 230000002730 additional Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- HJJOHHHEKFECQI-UHFFFAOYSA-N aluminum;phosphite Chemical compound [Al+3].[O-]P([O-])[O-] HJJOHHHEKFECQI-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000000740 bleeding Effects 0.000 description 1
- 231100000319 bleeding Toxicity 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 238000011109 contamination Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
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- 230000000875 corresponding Effects 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
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- 238000010438 heat treatment Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
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- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating Effects 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
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- 150000003609 titanium compounds Chemical class 0.000 description 1
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Abstract
A threaded joint for steel pipe includes a pin and a box each of which is provided with a contact surface that includes an unthreaded metal contact portion having a seal portion and a threaded portion. This threaded joint includes an ultraviolet ray-curable resin coating film that is formed on the contact surface of at least one of the pin and the box; and an acrylic silicone resin coating film that is formed on at least a portion of a surface of the ultraviolet ray-curable resin coating film.
Description
[Title of the Invention] THREADED JOINT FOR STEEL PIPE [Technical Field]
The présent invention relates to a threaded joint for a steel pipe having superior lubricating performance and rust prévention performance. The threaded joint for a steel pipe according to the présent invention exhibits sufficient rust prévention performance even in a tough storage environment, has sufficient lubricating performance for connecting oil country tubular goods (OCTG), and can also be used for simple repair. Therefore, this threaded joint is particularly suitable for use in connecting OCTG
Priority is clatmed on Japanese Patent Application No. 2012-130134, filed on June 7, 2012, the content of which is incorporated herein by reference.
[Background Art]
Oil country tubular goods (for example, a tubing through which a fluid such as crude oil flows; and a casing which surrounds a tubing), which are used in oil drilling for mîning crude oil or gas oil, are generally several tens of meters long and are connected using threaded joints until they hâve a length to reach an oil well. In the past, the depth of an oil well was 2,000 m to 3,000 m. However, in recent deep oil wells such as undersea oil wells, there are cases where the depth of an oil well reaches a range of 8,000 m to 10,000 m or deeper.
Depending on the usage environment thereof, a threaded joint for a steel pipe used for connecting oil country tubular goods is affected by a load such as an axial tension force caused by the weight of oil country tubular goods and a threaded joint; a complex pressure such as an internai or external surface pressure; and heat in the ground. Therefore, the threaded joint is required to maintain the airtightness of oil country tubular goods without being damaged even in such a tough environment.
FIG 1 is a diagram schematically illustrating an assembly state of oil country tubular goods A and a coupling B which is a threaded joint component In the oil country tubular goods A, a pin 1 having male threads 11 (refer to FIG 2) is formed on external surfaces of both ends thereof. In the coupling B, a box 2 having female threads 21 (refer to FIG 2) is formed on internai surfaces of both ends thereof. An end of the oil country tubular goods A is connected to an end of the coupling B in advance.
FIG 2 is a diagram schematically illustrating the details of a pin-box structure of a typical threaded joint (also referred to as a spécial threaded joint) used for connecting the oil country tubular goods A. The pin 1 is a joint component having the male threads 11 and is typically formed on an end portion of the oil country tubular goods A. The box 2 is a joint component having the female threads 21 and is typically formed on an internai surface of the threaded joint component (coupling B). The pin 1 further indudes, in addition to the male threads 11, a seal portion 13 and a shoulder portion 14 which are positioned doser to a tip end side of a steel pipe than the threaded portion. Correspondingly, the box 2 further indudes, in addition to the female threads 21, a seal portion 23 which is positioned inside ofthe joint portion; and a shoulderportion 24 which cornes into contact with the shoulder portion 14 of the pin 1. The seal portions 13 and 23 and the shoulder portions 14 and 24 of the pin 1 and the box 2 are an unthreaded métal contact portion of the threaded joint for a steel pipe. Référencé numéral 12 represents a lip portion at a tip end ofthe pin 1 and référencé numéral 31 represents a portion where the pin 1 is not in contact with the box 2 (a portion in which bleeding oil remains during connecting).
An end of the oil country tubular goods A is inserted into the coupling B, and the male threads 11 and the female threads 21 are connected to each other. As a resuit, the seal portion 13 of the pin 1 and the seal portion 23 of the box 2 corne into contact with each other at an
- 2 17226 appropriate interférence amount to form a métal seal. This métal seal secures the airtightness of the oil country tubular goods A connected to the coupling B. In this kind of threaded joint, in particular, in the seal portions 13 and 23, non-repairable seizure called galling may occur.
When the tubing and casing are lowered to an oil well, there are cases where a threaded joint connected thereto is disconnected due to various kinds of problems; they are pulled up from the oil well; and then they are connected and lowered again. American Petroleum Institute (API) requires galling résistance and airtightness in the sense that galling does not occur and the airtightness of oil country tubular goods is secured even when makeup (connecting) and breakout (disconnecting) are performed 10 times in the case of a tubing joint or 3 times in the case of a casing joint.
In order to improve airtightness and galling résistance during connecting, in the related art, a viscous liquid fabricant (referred to as “compound grease) containing heavy métal powder is coated onto a contact surface (the threaded portion and unthreaded métal contact portion) of the threaded joint. In API standard BUL5A2, such a compound grease is specified. The compound grease also exhibits rust prévention performance of preventing rust on the coated contact surface.
