NZ755504B2 - Oxime group-containing condensed heterocyclic compound or salt thereof, agricultural and horticultural insecticide comprising the compound or the salt, and method for using the insecticide - Google Patents
Oxime group-containing condensed heterocyclic compound or salt thereof, agricultural and horticultural insecticide comprising the compound or the salt, and method for using the insecticide Download PDFInfo
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- NZ755504B2 NZ755504B2 NZ755504A NZ75550417A NZ755504B2 NZ 755504 B2 NZ755504 B2 NZ 755504B2 NZ 755504 A NZ755504 A NZ 755504A NZ 75550417 A NZ75550417 A NZ 75550417A NZ 755504 B2 NZ755504 B2 NZ 755504B2
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- 238000000034 method Methods 0.000 title claims abstract description 48
- 239000002917 insecticide Substances 0.000 title claims abstract description 45
- 150000003839 salts Chemical class 0.000 title claims abstract description 43
- 150000002391 heterocyclic compounds Chemical class 0.000 title claims abstract description 32
- 125000003544 oxime group Chemical group 0.000 title claims abstract description 31
- 150000001875 compounds Chemical class 0.000 title description 191
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 34
- 239000004480 active ingredient Substances 0.000 claims abstract description 16
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 6
- -1 oxime compound Chemical class 0.000 claims description 187
- 125000005843 halogen group Chemical group 0.000 claims description 97
- 125000000217 alkyl group Chemical group 0.000 claims description 40
- 125000004414 alkyl thio group Chemical group 0.000 claims description 23
- 239000002689 soil Substances 0.000 claims description 23
- 241001465754 Metazoa Species 0.000 claims description 21
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 19
- 125000004644 alkyl sulfinyl group Chemical group 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 14
- 125000003342 alkenyl group Chemical group 0.000 claims description 12
- 125000000304 alkynyl group Chemical group 0.000 claims description 12
- 244000078703 ectoparasite Species 0.000 claims description 11
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 7
- 125000003302 alkenyloxy group Chemical group 0.000 claims description 7
- 125000005108 alkenylthio group Chemical group 0.000 claims description 7
- 125000005133 alkynyloxy group Chemical group 0.000 claims description 7
- 125000005109 alkynylthio group Chemical group 0.000 claims description 7
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 7
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
- 125000002883 imidazolyl group Chemical group 0.000 claims description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 125000001425 triazolyl group Chemical group 0.000 claims 2
- 241000607479 Yersinia pestis Species 0.000 abstract description 46
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- 238000011161 development Methods 0.000 abstract description 2
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- 239000000126 substance Substances 0.000 abstract description 2
- 125000001188 haloalkyl group Chemical group 0.000 abstract 2
- 125000004995 haloalkylthio group Chemical group 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 description 118
- 238000004519 manufacturing process Methods 0.000 description 90
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
- A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
- A61K31/4427—Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems
- A61K31/4439—Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems containing a five-membered ring with nitrogen as a ring hetero atom, e.g. omeprazole
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
- A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
- A61K31/4427—Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems
- A61K31/444—Non condensed pyridines; Hydrogenated derivatives thereof containing further heterocyclic ring systems containing a six-membered ring with nitrogen as a ring heteroatom, e.g. amrinone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
Abstract
The present invention addresses the problem of developing and providing a novel agricultural and horticultural insecticide due to factors such as the development of pests resistant to existing chemicals since damage by pests is still a major issue in crop production such as agriculture and horticulture. The present invention provides a fused heterocyclic compound having an oxime group represented by general formula (1) (in the formula, R1represents an alkoxy group, R2represents a haloalkyl group, R3represents a haloalkylthio group, A represents an oxygen atom, A1represents a CH group, m is 2, and n is 1) or salts thereof, agricultural/horticultural insecticides having these as active ingredients, and a method for using the insecticides. ure. The present invention provides a fused heterocyclic compound having an oxime group represented by general formula (1) (in the formula, R1represents an alkoxy group, R2represents a haloalkyl group, R3represents a haloalkylthio group, A represents an oxygen atom, A1represents a CH group, m is 2, and n is 1) or salts thereof, agricultural/horticultural insecticides having these as active ingredients, and a method for using the insecticides.
Description
DESCRIPTION OXIME GROUP-CONTAINING CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND OR THE SALT, AND METHOD FOR USING THE INSECTICIDE TECHNICAL FIELD The present invention relates to an oxime group-containing condensed heterocyclic compound or a salt thereof, an agricultural and horticultural insecticide comprising the compound or the salt as an active ingredient, and a method for using the insecticide.
BACKGROUND ART Various compounds have been examined for their potential as agricultural and horticultural insecticides, and among them, certain kinds of condensed heterocyclic compounds have been reported to be useful as insecticides (for example, see Patent Literature 1 to 7). The literature, however, does not specifically disclose any compound having an oxime group bound to a condensed heterocyclic ring.
CITATION LIST Patent Literature Patent Literature 1: JP-A 2009-280574 Patent Literature 2: JP-A 2010-275301 Patent Literature 3: JP-A 2011-79774 Patent Literature 4: JP-A 2012-131780 Patent Literature 5: Patent Literature 6: Patent Literature 7: SUMMARY OF INVENTION TECHNICAL PROBLEM id="p-4" id="p-4" id="p-4" id="p-4" id="p-4"
id="p-4"
[0004] In crop production in the fields of agriculture, horticulture and the like, the damage caused by insect pests etc. is still immense, and insect pests resistant to existing insecticides have emerged. Under such circumstances, the development of novel agricultural and horticultural insecticides is desired.
SOLUTION TO PROBLEM The present inventors conducted extensive research to solve the above-described problems. As a result, the present inventors found that an oxime group-containing condensed heterocyclic compound represented by the general formula (1) and a salt thereof are highly effective for the control of agricultural and horticultural pests and are moderately degradable in the environment and in the bodies of organisms excluding target pests to be controlled. Based on this finding, the present inventors completed the present invention.
That is, the present invention includes the following.
An oxime group-containing condensed heterocyclic compound represented by the general formula (1): {wherein R represents (a1) a halogen atom; (a2) a (C -C ) alkoxy group; (a3) a (C -C ) alkenyloxy group; (a4) a (C -C ) alkynyloxy group; 0 1 (a5) a (C -C ) alkylthio group; (a6) a (C2-C6) alkenylthio group; (a7) a (C -C ) alkynylthio group; (a8) an imidazole group; (a9) an imidazole group having, on the ring, 1 to 3 1 substituting groups which may be the same or different and are selected from (a) a halogen atom, (b) a cyano group, (c) a nitro group, (d) a formyl group, (e) a (C -C ) alkyl group, (f) a halo (C -C ) alkyl group, (g) a (C -C ) alkoxy 1 6 1 6 group, (h) a halo (C -C ) alkoxy group, (i) a (C -C ) 1 6 3 6 0 2 cycloalkyl (C -C ) alkoxy group, (j) a (C -C ) alkylthio 1 6 1 6 group, (k) a halo (C1-C6) alkylthio group, (l) a (C1-C6) alkylsulfinyl group, (m) a halo (C -C ) alkylsulfinyl group, (n) a (C -C ) alkylsulfonyl group and (o) a halo (C - 1 6 1 C ) alkylsulfonyl group; 2 (a10) a triazole group; (a11) a triazole group having, on the ring, 1 or 2 substituting groups which may be the same or different and are selected from (a) a halogen atom, (b) a cyano group, (c) a nitro group, (d) a formyl group, (e) a (C -C ) alkyl group, (f) a halo (C -C ) alkyl group, (g) a (C -C ) alkoxy 1 6 1 6 group, (h) a halo (C1-C6) alkoxy group, (i) a (C3-C6) cycloalkyl (C -C ) alkoxy group, (j) a (C -C ) alkylthio 1 6 1 6 group, (k) a halo (C -C ) alkylthio group, (l) a (C -C ) 1 6 1 6 alkylsulfinyl group, (m) a halo (C -C ) alkylsulfinyl group, (n) a (C -C ) alkylsulfonyl group and (o) a halo (C - 1 6 1 C ) alkylsulfonyl group; (a12) a (C -C ) alkoxy (C -C ) alkyl group; 1 6 1 6 0 1 (a13) a (C -C ) alkyl-CO-NH- group; (a14) a (C -C ) alkoxy-CO-NH- group; (a15) a (C -C ) alkylcarbonyl ((C -C ) alkyl)amino group; or 1 6 1 6 (a16) a (C -C ) alkoxy (C -C ) alkoxy group, 1 6 1 6 R represents 1 (b1) a hydrogen atom; (b2) a (C1-C6) alkyl group; (b3) a (C -C ) alkenyl group; (b4) a (C -C ) alkynyl group; (b5) a (C -C ) cycloalkyl group; 0 2 (b6) a (C -C ) cycloalkyl (C -C ) alkyl group; 3 6 1 6 (b7) a (C -C ) alkoxy (C -C ) alkyl group; 1 6 1 6 (b8) a halo (C -C ) alkyl group; (b9) a halo (C -C ) alkenyl group; (b10) a halo (C -C ) alkynyl group; or 2 (b11) a (C -C ) alkylthio (C -C ) alkyl group, 1 6 1 6 R represents (c1) a halogen atom; (c2) a halo (C -C ) alkyl group; (c3) a halo (C -C ) alkoxy group; (c4) a halo (C -C ) alkylthio group; (c5) a halo (C -C ) alkylsulfinyl group; or (c6) a halo (C -C ) alkylsulfonyl group, A represents an oxygen atom or N-R (wherein R represents (e1) a (C -C ) alkyl group; (e2) a (C -C ) cycloalkyl group; (e3) a (C -C ) alkenyl group; or (e4) a (C -C ) alkynyl group), A represents a CH group or a nitrogen atom, m represents 0, 1 or 2, and n represents 0, 1 or 2}, or a salt thereof. [2] The oxime group-containing condensed heterocyclic compound or the salt according to the above [1], wherein A is an oxygen atom and A is a CH group.
The oxime compound or the salt according to the above [1], wherein A is N-R (wherein R is as defined above). [4] An agricultural and horticultural insecticide comprising the oxime group-containing condensed heterocyclic compound or the salt according to any of the above [1] to [3] as an active ingredient.
A method for using an agricultural and horticultural insecticide, comprising treating plants or soil with an effective amount of the oxime group-containing condensed heterocyclic compound or the salt according to any of the above to [3].
An animal ectoparasite control agent comprising the oxime group-containing condensed heterocyclic compound or the salt according to any of the above [1] to [3] as an active ingredient.
ADVANTAGEOUS EFFECTS OF INVENTION id="p-6" id="p-6" id="p-6" id="p-6" id="p-6"
id="p-6"
[0006] The oxime group-containing condensed heterocyclic compound of the present invention or a salt thereof is not only highly effective as an agricultural and horticultural insecticide but also effective for the disinfection of pests which live on pets such as dogs and cats and domestic animals such as cattle and sheep, and of other harmful pests such as termites.
DESCRIPTION OF EMBODIMENTS In the definitions of the general formula (1) representing the oxime group-containing condensed heterocyclic compound of the present invention or a salt thereof, "halo" refers to a "halogen atom" and represents a chlorine atom, a bromine atom, an iodine atom or a fluorine atom. id="p-8" id="p-8" id="p-8" id="p-8" id="p-8"
id="p-8"
[0008] The "(C -C ) alkyl group" refers to a straight-chain or branched-chain alkyl group of 1 to 6 carbon atoms, for example, a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, an isobutyl group, a sec-butyl group, a tert-butyl group, a n-pentyl group, an isopentyl group, a tert-pentyl group, a neopentyl group, a 2,3-dimethylpropyl group, an 1-ethylpropyl group, a 1-methylbutyl group, a 2-methylbutyl group, a n-hexyl group, an isohexyl group, a 2-hexyl group, a 3-hexyl group, a 2-methylpentyl group, a 3-methylpentyl group, a 1,1,2-trimethyl propyl group, a 3,3-dimethylbutyl group or the like.
The "(C -C ) alkenyl group" refers to a straight-chain or branched-chain alkenyl group of 2 to 6 carbon atoms, for example, a vinyl group, an allyl group, an isopropenyl group, a 1-butenyl group, a 2-butenyl group, a 2-methylpropenyl group, a 1-methylpropenyl group, a 2-methylpropenyl group, a pentenyl group, a 1-hexenyl group, a 3,3-dimethylbutenyl group or the like.
The "(C -C ) alkynyl group" refers to a straight-chain or branched-chain alkynyl group of 2 to 6 carbon atoms, for example, an ethynyl group, a 1-propynyl group, a 2-propynyl group, a 1-butynyl group, a 2-butynyl group, a 3-butynyl group, a 3-methylpropynyl group, a 2-methylpropynyl group, a pentynyl group, a 1-hexynyl group, a 3-methylbutynyl group, a 3,3-dimethylbutynyl group or the like.
The "(C -C ) cycloalkyl group" refers to a cyclic alkyl group of 3 to 6 carbon atoms, for example, a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group or the like. The "(C -C ) alkoxy group" refers to a straight-chain or branched-chain alkoxy group of 1 to 6 carbon atoms, for example, a methoxy group, an ethoxy group, a n-propoxy group, an isopropoxy group, a n-butoxy group, a sec-butoxy group, a tert-butoxy group, a n-pentyloxy group, an isopentyloxy group, a tert-pentyloxy group, a neopentyloxy group, a 2,3-dimethylpropyloxy group, an 1-ethylpropyloxy group, a 1-methylbutyloxy group, a n-hexyloxy group, an isohexyloxy group, a 1,1,2-trimethylpropyloxy group or the like. The "(C -C ) alkenyloxy group" refers to a straight-chain or branched-chain alkenyloxy group of 2 to 6 carbon atoms, for example, a propenyloxy group, a butenyloxy group, a pentenyloxy group, a hexenyloxy group or the like. The "(C -C ) alkynyloxy group" refers to a straight-chain or branched-chain alkynyloxy group of 2 to 6 carbon atoms, for example, a propynyloxy group, a butynyloxy group, a pentynyloxy group, a hexynyloxy group or the like.
The "(C -C ) alkylthio group" refers to a straight-chain or branched-chain alkylthio group of 1 to 6 carbon atoms, for example, a methylthio group, an ethylthio group, a n-propylthio group, an isopropylthio group, a n-butylthio group, a sec-butylthio group, a tert-butylthio group, a n-pentylthio group, an isopentylthio group, a tert-pentylthio group, a neopentylthio group, a 2,3-dimethylpropylthio group, an 1-ethylpropylthio group, a 1-methylbutylthio group, a n-hexylthio group, an isohexylthio group, a 1,1,2-trimethylpropylthio group or the like. The "(C -C ) alkylsulfinyl group" refers to a straight-chain or branched-chain alkylsulfinyl group of 1 to 6 carbon atoms, for example, a methylsulfinyl group, an ethylsulfinyl group, a n-propylsulfinyl group, an isopropylsulfinyl group, a n-butylsulfinyl group, a sec-butylsulfinyl group, a tert-butylsulfinyl group, a n-pentylsulfinyl group, an isopentylsulfinyl group, a tert-pentylsulfinyl group, a neopentylsulfinyl group, a 2,3-dimethylpropylsulfinyl group, an 1-ethylpropylsulfinyl group, a 1-methylbutylsulfinyl group, a n-hexylsulfinyl group, an isohexylsulfinyl group, a 1,1,2-trimethylpropylsulfinyl group or the like. The "(C -C ) alkylsulfonyl group" refers to a straight-chain or branched-chain alkylsulfonyl group of 1 to 6 carbon atoms, for example, a methylsulfonyl group, an ethylsulfonyl group, a n-propylsulfonyl group, an isopropylsulfonyl group, a n-butylsulfonyl group, a sec-butylsulfonyl group, a tert-butylsulfonyl group, a n-pentylsulfonyl group, an isopentylsulfonyl group, a tert-pentylsulfonyl group, a neopentylsulfonyl group, a 2,3-dimethylpropylsulfonyl group, an 1-ethylpropylsulfonyl group, a 1-methylbutylsulfonyl group, a n-hexylsulfonyl group, an isohexylsulfonyl group, a 1,1,2-trimethylpropylsulfonyl group or the like.
The "(C -C ) alkenylthio group" refers to a straight-chain or branched-chain alkenylthio group of 2 to 6 carbon atoms, for example, a propenylthio group, a butenylthio group, a pentenylthio group, a hexenylthio group or the like. The "(C -C ) alkynylthio group" refers to a straight-chain or branched-chain alkynylthio group of 2 to 6 carbon atoms, for example, a propynylthio group, a butynylthio group, a pentynylthio group, a hexynylthio group or the like.
The "(C -C ) alkylcarbonylamino group" refers to a straight-chain or branched-chain alkylcarbonylamino group of 1 to 6 carbon atoms, for example, a methylcarbonylamino group, an ethylcarbonylamino group, a n-propylcarbonylamino group, an isopropylcarbonylamino group, a n-butylcarbonylamino group, a sec-butylcarbonylamino group, a tert-butylcarbonylamino group, a n-pentylcarbonylamino group, an isopentylcarbonylamino group, a tert-pentylcarbonylamino group, a neopentylcarbonylamino group, a 2,3-dimethylpropylcarbonylamino group, an 1-ethylpropylcarbonylamino group, a 1-methylbutylcarbonylamino group, a n-hexylcarbonylamino group, an isohexylcarbonylamino group, a 1,1,2-trimethylpropylcarbonylamino group or the like.
The "(C -C ) alkoxycarbonylamino group" refers to a straight-chain or branched-chain alkoxycarbonylamino group of 1 to 6 carbon atoms, for example, a methoxycarbonylamino group, an ethoxycarbonylamino group, a n-propoxycarbonylamino group, an isopropoxycarbonylamino group, a n-butoxycarbonylamino group, a sec-butoxycarbonylamino group, a tert-butoxycarbonylamino group, a n-pentoxycarbonylamino group, an isopentyloxycarbonylamino group, a tert-pentyloxycarbonylamino group, a neopentyloxycarbonylamino group, a 2,3-dimethylpropyloxycarbonylamino group, an 1-ethylpropyloxycarbonylamino group, a 1-methylbutyloxycarbonylamino group, a n-hexyloxycarbonylamino group, an isohexyloxycarbonylamino group, a 1,1,2-trimethylpropyloxycarbonylamino group or the like.
The above-mentioned "(C -C ) alkyl group", "(C -C ) alkenyl 1 6 2 6 group", "(C2-C6) alkynyl group", "(C3-C6) cycloalkyl group", "(C -C ) cycloalkyloxy group", "(C -C ) alkoxy group", "(C -C ) 3 6 1 6 2 6 alkenyloxy group", "(C -C ) alkynyloxy group", "(C -C ) 2 6 1 6 alkylthio group", "(C -C ) alkylsulfinyl group", "(C -C ) 1 6 1 6 alkylsulfonyl group", "(C -C ) alkenylthio group", "(C -C ) 2 6 2 6 alkynylthio group", "(C -C ) alkylcarbonylamino group", "(C -C ) alkoxycarbonylamino group", "(C -C ) alkenylsulfinyl 1 6 2 6 group", "(C -C ) alkynylsulfinyl group", "(C -C ) 2 6 2 6 alkenylsulfonyl group", "(C -C ) alkynylsulfonyl group", "(C3-C6) cycloalkylthio group", "(C3-C6) cycloalkylsulfinyl group" and "(C -C ) cycloalkylsulfonyl group" may be substituted with one or more halogen atoms at a substitutable position(s) in place of a hydrogen atom(s), and in the case where any of the above-listed groups is substituted with two or more halogen atoms, the halogen atoms may be the same or different.
The above-mentioned "groups substituted with one or more halogen atoms" are expressed as a "halo (C -C ) alkyl group", a "halo (C -C ) alkenyl group", a "halo (C -C ) alkynyl group", 2 6 2 6 a "halo (C -C ) cycloalkyl group", a "halo (C -C ) cycloalkyloxy 3 6 3 6 group", a "halo (C -C ) alkoxy group", a "halo (C -C ) alkenyloxy 1 6 2 6 group", a "halo (C -C ) alkynyloxy group", a "halo (C -C ) 2 6 1 6 alkylthio group", a "halo (C -C ) alkylsulfinyl group", a "halo (C -C ) alkylsulfonyl group", a "halo (C -C ) alkenylthio group", 1 6 2 6 a "halo (C -C ) alkynylthio group", a "halo (C -C ) 2 6 1 6 alkylcarbonylamino group", a "halo (C -C ) alkoxycarbonylamino group", a "halo (C -C ) alkenylsulfinyl group", a "halo (C -C ) 2 6 2 6 alkynylsulfinyl group", a "halo (C -C ) alkenylsulfonyl group", a "halo (C -C ) alkynylsulfonyl group", a "halo (C -C ) 2 6 3 6 cycloalkylthio group", a "halo (C3-C6) cycloalkylsulfinyl group" and a "halo (C -C ) cycloalkylsulfonyl group". The above definitions and examples of each group in the present invention are all obvious to those skilled in the art.
The expressions "(C -C )", "(C -C )", "(C -C )", etc. each 1 6 2 6 3 6 refer to the range of the number of carbon atoms in each group.
