NZ781580B2 - Agricultural or horticultural fungicide, method of controlling plant diseases, and product for controlling plant diseases - Google Patents

Agricultural or horticultural fungicide, method of controlling plant diseases, and product for controlling plant diseases

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Publication number
NZ781580B2
NZ781580B2 NZ781580A NZ78158020A NZ781580B2 NZ 781580 B2 NZ781580 B2 NZ 781580B2 NZ 781580 A NZ781580 A NZ 781580A NZ 78158020 A NZ78158020 A NZ 78158020A NZ 781580 B2 NZ781580 B2 NZ 781580B2
Authority
NZ
New Zealand
Prior art keywords
agricultural
horticultural fungicide
group
fungicide according
inhibitors
Prior art date
Application number
NZ781580A
Other versions
NZ781580A (en
Inventor
Mayumi Ishikawa
Erina Kimura
Tatsuyuki Koshiyama
Hideaki Tateishi
Original Assignee
Kureha Corporation
Filing date
Publication date
Application filed by Kureha Corporation filed Critical Kureha Corporation
Priority claimed from PCT/JP2020/016993 external-priority patent/WO2020213739A1/en
Publication of NZ781580A publication Critical patent/NZ781580A/en
Publication of NZ781580B2 publication Critical patent/NZ781580B2/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00—Fungicides

Abstract

Provided is an antifungal agent for agricultural or horticultural use, which has low toxicity to human bodies and animals and excellent handling safety and can exhibit an excellent controlling efficacy against a wide range of plant diseases and a high antifungal activity against pathogenic fungi. The antifungal agent for agricultural or horticultural use according to the present invention contains an azole derivative represented by general formula (I) as one active ingredient and further contains another active ingredient.

Claims (22)