However, since the compound grease contains a large amount of powder of heavy metais such as zinc, lead, and copper, the coated grease may be washed and overflow on an external surface during the connecting of the threaded joint. As a resuit, there is a possibility that, in particular, harmful heavy metais such as lead may hâve an adverse effect on the environment (in particular, marine organisms). In addition, since the work environment deteriorates due to the coating operation ofthe compound grease, there is a concern of an adverse effect on a human body by the coating operation. Therefore, a threaded joint for a steel pipe capable of exhibiting superior galling résistance without using the compound grease is required.
As a threaded joint which can be used for connecting oil country tubular goods without
- 3 17226 coatîng the compound grease, many threaded joints for a steel pipe hâve been proposed until now in which a contact surface thereof is coated with a solid lubricant coating film composed of an organic or înorganic resin containing lubricating powder such as molybdenum disulfide or graphite.
As described above, in a threaded joint for a steel pipe having a seal portion, since gallrng îs likely to occur particularly in the seal portion, it is necessary that rusting of the seal portion be prevented. This is because galling is likely to occur when the rust occurs. In addition, changes in the shape of the seal portion by corrosion causes détérioration in airtightness. In a threaded joint for a steel pipe which is not coated with the compound grease, since the rust prévention performance by the compound grease is not exhibited, the rust prévention of the seal portion is further important. However, the above-described solid lubricating coating film does not hâve sufficient rust prévention performance for preventing a eut portion of a joint including a seal portion from being rusted when being stored in a highly corrosive environment for a long period of time.
Patent Document 1 discloses a threaded joint for a steel pipe having superior rust prévention performance that includes an ultraviolet ray-curable resin coating film formed of a photocurable composition, which is curable by the irradiation of ultraviolet rays, on a contact surface of the threaded joint.
[Prior Art Document] [Patent Document] [Patent Document 1] Japanese Unexamined Patent Application, First Publication No. 2011-12251 [Disclosure of the Invention] [Problem that the Invention is to solve]
- 4 17226
The threaded joint for a steel pipe disclosed in Japanese Unexamined Patent Application, First Publication No. 2011-12251 is effective for preventing rust on a contact surface (threaded portions and unthreaded métal contact portions of a pin and a box) of the threaded joint for a steel pipe, but there are cases where rust prévention performance is not always sufficient and rust cannot be completely prevented when the storage state is not appropriate or when the storage environment is tough. For example, oil country tubular goods may be stored in a tough environment such as a coast or a desert. Therefore, even when the storage environment is poor, rust prévention is required.
In addition, when the cleanliness of a coating surface is insufficient during the coating of an ultraviolet ray-curable resin composition, there are cases where coating defects are generated on a formed ultraviolet ray-curable coating film and rust prévention performance is locally insufficient. For example, when point-like rust is generated in a seal portion, the galling résistance and airtightness of a threaded joint significantly deteriorates. Therefore, it is necessary that a seal portion, in particular, be completely coated such that coating defects are not generated thereon.
Furthermore, in a coating film formed of an ultraviolet ray-curable resin composition, there are cases where necessary lubricating performance is not sufficiently obtained. In addition, even when defects are observed in the coating film, there is a problem in that defects are not easily repaired.
The présent invention has been made in considération of the above-described circumstances, and an object thereof is to provide a threaded joint for a steel pipe including an ultraviolet ray-curable resin coating film in which, even in a tough storage environment, sufficient rust prévention performance for preventing the rusting of a threaded joint for a steel pipe, used for connecting oil country tubular goods, is obtained; sufficient lubricating performance is obtained as
- 5 17226 a threaded joint for a steel pipe used for connecting oil country tubular goods; and even when coating defects are generated during coating, the defects can be easily repaired.
[Means for Solving the Problems]
The présent invention adopts the following means in order to solve the above-described problems and achieve the object.
(1) According to an aspect of the présent invention, there is provided a threaded joint for a steel pipe including a pin and a box each of which is provided with a contact surface that includes: an unthreaded métal contact portion having a seal portion; and a threaded portion, the threaded joint including: an ultraviolet ray-curable resin coating film that is formed on the contact surface of at least one of the pin and the box; and an acrylic silicone resin coating film that is formed on at least a portion of a surface of the ultraviolet ray-curable resin coating film.
(2) In the threaded joint for a steel pipe according to (1), the acrylic silicone resin coating film may be formed on a portion which covers at least the seal portion on the surface of the ultraviolet ray-curable resin coating film.
(3) In the threaded joint for a steel pipe according to (1 ) or (2), the acrylic silicone resin coating film may be formed on the entire surface of the ultraviolet ray-curable resin coating film.
(4) In the threaded joint for a steel pipe according to any one of (1) to (3), the ultraviolet ray-curable resin coating film may contain a colorant.
[Advantageous Effects of the Invention]
According to the above-described aspect, at least a portion of the contact portions of the threaded joint for a steel pipe, preferably, a portion including the seal portion where galling is particularly likely to occur and which is important in terms of the airtightness of the threaded joint is
- 6 17226 coated with the coating film having a two-iayerstructure ofthe ultraviolet ray-curable resin coating film and the acrylic silicone resin coating film as an upper layer formed thereon. As a resuit, it is possible to provide a threaded joint for a steel pipe capable of preventing the rusting of the threaded joint for a steel pipe even when being stored in a tough environment; and exhibiting sufficient lubricating performance for connecting oil country tubular goods.