The same definition holds true for groups in which two or more of the above-mentioned groups are coupled together, and for example, the "(C1-C6) alkoxy (C1-C6) alkyl group" means that a straight-chain or branched-chain alkoxy group of 1 to 6 carbon atoms is bound to a straight-chain or branched-chain alkyl group of 1 to 6 carbon atoms. id="p-16" id="p-16" id="p-16" id="p-16" id="p-16"
id="p-16"
[0016] Examples of the salt of the oxime group-containing condensed heterocyclic compound represented by the general formula (1) of the present invention include inorganic acid salts, such as hydrochlorides, sulfates, nitrates and phosphates; organic acid salts, such as acetates, fumarates, maleates, oxalates, methanesulfonates, benzenesulfonates and p-toluenesulfonates; and salts with an inorganic or organic base such as a sodium ion, a potassium ion, a calcium ion and a trimethylammonium ion. id="p-17" id="p-17" id="p-17" id="p-17" id="p-17"
id="p-17"
[0017] The oxime group-containing condensed heterocyclic compound represented by the general formula (1) of the present invention and a salt thereof can have one or more chiral centers in the structural formula, and can exist as two or more kinds of optical isomers or diastereomers. All the optical isomers and mixtures of the isomers at any ratio are also included in the present invention. Further, the compound represented by the general formula (1) of the present invention and a salt thereof can exist as two kinds of geometric isomers due to a carbon-carbon double bond in the structural formula. All the geometric isomers and mixtures of the isomers at any ratio are also included in the present invention. The compound of the present invention can exist as a syn isomer (Z isomer) and/or an anti isomer (E isomer) due to the presence of the oxime group. The compound of the present invention may be either of these isomers, or a mixture of the isomers at any ratio.
In the oxime group-containing condensed heterocyclic compound represented by the general formula (1) of the present invention or a salt thereof, R is preferably (a1) a halogen atom; (a2) a (C -C ) alkoxy group; (a3) a (C -C ) alkenyloxy group; (a4) a (C -C ) alkynyloxy group; (a5) a (C -C ) alkylthio group; (a6) a (C -C ) alkenylthio group; (a7) a (C -C ) alkynylthio group; (a8) an imidazole group; (a9) an imidazole group having, on the ring, 1 to 3 substituting groups which may be the same or different and are selected from (a) a halogen atom, (b) a cyano group, (c) a nitro group, (d) a formyl group, (e) a (C -C ) alkyl group, (f) a halo (C -C ) 1 6 1 6 alkyl group, (g) a (C -C ) alkoxy group, (h) a halo (C -C ) alkoxy 1 6 1 6 group, (i) a (C3-C6) cycloalkyl (C1-C6) alkoxy group, (j) a (C -C ) alkylthio group, (k) a halo (C -C ) alkylthio group, (l) 1 6 1 6 a (C -C ) alkylsulfinyl group, (m) a halo (C -C ) alkylsulfinyl 1 6 1 6 group, (n) a (C -C ) alkylsulfonyl group and (o) a halo (C -C ) 1 6 1 6 alkylsulfonyl group; (a10) a triazole group; or (a11) a triazole group having, on the ring, 1 or 2 substituting groups which may be the same or different and are selected from (a) a halogen atom, (b) a cyano group, (c) a nitro group, (d) a formyl group, (e) a (C1-C6) alkyl group, (f) a halo (C1-C6) alkyl group, (g) a (C -C ) alkoxy group, (h) a halo (C -C ) alkoxy 1 6 1 6 group, (i) a (C -C ) cycloalkyl (C -C ) alkoxy group, (j) a 3 6 1 6 (C -C ) alkylthio group, (k) a halo (C -C ) alkylthio group, (l) 1 6 1 6 a (C -C ) alkylsulfinyl group, (m) a halo (C -C ) alkylsulfinyl 1 6 1 6 group, (n) a (C -C ) alkylsulfonyl group and (o) a halo (C -C ) 1 6 1 6 alkylsulfonyl group, R is preferably (b1) a hydrogen atom; (b2) a (C -C ) alkyl group; (b3) a (C -C ) alkenyl group; (b4) a (C -C ) alkynyl group; (b5) a (C -C ) cycloalkyl group; (b6) a (C -C ) cycloalkyl (C -C ) alkyl group; 3 6 1 6 (b7) a (C -C ) alkoxy (C -C ) alkyl group; 1 6 1 6 (b8) a halo (C -C ) alkyl group; (b9) a halo (C -C ) alkenyl group; or (b10) a halo (C -C ) alkynyl group, R is preferably (c1) a halogen atom; (c2) a halo (C1-C6) alkyl group; (c3) a halo (C -C ) alkoxy group; (c4) a halo (C -C ) alkylthio group; (c5) a halo (C -C ) alkylsulfinyl group; or (c6) a halo (C -C ) alkylsulfonyl group, A is preferably O or N-R (wherein R represents (e1) a (C -C ) alkyl group; (e2) a (C -C ) cycloalkyl group; (e3) a (C2-C6) alkenyl group; or (e4) a (C -C ) alkynyl group), A is preferably a CH group or a nitrogen atom, m is preferably 0, 1 or 2, and n is preferably 0, 1 or 2. 1 2 3 1 The combinations of the above defined R , R , R , A, A , m and n represent preferable examples of formula (1).
The oxime group-containing condensed heterocyclic compound of the present invention or a salt thereof can be produced according to, for example, the production methods described below, which are non-limiting examples. The intermediate compounds used in the production methods of the present invention are produced by known methods or methods known per se.
Production Method 1 [Chem. 2] 1 2 3 1 (In the formula, R , R , R , A, A and n are as defined above, X represents a leaving group such as a halogen atom, and MOM stands for methoxymethyl.) id="p-21" id="p-21" id="p-21" id="p-21" id="p-21"
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[0021] Production method at step [a] The compound represented by the general formula (2a-1) can be produced by reacting the compound represented by the general formula (2a) with the compound represented by the general formula (3a) in the presence of a base and an inert solvent.
Examples of the base that can be used in this reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogen carbonate and potassium hydrogen carbonate; alkali metal hydrides such as sodium hydride and potassium hydride; acetates such as potassium acetate; alkali metal alkoxides such as potassium t-butoxide, sodium methoxide and sodium ethoxide; tertiary amines such as triethylamine, diisopropylethylamine and 1,8-diazabicyclo[5.4.0]undecene; and nitrogen-containing aromatic compounds such as pyridine and dimethylaminopyridine. The amount of the base used is usually in the range of a 1- to 10-fold molar amount relative to the compound represented by the general formula (3a).
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the progress of the reaction, and examples include aromatic hydrocarbons such as benzene, toluene and xylene; halogenated aliphatic hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; straight-chain or cyclic ethers such as diethyl ether, methyl tert-butyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; amides such as dimethylformamide and dimethylacetamide; ketones such as acetone and methyl ethyl ketone; and polar solvents such as dimethyl sulfoxide and 1,3-dimethylimidazolidinone. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture.
Since this reaction is an equimolar reaction of the reactants, they are basically used in equimolar amounts, but either of them may be used in an excess amount. The reaction temperature may be in the range of room temperature to the boiling point of the inert solvent used. The reaction time varies with the reaction scale and the reaction temperature, but is basically in the range of a few minutes to 48 hours. After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest. id="p-25" id="p-25" id="p-25" id="p-25" id="p-25"
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[0025] Production method at step [b] The compound represented by the general formula (1A-6) can be produced from the compound represented by the general formula (2a-1) in the presence of an inert solvent according to the method described in Synthesis 1, 1981 (preferably in the presence of azodicarboxylic acid diester and triphenylphosphine).
Production method at step [c] The compound represented by the general formula (1A-5) can be produced by reacting the compound represented by the general formula (1A-6) with an oxidizing agent in an inert solvent.
Examples of the oxidizing agent used in this reaction include peroxides such as a hydrogen peroxide solution, perbenzoic acid and m-chloroperoxybenzoic acid. The amount of the oxidizing agent used is selected as appropriate from the range of a 3- to 5-fold molar amount relative to the compound represented by the general formula (1A-6).
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the reaction, and examples include straight-chain or cyclic ethers such as diethyl ether, tetrahydrofuran and dioxane; aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; nitriles such as acetonitrile; esters such as ethyl acetate; organic acids such as formic acid and acetic acid; and polar solvents such as N,N-dimethylformamide, N,N-dimethylacetamide, 1,3-dimethylimidazolidinone and water. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture. id="p-29" id="p-29" id="p-29" id="p-29" id="p-29"
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[0029] The reaction temperature in this reaction is appropriately selected from the range of -10 C to the reflux temperature of the inert solvent used. The reaction time varies with the reaction scale, the reaction temperature and the like and is not the same in every case, but is basically selected as appropriate from the range of a few minutes to 48 hours. After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production method at step [d] The compound represented by the general formula (1A-4) can be produced by deprotection of the compound represented by the general formula (1A-5) according to the method described in Greene’s Protective GROUPS in Organic SYNTHESIS (4th Edition).
Production method at step [e] The compound represented by the general formula (1A-3) can be produced from the compound represented by the general formula (1A-4) according to the method described in Synthesis 1153, 1996.
Production method at step [f] The compound represented by the general formula (1A-2) can be produced from the compound represented by the general formula (1A-3) by converting the formyl group into an oxime group according to the method described in ORGANIC FUNCTIONAL GROUP PREPARATIONS III, 2nd edition (ACADEMIC PRESS, INC.).
Production method at step [g] The compound represented by the general formula (1A-1) can be produced according to the method described in Journal of Agricultural and Food Chemistry, 56 (15), 6562-6566, 2008.
Specifically, the compound represented by the general formula (1A-2) is reacted with tert-butyl hypochlorite, N-bromosuccinimide (NBS), N-chlorosuccinimide (NCS) or the like in an inert solvent for conversion to a haloimidate compound, which is then reacted with a nucleophile, such as sodium methoxide, sodium ethoxide, 1,2,4-triazole or the like.
As an alternative to the above reaction, cross-coupling as described in Production method at step [j] below can also be used for the production of the haloimidate compound.
Production method at step [h] The compound represented by the general formula (1A) can be produced by reacting the compound represented by the general formula (1A-1) with the compound represented by the general formula (4) in the presence of a base and an inert solvent.
Examples of the base used in this reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, cesium carbonate, sodium hydrogen carbonate and potassium hydrogen carbonate; acetates such as sodium acetate and potassium acetate; alkali metal alkoxides such as potassium t-butoxide, sodium methoxide and sodium ethoxide; tertiary amines such as triethylamine, diisopropylethylamine and 1,8-diazabicyclo[5.4.0]undecene; and nitrogen-containing aromatic compounds such as pyridine and dimethylaminopyridine.
The amount of the base used is usually in the range of a 1- to -fold molar amount relative to the compound represented by the general formula (1A-1).
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the progress of the reaction, and examples include aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; straight-chain or cyclic ethers such as diethyl ether, methyl tert-butyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; amides such as dimethylformamide and dimethylacetamide; ketones such as acetone and methyl ethyl ketone; and polar solvents such as dimethyl sulfoxide and 1,3-dimethylimidazolidinone. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture.
Since this reaction is an equimolar reaction of the reactants, the compound represented by the general formula (1A-1) and the compound represented by the general formula (4) are used basically in equimolar amounts, but either of them may be used in an excess amount. The reaction temperature is in the range of -10 C to the boiling point of the inert solvent used. The reaction time varies with the reaction scale and the reaction temperature, but is basically in the range of a few minutes to 48 hours. After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production Method 2 [Chem. 3] 1 2 3 1 (In the formula, R , R , R , A, A and n are as defined above, Et stands for an ethyl group, and X represents a halogen atom.) Production method at step [a-1] The amide compound represented by the general formula (2a-2) can be produced by reacting the carboxylic acid chloride represented by the general formula (2h) with the compound represented by the general formula (3a) in the presence of a base and an inert solvent. The carboxylic acid chloride used in this reaction can be produced from 3,6-dichloropyridinecarboxylic acid by the usual method.
Examples of the base that can be used in this reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogen carbonate and potassium hydrogen carbonate; alkali metal hydrides such as sodium hydride and potassium hydride; acetates such as potassium acetate; alkali metal alkoxides such as potassium t-butoxide, sodium methoxide and sodium ethoxide; tertiary amines such as triethylamine, diisopropylethylamine and 1,8-diazabicyclo[5.4.0]undecene; and nitrogen-containing aromatic compounds such as pyridine and dimethylaminopyridine. The amount of the base used is usually in the range of a 1- to 10-fold molar amount relative to the compound represented by the general formula (2h).
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the progress of the reaction, and examples include aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; straight-chain or cyclic ethers such as diethyl ether, methyl tert-butyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; amides such as dimethylformamide and dimethylacetamide; ketones such as acetone and methyl ethyl ketone; and polar solvents such as dimethyl sulfoxide and 1,3-dimethylimidazolidinone. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture.
Since this reaction is an equimolar reaction of the reactants, they are basically used in equimolar amounts, but either of them may be used in an excess amount. The reaction temperature may be in the range of room temperature to the boiling point of the inert solvent used. The reaction time varies with the reaction scale and the reaction temperature, but is basically in the range of a few minutes to 48 hours. After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production method at step [b] The compound represented by the general formula (1B-8) can be produced from the amide compound represented by the general formula (2a-2) in the same manner as described in step [b] of Production Method 1 above. id="p-44" id="p-44" id="p-44" id="p-44" id="p-44"
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[0044] Production method at step [i] The compound represented by the general formula (1B-7) can be produced by reacting the compound represented by the general formula (1B-8) with the compound represented by the general formula (5) in the presence of a base and an inert solvent.
Examples of the base used in this reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogen carbonate and potassium hydrogen carbonate; acetates such as sodium acetate and potassium acetate; alkali metal alkoxides such as potassium t-butoxide, sodium methoxide and sodium ethoxide; tertiary amines such as triethylamine, diisopropylethylamine and 1,8-diazabicyclo[5.4.0]undecene; and nitrogen-containing aromatic compounds such as pyridine and dimethylaminopyridine.
The amount of the base used is usually in the range of a 1- to -fold molar amount relative to the compound represented by the general formula (1B-8). In the case where an alkali salt of the compound represented by the general formula (5) is used, it is not necessary to use a base.
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the progress of the reaction, and examples include aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; straight-chain or cyclic ethers such as diethyl ether, methyl tert-butyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; amides such as dimethylformamide and dimethylacetamide; ketones such as acetone and methyl ethyl ketone; and polar solvents such as dimethyl sulfoxide and 1,3-dimethylimidazolidinone. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture.
Since this reaction is an equimolar reaction of the reactants, the compound represented by the general formula (1B-8) and the compound represented by the general formula (5) are used basically in equimolar amounts, but either of them may be used in an excess amount. The reaction temperature is in the range of -10 C to the boiling point of the inert solvent used. The reaction time varies with the reaction scale and the reaction temperature, but is basically in the range of a few minutes to 48 hours. After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production method at step [c] The compound represented by the general formula (1B-6) can be produced from the compound represented by the general formula (1B-7) in the same manner as described in step [c] of Production Method 1 above.
Production method at step [j] The compound represented by the general formula (1B-5) can be produced by cross-coupling of the compound represented by the general formula (1B-6) with a vinylboronic acid compound in the presence of a metal catalyst and a base in an inert solvent.
Examples of the metal catalyst that can be used in this reaction include a palladium catalyst, a nickel catalyst, an iron catalyst, a ruthenium catalyst, a platinum catalyst, a rhodium catalyst and an iridium catalyst. Such a metal catalyst can be used in the form of "a metal", "a supported metal", "a metal salt such as a metal chloride, a metal bromide, a metal iodide, a metal nitrate, a metal sulfate, a metal carbonate, a metal oxalate, a metal acetate and a metal oxide", or "a complex compound such as an olefin complex, a phosphine complex, an amine complex, an ammine complex and an acetylacetonate complex". Preferred is a palladium catalyst.
Examples of the palladium catalyst include palladium metals such as palladium black and palladium sponge; and supported palladium metals such as palladium/alumina, palladium/carbon, palladium/silica and palladium/type Y zeolite. Also included are palladium metal salts such as palladium chloride, palladium bromide, palladium iodide and palladium acetate. Other examples of the palladium catalyst include palladium complex compounds such as π-allylpalladium chloride dimer, palladium acetylacetonate, dichlorobis(acetonitrile)palladium, dichlorobis(benzonitrile)palladium, bis(dibenzylideneacetone)palladium, tris(dibenzylideneacetone)dipalladium, tris(dibenzylideneacetone)dipalladium (chloroform adduct), dichlorodiamine palladium, dichlorobis(triphenylphosphine)palladium, dichlorobis(tricyclohexylphosphine)palladium, tetrakis(triphenylphosphine)palladium, dichloro[1,2-bis(diphenylphosphino)ethane]palladium, dichloro[1,3-bis(diphenylphosphino)propane]palladium, dichloro[1,4-bis(diphenylphosphino)butane]palladium, dichloro[1,1’-bis(diphenylphosphino)ferrocene]palladium and [(diphenylphosphino)ferrocene]dichloropalladium-dichloromet hane complex.
These palladium catalysts may be used alone or in combination with a tertiary phosphine. Examples of the tertiary phosphine that can be used in combination with the palladium catalyst include triphenylphosphine, trimethylphosphine, triethylphosphine, tributylphosphine, tri(tert-butyl)phosphine, tricyclohexylphosphine, tri-o-tolylphosphine, trioctylphosphine, 9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene, 2-(di-tert-butylphosphino)biphenyl, 2-(dicyclohexylphosphino)biphenyl, 1,2-bis(diphenylphosphino)ethane, 1,3-bis(diphenylphosphino)propane, 1,4-bis(diphenylphosphino)butane, 1,1’-bis(diphenylphosphino)ferrocene, (R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl, (S)-(-)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl and ( ±)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl.
Examples of the vinylboronic acid compound that can be used in this reaction include vinylmagnesium bromide, vinylmagnesium chloride, vinylzinc chloride, tributylvinyltin, potassium vinyltrifluoroborate, vinylboronic acid, vinylboronic anhydride, vinylboronic acid 2-methyl-2,4-pentanediol ester, vinylboronic acid pinacol ester and triethoxyvinylsilane.
Examples of the base that can be used in this reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, cesium carbonate, sodium hydrogen carbonate and potassium hydrogen carbonate; alkali metal hydrides such as sodium hydride and potassium hydride; and alkoxides such as sodium methoxide, sodium ethoxide and potassium tert-butoxide. The amount of the base used is usually in the range of an about 1- to 5-fold molar amount relative to the compound represented by the general formula (1B-6).
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the reaction, and examples include alcohols such as methanol, ethanol, propanol, butanol and 2-propanol; straight-chain or cyclic ethers such as diethyl ether, tetrahydrofuran, dioxane and 1,2-dimethoxyethane (DME); aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; nitriles such as acetonitrile; esters such as ethyl acetate; polar solvents such as N,N-dimethylformamide, N,N-dimethylacetamide, dimethyl sulfoxide and 1,3-dimethylimidazolidinone; and water. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture.
The reaction temperature in this reaction is usually in the range of about 0 C to the boiling point of the solvent used.
The reaction time varies with the reaction scale, the reaction temperature and the like, but is basically selected as appropriate from the range of a few minutes to 48 hours. This reaction may be conducted under the atmosphere of an inert gas such as nitrogen gas and argon gas. After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production method at step [k] The diol-containing condensed heterocyclic compound represented by the general formula (1B-4) can be produced by the reaction of the vinyl-containing condensed heterocyclic compound represented by the general formula (1B-5) in the presence of osmium tetroxide and an oxidizing agent according to the method described in the Lecture of Experimental Chemistry (Jikken Kagaku Kouza), 4th edition, vol. 23, Organic Chemistry V, Oxidation Reaction (published by Maruzen Co., Ltd.). After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production method at step [l] The compound represented by the general formula (1B-3) can be produced by reacting the diol compound represented by the general formula (1B-4) with a periodic acid compound in the presence of an inert solvent according to the method described in the New Lecture of Experimental Chemistry (Shin Jikken Kagaku Kouza), vol. 15, Oxidation and Reduction I-1 (published by Maruzen Co., Ltd). After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production method at step [f] The compound represented by the general formula (1B-2) can be produced from the compound represented by the general formula (1B-3) in the same manner as described in step [f] of Production Method 1 above. id="p-60" id="p-60" id="p-60" id="p-60" id="p-60"
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[0060] Production method at step [g] The compound represented by the general formula (1B-1) can be produced from the compound represented by the general formula (1B-2) in the same manner as described in step [g] of Production Method 1 above.
Production method at step [h] The compound represented by the general formula (1B) can be produced from the compound represented by the general formula (1B-1) in the same manner as described in step [h] of Production Method 1 above.
Production Method of Intermediate (2a) [Chem. 4] (In the formula, R represents a (C -C ) alkyl group.) The compound represented by the general formula (2a), which is an intermediate for the production of the compound of the present invention, can be produced by the following scheme. ,6-Dichloropyridinecarboxylic acid (2g), which is commonly available, is subjected to the reaction described in JP-A 2005-272338 (Heck reaction) to yield the pyridinecarboxylic acid with an ester group introduced at the C6 position (2f). After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. If desired, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
For production of pyridine-2,6-dicarboxylic acid ester (2e), the esterified pyridinecarboxylic acid (2f) is first reacted with a chlorinating agent in an inert solvent according to the usual synthesis method to yield a pyridine carboxylic acid chloride, and then the pyridine carboxylic acid chloride is reacted with a tert-butyl alcohol.