1. An agricultural or horticultural fungicide comprising an azole derivative represented by general formula (I) as an active ingredient, and further comprising another active ingredient: [Chemical Formula 1] wherein A is N; D is hydrogen; R is hydrogen; R is -OR ; R is hydrogen, a C1-C6-alkyl group, or C2-C6-alkenyl group; where the aliphatic group in R may have 1, 2, 3 or a maximum possible number of the same or different groups R s, where R s are independently selected from a halogen group, cyano group, nitro group, C1-C4-alkoxy group, and C1-C4-haloalkoxy group; R is a halogen group, cyano group, C -C -alkyl group, C -C -haloalkyl group, 1 4 1 4 C1-C4-alkoxy group, or C1-C4-haloalkoxy group; R is a halogen group, cyano group, C -C -haloalkyl group, C -C -alkoxy group, 1 4 1 4 or C -C -haloalkoxy group; E is a phenyl group; n R s are bonded at any substitution positions;n is 1 or 2; Y is an oxygen atom bonded to any position of E; Z is a phenyl group; m R s are bonded at any substitution positions; and m is 1 or 2.
2. The agricultural or horticultural fungicide according to claim 1, wherein the other active ingredient comprises at least one selected from: (i) an active ingredient of a fungicide selected from nucleic acid synthesis and metabolism inhibitors, mitotic division/cell division inhibitors, respiratory inhibitors, amino acid/protein biosynthesis inhibitor, signal transduction inhibitors, lipid biosynthesis or transport/cell membrane structure or function inhibitors, cell membrane sterol biosynthesis inhibitors, cell wall biosynthesis inhibitors, melanin biosynthesis inhibitors, host plant resistance inducers, and multi-site fungicides; (ii) an active ingredient of an insecticide selected from nicotinic acetylcholine receptor antagonizing modulators, sodium channel modulators, ryanodine receptor modulators, acetylcholinesterase inhibitors, oxidative phosphorylation uncouplers, and mitochondrial electron transport chain complex I inhibitors; and (iii) an active ingredient of a plant growth regulator.
3. The agricultural or horticultural fungicide according to claim 2, wherein the nucleic acid synthesis and metabolism inhibitor comprises at least one selected from benalaxyl, benalaxyl-M, furalaxyl, ofurace, bupyrimate, dimethirimol, ethirimol, octhilinone, metalaxyl, metalaxyl-M, oxadixyl, and hymexazol.
4. The agricultural or horticultural fungicide according to claim 2, wherein the mitotic division/cell division inhibitor comprises at least one selected from benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate, thiophanate- methyl, diethofencarb, zoxamide, ethaboxam, pencycuron, fluopicolide, phenamacril, metrafenone, and pyriofenone.
5. The agricultural or horticultural fungicide according to claim 2, wherein the respiratory inhibitor comprises at least one selected from tolfenpyrad, diflumetorim, fenazaquin, pydiflumetofen, fenfuram, carboxin, oxycarboxin, benodanyl, flutolanil, mepronil, isofetamid, benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, isopyrazam, penflufen, penthiopyrad, sedaxane, isoflucypram, boscalid, fluopyram, thifluzamide, pyraziflumid, pyribencarb, fluoxastrobin, fenamidon, mandestrobin, azoxystrobin, coumoxystrobin, enoxastrobin, flufenoxystrobin, picoxystrobin, pyraclostrobin, pyraoxystrobin, triclopyricarb, famoxadone, dimoxystrobin, fenaminstrobin, metminostrobin, orysastrobin, kresoxim-methyl, trifloxystrobin, cyazofamid, amisulbrom, fenpicoxamid, florylpicoxamid, binapacryl, meptyldinocap, dinocap, fluazinam, triphenyltin acetate, triphenyltin chloride, triphenyltin hydroxide, silthiopham, ametoctradin, metyltetraprole, pyrapropoyne, and inpyrfluxam.
6. The agricultural or horticultural fungicide according to claim 2, wherein the amino acid/protein biosynthesis inhibitor comprises at least one selected from cyprodinil, mepanipyrim, pyrimethanil, blasticidin, kasugamycin, streptomycin, and oxytetracycline.
7. The agricultural or horticultural fungicide according to claim 2, wherein the signal transduction inhibitor comprises at least one selected from quinoxyfen, proquinazid, chlozolinate, dimethachlon, fenpiclonil, fludioxonil, iprodione, procymidone, and vinclozolin.
8. The agricultural or horticultural fungicide according to claim 2, wherein the lipid biosynthesis or transport/cell membrane structure or function inhibitor comprises at least one selected from isoprothiolane, ediphenphos, iprobenfos (IBP), pyrazophos, biphenyl, chloroneb, dichloran, quintozene (PCNB), tecnazene (TCNB), tolclofos-methyl, etridiazole, prothiocarb, propamocarb, natamycin, oxathiapiprolin, and fluoxapiprolin.
9. The agricultural or horticultural fungicide according to claim 2, wherein the cell membrane sterol biosynthesis inhibitor comprises at least one selected from imazalil, oxpoconazole, pefurazoate, prochloraz, triflumizole, triforine, pyrifenox, pyrisoxazole, fenarimol, nuarimol, azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, metconazole, ipconazole, myclobutanil, penconazole, propiconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole, mefentrifluconazole, prothioconazole, tridemorph, fenpropimorph, fenpropidin, piperaline, spiroxamine, fenpyrazamine, fenhexamid, naphthifine, terbinafine, pyributicarb, and ipfentrifluconazole.
10. The agricultural or horticultural fungicide according to claim 2, wherein the cell wall biosynthesis inhibitor comprises at least one selected from polyoxin, dimethomorph, flumorph, pyrimorph, mandipropamid, benthiavalicarb, iprovalicarb, and valifenalate.