In addition, even if the cleanliness ofthe contact surface is insufficient and coating defects are generated on the ultraviolet ray-curable resin coating film, the defects can be repaired with the acrylic silicone resin coating film according to the above-described aspect. Therefore, rust prévention performance can be reliably obtained.
[Brief Description of the Drawings]
FIG 1 is a diagram schematically illustrating an assembly state of oil country tubular pipes and a coupling which is a threaded joint component.
FIG 2 is a diagram schematically illustrating a connecting portion of a threaded joint for a steel pipe.
FIG 3 shows images illustrating the results of a rust prévention test in Example 1.
FIG 4 is a torque chart illustrating the change of torque with respect to the number of tums of a threaded joint for a steel pipe.
[Best Mode for Carrying Out the Invention]
Hereinbelow, an embodiment of the présent invention will be described. Since the basic configuration of a threaded joint for a steel pipe according to the embodiment are the same as that illustrated in FIGS. 1 and 2, the description will be made referring to FIGS. 1 and 2 for
- 7 17226 convenience of description.
The threaded joint for a steel pipe according to the embodiment includes a pin 1 and a box 2 each of which is provided with a contact surface that has a threaded portion; and an unthreaded métal contact portion having a seal portion and a shoulder portion. That is, referring to FIGS. 1 and 2, the pin 1 includes male threads 11 as the threaded portion and includes a seal portion 13 and a shoulder portion 14 as the unthreaded métal contact portion. In addition, the box 2 includes female threads 21 as the threaded portion and includes a seal portion 23 and a shoulder portion 24 as the unthreaded métal contact portion.
The threaded joint for a steel pipe according to the embodiment includes an ultraviolet ray-curable resin coating film that is formed on the contact surface (preferably on the entire contact surface) of at least one (that is, only the pin 1, only the box 2, or both the pin 1 and the box 2) of the pin 1 and the box 2; and an acrylic silicone resin coating film that is formed on at least a portion of a surface of the ultraviolet ray-curable resin coating film, preferably on a portion which covers the seal portions 13 and 23.
Ultraviolet Ray-Curable Resin Coating Film
The ultraviolet ray-curable resin coating film can be formed using an appropriate ultraviolet ray-curable resin coating material which is applicable to a steel material. Generally, the ultraviolet ray-curable resin coating material contains at least a monomer, an oligomer, and a photopolymerization initiator and may further contain various kinds of additives such as a pigment, a rust preventing agent, a defoaming agent, and a leveling agent. An example of such an ultraviolet ray-curable resin coating material is disclosed in Japanese Unexamined Patent Application, First Publication No. 2011-12251 as a photocurable composition. However, the ultraviolet ray-curable resin coating material is not limited thereto. In addition, commercially available ultraviolet ray-curable resin coating materials may be used.
- 8 17226
As the ultraviolet ray-curable resin coating material, a material is préférable in which the rust prévention property of a coating film is superior; the curing rate is high; and a thick film can be obtained. In addition, in considération of a coating environment, it is préférable that a solventless ultraviolet ray-curable resin coating material be used. In order to enhance the lubricating property of a formed ultraviolet ray-curable resin coating film, at least one lubricant selected from waxes, metallic soaps, PTFE resin, and fibrous fillers may be added to the coating material in an amount of, for example, not more than 30% by mass in terms of solid content. As the rust preventing agent for enhancing the rust prévention performance of the ultraviolet ray-curable resin coating film, for example, aluminum tripolyphosphate or aluminum phosphite can be used. In this case, the amount thereof added is preferably less than or equal to 10% by mass in terms of solid content. As the pigment for coloring the coating film, a material which does not significantly impair the transparency of the coating film can be used. Examples of such a pigment include fluorescent pigments and light color pigments.
As the ultraviolet ray-curable coating material, it is particularly préférable that an epoxy acrylic resin having superior rust prévention performance be used. This kind of ultraviolet raycurable coating material contains acrylic acid (or methacrylic acid)-modified epoxy resin, obtained by adding acrylic acid (or methacrylic acid) to epoxy resin as the oligomer. In this case, an ultraviolet ray-curable resin coating material (for example, an urethane acrylic resin) other than the above-described coating material can be used. Examples of commercially available ultraviolet ray-curable resin coating materiais include an epoxy acrylic resin coating material which is manufactured by Chugoku Marine Paints Ltd. and has a trade name of Aulrex.
The ultraviolet ray-curable resin coating film can be formed by coating the contact surface (preferably, the entire contact surface) of at least one of the pin 1 and the box 2 of the threaded joint for a steel pipe with the ultraviolet ray-curable resin coating material using an appropriate
- 9 17226 method; and irradiating the coated contact surface with ultraviolet rays. As a coating method of the ultraviolet ray-curable coating material, it is préférable that spray coating be used. However, other coating methods such as brush coating or dip coating may be used. The irradiation of ultraviolet rays may be performed using an appropriate radiation source corresponding to the photopolymerization initiator to be used in the coating material.