The pyridine dicarboxylic acid ester (2d) can be produced by reacting the tert-butyl ester compound of pyridine represented by the general formula (2e) with the compound represented by the general formula (5) in the presence of a base and an inert solvent. id="p-67" id="p-67" id="p-67" id="p-67" id="p-67"
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[0067] Examples of the base used in this reaction include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogen carbonate and potassium hydrogen carbonate; acetates such as sodium acetate and potassium acetate; alkali metal alkoxides such as potassium t-butoxide, sodium methoxide and sodium ethoxide; tertiary amines such as triethylamine, diisopropylethylamine and 1,8-diazabicyclo[5.4.0]undecene; and nitrogen-containing aromatic compounds such as pyridine and dimethylaminopyridine.
The amount of the base used is usually in the range of a 1- to -fold molar amount relative to the tert-butyl ester compound represented by the general formula (2e). In the case where an alkali salt of the compound represented by the general formula (5) is used, it is not necessary to use a base.
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the progress of the reaction, and examples include aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; straight-chain or cyclic ethers such as diethyl ether, methyl tert-butyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; amides such as dimethylformamide and dimethylacetamide; ketones such as acetone and methyl ethyl ketone; and polar solvents such as dimethyl sulfoxide and 1,3-dimethylimidazolidinone. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture.
Since this reaction is an equimolar reaction of the reactants, the compound represented by the general formula (5) and the tert-butyl ester compound of pyridine represented by the general formula (2e) are used basically in equimolar amounts, but either of them may be used in an excess amount. The reaction temperature is in the range of -10 C to the boiling point of the inert solvent used. The reaction time varies with the reaction scale and the reaction temperature, but is basically in the range of a few minutes to 48 hours. After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
The pyridine dicarboxylic acid (2c) can be produced by hydrolyzing the tert-butyl ester compound of pyridine represented by the general formula (2d) in the presence of an acid and/or an inert solvent.
Examples of the acid used in this reaction include inorganic acids such as hydrochloric acid, sulfuric acid and nitric acid; organic acids such as formic acid, acetic acid, propionic acid, trifluoroacetic acid and benzoic acid; and sulfonic acids such as methanesulfonic acid and trifluoromethanesulfonic acid.
The amount of the acid used is appropriately selected from the range of a 1- to 10-fold molar amount relative to the tert-butyl ester compound represented by the general formula (2d). In some cases, the acid can be used also as the solvent for this reaction.
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the progress of the reaction, and examples include aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; straight-chain or cyclic ethers such as diethyl ether, methyl tert-butyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; amides such as dimethylformamide and dimethylacetamide; ketones such as acetone and methyl ethyl ketone; and polar solvents such as dimethyl sulfoxide and 1,3-dimethylimidazolidinone. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture. In the case where the acid is used also as the solvent, it is not necessary to use another solvent.
The reaction temperature may be in the range of room temperature to the boiling point of the inert solvent used. The reaction time varies with the reaction scale and the reaction temperature, but is basically in the range of a few minutes to 48 hours.
After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method.
As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
For production of the compound represented by the general formula (2b), the compound represented by the general formula (2c) is first converted to a carboxylic acid chloride by the usual method, and then the carboxylic acid chloride is reduced with sodium borohydride (NaBH ). id="p-75" id="p-75" id="p-75" id="p-75" id="p-75"
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[0075] The compound represented by the general formula (2a) can be produced from the compound represented by the general formula (2b) according to the method described in Greene’s Protective GROUPS in Organic SYNTHESIS (4th Edition). id="p-76" id="p-76" id="p-76" id="p-76" id="p-76"
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[0076] Production Method of Intermediate (1A-2a) [Chem. 5] 2 3 1 (In the formula, R , R and A are as defined above, X represents a halogen atom, and R represents a (C -C ) alkyl group.) The compound represented by the general formula (2d-1) can be produced from the compound represented by the general formula (2d), which can be produced in the same manner as described in Production Method of Intermediate (2a) above, in the same manner as described in step [a] of Production Method 1 above. id="p-78" id="p-78" id="p-78" id="p-78" id="p-78"
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[0078] The compound represented by the general formula (1A-10a) can be produced from the compound represented by the general formula (2d-1) in the same manner as described in step [b] of Production Method 1 above. id="p-79" id="p-79" id="p-79" id="p-79" id="p-79"
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[0079] The compound represented by the general formula (1A-9a) can be produced from the compound represented by the general formula (1A-10a) in the same manner as described in step [c] of Production Method 1 above. id="p-80" id="p-80" id="p-80" id="p-80" id="p-80"
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[0080] Production method at step [m] The compound represented by the general formula (1A-8a) can be produced by hydrolyzing the compound represented by the general formula (1A-9a) in the presence of an acid and/or an inert solvent. id="p-81" id="p-81" id="p-81" id="p-81" id="p-81"
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[0081] Examples of the acid used in this reaction include inorganic acids such as hydrochloric acid, sulfuric acid and nitric acid; organic acids such as formic acid, acetic acid, propionic acid, trifluoroacetic acid and benzoic acid; and sulfonic acids such as methanesulfonic acid and trifluoromethanesulfonic acid.
The amount of the acid used is selected as appropriate from the range of a 1- to 10-fold molar amount relative to the compound represented by the general formula (1A-9a). In some cases, the acid can be used also as the solvent for this reaction. id="p-82" id="p-82" id="p-82" id="p-82" id="p-82"
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[0082] The inert solvent used in this reaction may be any solvent that does not markedly inhibit the progress of the reaction, and examples include aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; straight-chain or cyclic ethers such as diethyl ether, methyl tert-butyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; amides such as dimethylformamide and dimethylacetamide; ketones such as acetone and methyl ethyl ketone; and polar solvents such as dimethyl sulfoxide and 1,3-dimethylimidazolidinone. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture. In the case where the acid is used also as the solvent, it is not necessary to use another solvent.
The reaction temperature may be in the range of room temperature to the boiling point of the inert solvent used. The reaction time varies with the reaction scale and the reaction temperature, but is basically in the range of a few minutes to 48 hours.
After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method.
As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production method at step [n] The compound represented by the general formula (1A-7a) can be produced by reacting the compound represented by the general formula (1A-8a) with the compound represented by R O-NH (wherein R is as defined above) in the presence of a condensing agent, a base and an inert solvent. id="p-85" id="p-85" id="p-85" id="p-85" id="p-85"
id="p-85"
[0085] Examples of the condensing agent used in this reaction include 1-(3-dimethylaminopropyl)ethylcarbodiimide hydrochloride (EDCl), diethyl phosphorocyanidate (DEPC), carbonyldiimidazole (CDI), 1,3-dicyclohexylcarbodiimide (DCC), chlorocarbonic esters and 2-chloromethylpyridinium iodide. The amount of the condensing agent used is appropriately selected from the range of a 1- to 1.5-fold molar amount relative to the compound represented by the general formula (1A-8a).
Examples of the base used include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogen carbonate and potassium hydrogen carbonate; acetates such as sodium acetate and potassium acetate; alkali metal alkoxides such as potassium t-butoxide, sodium methoxide and sodium ethoxide; tertiary amines such as triethylamine, diisopropylethylamine and 1,8-diazabicyclo[5.4.0]undecene; and nitrogen-containing aromatic compounds such as pyridine and dimethylaminopyridine.
The amount of the base used is usually in the range of a 1- to -fold molar amount relative to the compound represented by the general formula (1A-8a).
The inert solvent used in this reaction may be any solvent that does not markedly inhibit the progress of the reaction, and examples include aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride; halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene; straight-chain or cyclic ethers such as diethyl ether, methyl tert-butyl ether, dioxane and tetrahydrofuran; esters such as ethyl acetate; amides such as dimethylformamide and dimethylacetamide; ketones such as acetone and methyl ethyl ketone; and other solvents such as dimethyl sulfoxide and 1,3-dimethylimidazolidinone. One of these inert solvents may be used alone, and also two or more of them may be used as a mixture.
Since this reaction is an equimolar reaction of the reactants, they are basically used in equimolar amounts, but either of them may be used in an excess amount. The reaction temperature may be in the range of room temperature to the boiling point of the inert solvent used. The reaction time varies with the reaction scale and the reaction temperature, but is basically in the range of a few minutes to 48 hours. After the reaction is completed, the compound of interest is isolated from the post-reaction mixture by the usual method. As needed, recrystallization, column chromatography, etc. can be employed for the purification of the compound of interest.
Production method at step [o] The compound represented by the general formula (1A-2a) can be produced by the so-called Appel reaction (Org. Synth. 54, 63-63), i.e., by reacting the compound represented by the general formula (1A-7a) with triphenylphosphine and carbon tetrachloride or carbon tetrabromide.
The compound represented by the general formula (1A-2a), which is produced according to the production scheme described above, is subjected to the reactions described in step [g] of Production Method 1 above to yield the compound represented by the general formula (1A). id="p-91" id="p-91" id="p-91" id="p-91" id="p-91"
id="p-91"
[0091] Specific examples of the compound of the present invention are shown below. In the tables given below, Me stands for a methyl group, Et stands for an ethyl group, n-Pr stands for a n-propyl group, i-Pr stands for an isopropyl group, i-Bu stands for an isobutyl group, and t-Bu stands for a tert-butyl group.
Shown in the column of "Physical property" is a melting point or "NMR". NMR data are shown in Table 32.
[Chem. 6] [Table 1] Table 1 Compound Physical 1 2 3 R R R No. property 1-1 OMe Me CF 1-2 OMe Et CF 1-3 OMe n-Pr CF 1-4 OMe i-Pr CF 1-5 OMe CH CHF CF 2 2 3 1-6 OMe CH2CF3 CF3 NMR 1-7 OMe CH CF CHF CF 2 2 2 3 1-8 OMe CH CF CF CF 2 2 3 3 1-9 OMe CH2OCH3 CF3 1-10 OMe CH SCH CF NMR 2 3 3 1-11 OEt Me CF 1-12 OEt Et CF3 1-13 OEt n-Pr CF 1-14 OEt i-Pr CF 1-15 OEt CH CHF CF 2 2 3 1-16 OEt CH CF CF 2 3 3 1-17 OEt CH CF CHF CF 2 2 2 3 1-18 OEt CH CF CF CF 2 2 3 3 1-19 OEt CH OCH CF 2 3 3 1-20 OEt CH SCH CF 2 3 3 1-21 On-Pr Me CF 1-22 On-Pr Et CF 1-23 On-Pr n-Pr CF 1-24 On-Pr i-Pr CF 1-25 On-Pr CH CHF CF 2 2 3 [Table 2] Table 2 Compound Physical 1 2 3 R R R No. property 1-26 On-Pr CH CF CF 2 3 3 1-27 On-Pr CH CF CHF CF 2 2 2 3 1-28 On-Pr CH CF CF CF 2 2 3 3 1-29 On-Pr CH OCH CF 2 3 3 1-30 On-Pr CH SCH CF 2 3 3 1-31 Oi-Pr Me CF 1-32 Oi-Pr Et CF 1-33 Oi-Pr n-Pr CF 1-34 Oi-Pr i-Pr CF 1-35 Oi-Pr CH CHF CF 2 2 3 1-36 Oi-Pr CH CF CF 2 3 3 1-37 Oi-Pr CH CF CHF CF 2 2 2 3 1-38 Oi-Pr CH CF CF CF 2 2 3 3 1-39 Oi-Pr CH OCH CF 2 3 3 1-40 Oi-Pr CH SCH CF 2 3 3 1-41 Ot-Bu Me CF 1-42 Ot-Bu Et CF 1-43 Ot-Bu n-Pr CF 1-44 Ot-Bu i-Pr CF 1-45 Ot-Bu CH CHF CF 2 2 3 1-46 Ot-Bu CH CF CF 2 3 3 1-47 Ot-Bu CH CF CHF CF 2 2 2 3 1-48 Ot-Bu CH CF CF CF 2 2 3 3 1-49 Ot-Bu CH OCH CF 2 3 3 1-50 Ot-Bu CH SCH CF 2 3 3 [Table 3] Table 3 Compound Physical 1 2 3 R R R No. property 1-51 SEt Me CF 1-52 SEt Et CF 1-53 SEt n-Pr CF 1-54 SEt i-Pr CF3 1-55 SEt CH CHF CF 2 2 3 1-56 SEt CH CF CF 2 3 3 1-57 SEt CH CF CHF CF 2 2 2 3 1-58 SEt CH CF CF CF 2 2 3 3 1-59 SEt CH OCH CF 2 3 3 1-60 SEt CH SCH CF 2 3 3 1-61 1,2,4-Triazolyl Me CF 1-62 1,2,4-Triazolyl Et CF 1-63 1,2,4-Triazolyl n-Pr CF 1-64 1,2,4-Triazolyl i-Pr CF 1-65 1,2,4-Triazolyl CH CHF CF 2 2 3 1-66 1,2,4-Triazolyl CH CF CF 198-199 2 3 3 1-67 1,2,4-Triazolyl CH CF CHF CF 2 2 2 3 1-68 1,2,4-Triazolyl CH CF CF CF 2 2 3 3 1-69 1,2,4-Triazolyl CH OCH CF 2 3 3 1-70 1,2,4-Triazolyl CH SCH CF 2 3 3 1-71 NHAc CH CF CF 168-169 2 3 3 [Chem. 7] [Table 4] Table 4 Compound Physical 1 2 3 R R R No. property 2-1 OMe Me CF 2-2 OMe Et CF 2-3 OMe n-Pr CF 2-4 OMe i-Pr CF 2-5 OMe CH CHF CF 2 2 3 2-6 OMe CH CF CF 112-113 2 3 3 2-7 OMe CH CF CHF CF 2 2 2 3 2-8 OMe CH2CF2CF3 CF3 2-9 OMe CH OCH CF 2 3 3 2-10 OMe CH SCH CF 2 3 3 2-11 OEt Me CF3 2-12 OEt Et CF 2-13 OEt n-Pr CF 2-14 OEt i-Pr CF3 2-15 OEt CH CHF CF 2 2 3 2-16 OEt CH CF CF 2 3 3 2-17 OEt CH CF CHF CF 2 2 2 3 2-18 OEt CH CF CF CF 2 2 3 3 2-19 OEt CH OCH CF 2 3 3 2-20 OEt CH SCH CF 2 3 3 2-21 On-Pr Me CF 2-22 On-Pr Et CF 2-23 On-Pr n-Pr CF 2-24 On-Pr i-Pr CF 2-25 On-Pr CH CHF CF 2 2 3 [Table 5] Table 5 Compound Physical 1 2 3 R R R No. property 2-26 On-Pr CH CF CF 2 3 3 2-27 On-Pr CH CF CHF CF 2 2 2 3 2-28 On-Pr CH CF CF CF 2 2 3 3 2-29 On-Pr CH OCH CF 2 3 3 2-30 On-Pr CH SCH CF 2 3 3 2-31 Oi-Pr Me CF 2-32 Oi-Pr Et CF 2-33 Oi-Pr n-Pr CF 2-34 Oi-Pr i-Pr CF 2-35 Oi-Pr CH CHF CF 2 2 3 2-36 Oi-Pr CH CF CF 2 3 3 2-37 Oi-Pr CH CF CHF CF 2 2 2 3 2-38 Oi-Pr CH CF CF CF 2 2 3 3 2-39 Oi-Pr CH OCH CF 2 3 3 2-40 Oi-Pr CH SCH CF 2 3 3 2-41 Ot-Bu Me CF 2-42 Ot-Bu Et CF 2-43 Ot-Bu n-Pr CF 2-44 Ot-Bu i-Pr CF 2-45 Ot-Bu CH CHF CF 2 2 3 2-46 Ot-Bu CH CF CF 2 3 3 2-47 Ot-Bu CH CF CHF CF 2 2 2 3 2-48 Ot-Bu CH CF CF CF 2 2 3 3 2-49 Ot-Bu CH OCH CF 2 3 3 2-50 Ot-Bu CH SCH CF 2 3 3 [Table 6] Table 6 Compound Physical 1 2 3 R R R No. property 2-51 SEt Me CF3 2-52 SEt Et CF 2-53 SEt n-Pr CF 2-54 SEt i-Pr CF 2-55 SEt CH CHF CF 2 2 3 2-56 SEt CH CF CF 2 3 3 2-57 SEt CH CF CHF CF 2 2 2 3 2-58 SEt CH CF CF CF 2 2 3 3 2-59 SEt CH OCH CF 2 3 3 2-60 SEt CH SCH CF 2 3 3 2-61 1,2,4-Triazolyl Me CF 2-62 1,2,4-Triazolyl Et CF 2-63 1,2,4-Triazolyl n-Pr CF 2-64 1,2,4-Triazolyl i-Pr CF 2-65 1,2,4-Triazolyl CH CHF CF 2 2 3 2-66 1,2,4-Triazolyl CH CF CF 2 3 3 2-67 1,2,4-Triazolyl CH CF CHF CF 2 2 2 3 2-68 1,2,4-Triazolyl CH CF CF CF 2 2 3 3 2-69 1,2,4-Triazolyl CH OCH CF 2 3 3 2-70 1,2,4-Triazolyl CH SCH CF 2 3 3 [Chem. 8] [Table 7] Table 7 Compound 1 2 3 R R R Physical property 3-1 OMe Me CF 3-2 OMe Et CF3 3-3 OMe n-Pr CF 3-4 OMe i-Pr CF 3-5 OMe CH CHF CF 2 2 3 3-6 OMe CH CF CF 167-168 2 3 3 3-7 OMe CH CF CHF CF 2 