11. The agricultural or horticultural fungicide according to claim 2, wherein the melanin biosynthesis inhibitor comprises at least one selected from fthalide, tricyclazole, pyroquilon, carpropamid, diclocymet, fenoxanil, and tolprocarb.
12. The agricultural or horticultural fungicide according to claim 2, wherein the host plant resistance inducer comprises at least one selected from acibenzolar-S-methyl, probenazole, tiadinil, laminarin, isotianil, fosetyl-AI, phosphorous acid, and phosphonates.
13. The agricultural or horticultural fungicide according to claim 2, wherein the multi-site fungicide comprises at least one selected from cymoxanil, tecloftalam, triazoxide, flusulfamide, diclomezine, cyflufenamide, dodine, flutianil, ferimzone, tebufloquin, picarbutrazox, validamycin, mineral oil, baking soda, potassium carbonate, copper and copper compounds, sulfur, ferbam, mancozeb, maneb, metriram, propineb, thiram, zineb, ziram, captan, captafol, folpet, chlorothalonil (TPN), guazatin, iminoctadine acetate, iminoctadine albesilate, anilazine, dithianon, fluoroimide, methasulfocarb, florylpicoxamid, fluopimomide, ipflufenoquin, quinomethionate, pyridachlometyl, aminopyrifen, dichlobentiazox, quinofumelin, and dipymetitrone.
14. The agricultural or horticultural fungicide according to claim 2, wherein the nicotinic acetylcholine receptor antagonizing modulator comprises at least one selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, sulfoxaflor, flupyradifurone, and triflumezopyrim.
15. The agricultural or horticultural fungicide according to claim 2, wherein the sodium channel modulator comprises at least one pyrethroid compound selected from acrinathrin, allethrin, cypermethrin, bifenthrin, cycloprothrin, cyhalothrin, cypermethrin, deltamethrin, dimefluthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flubrocythrinate, flucythrinate, fluvalinate, halfenprox, cyhalothrin, metofluthrin, momfluorothrin, permethrin, profluthrin, tefluthrin, tralomethrin, cyfluthrin, bifenthrin, imiprothrin, pyrethrin, cyphenothrin, chloroprallethrin, epsilon-metofluthrin, and epsilon-momfluorothrin.
16. The agricultural or horticultural fungicide according to claim 2, wherein the ryanodine receptor modulator comprises at least one selected from chlorantraniliprole, cyantraniliprole, flubendiamide, and cyhalodiamide.
17. The agricultural or horticultural fungicide according to claim 2, wherein the acetylcholinesterase inhibitor comprises at least one selected from acephate, azinphos-methyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlorpyrifos, cyanophos, demeton-S-methyl, diazinon, dichlorvos (DDVP), dicrotophos, dimethoate, disulfoton, ethion, ethoprophos, EPN, fenamiphos, fenitrothion (MEP), fenthion (MPP), fosthiazate, imicyafos, isofenphos, isoxathion, malathion, methamidophos, methidathion, mevinphos, monocrotophos, omethoate, oxydemeton-methyl, parathion, parathion-methyl, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pirimiphos-methyl, profenofos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, tebupirimphos, terbufos, triazophos, trichlorfon (DEP), alanycarb, aldicarb, benfuracarb, carbaryl (NAC), carbofuran, carbosulfan, cartap, fenobucarb (BPMC), formetanate, isoprocarb (MIPC), methiocarb, methomyl, oxamyl, pirimicarb, thiodicarb, XMC, bendiocarb, ethiofencarb, fenoxycarb, fenothiocarb, furathiocarb, metolcarb, and xylylcarb.
18. The agricultural or horticultural fungicide according to claim 2, wherein the oxidative phosphorylation uncoupler comprises at least one selected from chlorfenapyr, DNOC, and sulfluramid.
19. The agricultural or horticultural fungicide according to claim 2, wherein the mitochondrial electron transport chain complex I inhibitor comprises at least one selected from tebufenpyrad, tolfenpyrad, fenazaquin, fenpyroximate, pyridaben, pyrimidifen, and rotenone.
20. The agricultural or horticultural fungicide according to claim 2, wherein the active ingredient of the plant growth regulator comprises at least one selected from aminoethoxyvinylglycine, chlormequat, chlorpropham, cyclanilide, dikegulac, daminozide, ethephon, flurprimidol, flumetralin, forchlorfenuron, gibberellin, hydrazide maleate, mepiquat chloride, methylcyclopropene, benzylaminopurine, paclobutrazol, prohexadione, thidiazuron, tributylphosphorotrithioate, trinexapac-ethyl, and uniconazole.
21. A method of controlling plant diseases comprising performing foliage treatment or non-foliage treatment using the agricultural or horticultural fungicide described in any one of claims 1 to 20.
22. A product for controlling plant diseases for preparing the agricultural or horticultural fungicide described in any one of claims 1 to 20, comprising the azole derivative and another active ingredient separately as a combination preparation to be mixed before use.
NZ781580A 2020-04-20 Agricultural or horticultural fungicide, method of controlling plant diseases, and product for controlling plant diseases NZ781580B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019080497 2019-04-19
PCT/JP2020/016993 WO2020213739A1 (en) 2019-04-19 2020-04-20 Bactericidal agent for agricultural or horticultural use, plant disease control method, and product for plant disease control use

Publications (2)

Publication Number Publication Date
NZ781580A NZ781580A (en) 2024-01-26
NZ781580B2 true NZ781580B2 (en) 2024-04-30

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