The thickness ofthe ultraviolet ray-curable resin coating film can be adjusted within a range of 1 pm to 100 pm, preferably, within a range of 5 pm to 30 pm. Generally, since the ultraviolet ray-curable resin coating film has superior adhesion with a substrate (the contact surface of the threaded joint for a steel pipe) and is an imperméable coating film having high transparency, rust prévention performance is superior.
Acrylic Silicone Resin Coating Film
The acrylic silicone resin coating film is formed on at least a portion of a surface ofthe ultraviolet ray-curable resin coating film. That is, in the threaded joint for a steel pipe according to the embodiment, a coating film having the two-layer structure ofthe ultraviolet ray-curable resin coating film as the lower layer and the acrylic silicone resin coating film as the upper layer is formed on at least a portion of the contact portion of at least one ofthe pin 1 and the box 2. By providing the acrylic silicone resin coating film on the ultraviolet ray-curable resin coating film, not only the above-described repairing effect but also the lubricating performance of the threaded joint for a steel pipe can be improved. As a resuit, galling is difficult to occur.
When the acrylic silicone resin coating film is formed on only a portion of the surface of the ultraviolet ray-curable resin coating film, it is préférable that the acrylic silicone resin coating film be formed on a portion which covers the seal portion, in which galling is most likely to occur, on the surface of the ultraviolet ray-curable resin coating film. For example, a configuration may be adopted in which the threaded portions are coated with only the ultraviolet ray-curable resin
- 10 17226 coating film; and the seal portions and the shoulder portions (that is, the unthreaded métal contact portions) are coated with the coating film having the two-layer structure of the ultraviolet raycurable resin coating film as the lower layer and the acrylic silicone resin coating film as the upper layer. Since the ultraviolet ray-curable resin coating film and the acrylic silicone resin coating film with which the threaded portions and the seal portions are coated hâve superior transparency, the states of the threaded portions and the seal portions can be observed above the coating film. In particular, the pin 1 is easîly damaged because the threaded portion (male threads 11) and the seal portion 13 are formed on the external surface. Therefore, it is desired that the damage state of the threaded portion be checked in advance for each connecting. According to the embodiment, even when both the ultraviolet ray-curable resin coating film and the acrylic silicone resin coating film are coated, the damage state of the threaded joint can be verified, for example, by Visual inspection as in the case where no coating film is provided.
In this case, the acrylic silicone resin coating film as the upper layer can be formed on a portion of a contact surface not having the seal portion, for example, for the purpose of repair. Spécifie examples of such a case include a case where a pinhole, a non-uniformly coated portion, or the Iike is generated on the ultraviolet ray-curable resin coating film as the lower layer; and a case where the ultraviolet ray-curable resin coating film is partiaily damaged for some reasons. In such cases, there is a concern of détérioration of the rust prévention property such as the rusting of damaged portions. However, by forming the acrylic silicone resin coating film on the portions, the damage is repaired and the détérioration of the rust prévention property can be prevented. When the ultraviolet ray-curable resin coating film is damaged, it is préférable that the acrylic silicone resin coating film be formed such that the vicinity of damaged portions is also coated. When the ultraviolet ray-curable resin coating film is colored with a colorant such as a fluorescent pigment, damaged portions and non-uniformly coated portions of the coating film can be checked by Visual inspection or the irradiation of ultraviolet rays.
In considération of the rust prévention property and the lubricating property, it is préférable that the acrylic silicone resin coating film as the upper layer be formed on the entire surface of the ultraviolet ray-curable resin coating film. When the ultraviolet ray-curable resin coating film as the lower layer and the acrylic silicone resin coating film as the upper layer are formed on the entire contact surface, as described below in Examples, the torque on shoulder résistance is increased and the connecting torque specified by the threaded joint for a steel pipe can be adjusted to a high value. As a resuit, the additional effect of increasing the sealing property (airtightness) of the threaded joint for a steel pipe can be obtained.
An acrylic silicone resin coating material includes a reaction product of silicone resin and acrylic resin as the coating film-forming component. This coating material can form a dense resin coating film having a siloxane bond as the skeleton and has a strong adhesion force with an undercoat layer. The formed coating film can hâve high performance in adhesion, gloss maintainability, color maintainability, water résistance, chemical résistance (acid résistance and alkalî résistance), oil résistance, contamination résistance, and long-term weather résistance, in addition to water repellency by the silicone component. The acrylic silicone resin coating material includes an oil type (solvent type; strong solvent type and weak solvent type) and an aqueous type (réaction curing type émulsion coating material). Both types can be used, but an oil type material is préférable because a coating film can be obtained by drying at a relatively low température within a short period of time. In particular, it is préférable that a normal température curing-type material be used. Since the température curing-type acrylic silicone resin material has a superior quick-drying property, heating is not required, a coating film can be rapidly formed, and the continuous operation can be performed. Therefore, there are no adverse effects on the productivity of the threaded joint for a steel pipe.
The présent inventors hâve thoroughly investigated various kinds of materials of the resin
- 12 17226 coating film which is formed as the upper layer formed on the ultraviolet ray-curable resin coating film; and as a resuit, hâve found that, when the acrylic silicone resin coating film is formed as the upper layer, the rust prévention property is particulariy improved and superior rust prévention performance is exhibited in a corrosive environment under sait spray conditions, as compared to an acrylic resin coating material or a fluororesin coating material which is generally known to hâve superior corrosion résistance.