2 2 3 3-8 OMe CH CF CF CF 2 2 3 3 3-9 OMe CH OCH CF 2 3 3 3-10 OMe CH SCH CF 2 3 3 3-11 OEt Me CF 3-12 OEt Et CF 3-13 OEt n-Pr CF 3-14 OEt i-Pr CF 3-15 OEt CH CHF CF 2 2 3 3-16 OEt CH CF CF 2 3 3 3-17 OEt CH CF CHF CF 2 2 2 3 3-18 OEt CH CF CF CF 2 2 3 3 3-19 OEt CH OCH CF 2 3 3 3-20 OEt CH SCH CF 2 3 3 3-21 On-Pr Me CF 3-22 On-Pr Et CF 3-23 On-Pr n-Pr CF 3-24 On-Pr i-Pr CF 3-25 On-Pr CH CHF CF 2 2 3 [Table 8] Table 8 Compound Physical 1 2 3 R R R No. property 3-26 On-Pr CH CF CF 2 3 3 3-27 On-Pr CH CF CHF CF 2 2 2 3 3-28 On-Pr CH CF CF CF 2 2 3 3 3-29 On-Pr CH OCH CF 2 3 3 3-30 On-Pr CH SCH CF 2 3 3 3-31 Oi-Pr Me CF 3-32 Oi-Pr Et CF 3-33 Oi-Pr n-Pr CF 3-34 Oi-Pr i-Pr CF 3-35 Oi-Pr CH CHF CF 2 2 3 3-36 Oi-Pr CH CF CF 2 3 3 3-37 Oi-Pr CH CF CHF CF 2 2 2 3 3-38 Oi-Pr CH CF CF CF 2 2 3 3 3-39 Oi-Pr CH OCH CF 2 3 3 3-40 Oi-Pr CH SCH CF 2 3 3 3-41 Ot-Bu Me CF 3-42 Ot-Bu Et CF 3-43 Ot-Bu n-Pr CF 3-44 Ot-Bu i-Pr CF 3-45 Ot-Bu CH CHF CF 2 2 3 3-46 Ot-Bu CH CF CF 2 3 3 3-47 Ot-Bu CH CF CHF CF 2 2 2 3 3-48 Ot-Bu CH CF CF CF 2 2 3 3 3-49 Ot-Bu CH OCH CF 2 3 3 3-50 Ot-Bu CH SCH CF 2 3 3 [Table 9] Table 9 Compound Physical 1 2 3 R R R No. property 3-51 SEt Me CF 3-52 SEt Et CF 3-53 SEt n-Pr CF 3-54 SEt i-Pr CF 3-55 SEt CH CHF CF 2 2 3 3-56 SEt CH CF CF 2 3 3 3-57 SEt CH2CF2CHF2 CF3 3-58 SEt CH CF CF CF 2 2 3 3 3-59 SEt CH OCH CF 2 3 3 3-60 SEt CH2SCH3 CF3 3-61 1,2,4-Triazolyl Me CF 3-62 1,2,4-Triazolyl Et CF 3-63 1,2,4-Triazolyl n-Pr CF3 3-64 1,2,4-Triazolyl i-Pr CF 3-65 1,2,4-Triazolyl CH CHF CF 2 2 3 3-66 1,2,4-Triazolyl CH CF CF 2 3 3 3-67 1,2,4-Triazolyl CH CF CHF CF 2 2 2 3 3-68 1,2,4-Triazolyl CH CF CF CF 2 2 3 3 3-69 1,2,4-Triazolyl CH OCH CF 2 3 3 3-70 1,2,4-Triazolyl CH SCH CF 2 3 3 [Table 10] Table 10 Compound Physical 1 2 3 R R R No. property 3-71 OMe Me SCF 3-72 OMe Et SCF 3-73 OMe n-Pr SCF 3-74 OMe i-Pr SCF 3-75 OMe CH CHF SCF 2 2 3 3-76 OMe CH CF SCF 135-136 2 3 3 3-77 OMe CH CF CHF SCF 2 2 2 3 3-78 OMe CH CF CF SCF 2 2 3 3 3-79 OMe CH OCH SCF 2 3 3 3-80 OMe CH SCH SCF 2 3 3 3-81 OEt Me SCF 3-82 OEt Et SCF 3-83 OEt n-Pr SCF 3-84 OEt i-Pr SCF 3-85 OEt CH CHF SCF 2 2 3 3-86 OEt CH CF SCF 118-119 2 3 3 3-87 OEt CH CF CHF SCF 2 2 2 3 3-88 OEt CH CF CF SCF 2 2 3 3 3-89 OEt CH OCH SCF 2 3 3 3-90 OEt CH SCH SCF 2 3 3 3-91 On-Pr Me SCF 3-92 On-Pr Et SCF 3-93 On-Pr n-Pr SCF 3-94 On-Pr i-Pr SCF 3-95 On-Pr CH CHF SCF 2 2 3 [Table 11] Table 11 Compound Physical 1 2 3 R R R No. property 3-96 On-Pr CH CF SCF 2 3 3 3-97 On-Pr CH CF CHF SCF 2 2 2 3 3-98 On-Pr CH CF CF SCF 2 2 3 3 3-99 On-Pr CH OCH SCF 2 3 3 3-100 On-Pr CH SCH SCF 2 3 3 3-101 Oi-Pr Me SCF 3-102 Oi-Pr Et SCF 3-103 Oi-Pr n-Pr SCF 3-104 Oi-Pr i-Pr SCF 3-105 Oi-Pr CH CHF SCF 2 2 3 3-106 Oi-Pr CH CF SCF 2 3 3 3-107 Oi-Pr CH CF CHF SCF 2 2 2 3 3-108 Oi-Pr CH CF CF SCF 2 2 3 3 3-109 Oi-Pr CH OCH SCF 2 3 3 3-110 Oi-Pr CH SCH SCF 2 3 3 3-111 Ot-Bu Me SCF 3-112 Ot-Bu Et SCF 3-113 Ot-Bu n-Pr SCF 3-114 Ot-Bu i-Pr SCF 3-115 Ot-Bu CH CHF SCF 2 2 3 3-116 Ot-Bu CH CF SCF 2 3 3 3-117 Ot-Bu CH CF CHF SCF 2 2 2 3 3-118 Ot-Bu CH CF CF SCF 2 2 3 3 3-119 Ot-Bu CH OCH SCF 2 3 3 3-120 Ot-Bu CH SCH SCF 2 3 3 [Table 12] Table 12 Compound Physical 1 2 3 R R R No. property 3-121 SEt Me SCF 3-122 SEt Et SCF 3-123 SEt n-Pr SCF 3-124 SEt i-Pr SCF 3-125 SEt CH CHF SCF 2 2 3 3-126 SEt CH CF SCF 98-99 2 3 3 3-127 SEt CH CF CHF SCF 2 2 2 3 3-128 SEt CH CF CF SCF 2 2 3 3 3-129 SEt CH OCH SCF 2 3 3 3-130 SEt CH SCH SCF 2 3 3 3-131 1,2,4-Triazolyl Me SCF 3-132 1,2,4-Triazolyl Et SCF 3-133 1,2,4-Triazolyl n-Pr SCF 88-89 3-134 1,2,4-Triazolyl i-Pr SCF 3-135 1,2,4-Triazolyl CH CHF SCF 2 2 3 3-136 1,2,4-Triazolyl CH CF SCF 2 3 3 3-137 1,2,4-Triazolyl CH CF CHF SCF 2 2 2 3 3-138 1,2,4-Triazolyl CH CF CF SCF 2 2 3 3 3-139 1,2,4-Triazolyl CH OCH SCF 2 3 3 3-140 1,2,4-Triazolyl CH SCH SCF 2 3 3 [Table 13] Table 13 Compound Physical 1 2 3 R R R No. property 3-141 OMe Me OCF 3-142 OMe Et OCF 3-143 OMe n-Pr OCF 3-144 OMe i-Pr OCF 3-145 OMe CH CHF OCF 2 2 3 3-146 OMe CH CF OCF 129-130 2 3 3 3-147 OMe CH CF CHF OCF 2 2 2 3 3-148 OMe CH CF CF OCF 2 2 3 3 3-149 OMe CH OCH OCF 2 3 3 3-150 OMe CH SCH OCF 2 3 3 3-151 OEt Me OCF 3-152 OEt Et OCF 3-153 OEt Pr OCF 3-154 OEt i-Pr OCF 3-155 OEt CH CHF OCF 2 2 3 3-156 OEt CH CF OCF 2 3 3 3-157 OEt CH2CF2CHF2 OCF3 3-158 OEt CH CF CF OCF 2 2 3 3 3-159 OEt CH OCH OCF 2 3 3 3-160 OEt CH2SCH3 OCF3 3-161 OPr Me OCF 3-162 OPr Et OCF 3-163 OPr n-Pr OCF3 3-164 OPr i-Pr OCF 3-165 OPr CH CHF OCF 2 2 3 [Table 14] Table 14 Compound Physical 1 2 3 R R R No. property 3-166 OPr CH CF OCF 2 3 3 3-167 OPr CH CF CHF OCF 2 2 2 3 3-168 OPr CH CF CF OCF 2 2 3 3 3-169 OPr CH OCH OCF 2 3 3 3-170 OPr CH SCH OCF 2 3 3 3-171 Oi-Pr Me OCF 3-172 Oi-Pr Et OCF 3-173 Oi-Pr n-Pr OCF 3-174 Oi-Pr i-Pr OCF 3-175 Oi-Pr CH CHF OCF 2 2 3 3-176 Oi-Pr CH CF OCF 2 3 3 3-177 Oi-Pr CH CF CHF OCF 2 2 2 3 3-178 Oi-Pr CH CF CF OCF 2 2 3 3 3-179 Oi-Pr CH OCH OCF 2 3 3 3-180 Oi-Pr CH SCH OCF 2 3 3 3-181 Ot-Bu Me OCF 3-182 Ot-Bu Et OCF 3-183 Ot-Bu n-Pr OCF 3-184 Ot-Bu i-Pr OCF 3-185 Ot-Bu CH CHF OCF 2 2 3 3-186 Ot-Bu CH CF OCF 2 3 3 3-187 Ot-Bu CH2CF2CHF2 OCF3 3-188 Ot-Bu CH CF CF OCF 2 2 3 3 3-189 Ot-Bu CH OCH OCF 2 3 3 3-190 Ot-Bu CH2SCH3 OCF3 [Table 15] Table 15 Compound Physical 1 2 3 R R R No. property 3-191 SEt Me OCF 3-192 SEt Et OCF 3-193 SEt n-Pr OCF 3-194 SEt i-Pr OCF 3-195 SEt CH CHF OCF 2 2 3 3-196 SEt CH CF OCF 2 3 3 3-197 SEt CH CF CHF OCF 2 2 2 3 3-198 SEt CH CF CF OCF 2 2 3 3 3-199 SEt CH OCH OCF 2 3 3 3-200 SEt CH SCH OCF 2 3 3 3-201 1,2,4-Triazolyl Me OCF 3-202 1,2,4-Triazolyl Et OCF 3-203 1,2,4-Triazolyl n-Pr OCF 3-204 1,2,4-Triazolyl i-Pr OCF 3-205 1,2,4-Triazolyl CH CHF OCF 2 2 3 3-206 1,2,4-Triazolyl CH CF OCF 2 3 3 3-207 1,2,4-Triazolyl CH CF CHF OCF 2 2 2 3 3-208 1,2,4-Triazolyl CH CF CF OCF 2 2 3 3 3-209 1,2,4-Triazolyl CH OCH OCF 2 3 3 3-210 1,2,4-Triazolyl CH SCH OCF 2 3 3 [Table 16] Table 16 Compound Physical 1 2 3 R R R No. property 3-211 OMe Me SO CF 3-212 OMe Et SO CF 3-213 OMe n-Pr SO CF 3-214 OMe i-Pr SO CF 3-215 OMe CH CHF SO CF 2 2 2 3 3-216 OMe CH CF SO CF 114-115 2 3 2 3 3-217 OMe CH CF CHF SO CF 2 2 2 2 3 3-218 OMe CH CF CF SO CF 2 2 3 2 3 3-219 OMe CH OCH SO CF 2 3 2 3 3-220 OMe CH SCH SO CF 2 3 2 3 3-221 OEt Me SO CF 3-222 OEt Et SO CF 3-223 OEt n-Pr SO CF 3-224 OEt i-Pr SO CF 3-225 OEt CH CHF SO CF 2 2 2 3 3-226 OEt CH CF SO CF 2 3 2 3 3-227 OEt CH CF CHF SO CF 2 2 2 2 3 3-228 OEt CH CF CF SO CF 2 2 3 2 3 3-229 OEt CH OCH SO CF 2 3 2 3 3-230 OEt CH SCH SO CF 2 3 2 3 3-231 On-Pr Me SO CF 3-232 On-Pr Et SO CF 3-233 On-Pr n-Pr SO CF 3-234 On-Pr i-Pr SO CF 3-235 On-Pr CH CHF SO CF 2 2 2 3 [Table 17] Table 17 Compound Physical 1 2 3 R R R No. property 3-236 On-Pr CH CF SO CF 2 3 2 3 3-237 On-Pr CH CF CHF SO CF 2 2 2 2 3 3-238 On-Pr CH CF CF SO CF 2 2 3 2 3 3-239 On-Pr CH OCH SO CF 2 3 2 3 3-240 On-Pr CH SCH SO CF 2 3 2 3 3-241 Oi-Pr Me SO CF 3-242 Oi-Pr Et SO CF 3-243 Oi-Pr n-Pr SO CF 3-244 Oi-Pr i-Pr SO CF 3-245 Oi-Pr CH CHF SO CF 2 2 2 3 3-246 Oi-Pr CH CF SO CF 2 3 2 3 3-247 Oi-Pr CH CF CHF SO CF 2 2 2 2 3 3-248 Oi-Pr CH CF CF SO CF 2 2 3 2 3 3-249 Oi-Pr CH OCH SO CF 2 3 2 3 3-250 Oi-Pr CH SCH SO CF 2 3 2 3 3-251 Ot-Bu Me SO CF 3-252 Ot-Bu Et SO CF 3-253 Ot-Bu n-Pr SO CF 3-254 Ot-Bu i-Pr SO CF 3-255 Ot-Bu CH CHF SO CF 2 2 2 3 3-256 Ot-Bu CH CF SO CF 2 3 2 3 3-257 Ot-Bu CH CF CHF SO CF 2 2 2 2 3 3-258 Ot-Bu CH CF CF SO CF 2 2 3 2 3 3-259 Ot-Bu CH OCH SO CF 2 3 2 3 3-260 Ot-Bu CH SCH SO CF 2 3 2 3 [Table 18] Table 18 Compound Physical 1 2 3 R R R No. property 3-261 SEt Me SO CF 3-262 SEt Et SO CF 3-263 SEt n-Pr SO CF 3-264 SEt i-Pr SO CF 3-265 SEt CH CHF SO CF 2 2 2 3 3-266 SEt CH CF SO CF 2 3 2 3 3-267 SEt CH CF CHF SO CF 2 2 2 2 3 3-268 SEt CH CF CF SO CF 2 2 3 2 3 3-269 SEt CH OCH SO CF 2 3 2 3 3-270 SEt CH SCH SO CF 2 3 2 3 3-271 1,2,4-Triazolyl Me SO CF 3-272 1,2,4-Triazolyl Et SO CF 3-273 1,2,4-Triazolyl n-Pr SO CF 3-274 1,2,4-Triazolyl i-Pr SO CF 3-275 1,2,4-Triazolyl CH CHF SO CF NMR 2 2 2 3 3-276 1,2,4-Triazolyl CH CF SO CF 166-167 2 3 2 3 3-277 1,2,4-Triazolyl CH CF CHF SO CF 2 2 2 2 3 3-278 1,2,4-Triazolyl CH2CF2CF3 SO2CF3 3-279 1,2,4-Triazolyl CH OCH SO CF 2 3 2 3 3-280 1,2,4-Triazolyl CH SCH SO CF 2 3 2 3 3-281 OMe CH2CF3 SOCF3 91-93 3-282 On-Pr CH CF SOCF 60-61 2 3 3 3-283 On-Bu CH CF SOCF 50-51 2 3 3 3-284 Oi-Bu CH2CF3 SOCF3 44-45 3-285 OCH C≡CH CH CF SOCF 53-54 2 2 3 3 [Table 19] Table 19 Compound Physical 1 2 3 R R R No. property 3-286 OCH CH OCH CH CF SCF 136-137 2 2 3 2 3 3 3-287 OCH C≡CH CH CF SO CF 122-123 2 2 3 2 3 3-288 SMe CH CF SCF NMR 2 3 3 3-289 1,2,4-Triazolyl CH CF SOCF 51-52 2 3 3 3-290 1,2,4-Triazolyl CH CHF SOCF 77-78 2 2 3 3-291 NHAc CH CF SOCF 89-90 2 3 3 3-292 NHCOOMe CH CF SOCF 167-168 2 3 3 3-293 NHAc CH CF SO CF 131-132 2 3 2 3 3-294 NMeAc CH CF SO CF 102-103 2 3 2 3 [Chem. 9] [Table 20] Table 20 Compound Physical 1 2 3 R R R No. property 4-1 OMe Me CF 4-2 OMe Et CF 4-3 OMe Pr CF 4-4 OMe i-Pr CF3 4-5 OMe CH CHF CF 2 2 3 4-6 OMe CH CF CF 2 3 3 4-7 OMe CH CF CHF CF 2 2 2 3 4-8 OMe CH CF CF CF 2 2 3 3 4-9 OMe CH OCH CF 2 3 3 4-10 OMe CH SCH CF 2 3 3 4-11 OEt Me CF 4-12 OEt Et CF 4-13 OEt n-Pr CF 4-14 OEt i-Pr CF 4-15 OEt CH CHF CF 2 2 3 4-16 OEt CH CF CF 2 3 3 4-17 OEt CH CF CHF CF 2 2 2 3 4-18 OEt CH CF CF CF 2 2 3 3 4-19 OEt CH OCH CF 2 3 3 4-20 OEt CH SCH CF 2 3 3 4-21 On-Pr Me CF 4-22 On-Pr Et CF 4-23 On-Pr n-Pr CF 4-24 On-Pr i-Pr CF 4-25 On-Pr CH CHF CF 2 2 3 [Table 21] Table 21 Compound Physical 1 2 3 R R R No. property 4-26 On-Pr CH CF CF 2 3 3 4-27 On-Pr CH CF CHF CF 2 2 2 3 4-28 On-Pr CH CF CF CF 2 2 3 3 4-29 On-Pr CH OCH CF 2 3 3 4-30 On-Pr CH SCH CF 2 3 3 4-31 Oi-Pr Me CF 4-32 Oi-Pr Et CF 4-33 Oi-Pr n-Pr CF 4-34 Oi-Pr i-Pr CF 4-35 Oi-Pr CH CHF CF 2 2 3 4-36 Oi-Pr CH CF CF 2 3 3 4-37 Oi-Pr CH2CF2CHF2 CF3 4-38 Oi-Pr CH CF CF CF 2 2 3 3 4-39 Oi-Pr CH OCH CF 2 3 3 4-40 Oi-Pr CH2SCH3 CF3 4-41 Ot-Bu Me CF 4-42 Ot-Bu Et CF 4-43 Ot-Bu n-Pr CF3 4-44 Ot-Bu i-Pr CF 4-45 Ot-Bu CH CHF CF 2 2 3 4-46 Ot-Bu CH CF CF 2 3 3 4-47 Ot-Bu CH CF CHF CF 2 2 2 3 4-48 Ot-Bu CH CF CF CF 2 2 3 3 4-49 Ot-Bu CH OCH CF 2 3 3 4-50 Ot-Bu CH SCH CF 2 3 3 [Table 22] Table 22 Compound Physical 1 2 3 R R R No. property 4-51 SEt Me CF 4-52 SEt Et CF 4-53 SEt n-Pr CF 4-54 SEt i-Pr CF 4-55 SEt CH CHF CF 2 2 3 4-56 SEt CH CF CF 2 3 3 4-57 SEt CH CF CHF CF 2 2 2 3 4-58 SEt CH CF CF CF 2 2 3 3 4-59 SEt CH OCH CF 2 3 3 4-60 SEt CH SCH CF 2 3 3 4-61 1,2,4-Triazolyl Me CF 4-62 1,2,4-Triazolyl Et CF 4-63 1,2,4-Triazolyl n-Pr CF 4-64 1,2,4-Triazolyl i-Pr CF 4-65 1,2,4-Triazolyl CH CHF CF 2 2 3 4-66 1,2,4-Triazolyl CH CF CF 2 3 3 4-67 1,2,4-Triazolyl CH CF CHF CF 2 2 2 3 4-68 1,2,4-Triazolyl CH CF CF CF 2 2 3 3 4-69 1,2,4-Triazolyl CH OCH CF 2 3 3 4-70 1,2,4-Triazolyl CH SCH CF 2 3 3 [Table 23] Table 23 Compound Physical 1 2 3 R R R No. property 4-71 OMe Me SCF 4-72 OMe Et SCF 4-73 OMe n-Pr SCF 4-74 OMe i-Pr SCF 4-75 OMe CH CHF SCF 2 2 3 4-76 OMe CH CF SCF 2 3 3 4-77 OMe CH CF CHF SCF 2 2 2 3 4-78 OMe CH CF CF SCF 2 2 3 3 4-79 OMe CH OCH SCF 2 3 3 4-80 OMe CH SCH SCF 2 3 3 4-81 OEt Me SCF 4-82 OEt Et SCF 4-83 OEt n-Pr SCF 4-84 OEt i-Pr SCF 4-85 OEt CH CHF SCF 2 2 3 4-86 OEt CH CF SCF 2 3 3 4-87 OEt CH CF CHF SCF 2 2 2 3 4-88 OEt CH CF CF SCF 2 2 3 3 4-89 OEt CH OCH SCF 2 3 3 4-90 OEt CH SCH SCF 2 3 3 4-91 On-Pr Me SCF 4-92 On-Pr Et SCF 4-93 On-Pr n-Pr SCF 4-94 On-Pr i-Pr SCF 4-95 On-Pr CH CHF SCF 2 2 3 [Table 24] Table 24 Compound Physical 1 2 3 R R R No. property 4-96 On-Pr CH CF SCF 2 3 3 4-97 On-Pr CH CF CHF SCF 2 2 2 3 4-98 On-Pr CH CF CF SCF 2 2 3 3 4-99 On-Pr CH OCH SCF 2 3 3 4-100 On-Pr CH SCH SCF 2 3 3 4-101 Oi-Pr Me SCF 4-102 Oi-Pr Et SCF 4-103 Oi-Pr n-Pr SCF 4-104 Oi-Pr i-Pr SCF 4-105 Oi-Pr CH CHF SCF 2 2 3 4-106 Oi-Pr CH CF SCF 2 3 3 4-107 Oi-Pr CH CF CHF SCF 2 2 2 3 4-108 Oi-Pr CH CF CF SCF 2 2 3 3 4-109 Oi-Pr CH OCH SCF 2 3 3 4-110 Oi-Pr CH SCH SCF 2 3 3 4-111 Ot-Bu Me SCF 4-112 Ot-Bu Et SCF 4-113 Ot-Bu n-Pr SCF 4-114 Ot-Bu i-Pr SCF 4-115 Ot-Bu CH CHF SCF 2 2 3 4-116 Ot-Bu CH CF SCF 2 3 3 4-117 Ot-Bu CH CF CHF SCF 2 2 2 3 4-118 Ot-Bu CH CF CF SCF 2 2 3 3 4-119 Ot-Bu CH OCH SCF 2 3 3 4-120 Ot-Bu CH SCH SCF 2 3 3 [Table 25] Table 25 Compound Physical 1 2 3 R R R No. property 4-121 SEt Me SCF 4-122 SEt Et SCF 4-123 SEt n-Pr SCF 4-124 SEt i-Pr SCF 4-125 SEt CH CHF SCF 2 2 3 4-126 SEt CH CF SCF 2 3 3 4-127 SEt CH CF CHF SCF 2 2 2 3 4-128 SEt CH CF CF SCF 2 2 3 3 4-129 SEt CH OCH SCF 2 3 3 4-130 SEt CH SCH SCF 2 3 3 4-131 1,2,4-Triazolyl Me SCF 4-132 1,2,4-Triazolyl Et SCF 4-133 1,2,4-Triazolyl n-Pr SCF 4-134 1,2,4-Triazolyl i-Pr SCF 4-135 1,2,4-Triazolyl CH CHF SCF 2 2 3 4-136 1,2,4-Triazolyl CH2CF3 SCF3 4-137 1,2,4-Triazolyl CH CF CHF SCF 2 2 2 3 4-138 1,2,4-Triazolyl CH CF CF SCF 2 2 3 3 4-139 1,2,4-Triazolyl CH2OCH3 SCF3 4-140 1,2,4-Triazolyl CH SCH SCF 2 3 3 [Table 26] Table 26 Compound Physical 1 2 3 R R R No. property 4-141 OMe Me SO CF 4-142 OMe Et SO CF 4-143 OMe n-Pr SO CF 4-144 OMe i-Pr SO CF 4-145 OMe CH CHF SO CF 2 2 2 3 4-146 OMe CH CF SO CF 2 3 2 3 4-147 OMe CH CF CHF SO CF 2 2 2 2 3 4-148 OMe CH CF CF SO CF 2 2 3 2 3 4-149 OMe CH OCH SO CF 2 3 2 3 4-150 OMe CH SCH SO CF 2 3 2 3 4-151 OEt Me SO CF 4-152 OEt Et SO CF 4-153 OEt n-Pr SO CF 4-154 OEt i-Pr SO CF 4-155 OEt CH CHF SO CF 2 2 2 3 4-156 OEt CH CF SO CF 2 3 2 3 4-157 OEt CH CF CHF SO CF 2 2 2 2 3 4-158 OEt CH CF CF SO CF 2 2 3 2 3 4-159 OEt CH OCH SO CF 2 3 2 3 4-160 OEt CH SCH SO CF 2 3 2 3 4-161 On-Pr Me SO CF 4-162 On-Pr Et SO CF 4-163 On-Pr n-Pr SO CF 4-164 On-Pr i-Pr SO CF 4-165 On-Pr CH CHF SO CF 2 2 2 3 [Table 27] Table 27 Compound Physical 1 2 3 R R R No. property 4-166 On-Pr CH CF SO CF 2 3 2 3 4-167 On-Pr CH CF CHF SO CF 2 2 2 2 3 4-168 On-Pr CH CF CF SO CF 2 2 3 2 3 4-169 On-Pr CH OCH SO CF 2 3 2 3 4-170 On-Pr CH SCH SO CF 2 3 2 3 4-171 Oi-Pr Me SO CF 4-172 Oi-Pr Et SO CF 4-173 Oi-Pr n-Pr SO CF 4-174 Oi-Pr i-Pr SO CF 4-175 Oi-Pr CH CHF SO CF 2 2 2 3 4-176 Oi-Pr CH CF SO CF 2 3 2 3 4-177 Oi-Pr CH CF CHF SO CF 2 2 2 2 3 4-178 Oi-Pr CH CF CF SO CF 2 2 3 2 3 4-179 Oi-Pr CH OCH SO CF 2 3 2 3 4-180 Oi-Pr CH SCH SO CF 2 3 2 3 4-181 Ot-Bu Me SO CF 4-182 Ot-Bu Et SO CF 4-183 Ot-Bu n-Pr SO CF 4-184 Ot-Bu i-Pr SO CF 4-185 Ot-Bu CH CHF SO CF 2 2 2 3 4-186 Ot-Bu CH CF SO CF 2 3 2 3 4-187 Ot-Bu CH CF CHF SO CF 2 2 2 2 3 4-188 Ot-Bu CH CF CF SO CF 2 2 3 2 3 4-189 Ot-Bu CH OCH SO CF 2 3 2 3 4-190 Ot-Bu CH SCH SO CF 2 3 2 3 [Table 28] Table 28 Compound Physical 1 2 3 R R R No. property 4-191 SEt Me SO CF 4-192 SEt Et SO CF 4-193 SEt n-Pr SO CF 4-194 SEt i-Pr SO CF 4-195 SEt CH CHF SO CF 2 2 2 3 4-196 SEt CH CF SO CF 2 3 2 3 4-197 SEt CH CF CHF SO CF 2 2 2 2 3 4-198 SEt CH CF CF SO CF 2 2 3 2 3 4-199 SEt CH OCH SO CF 2 3 2 3 4-200 SEt CH SCH SO CF 2 3 2 3 4-201 1,2,4-Triazolyl Me SO CF 4-202 1,2,4-Triazolyl Et SO CF 4-203 1,2,4-Triazolyl n-Pr SO CF 4-204 1,2,4-Triazolyl i-Pr SO CF 4-205 1,2,4-Triazolyl CH CHF SO CF 2 2 2 3 4-206 1,2,4-Triazolyl CH CF SO CF 2 3 2 3 4-207 1,2,4-Triazolyl CH CF CHF SO CF 2 2 2 2 3 4-208 1,2,4-Triazolyl CH CF CF SO CF 2 2 3 2 3 4-209 1,2,4-Triazolyl CH OCH SO CF 2 3 2 3 4-210 1,2,4-Triazolyl CH SCH SO CF 2 3 2 3 4-211 OMe Me OCF 4-212 OMe Et OCF 4-213 OMe n-Pr OCF 4-214 OMe i-Pr OCF 4-215 OMe CH CHF OCF 2 2 3 [Table 29] Table 29 Compound Physical 1 2 3 R R R No. property 4-216 OMe CH CF OCF 2 3 3 4-217 OMe CH CF CHF OCF 2 2 2 3 4-218 OMe CH CF CF OCF 2 2 3 3 4-219 OMe CH OCH OCF 2 3 3 4-220 OMe CH SCH OCF 2 3 3 4-221 OEt Me OCF 4-222 OEt Et OCF 4-223 OEt n-Pr OCF 4-224 OEt i-Pr OCF 4-225 OEt CH CHF OCF 2 2 3 4-226 OEt CH CF OCF 2 3 3 4-227 OEt CH2CF2CHF2 OCF3 4-228 OEt CH CF CF OCF 2 2 3 3 4-229 OEt CH OCH OCF 2 3 3 4-230 OEt CH2SCH3 OCF3 4-231 On-Pr Me OCF 4-232 On-Pr Et OCF 4-233 On-Pr n-Pr OCF3 4-234 On-Pr i-Pr OCF 4-235 On-Pr CH CHF OCF 2 2 3 4-236 On-Pr CH CF OCF 2 3 3 4-237 On-Pr CH CF CHF OCF 2 2 2 3 4-238 On-Pr CH CF CF OCF 2 2 3 3 4-239 On-Pr CH OCH OCF 2 3 3 4-240 On-Pr CH SCH OCF 2 3 3 [Table 30] Table 30 Compound Physical 1 2 3 R R R No. property 4-241 Oi-Pr Me OCF 4-242 Oi-Pr Et OCF 4-243 Oi-Pr n-Pr OCF 4-244 Oi-Pr i-Pr OCF 4-245 Oi-Pr CH CHF OCF 2 2 3 4-246 Oi-Pr CH CF OCF 2 3 3 4-247 Oi-Pr CH CF CHF OCF 2 2 2 3 4-248 Oi-Pr CH CF CF OCF 2 2 3 3 4-249 Oi-Pr CH OCH OCF 2 3 3 4-250 Oi-Pr CH SCH OCF 2 3 3 4-251 Ot-Bu Me OCF 4-252 Ot-Bu Et OCF 4-253 Ot-Bu n-Pr OCF 4-254 Ot-Bu i-Pr OCF 4-255 Ot-Bu CH CHF OCF 2 2 3 4-256 Ot-Bu CH CF OCF 2 3 3 4-257 Ot-Bu CH2CF2CHF2 OCF3 4-258 Ot-Bu CH CF CF OCF 2 2 3 3 4-259 Ot-Bu CH OCH OCF 2 3 3 4-260 Ot-Bu CH2SCH3 OCF3 4-261 SEt Me OCF 4-262 SEt Et OCF 4-263 SEt n-Pr OCF3 4-264 SEt i-Pr OCF 4-265 SEt CH CHF OCF 2 2 3 [Table 31] Table 31 Compound Physical 1 2 3 R R R No. property 4-266 SEt CH CF OCF 2 3 3 4-267 SEt CH CF CHF OCF 2 2 2 3 4-268 SEt CH CF CF OCF 2 2 3 3 4-269 SEt CH OCH OCF 2 3 3 4-270 SEt CH SCH OCF 2 3 3 4-271 1,2,4-Triazolyl Me OCF 4-272 1,2,4-Triazolyl Et OCF 4-273 1,2,4-Triazolyl n-Pr OCF 4-274 1,2,4-Triazolyl i-Pr OCF 4-275 1,2,4-Triazolyl CH CHF OCF 2 2 3 4-276 1,2,4-Triazolyl CH CF OCF 2 3 3 4-277 1,2,4-Triazolyl CH CF CHF OCF 2 2 2 3 4-278 1,2,4-Triazolyl CH CF CF OCF 2 2 3 3 4-279 1,2,4-Triazolyl CH OCH OCF 2 3 3 4-280 1,2,4-Triazolyl CH SCH OCF 2 3 3 [Table 32] Table 32 NMR data Compound No. H-NMR data (CDCl ) 9.31(d, 1H), 8.80(d, 1H), 8.77(d, 1H), 8.31(d, 1H), 4.53(q, 2H), 4.34(s, 3H), 3.89(s, 3H), 3.88(t, 3H), 1.39(t, 3H) 9.33(d, 1H), 8.80(d, 1H), 8.76(d, 1H), 8.31(d, 1H), 5.25(s, 2H), 1-10 4.31(s, 3H), 3.89(s, 3H), 3.87(q, 2H), 2.34(s, 3H), 1.39(t, 3H) 9.19(d, 1H), 9.15(s, 1H), 8.77(d, 1H), 8.61(d, 1H), 8.19(dd, 1H), 3-275 8.13(s, 1H), 7.98(d, 1H), 6.14(tt, 1H), 4.62(td, 2H), 4.03(q, 2H), 1.48(t, 3H) 9.14(d, 1H), 8.73(d, 1H), 8.20(d, 1H), 7.79(d, 1H), 7.76(dd, 1H), 3-288 4.66(q, 2H), 4.10(q, 2H), 2.37(s, 3H), 1.46(t, 3H) The agricultural and horticultural insecticide comprising the oxime group-containing condensed heterocyclic compound represented by the general formula (1) of the present invention or a salt thereof as an active ingredient is suitable for controlling a variety of pests which may damage paddy rice, fruit trees, vegetables, other crops and ornamental flowering plants. The target pests are, for example, agricultural and forest pests, horticultural pests, stored grain pests, sanitary pests, other pests such as nematodes and termites, etc.