As the acrylic silicone resin coating material, commercially available products can be used. Examples of commercially available acrylic silicone resin coating materials include an acrylic silicone resin material which is adopted as an oil silicone lacquer spray manufactured by Kanpe Hapio Co„ Ltd,
The acrylic silicone resin coating material is coated onto the contact surface of the threaded joint for a steel pipe, on which the ultraviolet ray-curable resin coating film is formed, using the same appropriate method as that of the description of the ultraviolet ray-curable resin coating material followed by volatilizing the solvent to cure a coating film. As a resuit, a cured coating film can be formed.
It is préférable that the thickness of the acrylic silicone resin coating film be in a range of 1 pm to 100 gm. When the thickness of the acrylic silicone resin coating film is less than 1 pm, the rust prévention property signifîcantly deteriorates. When the thickness of the acrylic silicone resin coating film is greater than 100 pm, the lubricating property signifîcantly deteriorates. In the viewpoint of coexistence with the rust prévention property and the lubricating property, it is more préférable that the thickness of the acrylic silicone resin coating film be in a range of 5 pm to 10 pm.
When the thickness of the acrylic silicone resin coating film is in a range of 5 pm to 10 pm, an improvement of a constant rust prévention performance can be confirmed. However, when
- 13 17226 the thickness of the acrylic silicone resin coating film is greater than 10 pm, an improvement of a further rust prévention performance cannot be confirmée!. On the other hand, when the thickness of the acrylic silicone resin coating film becomes greater, the galling résistance is inhibited. As a resuit, the allowance frequency of the répétition with connection and disconnection decreases.
The ultraviolet ray-curable resin coating film is obtained through a curing process in which a coating material containîng a monomer, an oligomer, a photopolymerization initiator, and the like are irradiated with ultraviolet rays to produce radicals from the photopolymerization initiator; the monomer is converted into a polymer by these radicals; and the coating material is cured. On the other hand, the acrylic silicone resin coating film is obtained through a curing process in which in a coating material (for example, oil silicone lacquer spray) containîng acrylic silicone resin, a volatile solvent, a curing agent, and the like, the solvent volatilizes; and the coating material is cured.
That is, the curing processes ofthe ultraviolet ray-curable resin coating film and the acrylic silicone resin coating film are basîcally totally different from each other,
Undercoat Treatment
The threaded portions and the unthreaded métal contact portions, which are the contact surface of the threaded joint for a steel pipe on which the ultraviolet ray-curable resin coating film is formed, are formed through a cutting process inciuding thread cutting, and the surface roughness thereof is generally about 3 pm to 5 pm. When the surface roughness of the contact surface is greater than the above-described range, the adhesion of a coating film formed thereon can be increased. As a resuit, the performance of the threaded joint such as the connecting property and rust prévention property can be improved. To that end, before the formation of the ultraviolet ray-curable resin coating film, an undercoat treatment capable of increasing the surface roughness may be performed on the contact surface of the threaded joint for a steel pipe.
- 14 17226
Examples of such an undercoat treatment include a blast treatment of blasting an abrasive such as a spherical shot material or a horn-shaped grid material; and an acid washing treatment of dipping the contact surface in a strong acid solution such as sulfuric acid, hydrochloric acid, nitric acid, or hydrofluoric acid to roughen the surface. These treatments can increase the surface roughness of a base material itself.
Otherexamples ofthe undercoattreatment include chemical conversion coating such as a phosphating treatment, an oxalating treatment, or a borating treatment; and métal plating.
In the chemical conversion treatment, a conversion coating film formed of needle crystal and having a large surface roughness is formed. As a resuit, the surface roughness is increased and the adhesion of a solid rust prévention film and a solid lubricating coating film formed thereon can be increased. In order to further improve the rust prévention property, it is préférable that an undercoat layer (lower layer formed below the ultraviolet ray-curable resin coating film) be formed of zinc phosphate, manganèse phosphate, or the like.
Métal plating can improve the galling résistance of the threaded joint for a steel pipe, and partial métal plating can increase the surface roughness. Examples of métal plating for increasing the surface roughness include plating of copper, iron, and an alloy thereof using an electroplating method; impact plating of zinc or a zinc alloy in which particles, obtained by coating iron cores with zinc, an zinc-iron alloy, or the like, are blown by a centrifugal force or an air pressure, zinc particles or zinc-iron alloy particles are deposited, and a porous métal coating film is formed; and composite métal plating of dispersing solid fine particles in a métal to form a coating film. In particular, the impact plating is effective for increasing the surface roughness.
No matter which method is used in the undercoat treatment of the contact surface, it is préférable that the surface roughness Rz be adjusted to 5 pm to 40 pm after the surface roughening ofthe undercoat treatment. When the surface roughness Rz is less than 5 pm, there are cases in which the adhesion with a coating film formed on the contact surface is insufficient. On the other hand, when the surface roughness Rz is greater than 40 pm, the friction of the surface increases and there are cases where, when a high surface pressure is applied thereto, a coating film formed on the contact surface cannot endure a shearing force and a compression force and is broken or peeled off. As the undercoat treatment for surface roughening, two or more kinds of treatments may be used in combination.
Other Coating Films
When the ultraviolet ray-curable resin coating film as the lower layer and the acrylic silicone resin coating film as the upper layer are formed on the contact surface of at least one (for example, the pin 1 ) of the pin 1 and the box 2 of the threaded joint for a steel pipe, the treatment on the contact surface of the other one (for example, the box 2) is not particularly limited. For example, only the ultraviolet ray-curable resin coating film as the lower layer may be formed. Altematively, various kinds of surface treatments of a threaded joint for a steel pipe, which hâve been disclosed and will be disclosed in the related art, may be applied thereto.
The coating film having a two layer structure according to the présent invention of the ultraviolet ray-curable resin coating film as the lower layer and the acrylic silicone resin coating film as the upper layer has a superior rust prévention property. However, when this coating film having the two-layer structure is formed on the contact surfaces of both the pin 1 and the box 2, there are cases where galling résistance is insufficient for the connecting of the threaded joint for a steel pipe. In this case, it is préférable that the coating film having the two-layer structure according to the présent invention be formed on the contact surface of at least one of the pin 1 and the box 2; and a solid lubricating coating film described below be formed on the contact surface of the other one.
Examples of the solid lubricating coating film include a coating film which contains
- 16 17226 lubricating powder and optionally other components in an organic or inorganic resin. Examples of the lubricating powder include molybdenum disulfide, tungsten disulfide, graphite, and polytetrafluoroethylene. Examples of the resin which is a binder include organic resins such as epoxy resin, polyamide resin, and polyamideimide resin; and silicon or titanium compounds (for example, alkyl silicate, silica sol, and titania sol) which can form an silica or titania inorganic resin coating film. The solid lubricating coating film may be a thin lubricating film having no stickiness disclosed in WO 2007/042231 in which solid lubricant particles having plastic or viscoplastic rheological behavior (flow characteristic) are dispersed in a solid matrix. This lubricating coating film can be formed by coating, using a hot melt method, a composition which contains, for example, polyethylene as a thermoplastic polymer; wax (for example, carnauba wax) and metallic soap (for example, zinc stéarate) as lubricating components; and calcium sulfonate as a corrosion inhibitor. Wax, metallic soap, calcium sulfonate, and the like can be added to the above-described solid lubricating coating film containing lubricating powder in the resin.
The thickness ofthe solid lubricating coating film is not particularlylimited, but isgenerally in a range of 5 pm to 100 pm and preferably in a range of 5 pm to 50 pm. When the solid lubricating coating film is formed, similarly, in order to improve the coating adhesion, it is préférable that the above-described undercoat treatment for increasing the surface roughness be performed on the contact surface to be coated.
Since the solid lubricating coating film is generally opaque, it is préférable that the solid lubricating film be applied to the contact surface of the box 2 in which the threaded portion is not easily damaged compared to the pin 1 ; and that the two-layer coating film according to the présent invention including the ultraviolet ray-curable resin coating film as the lower layer and the acrylic silicone resin coating film as the upper layer be formed on the contact surface of the pin 1. By doing so, since the two-layer coating film has superior transparency, the two-layer coating film is
- 17 17226 typically formed on extemal surfaces of both ends of a long steel pipe and thus the state of the threaded portion of the pin portion which is easily damaged can be observed by Visual inspection from the above of the two-layer coating film which covers the pin 1.
In the above-described embodiment, the threaded joint for a steel pipe including the shoulder portions 14 and 24 has been described as an example. However, the présent invention can be applied to a threaded joint for a steel pipe not including the shoulder portions 14 and 24. For example, the threaded joint for a steel pipe is a threaded joint that a thread (for example, a wedge-shaped thread or the like) itself has a locking fonction which stops the rotation of connection.
The effects of the présent invention will be described using the following examples. Hereinbelow, the contact surface including the threaded portion and the unthreaded métal contact portion of the pin will be referred to as “pin surface; and the contact surface including the threaded portion and the unthreaded métal contact portion of the box will be referred to as “box surface. In the examples, “%” represents “% by mass unless specified otherwise.
[Examples]
Example 1
In this example, various kinds of resin coating films were formed on the ultraviolet raycurable resin coating film which covers the contact surface of the threaded joint for a steel pipe to investigate the rust prévention property. For reference, the same test was performed for a case where only the ultraviolet ray-curable resin coating film was formed and a case where a penetrating lubricant CRC 5-56 (KURE 5-56, manufactured by Kure Engineering Ltd.) which is known to hâve a high rust prévention effect was coated on the ultraviolet ray-curable resin coating film.
- 18 17226
A thread cutting treatment was performed on a portion of a carbon steel pipe (outer diameter: 177.8 mm) approximately 120 mm distant from a pipe end. This threaded portion was spray-coated with a commercially available ultraviolet ray-curable resin coating material of epoxy acrylic resin (Aulrex 550, manufactured by Chugoku Marine Paints Ltd.) and was irradiated with ultraviolet rays at room température for 60 seconds to cure the coating film. Spray-coating and irradiation of ultraviolet rays were performed while rotating the steel pipe. A high-pressure mercury lamp was used as an ultraviolet light source, and the irradiation was approximately 500 mJ/cm2. In this way, the ultraviolet ray-curable resin coating film having an average thickness of 30 pm was formed on the surface of the threaded portion.
The threaded portion on which the ultraviolet ray-curable resin coating film was formed was eut into plural strip specimens. Various kinds of commercially available resin coating materials or the above-described penetrating fabricant CRC 5-56 was spray-coated on the ultraviolet ray-curable resin coating films of the strip specimens. The three kinds of coating materials used are as foilows.