Specific examples of the pests, nematodes, etc. include the following: the species of the order Lepidoptera such as Parasa consocia, Anomis mesogona, Papilio xuthus, Matsumuraeses azukivora, Ostrinia scapulalis, Spodoptera exempta, Hyphantria cunea, Ostrinia furnacalis, Pseudaletia separata, Tinea translucens, Bactra furfurana, Parnara guttata, Marasmia exigua, Parnara guttata, Sesamia inferens, Brachmia triannulella, Monema flavescens, Trichoplusia ni, Pleuroptya ruralis, Cystidia couaggaria, Lampides boeticus, Cephonodes hylas, Helicoverpa armigera, Phalerodonta manleyi, Eumeta japonica, Pieris brassicae, Malacosoma neustria testacea, Stathmopoda masinissa, Cuphodes diospyrosella, Archips xylosteanus, Agrotis segetum, Tetramoera schistaceana, Papilio machaon hippocrates, Endoclyta sinensis, Lyonetia prunifoliella, Phyllonorycter ringoneella, Cydia kurokoi, Eucoenogenes aestuosa, Lobesia botrana, Latoia sinica, Euzophera batangensis, Phalonidia mesotypa, Spilosoma imparilis, Glyphodes pyloalis, Olethreutes mori, Tineola bisselliella, Endoclyta excrescens, Nemapogon granellus, Synanthedon hector, Cydia pomonella, Plutella xylostella, Cnaphalocrocis medinalis, Sesamia calamistis, Scirpophaga incertulas, Pediasia teterrellus, Phthorimaea operculella, Stauropus fagi persimilis, Etiella zinckenella, Spodoptera exigua, Palpifer sexnotata, Spodoptera mauritia, Scirpophaga innotata, Xestia c-nigrum, Spodoptera depravata, Ephestia kuehniella, Angerona prunaria, Clostera anastomosis, Pseudoplusia includens, Matsumuraeses falcana, Helicoverpa assulta, Autographa nigrisigna, Agrotis ipsilon, Euproctis pseudoconspersa, Adoxophyes orana, Caloptilia theivora, Homona magnanima, Ephestia elutella, Eumeta minuscula, Clostera anachoreta, Heliothis maritima, Sparganothis pilleriana, Busseola fusca, Euproctis subflava, Biston robustum, Heliothis zea, Aedia leucomelas, Narosoideus flavidorsalis, Viminia rumicis, Bucculatrix pyrivorella, Grapholita molesta, Spulerina astaurota, Ectomyelois pyrivorella, Chilo suppressalis, Acrolepiopsis sapporensis, Plodia interpunctella, Hellula undalis, Sitotroga cerealella, Spodoptera litura, a species of the family Tortricidae (Eucosma aporema), Acleris comariana, Scopelodes contractus, Orgyia thyellina, Spodoptera frugiperda, Ostrinia zaguliaevi, Naranga aenescens, Andraca bipunctata, Paranthrene regalis, Acosmeryx castanea, Phyllocnistis toparcha, Endopiza viteana, Eupoecillia ambiguella, Anticarsia gemmatalis, Cnephasia cinereipalpana, Lymantria dispar, Dendrolimus spectabilis, Leguminivora glycinivorella, Maruca testulalis, Matsumuraeses phaseoli, Caloptilia soyella, Phyllocnistis citrella, Omiodes indicata, Archips fuscocupreanus, Acanthoplusia agnata, Bambalina sp., Carposina niponensis, Conogethes punctiferalis, Synanthedon sp., Lyonetia clerkella, Papilio helenus, Colias erate poliographus, Phalera flavescens, the species of the family Pieridae such as Pieris rapae crucivora and Pieris rapae, Euproctis similis, Acrolepiopsis suzukiella, Ostrinia nubilalis, Mamestra brassicae, Ascotis selenaria, Phtheochroides clandestina, Hoshinoa adumbratana, Odonestis pruni japonensis, Triaena intermedia, Adoxophyes orana fasciata, Grapholita inopinata, Spilonota ocellana, Spilonota lechriaspis, Illiberis pruni, Argyresthia conjugella, Caloptilia zachrysa, Archips breviplicanus, Anomis flava, Pectinophora gossypiella, Notarcha derogata, Diaphania indica, Heliothis virescens and Earias cupreoviridis; the species of the order Hemiptera such as Nezara antennata, Stenotus rubrovittatus, Graphosoma rubrolineatum, Trigonotylus coelestialium, Aeschynteles maculatus, Creontiades pallidifer, Dysdercus cingulatus, Chrysomphalus ficus, Aonidiella aurantii, Graptopsaltria nigrofuscata, Blissus leucopterus, Icerya purchasi, Piezodorus hybneri, Lagynotomus elongatus, Thaia subrufa, Scotinophara lurida, Sitobion ibarae, Stariodes iwasakii, Aspidiotus destructor, Taylorilygus pallidulus, Myzus mumecola, Pseudaulacaspis prunicola, Acyrthosiphon pisum, Anacanthocoris striicornis, Ectometopterus micantulus, Eysarcoris lewisi, Molipteryx fuliginosa, Cicadella viridis, Rhopalosophum rufiabdominalis, Saissetia oleae, Trialeurodes vaporariorum, Aguriahana quercus, Lygus spp., Euceraphis punctipennis, Andaspis kashicola, Coccus pseudomagnoliarum, Cavelerius saccharivorus, Galeatus spinifrons, Macrosiphoniella sanborni, Aonidiella citrina, Halyomorpha mista, Stephanitis fasciicarina, Trioza camphorae, Leptocorisa chinensis, Trioza quercicola, Uhlerites latius, Erythroneura comes, Paromius exiguus, Duplaspidiotus claviger, Nephotettix nigropictus, Halticiellus insularis, Perkinsiella saccharicida, Psylla malivorella, Anomomeura mori, Pseudococcus longispinis, Pseudaulacaspis pentagona, Pulvinaria kuwacola, Apolygus lucorum, Togo hemipterus, Toxoptera aurantii, Saccharicoccus sacchari, Geoica lucifuga, Numata muiri, Comstockaspis perniciosa, Unaspis citri, Aulacorthum solani, Eysarcoris ventralis, Bemisia argentifolii, Cicadella spectra, Aspidiotus hederae, Liorhyssus hyalinus, Calophya nigridorsalis, Sogatella furcifera, Megoura crassicauda, Brevicoryne brassicae, Aphis glycines, Leptocorisa oratorius, Nephotettix virescens, Uroeucon formosanum, Cyrtopeltis tennuis, Bemisia tabaci, Lecanium persicae, Parlatoria theae, Pseudaonidia paeoniae, Empoasca onukii, Plautia stali, Dysaphis tulipae, Macrosiphum euphorbiae, Stephanitis pyrioides, Ceroplastes ceriferus, Parlatoria camelliae, Apolygus spinolai, Nephotettix cincticeps, Glaucias subpunctatus, Orthotylus flavosparsus, Rhopalosiphum maidis, Peregrinus maidis, Eysarcoris parvus, Cimex lectularius, Psylla abieti, Nilaparvata lugens, Psylla tobirae, Eurydema rugosum, Schizaphis piricola, Psylla pyricola, Parlatoreopsis pyri, Stephanitis nashi, Dysmicoccus wistariae, Lepholeucaspis japonica, Sappaphis piri, Lipaphis erysimi, Neotoxoptera formosana, Rhopalosophum nymphaeae, Edwardsiana rosae, Pinnaspis aspidistrae, Psylla alni, Speusotettix subfusculus, Alnetoidia alneti, Sogatella panicicola, Adelphocoris lineolatus, Dysdercus poecilus, Parlatoria ziziphi, Uhlerites debile, Laodelphax striatellus, Eurydema pulchrum, Cletus trigonus, Clovia punctata, Empoasca spp., Coccus hesperidum, Pachybrachius luridus, Planococcus kraunhiae, Stenotus binotatus, Arboridia apicalis, Macrosteles fascifrons, Dolycoris baccarum, Adelphocoris triannulatus, Viteus vitifolii, Acanthocoris sordidus, Leptocorisa acuta, Macropes obnubilus, Cletus punctiger, Riptortus clavatus, Paratrioza cockerelli, Aphrophora costalis, Lygus disponsi, Lygus saundersi, Crisicoccus pini, Empoasca abietis, Crisicoccus matsumotoi, Aphis craccivora, Megacopta punctatissimum, Eysarcoris guttiger, Lepidosaphes beckii, Diaphorina citri, Toxoptera citricidus, Planococcus citri, Dialeurodes citri, Aleurocanthus spiniferus, Pseudococcus citriculus, Zyginella citri, Pulvinaria citricola, Coccus discrepans, Pseudaonidia duplex, Pulvinaria aurantii, Lecanium corni, Nezara viridula, Stenodema calcaratum, Rhopalosiphum padi, Sitobion akebiae, Schizaphis graminum, Sorhoanus tritici, Brachycaudus helichrysi, Carpocoris purpureipennis, Myzus persicae, Hyalopterus pruni, Aphis farinose yanagicola, Metasalis populi, Unaspis yanonensis, Mesohomotoma camphorae, Aphis spiraecola, Aphis pomi, Lepidosaphes ulmi, Psylla mali, Heterocordylus flavipes, Myzus malisuctus, Aphidonuguis mali, Orientus ishidai, Ovatus malicolens, Eriosoma lanigerum, Ceroplastes rubens and Aphis gossypii; the species of the order Coleoptera such as Xystrocera globosa, Paederus fuscipes, Eucetonia roelofsi, Callosobruchus chinensis, Cylas formicarius, Hypera postica, Echinocnemus squameus, Oulema oryzae, Donacia provosti, Lissorhoptrus oryzophilus, Colasposoma dauricum, Euscepes postfasciatus, Epilachna varivestis, Acanthoscelides obtectus, Diabrotica virgifera virgifera, Involvulus cupreus, Aulacophora femoralis, Bruchus pisorum, Epilachna vigintioctomaculata, Carpophilus dimidiatus, Cassida nebulosa, Luperomorpha tunebrosa, Phyllotreta striolata, Psacothea hilaris, Aeolesthes chrysothrix, Curculio sikkimensis, Carpophilus hemipterus, Oxycetonia jucunda, Diabrotica spp., Mimela splendens, Sitophilus zeamais, Tribolium castaneum, Sitophilus oryzae, Palorus subdepressus, Melolontha japonica, Anoplophora malasiaca, Neatus picipes, Leptinotarsa decemlineata, Diabrotica undecimpunctata howardi, Sphenophorus venatus, Crioceris quatuordecimpunctata, Conotrachelus nenuphar, Ceuthorhynchidius albosuturalis, Phaedon brassicae, Lasioderma serricorne, Sitona japonicus, Adoretus tenuimaculatus, Tenebrio molitor, Basilepta balyi, Hypera nigrirostris, Chaetocnema concinna, Anomala cuprea, Heptophylla picea, Epilachna vigintioctopunctata, Diabrotica longicornis, Eucetonia pilifera, Agriotes spp., Attagenus unicolor japonicus, Pagria signata, Anomala rufocuprea, Palorus ratzeburgii, Alphitobius laevigatus, Anthrenus verbasci, Lyctus brunneus, Tribolium confusum, Medythia nigrobilineata, Xylotrechus pyrrhoderus, Epitrix cucumeris, Tomicus piniperda, Monochamus alternatus, Popillia japonica, Epicauta gorhami, Sitophilus zeamais, Rhynchites heros, Listroderes costirostris, Callosobruchus maculatus, Phyllobius armatus, Anthonomus pomorum, Linaeidea aenea and Anthonomus grandis; the species of the order Diptera such as Culex pipiens pallens, Pegomya hyoscyami, Liriomyza huidobrensis, Musca domestica, Chlorops oryzae, Hydrellia sasakii, Agromyza oryzae, Hydrellia griseola, Hydrellia griseola, Ophiomyia phaseoli, Dacus cucurbitae, Drosophila suzukii, Rhacochlaena japonica, Muscina stabulans, the species of the family Phoridae such as Megaselia spiracularis, Clogmia albipunctata, Tipula aino, Phormia regina, Culex tritaeniorhynchus, Anopheles sinensis, Hylemya brassicae, Asphondylia sp., Delia platura, Delia antiqua, Rhagoletis cerasi, Culex pipiens molestus Forskal, Ceratitis capitata, Bradysia agrestis, Pegomya cunicularia, Liriomyza sativae, Liriomyza bryoniae, Chromatomyia horticola, Liriomyza chinensis, Culex quinquefasciatus, Aedes aegypti, Aedes albopictus, Liriomyza trifolii, Liriomyza sativae, Dacus dorsalis, Dacus tsuneonis, Sitodiplosis mosellana, Meromuza nigriventris, Anastrepha ludens and Rhagoletis pomonella; the species of the order Hymenoptera such as Pristomyrmex pungens, the species of the family Bethylidae, Monomorium pharaonis, Pheidole noda, Athalia rosae, Dryocosmus kuriphilus, Formica fusca japonica, the species of the subfamily Vespinae, Athalia infumata infumata, Arge pagana, Athalia japonica, Acromyrmex spp., Solenopsis spp., Arge mali and Ochetellus glaber; the species of the order Orthoptera such as Homorocoryphus lineosus, Gryllotalpa sp., Oxya hyla intricata, Oxya yezoensis, Locusta migratoria, Oxya japonica, Homorocoryphus jezoensis and Teleogryllus emma; the species of the order Thysanoptera such as Selenothrips rubrocinctus, Stenchaetothrips biformis, Haplothrips aculeatus, Ponticulothrips diospyrosi, Thrips flavus, Anaphothrips obscurus, Liothrips floridensis, Thrips simplex, Thrips nigropilosus, Heliothrips haemorrhoidalis, Pseudodendrothrips mori, Microcephalothrips abdominalis, Leeuwenia pasanii, Litotetothrips pasaniae, Scirtothrips citri, Haplothrips chinensis, Mycterothrips glycines, Thrips setosus, Scirtothrips dorsalis, Dendrothrips minowai, Haplothrips niger, Thrips tabaci, Thrips alliorum, Thrips hawaiiensis, Haplothrips kurdjumovi, Chirothrips manicatus, Frankliniella intonsa, Thrips coloratus, Franklinella occidentalis, Thrips palmi, Frankliniella lilivora and Liothrips vaneeckei; the species of the order Acari such as Leptotrombidium akamushi, Tetranychus ludeni, Dermacentor variabilis, Tetranychus truncatus, Ornithonyssus bacoti, Demodex canis, Tetranychus viennensis, Tetranychus kanzawai, the species of the family Ixodidae such as Rhipicephalus sanguineus, Cheyletus malaccensis, Tyrophagus putrescentiae, Dermatophagoides farinae, Latrodectus hasseltii, Dermacentor taiwanensis, Acaphylla theavagrans, Polyphagotarsonemus latus, Aculops lycopersici, Ornithonyssus sylvairum, Tetranychus urticae, Eriophyes chibaensis, Sarcoptes scabiei, Haemaphysalis longicornis, Ixodes scapularis, Tyrophagus similis, Cheyletus eruditus, Panonychus citri, Cheyletus moorei, Brevipalpus phoenicis, Octodectes cynotis, Dermatophagoides ptrenyssnus, Haemaphysalis flava, Ixodes ovatus, Phyllocoptruta citri, Aculus schlechtendali, Panonychus ulmi, Amblyomma americanum, Dermanyssus gallinae, Rhyzoglyphus robini and Sancassania sp.; id="p-137" id="p-137" id="p-137" id="p-137" id="p-137"
id="p-137"
[0137] the species of the order Isoptera such as Reticulitermes miyatakei, Incisitermes minor, Coptotermes formosanus, Hodotermopsis japonica, Reticulitermes sp., Reticulitermes flaviceps amamianus, Glyptotermes kushimensis, Coptotermes guangzhoensis, Neotermes koshunensis, Glyptotermes kodamai, Glyptotermes satsumensis, Cryptotermes domesticus, Odontotermes formosanus, Glyptotermes nakajimai, Pericapritermes nitobei and Reticulitermes speratus; the species of the order Blattodea such as Periplaneta fuliginosa, Blattella germanica, Blatta orientalis, Periplaneta brunnea, Blattella lituricollis, Periplaneta japonica and Periplaneta americana; the species of the order Siphonaptera such as Pulex irritans, Ctenocephalides felis and Ceratophyllus gallinae; the species of the phylum Nematoda such as Nothotylenchus acris, Aphelenchoides besseyi, Pratylenchus penetrans, Meloidogyne hapla, Meloidogyne incognita, Globodera rostochiensis, Meloidogyne javanica, Heterodera glycines, Pratylenchus coffeae, Pratylenchus neglectus and Tylenchus semipenetrans; id="p-141" id="p-141" id="p-141" id="p-141" id="p-141"
id="p-141"
[0141] the species of the phylum Mollusca such as Pomacea canaliculata, Achatina fulica, Meghimatium bilineatum, Lehmannina valentiana, Limax flavus and Acusta despecta sieboldiana.
In addition, the agricultural and horticultural insecticide of the present invention has a strong insecticidal effect on Tuta absoluta as well.
Further, mites and ticks parasitic on animals are also included in the target pests, and the examples include the species of the family Ixodidae such as Boophilus microplus, Rhipicephalus sanguineus, Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysalis campanulata, Haemaphysalis concinna, Haemaphysalis japonica, Haemaphysalis kitaokai, Haemaphysalis ias, Ixodes ovatus, Ixodes nipponensis, Ixodes persulcatus, Amblyomma testudinarium, Haemaphysalis megaspinosa, Dermacentor reticulatus and Dermacentor taiwanensis; Dermanyssus gallinae; the species of the genus Ornithonyssus such as Ornithonyssus sylviarum and Ornithonyssus bursa; the species of the family Trombiculidae such as Eutrombicula wichmanni, Leptotrombidium akamushi, Leptotrombidium pallidum, Leptotrombidium fuji, Leptotrombidium tosa, Neotrombicula autumnalis, Eutrombicula alfreddugesi and Helenicula miyagawai; the species of the family Cheyletidae such as Cheyletiella yasguri, Cheyletiella parasitivorax and Cheyletiella blakei; the species of the superfamily Sarcoptoidea such as Psoroptes cuniculi, Chorioptes bovis, Otodectes cynotis, Sarcoptes scabiei and Notoedres cati; and the species of the family Demodicidae such as Demodex canis.
Other target pests include fleas including ectoparasitic wingless insects belonging to the order Siphonaptera, more specifically, the species belonging to the families Pulicidae and Ceratophyllidae. Examples of the species belonging to the family Pulicidae include Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Echidnophaga gallinacea, Xenopsylla cheopis, Leptopsylla segnis, Nosopsyllus fasciatus and Monopsyllus anisus.
Other target pests include ectoparasites, for example, the species of the suborder Anoplura such as Haematopinus eurysternus, Haematopinus asini, Dalmalinia ovis, Linognathus vituli, Haematopinus suis, Phthirus pubis and Pediculus capitis; the species of the suborder Mallophaga such as Trichodectes canis; and hematophagous Dipteran insect pests such as Tabanus trigonus, Culicoides schultzei and Simulium ornatum. In addition, examples of endoparasites include nematodes such as lungworms, whipworms, nodular worms, endogastric parasitic worms, ascarides and filarial worms; cestodes such as Spirometra erinacei, Diphyllobothrium latum, Dipylidium caninum, Multiceps multiceps, Echinococcus granulosus and Echinococcus multilocularis; trematodes such as Schistosoma japonicum and Fasciola hepatica; and protozoa such as coccidia, Plasmodium, intestinal Sarcocystis, Toxoplasma and Cryptosporidium.
The agricultural and horticultural insecticide comprising the oxime group-containing condensed heterocyclic compound represented by the general formula (1) of the present invention or a salt thereof as an active ingredient has a remarkable control effect on the above-described pests which damage lowland crops, field crops, fruit trees, vegetables, other crops, ornamental flowering plants, etc. The desired effect can be obtained when the agricultural and horticultural insecticide is applied to nursery facilities for seedlings, paddy fields, fields, fruit trees, vegetables, other crops, ornamental flowering plants, etc. and their seeds, paddy water, foliage, cultivation media such as soil, or the like around the expected time of pest infestation, i.e., before the infestation or upon the confirmation of the infestation. In particularly preferable embodiments, the application of the agricultural and horticultural insecticide utilizes so-called penetration and translocation. That is, nursery soil, soil in transplanting holes, plant foot, irrigation water, cultivation water in hydroponics, or the like is treated with the agricultural and horticultural insecticide to allow crops, ornamental flowering plants, etc. to absorb the compound of the present invention through the roots via soil or otherwise.
Examples of useful plants to which the agricultural and horticultural insecticide of the present invention can be applied include, but are not particularly limited to, cereals (e.g., rice, barley, wheat, rye, oats, corn, etc.), legumes (e.g., soybeans, azuki beans, broad beans, green peas, kidney beans, peanuts, etc.), fruit trees and fruits (e.g., apples, citrus fruits, pears, grapes, peaches, plums, cherries, walnuts, chestnuts, almonds, bananas, etc.), leaf and fruit vegetables (e.g., cabbages, tomatoes, spinach, broccoli, lettuce, onions, green onions (chives and Welsh onions), green peppers, eggplants, strawberries, pepper crops, okra, Chinese chives, etc.), root vegetables (e.g., carrots, potatoes, sweet potatoes, taros, Japanese radishes, turnips, lotus roots, burdock roots, garlic, Chinese scallions, etc.), crops for processing (e.g., cotton, hemp, beet, hops, sugarcane, sugar beet, olives, rubber, coffee, tobacco, tea, etc.), gourds (e.g., Japanese pumpkins, cucumbers, watermelons, oriental sweet melons, melons, etc.), pasture grass (e.g., orchardgrass, sorghum, timothy, clover, alfalfa, etc.), lawn grass (e.g., Korean lawn grass, bent grass, etc.), spice and aromatic crops and ornamental crops (e.g., lavender, rosemary, thyme, parsley, pepper, ginger, etc.), ornamental flowering plants (e.g., chrysanthemum, rose, carnation, orchid, tulip, lily, etc.), garden trees (e.g., ginkgo trees, cherry trees, Japanese aucuba, etc.) and forest trees (e.g., Abies sachalinensis, Picea jezoensis, pine, yellow cedar, Japanese cedar, hinoki cypress, eucalyptus, etc.).
The above-mentioned "plants" also include plants provided with herbicide tolerance by a classical breeding technique or a gene recombination technique. Examples of such herbicide tolerance include tolerance to HPPD inhibitors, such as isoxaflutole; ALS inhibitors, such as imazethapyr and thifensulfuron-methyl; EPSP synthase inhibitors, such as glyphosate; glutamine synthetase inhibitors, such as glufosinate; acetyl-CoA carboxylase inhibitors, such as sethoxydim; or other herbicides, such as bromoxynil, dicamba and 2,4-D.
Examples of the plants provided with herbicide tolerance by a classical breeding technique include varieties of rapeseed, wheat, sunflower and rice tolerant to the imidazolinone family of ALS-inhibiting herbicides such as imazethapyr, and such plants are sold under the trade name of Clearfield (registered trademark). Also included is a variety of soybean provided with tolerance to the sulfonyl urea family of ALS-inhibiting herbicides such as thifensulfuron-methyl by a classical breeding technique, and this is sold under the trade name of STS soybean. Also included are plants provided with tolerance to acetyl-CoA carboxylase inhibitors such as trione oxime herbicides and aryloxy phenoxy propionic acid herbicides by a classical breeding technique, for example, SR corn and the like.
Plants provided with tolerance to acetyl-CoA carboxylase inhibitors are described in Proc. Natl. Acad. Sci. USA, 87, 7175-7179 (1990), and the like. Further, acetyl-CoA carboxylase mutants resistant to acetyl-CoA carboxylase inhibitors are reported in Weed Science, 53, 728-746 (2005), and the like, and by introducing the gene of such an acetyl-CoA carboxylase mutant into plants by a gene recombination technique, or introducing a resistance-conferring mutation into acetyl-CoA carboxylase of plants, plants tolerant to acetyl-CoA carboxylase inhibitors can be engineered.
Alternatively, by introducing a nucleic acid causing base substitution mutation into plant cells (a typical example of this technique is chimeraplasty technique (Gura T. 1999.
Repairing the Genome’s Spelling Mistakes. Science 285: 316-318.)) to allow site-specific substitution mutation in the amino acids encoded by an acetyl-CoA carboxylase gene, an ALS gene or the like of plants, plants tolerant to acetyl-CoA carboxylase inhibitors, ALS inhibitors or the like can be engineered. The agricultural and horticultural insecticide of the present invention can be applied to these plants as well.
Further, exemplary toxins expressed in genetically modified plants include insecticidal proteins of Bacillus cereus or Bacillus popilliae; Bacillus thuringiensis δ-endotoxins, such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 and Cry9C, and other insecticidal proteins, such as VIP1, VIP2, VIP3 and VIP3A; nematode insecticidal proteins; toxins produced by animals, such as scorpion toxins, spider toxins, bee toxins and insect-specific neurotoxins; toxins of filamentous fungi; plant lectins; agglutinin; protease inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin and papain inhibitors; ribosome inactivating proteins (RIP), such as ricin, maize RIP, abrin, luffin, saporin and bryodin; steroid metabolizing enzymes, such as 3-hydroxy steroid oxidase, ecdysteroid-UDP-glucosyltransferase and cholesterol oxidase; ecdysone inhibitors; HMG-CoA reductase; ion channel inhibitors, such as sodium channel inhibitors and calcium channel inhibitors; juvenile hormone esterase; diuretic hormone receptors; stilbene synthase; bibenzyl synthase; chitinase; and glucanase.
Also included are hybrid toxins, partially deficient toxins and modified toxins derived from the following: δ-endotoxin proteins such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1, Cry9C, Cry34Ab and Cry35Ab, and other insecticidal proteins such as VIP1, VIP2, VIP3 and VIP3A. The hybrid toxin can be produced by combining some domains of these proteins differently from the original combination in nature with the use of a recombination technique. As the partially deficient toxin, a Cry1Ab toxin in which a part of the amino acid sequence is deleted is known. In the modified toxin, one or more amino acids of a naturally occurring toxin are substituted.
Examples of the foregoing toxins and genetically modified plants capable of synthesizing these toxins are described in EP-A-0 374 753, WO 93/07278, WO 95/34656, EP-A-0 427 529, EP-A-451 878, WO 03/052073, etc. id="p-152" id="p-152" id="p-152" id="p-152" id="p-152"
id="p-152"
[0152] Due to the toxins contained in such genetically modified plants, the plants exhibit resistance to pests, in particular, Coleopteran insect pests, Hemipteran insect pests, Dipteran insect pests, Lepidopteran insect pests and nematodes. The above-described technologies and the agricultural and horticultural insecticide of the present invention can be used in combination or used systematically.
In order to control target pests, the agricultural and horticultural insecticide of the present invention, with or without appropriate dilution or suspension in water etc., is applied to plants potentially infested with the target insect pests or nematodes in an amount effective for the control of the insect pests or nematodes. For example, in order to control insect pests and nematodes that may damage crop plants such as fruit trees, cereals and vegetables, foliar application and seed treatment such as dipping, dust coating and calcium peroxide coating can be performed. Further, treatment of soil or the like may also be performed to allow plants to absorb agrochemicals through their roots. Examples of such treatment include whole soil incorporation, planting row treatment, bed soil incorporation, plug seedling treatment, planting hole treatment, plant foot treatment, top-dressing, treatment of nursery boxes for paddy rice, and submerged application. In addition, application to culture media in hydroponics, smoking treatment, trunk injection and the like can also be performed.
Further, the agricultural and horticultural insecticide of the present invention, with or without appropriate dilution or suspension in water etc., can be applied to sites potentially infested with pests in an amount effective for the control of the pests. For example, it can be directly applied to stored grain pests, house pests, sanitary pests, forest pests, etc., and also be used for coating of residential building materials, for smoking treatment, or as a bait formulation.
Exemplary methods of seed treatment include dipping of seeds in a diluted or undiluted fluid of a liquid or solid formulation for the permeation of agrochemicals into the seeds; mixing or dust coating of seeds with a solid or liquid formulation for the adherence of the formulation onto the surfaces of the seeds; coating of seeds with a mixture of an agrochemical and an adhesive carrier such as resins and polymers; and application of a solid or liquid formulation to the vicinity of seeds at the same time as seeding.
The term "seed" in the above-mentioned seed treatment refers to a plant body which is in the early stages of cultivation and used for plant propagation. The examples include, in addition to a so-called seed, a plant body for vegetative propagation, such as a bulb, a tuber, a seed potato, a bulbil, a propagule, a discoid stem and a stem used for cuttage.
The term "soil" or "cultivation medium" in the method of the present invention for using an agricultural and horticultural insecticide refers to a support medium for crop cultivation, in particular a support medium which allows crop plants to spread their roots therein, and the materials are not particularly limited as long as they allow plants to grow.
Examples of the support medium include what is called soils, seedling mats and water, and specific examples of the materials include sand, pumice, vermiculite, diatomite, agar, gelatinous substances, high-molecular-weight substances, rock wool, glass wool, wood chip and bark.
Exemplary methods of the application to crop foliage or to stored grain pests, house pests, sanitary pests, forest pests, etc. include application of a liquid formulation, such as an emulsifiable concentrate and a flowable, or a solid formulation, such as a wettable powder and a water-dispersible granule, after appropriate dilution in water; dust application; and smoking.
Exemplary methods of soil application include application of a water-diluted or undiluted liquid formulation to the foot of plants, nursery beds for seedlings, or the like; application of a granule to the foot of plants, nursery beds for seedlings, or the like; application of a dust, a wettable powder, a water-dispersible granule, a granule or the like onto soil and subsequent incorporation of the formulation into the whole soil before seeding or transplanting; and application of a dust, a wettable powder, a water-dispersible granule, a granule or the like to planting holes, planting rows or the like before seeding or planting.
To nursery boxes for paddy rice, for example, a dust, a water-dispersible granule, a granule or the like can be applied, although the suitable formulation may vary depending on the application timing, in other words, depending on the cultivation stage such as seeding time, greening period and planting time. A formulation such as a dust, a water-dispersible granule and a granule may be mixed with nursery soil. For example, such a formulation is incorporated into bed soil, covering soil or the whole soil. Simply, nursery soil and such a formulation may be alternately layered.
In the application to paddy fields, a solid formulation, such as a jumbo, a pack, a granule and a water-dispersible granule, or a liquid formulation, such as a flowable and an emulsifiable concentrate, is applied usually to flooded paddy fields. In a rice planting period, a suitable formulation, as it is or after mixed with a fertilizer, may be applied onto soil or injected into soil. In addition, an emulsifiable concentrate, a flowable or the like may be applied to the source of water supply for paddy fields, such as a water inlet and an irrigation device. In this case, treatment can be accomplished with the supply of water and thus achieved in a labor-saving manner.
In the case of field crops, their seeds, cultivation media in the vicinity of their plants, or the like may be treated in the period of seeding to seedling culture. In the case of plants of which the seeds are directly sown in the field, in addition to direct seed treatment, plant foot treatment during cultivation is preferable. Specifically, the treatment can be performed by, for example, applying a granule onto soil, or drenching soil with a formulation in a water-diluted or undiluted liquid form. Another preferable treatment is incorporation of a granule into cultivation media before seeding.
In the case of culture plants to be transplanted, preferable examples of the treatment in the period of seeding to seedling culture include, in addition to direct seed treatment, drench treatment of nursery beds for seedlings with a formulation in a liquid form; and granule application to nursery beds for seedlings. Also included are treatment of planting holes with a granule; and incorporation of a granule into cultivation media in the vicinity of planting points at the time of fix planting.
The agricultural and horticultural insecticide of the present invention is commonly used as a formulation convenient for application, which is prepared by the usual method for preparing agrochemical formulations.