(1) Thermosetting acrylic resin coating material: Acrylic lacquer spray a (manufactured by Dai Nippon Co., Ltd.) (2) Fluororesin coating material: Spray coating material of polytetrafluoroethylene (manufactured by Henkel Japan Ltd.) (3) Acrylic silicone resin coating material: Silicone lacquer spray (acrylic silicone resin coating material; manufactured by Kanpe Hapio Co., Ltd.)
After coating, the coating films were naturally dried according to the instruction of the coating material. Various kinds of resin coating materials or the penetrating fabricant CRC 5-56 was coated for about 5 seconds.
- 19 17226
Using the strip specimens on which the ultraviolet ray-curable resin coating film as the lower layer and the resin coating film or the penetrating lubricant coating film as the upper layer were formed, a sait spray test (aqueous 5% NaCI solution, 40°C) was performed for 200 hours according to JIS Z2371. The rust area ratios of the specimens 200 hours after the spray sait test were evaluated by Visual inspection, and the results thereof are shown in Table 1 and FIG. 3.
Table 1
| Conditions | 1-1 | 1-2 | 1-3 | 1-4 | 1-5 |
| Lower-Layer Coating Film | Ultraviolet Ray-Curable Resin Coating Film | ||||
| Upper-Layer Coating Film | None | CRC 5-56 | Acrylic Resin | Fluororesin | Acrylic Silicone Resin |
| Rust Area Ratio | 50% or higher | 40% to 50% | 30% to 40% | 40% to 50% | 0% to 10% |
As illustrated in Table 1 and FIG. 3, under the condition 1-1 that only the ultraviolet raycurable resin coating film was formed and the resin coating film was not formed as the upper layer, rust was observed on 50% or higher of the entire surface of the threaded portion of the specimen.
Meanwhile, under the condition 1-2 that the penetrating lubricant CRC 5-56 which is known to hâve a high rust prévention effect was coated for the upper layer, the rust area ratio was reduced to 40% to 50%. Under the condition 1 -4 that the fluororesin was coated for the upper layer, the same effect was obtained. Under the condition 1 -3 that the acrylic resin was coated for the upper layer, the rust area ratio was reduced to 30% to 40% but was insufficient. On the other hand, under the condition 1-5 that the acrylic silicone resin was coated for the upper layer, the rust area ratio could be reduced to approximately 10% or lower. It was clearly seen that the effect of the acrylic silicone resin was particularly higher as the upper-layer resin coating film for enhancing the rust prévention property of the ultraviolet ray-curable resin coating film.
Example 2
- 20 17226
It was verified in Example 1 that the rust prévention effect of the coating film having the two-layer structure of the ultraviolet ray-curable resin coating film as the lower layer and the acrylic silicone resin coating film as the upper layer is significantly high. However, in the case of a threaded joint for a steel pipe, the connecting property of the threaded joint is the most important performance, and there is a concern that the formation of the acrylic silicone resin coating film may inhibit this performance. Therefore, the influence of the two-layer coating film on connecting performance and airtightness was înspected.
The pin surface of a threaded joint for a steel pipe (VAMTOP, registered trade name) having a seal portion, which was formed at a pipe end of an OCTG steel pipe having an outer diameter of 177.8 mm, was spray-coated with the same ultraviolet ray-curable resin coating material of epoxy acrylic resin as that used in Example 1 and was inadiated with ultraviolet rays at room température for 60 seconds to cure the coating film. Spray-coating and irradiation of ultraviolet rays were performed while rotating the steel pipe. The ultraviolet light source, the irradiation dose, and the thickness of the coating film were the same as those of Example 1. In this way, the ultraviolet ray-curable resin coating film was formed on the entire pin surface containing a seal portion and a shoulder portion.
Regarding the pin surface which was coated with the ultraviolet ray-curable resin coating film, only the seal portion and the shoulder portion of the pin tip end or the entire pin surface containing the threaded portion was spray-coated with the same acrylic silicone resin coating material as that used in Example 1 and was naturally dried to form a coating film. Coating was performed while rotating the steel pipe. The thickness of the coating film was approximately 5 pm.
As shown in Table 2, the condition 2-1 was that the acrylic silicone resin was not coated (only the ultraviolet ray-curable resin coating film was coated); the condition 2-2 was that the acrylic silicone resin coating film was formed on only the pin tip end (the seal portion and the
- 21 17226 shoulder portion); and the condition 2-3 was that the acrylic silicone resin coating film was formed on the entire pin surface containing the threaded portion.
On the box surface, under any conditions, a solid lubricating solid film (thickness: 50 pm) containing high basic calcium sulfonate as a major component in a substrate having a wax component was formed.
The undercoat treatment performed before forming the ultraviolet ray-curable resin coating film was a zinc phosphating treatment on the pin surface and was a copper-tin-zinc ternary alloy plating treatment on the box treatment.
Using the threaded joint subjected to the surface treatment as described above, the connecting performance and the airtightness were inspected as follows.