That is, the oxime group-containing condensed heterocyclic compound represented by the general formula (1) of the present invention or a salt thereof and an appropriate inactive carrier, and if needed an adjuvant, are blended in an appropriate ratio, and through the step of dissolution, separation, suspension, mixing, impregnation, adsorption and/or adhesion, are formulated into an appropriate form for application, such as a suspension concentrate, an emulsifiable concentrate, a soluble concentrate, a wettable powder, a water-dispersible granule, a granule, a dust, a tablet and a pack.
The composition (agricultural and horticultural insecticide or animal parasite control agent) of the present invention can optionally contain an additive usually used for agrochemical formulations or animal parasite control agents in addition to the active ingredient. Examples of the additive include carriers such as solid or liquid carriers, surfactants, dispersants, wetting agents, binders, tackifiers, thickeners, colorants, spreaders, sticking/spreading agents, antifreezing agents, anti-caking agents, disintegrants and stabilizing agents. If needed, preservatives, plant fragments, etc. may also be used as the additive. One of these additives may be used alone, and also two or more of them may be used in combination.
Examples of the solid carriers include natural minerals, such as quartz, clay, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, attapulgite, zeolite and diatomite; inorganic salts, such as calcium carbonate, ammonium sulfate, sodium sulfate and potassium chloride; organic solid carriers, such as synthetic silicic acid, synthetic silicates, starch, cellulose and plant powders (for example, sawdust, coconut shell, corn cob, tobacco stalk, etc.); plastics carriers, such as polyethylene, polypropylene and polyvinylidene chloride; urea; hollow inorganic materials; hollow plastic materials; and fumed silica (white carbon). One of these solid carriers may be used alone, and also two or more of them may be used in combination.
Examples of the liquid carriers include alcohols including monohydric alcohols, such as methanol, ethanol, propanol, isopropanol and butanol, and polyhydric alcohols, such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol and glycerin; polyol compounds, such as propylene glycol ether; ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone and cyclohexanone; ethers, such as ethyl ether, dioxane, ethylene glycol monoethyl ether, dipropyl ether and tetrahydrofuran; aliphatic hydrocarbons, such as normal paraffin, naphthene, isoparaffin, kerosene and mineral oil; aromatic hydrocarbons, such as benzene, toluene, xylene, solvent naphtha and alkyl naphthalene; halogenated hydrocarbons, such as dichloromethane, chloroform and carbon tetrachloride; esters, such as ethyl acetate, diisopropyl phthalate, dibutyl phthalate, dioctyl phthalate and dimethyl adipate; lactones, such as γ-butyrolactone; amides, such as dimethylformamide, diethylformamide, dimethylacetamide and N-alkyl pyrrolidinone; nitriles, such as acetonitrile; sulfur compounds, such as dimethyl sulfoxide; vegetable oils, such as soybean oil, rapeseed oil, cotton seed oil and castor oil; and water. One of these liquid carriers may be used alone, and also two or more of them may be used in combination.
Exemplary surfactants used as the dispersant or the wetting/spreading agent include nonionic surfactants, such as sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene resin acid ester, polyoxyethylene fatty acid diester, polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, polyoxyethylene alkyl phenyl ether-formaldehyde condensates, polyoxyethylene-polyoxypropylene block copolymers, polystyrene-polyoxyethylene block polymers, alkyl polyoxyethylene-polypropylene block copolymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene fatty acid bis(phenyl ether), polyalkylene benzyl phenyl ether, polyoxyalkylene styryl phenyl ether, acetylene diol, polyoxyalkylene-added acetylene diol, polyoxyethylene ether-type silicone, ester-type silicone, fluorosurfactants, polyoxyethylene castor oil and polyoxyethylene hydrogenated castor oil; anionic surfactants, such as alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, polyoxyethylene styryl phenyl ether sulfates, alkylbenzene sulfonates, alkylaryl sulfonates, lignosulfonates, alkyl sulfosuccinates, naphthalene sulfonates, alkylnaphthalene sulfonates, salts of naphthalenesulfonic acid-formaldehyde condensates, salts of alkylnaphthalenesulfonic acid-formaldehyde condensates, fatty acid salts, polycarboxylic acid salts, polyacrylates, N-methyl-fatty acid sarcosinates, resinates, polyoxyethylene alkyl ether phosphates and polyoxyethylene alkyl phenyl ether phosphates; cationic surfactants including alkyl amine salts, such as lauryl amine hydrochloride, stearyl amine hydrochloride, oleyl amine hydrochloride, stearyl amine acetate, stearyl aminopropyl amine acetate, alkyl trimethyl ammonium chloride and alkyl dimethyl benzalkonium chloride; and amphoteric surfactants, such as amino acid-type or betaine-type amphoteric surfactants. One of these surfactants may be used alone, and also two or more of them may be used in combination. id="p-162" id="p-162" id="p-162" id="p-162" id="p-162"
id="p-162"
[0162] Examples of the binders or the tackifiers include carboxymethyl cellulose or salts thereof, dextrin, soluble starch, xanthan gum, guar gum, sucrose, polyvinyl pyrrolidone, gum arabic, polyvinyl alcohol, polyvinyl acetate, sodium polyacrylate, polyethylene glycols with an average molecular weight of 6,000 to 20,000, polyethylene oxides with an average molecular weight of 100,000 to 5,000,000, phospholipids (for example, cephalin, lecithin, etc.), cellulose powder, dextrin, modified starch, polyaminocarboxylic acid chelating compounds, cross-linked polyvinyl pyrrolidone, maleic acid-styrene copolymers, (meth)acrylic acid copolymers, half esters of polyhydric alcohol polymer and dicarboxylic anhydride, water soluble polystyrene sulfonates, paraffin, terpene, polyamide resins, polyacrylates, polyoxyethylene, waxes, polyvinyl alkyl ether, alkylphenol-formaldehyde condensates and synthetic resin emulsions.
Examples of the thickeners include water soluble polymers, such as xanthan gum, guar gum, diutan gum, carboxymethyl cellulose, polyvinyl pyrrolidone, carboxyvinyl polymers, acrylic polymers, starch compounds and polysaccharides; and inorganic fine powders, such as high grade bentonite and fumed silica (white carbon). id="p-164" id="p-164" id="p-164" id="p-164" id="p-164"
id="p-164"
[0164] Examples of the colorants include inorganic pigments, such as iron oxide, titanium oxide and Prussian blue; and organic dyes, such as alizarin dyes, azo dyes and metal phthalocyanine dyes. id="p-165" id="p-165" id="p-165" id="p-165" id="p-165"
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[0165] Examples of the antifreezing agents include polyhydric alcohols, such as ethylene glycol, diethylene glycol, propylene glycol and glycerin.
Examples of the adjuvants serving to prevent caking or facilitate disintegration include polysaccharides (starch, alginic acid, mannose, galactose, etc.), polyvinyl pyrrolidone, fumed silica (white carbon), ester gum, petroleum resin, sodium tripolyphosphate, sodium hexametaphosphate, metal stearates, cellulose powder, dextrin, methacrylate copolymers, polyvinyl pyrrolidone, polyaminocarboxylic acid chelating compounds, sulfonated styrene-isobutylene-maleic anhydride copolymers and starch-polyacrylonitrile graft copolymers. id="p-167" id="p-167" id="p-167" id="p-167" id="p-167"
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[0167] Examples of the stabilizing agents include desiccants, such as zeolite, quicklime and magnesium oxide; antioxidants, such as phenolic compounds, amine compounds, sulfur compounds and phosphoric acid compounds; and ultraviolet absorbers, such as salicylic acid compounds and benzophenone compounds.
Examples of the preservatives include potassium sorbate and 1,2-benzothiazolinone.
Further, other adjuvants including functional spreading agents, activity enhancers such as metabolic inhibitors (piperonyl butoxide etc.), antifreezing agents (propylene glycol etc.), antioxidants (BHT etc.) and ultraviolet absorbers can also be used if needed.
The amount of the active ingredient compound in the agricultural and horticultural insecticide of the present invention can be adjusted as needed, and basically, the amount of the active ingredient compound is appropriately selected from the range of 0.01 to 90 parts by weight in 100 parts by weight of the agricultural and horticultural insecticide. For example, in the case where the agricultural and horticultural insecticide is a dust, a granule, an emulsifiable concentrate or a wettable powder, it is suitable that the amount of the active ingredient compound is 0.01 to 50 parts by weight (0.01 to 50% by weight relative to the total weight of the agricultural and horticultural insecticide).
The application rate of the agricultural and horticultural insecticide of the present invention may vary with various factors, for example, the purpose, the target pest, the growing conditions of crops, the tendency of pest infestation, the weather, the environmental conditions, the dosage form, the application method, the application site, the application timing, etc., but basically, the application rate of the active ingredient compound is appropriately selected from the range of 0.001 g to 10 kg, and preferably 0.01 g to 1 kg per 10 ares depending on the purpose.
Furthermore, for the expansion of the range of target pests and the appropriate time for pest control, or for dose reduction, the agricultural and horticultural insecticide of the present invention can be used after mixed with other agricultural and horticultural insecticides, acaricides, nematicides, microbicides, biopesticides and/or the like. Further, the agricultural and horticultural insecticide can be used after mixed with herbicides, plant growth regulators, fertilizers and/or the like depending on the situation.
Examples of such additional agricultural and horticultural insecticides, acaricides and nematicides used for the above-mentioned purposes include 3,5-xylyl methylcarbamate (XMC), crystalline protein toxins produced by Bacillus thuringiensis such as Bacillus thuringiensis aizawai, Bacillus thuringiensis israelensis, Bacillus thuringiensis japonensis, Bacillus thuringiensis kurstaki and Bacillus thuringiensis tenebrionis, BPMC, Bt toxin-derived insecticidal compounds, CPCBS (chlorfenson), DCIP (dichlorodiisopropyl ether), D-D (1,3-dichloropropene), DDT, NAC, Odimethylsulfamoylphenyl O,O-diethyl phosphorothioate (DSP), O-ethyl Onitrophenyl phenylphosphonothioate (EPN), tripropylisocyanurate (TPIC), acrinathrin, azadirachtin, azinphos-methyl, acequinocyl, acetamiprid, acetoprole, acephate, abamectin, avermectin-B, amidoflumet, amitraz, alanycarb, aldicarb, aldoxycarb, aldrin, alpha-endosulfan, alpha-cypermethrin, albendazole, allethrin, isazofos, isamidofos, isoamidofos isoxathion, isofenphos, isoprocarb (MIPC), ivermectin, imicyafos, imidacloprid, imiprothrin, indoxacarb, esfenvalerate, ethiofencarb, ethion, ethiprole, etoxazole, ethofenprox, ethoprophos, etrimfos, emamectin, emamectin-benzoate, endosulfan, empenthrin, oxamyl, oxydemeton-methyl, oxydeprofos (ESP), oxibendazole, oxfendazole, potassium oleate, sodium oleate, cadusafos, cartap, carbaryl, carbosulfan, carbofuran, gamma-cyhalothrin, xylylcarb, quinalphos, kinoprene, chinomethionat, cloethocarb, clothianidin, clofentezine, chromafenozide, chlorantraniliprole, chlorethoxyfos, chlordimeform, chlordane, chlorpyrifos, chlorpyrifos-methyl, chlorphenapyr, chlorfenson, chlorfenvinphos, chlorfluazuron, chlorobenzilate, chlorobenzoate, kelthane (dicofol), salithion, cyanophos (CYAP), diafenthiuron, diamidafos, cyantraniliprole, theta-cypermethrin, dienochlor, cyenopyrafen, dioxabenzofos, diofenolan, sigma-cypermethrin, dichlofenthion (ECP), cycloprothrin, dichlorvos (DDVP), disulfoton, dinotefuran, cyhalothrin, cyphenothrin, cyfluthrin, diflubenzuron, cyflumetofen, diflovidazin, cyhexatin, cypermethrin, dimethylvinphos, dimethoate, dimefluthrin, silafluofen, cyromazine, spinetoram, spinosad, spirodiclofen, spirotetramat, spiromesifen, sulfluramid, sulprofos, sulfoxaflor, zeta-cypermethrin, diazinon, tau-fluvalinate, dazomet, thiacloprid, thiamethoxam, thiodicarb, thiocyclam, thiosultap, thiosultap-sodium, thionazin, thiometon, deet, dieldrin, tetrachlorvinphos, tetradifon, tetramethylfluthrin, tetramethrin, tebupirimfos, tebufenozide, tebufenpyrad, tefluthrin, teflubenzuron, demeton-S-methyl, temephos, deltamethrin, terbufos, tralopyril, tralomethrin, transfluthrin, triazamate, triazuron, trichlamide, trichlorphon (DEP), triflumuron, tolfenpyrad, naled (BRP), nithiazine, nitenpyram, novaluron, noviflumuron, hydroprene, vaniliprole, vamidothion, parathion, parathion-methyl, halfenprox, halofenozide, bistrifluron, bisultap, hydramethylnon, hydroxy propyl starch, binapacryl, bifenazate, bifenthrin, pymetrozine, pyraclofos, pyrafluprole, pyridafenthion, pyridaben, pyridalyl, pyrifluquinazon, pyriprole, pyriproxyfen, pirimicarb, pyrimidifen, pirimiphos-methyl, pyrethrins, fipronil, fenazaquin, fenamiphos, bromopropylate, fenitrothion (MEP), fenoxycarb, fenothiocarb, phenothrin, fenobucarb, fensulfothion, fenthion (MPP), phenthoate (PAP), fenvalerate, fenpyroximate, fenpropathrin, fenbendazole, fosthiazate, formetanate, butathiofos, buprofezin, furathiocarb, prallethrin, fluacrypyrim, fluazinam, fluazuron, fluensulfone, flucycloxuron, flucythrinate, fluvalinate, flupyrazofos, flufenerim, flufenoxuron, flufenzine, flufenprox, fluproxyfen, flubrocythrinate, flubendiamide, flumethrin, flurimfen, prothiofos, protrifenbute, flonicamid, propaphos, propargite (BPPS), profenofos, profluthrin, propoxur (PHC), bromopropylate, beta-cyfluthrin, hexaflumuron, hexythiazox, heptenophos, permethrin, benclothiaz, bendiocarb, bensultap, benzoximate, benfuracarb, phoxim, phosalone, fosthiazate, fosthietan, phosphamidon, phosphocarb, phosmet (PMP), polynactins, formetanate, formothion, phorate, machine oil, malathion, milbemycin, milbemycin-A, milbemectin, mecarbam, mesulfenfos, methomyl, metaldehyde, metaflumizone, methamidophos, metam-ammonium, metam-sodium, methiocarb, methidathion (DMTP), methylisothiocyanate, methylneodecanamide, methylparathion, metoxadiazone, methoxychlor, methoxyfenozide, metofluthrin, methoprene, metolcarb, meperfluthrin, mevinphos, monocrotophos, monosultap, lambda-cyhalothrin, ryanodine, lufenuron, resmethrin, lepimectin, rotenone, levamisole hydrochloride, fenbutatin oxide, morantel tartarate, methyl bromide, tricyclohexyltin hydroxide (cyhexatin), calcium cyanamide, calcium polysulfide, sulfur and nicotine-sulfate.
Exemplary agricultural and horticultural microbicides used for the same purposes as above include aureofungin, azaconazole, azithiram, acypetacs, acibenzolar, acibenzolar-S-methyl, azoxystrobin, anilazine, amisulbrom, ampropylfos, ametoctradin, allyl alcohol, aldimorph, amobam, isotianil, isovaledione, isopyrazam, isoprothiolane, ipconazole, iprodione, iprovalicarb, iprobenfos, imazalil, iminoctadine, iminoctadine-albesilate, iminoctadine-triacetate, imibenconazole, uniconazole, uniconazole-P, echlomezole, edifenphos, etaconazole, ethaboxam, ethirimol, etem, ethoxyquin, etridiazole, enestroburin, epoxiconazole, oxadixyl, oxycarboxin, copperquinolinolate, oxytetracycline, copper-oxinate, oxpoconazole, oxpoconazole-fumarate, oxolinic acid, octhilinone, ofurace, orysastrobin, metam-sodium, kasugamycin, carbamorph, carpropamid, carbendazim, carboxin, carvone, quinazamid, quinacetol, quinoxyfen, quinomethionate, captafol, captan, kiralaxyl, quinconazole, quintozene, guazatine, cufraneb, cuprobam, glyodin, griseofulvin, climbazole, cresol, kresoxim-methyl, chlozolinate, clotrimazole, chlobenthiazone, chloraniformethan, chloranil, chlorquinox, chloropicrin, chlorfenazole, chlorodinitronaphthalene, chlorothalonil, chloroneb, zarilamid, salicylanilide, cyazofamid, diethyl pyrocarbonate, diethofencarb, cyclafuramid, diclocymet, dichlozoline, diclobutrazol, dichlofluanid, cycloheximide, diclomezine, dicloran, dichlorophen, dichlone, disulfiram, ditalimfos, dithianon, diniconazole, diniconazole-M, zineb, dinocap, dinocton, dinosulfon, dinoterbon, dinobuton, dinopenton, dipyrithione, diphenylamine, difenoconazole, cyflufenamid, diflumetorim, cyproconazole, cyprodinil, cyprofuram, cypendazole, simeconazole, dimethirimol, dimethomorph, cymoxanil, dimoxystrobin, methyl bromide, ziram, silthiofam, streptomycin, spiroxamine, sultropen, sedaxane, zoxamide, dazomet, thiadiazin, tiadinil, thiadifluor, thiabendazole, tioxymid, thiochlorfenphim, thiophanate, thiophanate-methyl, thicyofen, thioquinox, chinomethionat, thifluzamide, thiram, decafentin, tecnazene, tecloftalam, tecoram, tetraconazole, debacarb, dehydroacetic acid, tebuconazole, tebufloquin, dodicin, dodine, dodecyl benzensulfonate bis-ethylene diamine copper(II) (DBEDC), dodemorph, drazoxolon, triadimenol, triadimefon, triazbutil, triazoxide, triamiphos, triarimol, trichlamide, tricyclazole, triticonazole, tridemorph, tributyltin oxide, triflumizole, trifloxystrobin, triforine, tolylfluanid, tolclofos-methyl, natamycin, nabam, nitrothal-isopropyl, nitrostyrene, nuarimol, copper nonylphenol sulfonate, halacrinate, validamycin, valifenalate, harpin protein, bixafen, picoxystrobin, picobenzamide, bithionol, bitertanol, hydroxyisoxazole, hydroxyisoxazole-potassium, binapacryl, biphenyl, piperalin, hymexazol, pyraoxystrobin, pyracarbolid, pyraclostrobin, pyrazophos, pyrametostrobin, pyriofenone, pyridinitril, pyrifenox, pyribencarb, pyrimethanil, pyroxychlor, pyroxyfur, pyroquilon, vinclozolin, famoxadone, fenapanil, fenamidone, fenaminosulf, fenarimol, fenitropan, fenoxanil, ferimzone, ferbam, fentin, fenpiclonil, fenpyrazamine, fenbuconazole, fenfuram, fenpropidin, fenpropimorph, fenhexamid, phthalide, buthiobate, butylamine, bupirimate, fuberidazole, blasticidin-S, furametpyr, furalaxyl, fluacrypyrim, fluazinam, fluoxastrobin, fluotrimazole, fluopicolide, fluopyram, fluoroimide, furcarbanil, fluxapyroxad, fluquinconazole, furconazole, furconazole-cis, fludioxonil, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, furfural, furmecyclox, flumetover, flumorph, proquinazid, prochloraz, procymidone, prothiocarb, prothioconazole, propamocarb, propiconazole, propineb, furophanate, probenazole, bromuconazole, hexachlorobutadiene, hexaconazole, hexylthiofos, bethoxazin, benalaxyl, benalaxyl-M, benodanil, benomyl, pefurazoate, benquinox, penconazole, benzamorf, pencycuron, benzohydroxamic acid, bentaluron, benthiazole, benthiavalicarb-isopropyl, penthiopyrad, penflufen, boscalid, phosdiphen, fosetyl, fosetyl-Al, polyoxins, polyoxorim, polycarbamate, folpet, formaldehyde, machine oil, maneb, mancozeb, mandipropamid, myclozolin, myclobutanil, mildiomycin, milneb, mecarbinzid, methasulfocarb, metazoxolon, metam, metam-sodium, metalaxyl, metalaxyl-M, metiram, methyl isothiocyanate, meptyldinocap, metconazole, metsulfovax, methfuroxam, metominostrobin, metrafenone, mepanipyrim, mefenoxam, meptyldinocap, mepronil, mebenil, iodomethane, rabenzazole, benzalkonium chloride, basic copper chloride, basic copper sulfate, inorganic microbicides such as silver, sodium hypochlorite, cupric hydroxide, wettable sulfur, calcium polysulfide, potassium hydrogen carbonate, sodium hydrogen carbonate, sulfur, copper sulfate anhydride, nickel dimethyldithiocarbamate, copper compounds such as copperquinolinolate (oxine copper), zinc sulfate and copper sulfate pentahydrate.