Connecting Performance
The connecting performance was evaluated based on the influence on the shouldering torque and the torque on shoulder résistance. The shouldering torque refers to the torque value when the shoulder portions of the pin and the box are in contact with each other (when interférence starts). In addition, the torque on shoulder résistance refers to the torque différence between the shouldering torque and the torque at the time of the yield deformation of the shoulder portion. As the torque on shoulder résistance is higher, the specified torque value during the connecting of the threaded joint can be set to be higher. Therefore, when connecting is performed at the specified torque value, the interférence amount of the seal portion, that is, the airtightness of the threaded joint can be increased. When the threaded joint was finally connected at the specified torque value, the différence between the specified torque value and the shouldering torque value affects the contact pressure of the seal portions of the pin and the box. Therefore, the control of the shouldering torque value and the torque on shoulder résistance value
- 22 17226 is important.
Using the threaded joint in which the pin surface and the box surface were treated as described above, connecting started at a predetermined rotating speed. Connecting continued by applying the torque while monitoring the torque with respect to the number of tums until it was confirmed that the joint shoulder yielded. From the monitoring results (torque chart illustrating the torque change with respect to the number of turns; refer to FIG 4), the torque at the point at which the rapid increase of toque increases was obtained as the shouldering torque Ts; and the différence between the torque (yield torque Ty) at the point at which the rapid increase of toque is stopped and the shouldering torque Ts was obtained as the torque on shoulder résistance ΔΤ.
The test results under the respective conditions are collectively shown in Table 2.
Table 2
| Coating Conditions of Acrylic Silicone Resin Coating Film | Shouldering Torque (ft-lbs) | Torque On Shoulder Résistance (ft-lbs) | |
| Condition 2-1 | No Coating | 4851 | 7836 |
| Condition 2-2 | Coating on Only Pin Tip End (Seal Portion and Shoulder Portion) | 4432 | 7898 |
| Condition 2-3 | Coating On Entire Pin Surface | 4307 | 8725 |
As can be seen from the results of Table. 2, as compared to the condition 2-1, the value of the shouldering torque Ts was reduced under the condition 2-2 and was further reduced under the condition 2-3. Under the condition 2-3 that the acrylic silicone resin coating film was coated on the entire pin surface, the value of the shouldering torque Ts was reduced by approximately 11% as compared to the condition 2-1. It was confirmed from these results that the formation of the acrylic silicone resin coating film on the ultraviolet ray-curable resin coating film does not inhibit the lubrication of the joint. Against the optimum torque To illustrated in FIG.4, the lower limit of the
- 23 17226 shouldering torque Ts is substantially within a range of 5% to 15%, and the upper limit of the shouldering torque Ts îs substantially within a range of 70% to 85%. Therefore, the variation of approximately 11% is a levei which becomes no problems.
Meanwhile, the torque on shoulder résistance ΔΤ, which is the torque différence between the shoulder torque Ts and the torque (yield torque Ty) at the time of shoulder deformation, was increased by approximately 11% particularly under the condition 2-3 that the acrylic silicone resin coating film was formed on the entire pin surface, as compared to a case where the acrylic silicone resin coating film was not formed. The increase in the torque on shoulder résistance ΔΤ represents that the specified connecting torque is set to be higher correspondingly. Accordingly, the seal performance of the threaded joint for a steel pipe can be increased.
Airtightness
The threaded joint for a steel pipe in which the pin surface and the box surface were treated as described above was connected with the specified torque (7470 ft-lbs) and was heated at 180°C according to a method of ISO13679 to perform an airtightness test under a complex load of internai pressure/extemal pressure and tension/compression. It was confirmed from the results for the airtightness that the existence of the acrylic silicone resin coating film does not affect the airtightness performance.
It was found from the above results that, when the acrylic silicone resin coating film is formed on the ultraviolet ray-curable resin coating film, the rust prévention property of the threaded joint for a steel pipe can be significantly improved; there are no adverse effects on the airtightness ofthe threaded joint for a steel pipe; and the specified torque can be set to be high because the torque on shoulder résistance ΔΤ is increased, thereby obtaining the effect of improving the sealing property of the threaded joint for a steel pipe.
- 24 17226 [Explanation of Référencés]
A: oil country tubular goods
B: coupling
1: pin
2: box
11: male thread
21: female thread
13, 23: seal portion
14, 24: shoulder portion
Claims (4)
- [Désignation of Document] CLAIMS [Claim 1]A threaded joint for a steel pipe including a pin and a box each of which is provided with a contact surface that includes: an unthreaded métal contact portion having a seal portion; and a threaded portion, the threaded joint comprising:an ultraviolet ray-curable resin coating film that is formed on the contact surface of at least one of the pin and the box; and an acrylic silicone resin coating film that isformed on at least a portion of a surface ofthe ultraviolet ray-curable resin coating film.
- [Claim 2]The threaded joint for a steel pipe according to claim 1, wherein the acrylic silicone resin coating film is formed on a portion which covers at least the seal portion on the surface of the ultraviolet ray-curable resin coating film.
- [Claim 3]The threaded joint for a steel pipe according to claim 1 or 2, wherein the acrylic silicone resin coating film is formed on an entire surface of the ultraviolet ray-curable resin coating film.
- [Claim 4]The threaded joint for a steel pipe according to any one of claims 1 to 3, wherein the ultraviolet ray-curable resin coating film contains a colorant.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012-130134 | 2012-06-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| OA17226A true OA17226A (en) | 2016-04-20 |
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