Exemplary herbicides used for the same purposes as above include 1-naphthylacetamide, 2,4-PA, 2,3,6-TBA, 2,4,5-T, 2,4,5-TB, 2,4-D, 2,4-DB, 2,4-DEB, 2,4-DEP, 3,4-DA, 3,4-DB, 3,4-DP, 4-CPA, 4-CPB, 4-CPP, MCP, MCPA, MCPA-thioethyl, MCPB, ioxynil, aclonifen, azafenidin, acifluorfen, aziprotryne, azimsulfuron, asulam, acetochlor, atrazine, atraton, anisuron, anilofos, aviglycine, abscisic acid, amicarbazone, amidosulfuron, amitrole, aminocyclopyrachlor, aminopyralid, amibuzin, amiprophos-methyl, ametridione, ametryn, alachlor, allidochlor, alloxydim, alorac, isouron, isocarbamid, isoxachlortole, isoxapyrifop, isoxaflutole, isoxaben, isocil, isonoruron, isoproturon, isopropalin, isopolinate, isomethiozin, inabenfide, ipazine, ipfencarbazone, iprymidam, imazaquin, imazapic, imazapyr, imazamethapyr, imazamethabenz, imazamethabenz-methyl, imazamox, imazethapyr, imazosulfuron, indaziflam, indanofan, indolebutyric acid, uniconazole-P, eglinazine, esprocarb, ethametsulfuron, ethametsulfuron-methyl, ethalfluralin, ethiolate, ethychlozate-ethyl, ethidimuron, etinofen, ethephon, ethoxysulfuron, ethoxyfen, etnipromid, ethofumesate, etobenzanid, epronaz, erbon, endothal, oxadiazon, oxadiargyl, oxaziclomefone, oxasulfuron, oxapyrazon, oxyfluorfen, oryzalin, orthosulfamuron, orbencarb, cafenstrole, cambendichlor, carbasulam, carfentrazone, carfentrazone-ethyl, karbutilate, carbetamide, carboxazole, quizalofop, quizalofop-P, quizalofop-ethyl, xylachlor, quinoclamine, quinonamid, quinclorac, quinmerac, cumyluron, cliodinate, glyphosate, glufosinate, glufosinate-P, credazine, clethodim, cloxyfonac, clodinafop, clodinafop-propargyl, chlorotoluron, clopyralid, cloproxydim, cloprop, chlorbromuron, clofop, clomazone, chlomethoxynil, chlomethoxyfen, clomeprop, chlorazifop, chlorazine, cloransulam, chloranocryl, chloramben, cloransulam-methyl, chloridazon, chlorimuron, chlorimuron-ethyl, chlorsulfuron, chlorthal, chlorthiamid, chlortoluron, chlornitrofen, chlorfenac, chlorfenprop, chlorbufam, chlorflurazole, chlorflurenol, chlorprocarb, chlorpropham, chlormequat, chloreturon, chloroxynil, chloroxuron, chloropon, saflufenacil, cyanazine, cyanatryn, di-allate, diuron, diethamquat, dicamba, cycluron, cycloate, cycloxydim, diclosulam, cyclosulfamuron, dichlorprop, dichlorprop-P, dichlobenil, diclofop, diclofop-methyl, dichlormate, dichloralurea, diquat, cisanilide, disul, siduron, dithiopyr, dinitramine, cinidon-ethyl, dinosam, cinosulfuron, dinoseb, dinoterb, dinofenate, dinoprop, cyhalofop-butyl, diphenamid, difenoxuron, difenopenten, difenzoquat, cybutryne, cyprazine, cyprazole, diflufenican, diflufenzopyr, dipropetryn, cypromid, cyperquat, gibberellin, simazine, dimexano, dimethachlor, dimidazon, dimethametryn, dimethenamid, simetryn, simeton, dimepiperate, dimefuron, cinmethylin, swep, sulglycapin, sulcotrione, sulfallate, sulfentrazone, sulfosulfuron, sulfometuron, sulfometuron-methyl, secbumeton, sethoxydim, sebuthylazine, terbacil, daimuron, dazomet, dalapon, thiazafluron, thiazopyr, thiencarbazone, thiencarbazone-methyl, tiocarbazil, tioclorim, thiobencarb, thidiazimin, thidiazuron, thifensulfuron, thifensulfuron-methyl, desmedipham, desmetryn, tetrafluron, thenylchlor, tebutam, tebuthiuron, terbumeton, tepraloxydim, tefuryltrione, tembotrione, delachlor, terbacil, terbucarb, terbuchlor, terbuthylazine, terbutryn, topramezone, tralkoxydim, triaziflam, triasulfuron, tri-allate, trietazine, tricamba, triclopyr, tridiphane, tritac, tritosulfuron, triflusulfuron, triflusulfuron-methyl, trifluralin, trifloxysulfuron, tripropindan, tribenuron-methyl, tribenuron, trifop, trifopsime, trimeturon, naptalam, naproanilide, napropamide, nicosulfuron, nitralin, nitrofen, nitrofluorfen, nipyraclofen, neburon, norflurazon, noruron, barban, paclobutrazol, paraquat, parafluron, haloxydine, haloxyfop, haloxyfop-P, haloxyfop-methyl, halosafen, halosulfuron, halosulfuron-methyl, picloram, picolinafen, bicyclopyrone, bispyribac, bispyribac-sodium, pydanon, pinoxaden, bifenox, piperophos, hymexazol, pyraclonil, pyrasulfotole, pyrazoxyfen, pyrazosulfuron, pyrazosulfuron-ethyl, pyrazolate, bilanafos, pyraflufen-ethyl, pyriclor, pyridafol, pyrithiobac, pyrithiobac-sodium, pyridate, pyriftalid, pyributicarb, pyribenzoxim, pyrimisulfan, primisulfuron, pyriminobac-methyl, pyroxasulfone, pyroxsulam, fenasulam, phenisopham, fenuron, fenoxasulfone, fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, phenothiol, fenoprop, phenobenzuron, fenthiaprop, fenteracol, fentrazamide, phenmedipham, phenmedipham-ethyl, butachlor, butafenacil, butamifos, buthiuron, buthidazole, butylate, buturon, butenachlor, butroxydim, butralin, flazasulfuron, flamprop, furyloxyfen, prynachlor, primisulfuron-methyl, fluazifop, fluazifop-P, fluazifop-butyl, fluazolate, fluroxypyr, fluothiuron, fluometuron, fluoroglycofen, flurochloridone, fluorodifen, fluoronitrofen, fluoromidine, flucarbazone, flucarbazone-sodium, fluchloralin, flucetosulfuron, fluthiacet, fluthiacet-methyl, flupyrsulfuron, flufenacet, flufenican, flufenpyr, flupropacil, flupropanate, flupoxam, flumioxazin, flumiclorac, flumiclorac-pentyl, flumipropyn, flumezin, fluometuron, flumetsulam, fluridone, flurtamone, fluroxypyr, pretilachlor, proxan, proglinazine, procyazine, prodiamine, prosulfalin, prosulfuron, prosulfocarb, propaquizafop, propachlor, propazine, propanil, propyzamide, propisochlor, prohydrojasmon, propyrisulfuron, propham, profluazol, profluralin, prohexadione-calcium, propoxycarbazone, propoxycarbazone-sodium, profoxydim, bromacil, brompyrazon, prometryn, prometon, bromoxynil, bromofenoxim, bromobutide, bromobonil, florasulam, hexachloroacetone, hexazinone, pethoxamid, benazolin, penoxsulam, pebulate, beflubutamid, vernolate, perfluidone, bencarbazone, benzadox, benzipram, benzylaminopurine, benzthiazuron, benzfendizone, bensulide, bensulfuron-methyl, benzoylprop, benzobicyclon, benzofenap, benzofluor, bentazone, pentanochlor, benthiocarb, pendimethalin, pentoxazone, benfluralin, benfuresate, fosamine, fomesafen, foramsulfuron, forchlorfenuron, maleic hydrazide, mecoprop, mecoprop-P, medinoterb, mesosulfuron, mesosulfuron-methyl, mesotrione, mesoprazine, methoprotryne, metazachlor, methazole, metazosulfuron, methabenzthiazuron, metamitron, metamifop, metam, methalpropalin, methiuron, methiozolin, methiobencarb, methyldymron, metoxuron, metosulam, metsulfuron, metsulfuron-methyl, metflurazon, metobromuron, metobenzuron, methometon, metolachlor, metribuzin, mepiquat-chloride, mefenacet, mefluidide, monalide, monisouron, monuron, monochloroacetic acid, monolinuron, molinate, morfamquat, iodosulfuron, iodosulfuron-methyl-sodium, iodobonil, iodomethane, lactofen, linuron, rimsulfuron, lenacil, rhodethanil, calcium peroxide and methyl bromide.
Exemplary biopesticides used for the same purposes as above include viral formulations such as nuclear polyhedrosis viruses (NPV), granulosis viruses (GV), cytoplasmic polyhedrosis viruses (CPV) and entomopox viruses (EPV); microbial pesticides used as an insecticide or a nematicide, such as Monacrosporium phymatophagum, Steinernema carpocapsae, Steinernema kushidai and Pasteuria penetrans; microbial pesticides used as a microbicide, such as Trichoderma lignorum, Agrobacterium radiobactor, avirulent Erwinia carotovora and Bacillus subtilis; and biopesticides used as a herbicide, such as Xanthomonas campestris. Such a combined use of the agricultural and horticultural insecticide of the present invention with the foregoing biopesticide as a mixture can be expected to provide the same effect as above.
Other examples of the biopesticides include natural predators such as Encarsia formosa, Aphidius colemani, Aphidoletes aphidimyza, Diglyphus isaea, Dacnusa sibirica, Phytoseiulus persimilis, Amblyseius cucumeris and Orius sauteri; microbial pesticides such as Beauveria brongniartii; and pheromones such as (Z)tetradecenyl acetate, (E,Z)-4,10-tetradecadienyl acetate, (Z)dodecenyl acetate, (Z)tetradecenyl acetate, (Z)icosenone and 14-methyloctadecene.
The compound of the present invention or a salt thereof is also suitable for the disinfection of parasites that live in the interior of or on the exterior of animals such as humans, domestic animals and pets.
The present invention also includes an animal ectoparasite control agent comprising the compound of the present invention or a salt thereof as an active ingredient; and a method for controlling animal ectoparasites, comprising treating animal ectoparasites with the animal ectoparasite control agent. The compound of the present invention can be used by spot-on or pour-on application usually to one site or two sites on the skin of an animal such as a cat or a dog. The application area is usually 5 to 10 cm . Once applied, the compound of the present invention preferably diffuses throughout the animal’s body and then dries without crystallization or changes in visual appearance or texture. The preferable amount of the compound used is selected from the range of 0.1 to 10 mL according to the weight of the animal, and in particular, is about 0.5 to 1 mL for a cat and about 0.3 to 3 mL for a dog.
The ectoparasite control agent of the present invention is effective against, for example, the following animal ectoparasites. Siphonaptera parasites include the species of the genus Pulex such as Pulex irritans; the species of the genus Ctenocephalides such as Ctenocephalides felis and Ctenocephalides canis; the species of the genus Xenopsylla such as Xenopsylla cheopis; the species of the genus Tunga such as Tunga penetrans; the species of the genus Echidnophaga such as Echidnophaga gallinacea; and the species of the genus Nosopsyllus such as Nosopsyllus fasciatus. id="p-178" id="p-178" id="p-178" id="p-178" id="p-178"
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[0178] Siphunculata parasites include the species of the genus Pediculus such as Pediculus humanus capitis; the species of the genus Pthirus such as Pthirus pubis; the species of the genus Haematopinus such as Haematopinus eurysternus and Haematopinus suis; the species of the genus Damalinia such as Damalinia ovis and Damalinia bovis; the species of the genus Linognathus such as Linognathus vituli and Linognathus ovillus (parasitic on the trunk of a sheep’s body); and the species of the genus Solenopotes such as Solenopotes capillatus.
Mallophaga parasites include the species of the genus Menopon such as Menopon gallinae; Trimenopon spp.; Trinoton spp.; the species of the genus Trichodectes such as Trichodectes canis; the species of the genus Felicola such as Felicola subrostratus; the species of the genus Bovicola such as Bovicola bovis; the species of the genus Menacanthus such as Menacanthus stramineus; Werneckiella spp.; and Lepikentron spp.
Hemiptera parasites include the species of the genus Cimex such as Cimex lectularius and Cimex hemipterus; the species of the genus Reduvius such as Reduvius senilis; the species of the genus Arilus such as Arilus critatus; the species of the genus Rhodnius such as Rhodnius prolixus; the species of the genus Triatoma such as Triatoma rubrofasciata; and Panstrongylus spp.
Acarina parasites include the species of the genus Amblyomma such as Amblyomma americanum and Amblyomma maculatum; the species of the genus Boophilus such as Boophilus microplus and Boophilus annulatus; the species of the genus Dermacentor such as Dermacentor variabilis, Dermacentor taiwanensis and Dermacentor andersoni; the species of the genus Haemaphysalis such as Haemaphysalis longicornis, Haemaphysalis flava and Haemaphysalis campanulata; the species of the genus Ixodes such as Ixodes ovatus, Ixodes persulcatus, Ixodes scapularis, Ixodes pacificus and Ixodes holocyclus; the species of the genus Rhipicephalus such as Rhipicephalus sanguineus and Rhipicephalus appendiculatus; the species of the genus Argas such as Argas persicus; the species of the genus Ornithodoros such as Ornithodoros hermsi and Ornithodoros turicata; the species of the genus Psoroptes such as Psoroptes ovis and Psoroptes equi; the species of the genus Knemidocoptes such as Knemidocoptes mutans; the species of the genus Notoedres such as Notoedres cati and Notoedres muris; the species of the genus Sarcoptes such as Sarcoptes scabiei; the species of the genus Otodectes such as Otodectes cynotis; the species of the genus Listrophorus such as Listrophorus gibbus; Chorioptes spp.; Hypodectes spp.; Pterolichus spp.; Cytodites spp.; Laminosioptes spp.; the species of the genus Dermanyssus such as Dermanyssus gallinae; the species of the genus Ornithonyssus such as Ornithonyssus sylviarum and Ornithonyssus bacoti; the species of the genus Varroa such as Varroa jacobsoni; the species of the genus Cheyletiella such as Cheyletiella yasguri and Cheyletiella blakei; Ornithocheyletia spp.; the species of the genus Demodex such as Demodex canis and Demodex cati; Myobia spp.; Psorergates spp.; and the species of the genus Trombicula such as Trombicula akamushi, Trombicula pallida and Trombicula scutellaris. Preferred are Siphonaptera parasites, Siphunculata parasites and Acarina parasites.
The animals to which the ectoparasite control agent of the present invention is administrable can be host animals for the above-mentioned animal ectoparasites. Such animals are usually homeotherms and poikilotherms which are bred as domestic animals or pets. Such homeotherms include mammals such as cattle, buffalos, sheep, goats, pigs, camels, deer, fallow deer, reindeer, horses, donkeys, dogs, cats, rabbits, ferrets, mice, rats, hamsters, squirrels and monkeys; fur-bearing animals such as minks, chinchillas and raccoons; and birds such as chickens, geese, turkeys, domestic ducks, pigeons, parrots and quails. The above-mentioned poikilotherms include reptiles such as tortoises, sea turtles, pond sliders, Japanese pond turtles, lizards, iguanas, chameleons, geckos, pythons, colubrid snakes and cobras.
Preferred are homeotherms, and more preferred are mammals such as dogs, cats, cattle, horses, pigs, sheep and goats.
Hereinafter, the production examples of representative compounds of the present invention and their intermediates will be described in more detail, but the present invention is not limited only to these examples.
EXAMPLES Intermediate (2a) Production Example 1 Production method of -chloroethoxycarbonylpyridinecarboxylic acid [Chem. 10] An autoclave was charged with an ethanol (60 mL) solution of 5,6-dichloropyridinecarboxylic acid (10 g, 52 mmol). To this, DPPB (1,4-bis(diphenylphosphino)butane) (2.2 g, 10 mol%), triethylamine (14 g, 2.5 Eq) and PdCl (PPh ) (911 mg, 2.5 mol%) 2 3 2 were added. The reaction mixture was purged with carbon monoxide (CO pressure, 4.0 MPa) and stirred at 135 C for 4 hours.
To this, water and 3 N hydrochloric acid were added to acidify the aqueous layer, and ethyl acetate extraction was performed several times. The organic layer was dried over sodium sulfate and then concentrated. The resulting solid was washed with a hexane-ethyl acetate (2:1 (v/v)) mixture to give the desired compound, i.e., -chloroethoxycarbonylpyridinecarboxylic acid (10.9 g, 76%).
Physical property: H-NMR (CDCl ): 9.02 (d, 1H), 8.44 (d, 1H), 4.42 (dd, 2H), 1.33 (t, 3H) Intermediate (2a) Production Example 2 Production method of 5-chloroethoxycarbonylpyridinecarboxylic acid t-butyl ester [Chem. 11] The 5-chloroethoxycarbonylpyridinecarboxylic acid (10.9 g, 47.6 mmol) obtained in the previous step was dissolved in toluene (30 mL), and DMF (dimethylformamide) (4 mL) was added.
Subsequently, thionyl chloride (11 g, 2 Eq) was added, and the mixture was heated with stirring at 90 C for 3 hours. The reaction mixture was allowed to come to room temperature and then concentrated. The concentrated residue was slowly added to a mixture of t-butanol (35 mL, 10 Eq), THF (tetrahydrofuran) (100 mL), diisopropylethylamine (50 mL, 7 Eq) and DMAP (N,N-dimethylaminopyridine) (6 g, 1 Eq) in another vessel under ice cooling. The reaction mixture was heated under reflux for 3 hours and then allowed to cool down to room temperature.
To this, water and ethyl acetate were added, and extraction was performed several times. The organic layer was dried over sodium sulfate and then concentrated. The residue was subjected to column chromatography (hexane-AcOEt (acetic acid ethyl ester) = 5:1 (v/v)) to give the desired compound, i.e., 5-chloroethoxycarbonylpyridinecarboxylic acid t-butyl ester (8.43 g, 62%).
Physical property: H-NMR (CDCl ): 9.05 (d, 1H), 8.30 (d, 1H), 4.50 (dd, 2H), 1.61 (s, 9H), 1.44 (t, 3H) Intermediate (2a) Production Example 3 Production method of -ethylthioethoxycarbonylpyridinecarboxylic acid t-butyl ester [Chem. 12] -Chloroethoxycarbonylpyridinecarboxylic acid t-butyl ester (8.43 g, 21.65 mmol) was dissolved in DMF (100 mL). To the solution, sodium ethanethiolate (2.27 g, 1 Eq) was slowly added under ice cooling, and the mixture was stirred for minutes. To this, water and 0.5 N hydrochloric acid were successively added. After ethyl acetate extraction was performed several times, the organic layer was dried over sodium sulfate and then concentrated. The residue was subjected to column chromatography (hexane-AcOEt = 5:1 (v/v)) to give the desired compound, i.e., 5-ethylthioethoxycarbonylpyridinecarboxylic acid t-butyl ester (6.17 g, 92%).
Physical property: H-NMR (CDCl ): 8.91 (d, 1H), 8.22 (d, 1H), 4.49 (dd, 2H), 2.99 (dd, 2H), 1.61 (s, 9H), 1.45 (t, 3H), 1.40 (t, 3H) id="p-187" id="p-187" id="p-187" id="p-187" id="p-187"
id="p-187"
[0187] Intermediate (2a) Production Example 4 Production method of 3-ethylthiohydroxymethylpyridinecarboxylic acid ethyl ester [Chem. 13] To a THF solution (100 mL) of -ethylthioethoxycarbonylpyridinecarboxylic acid (10 g), which compound was produced according to the production method described in Production Example 3 above, CDI (carbonyldiimidazole) (10 g) was added, and the mixture was stirred at room temperature for 2 hours. This THF solution was slowly added to 100 mL of an aqueous solution of NaBH (5.5 g) at 0 C, and the mixture was stirred at room temperature for 1 hour. After the completion of the reaction, a 4 M hydrochloric acid solution was added for adjustment of the pH to 2, and ethyl acetate extraction was performed. The organic layer was washed with a saturated aqueous sodium chloride solution, dried over anhydrous magnesium sulfate, and then concentrated in vacuo.
The residue was purified by silica gel chromatography to give 3-ethylthiohydroxymethylpyridinecarboxylic acid ethyl ester (6.4 g, 62%).
Physical property: H-NMR (CDCl ): 8.39 (d, 1H), 7.73 (d, 1H), 4.81 (d, 2H), 4.49 (q, 2H), 2.96 (q, 2H), 1.92 (t, 1H), 1.45 (t, 3H), 1.40 (t, 3H) id="p-188" id="p-188" id="p-188" id="p-188" id="p-188"
id="p-188"
[0188] Intermediate (2a) Production Example 5 Production method of 3-ethylthiomethoxymethoxypyridinecarboxylic acid ethyl ester [Chem. 14] To a CHCl solution (50 mL) of 3-ethylthiohydroxymethylpyridinecarboxylic acid ethyl ester (6.4 g), DIPEA (N,N-diisopropylethylamine) (13.6 mL) and methoxymethyl chloride (MOMCl) (6.0 mL) were added, and the mixture was stirred at room temperature for 1 hour. After the completion of the reaction, an aqueous ammonium chloride solution was added, and ethyl acetate extraction was performed.
The organic layer was washed with a saturated aqueous sodium chloride solution, dried over anhydrous magnesium sulfate, and then concentrated in vacuo to give 3-ethylthiomethoxymethoxypyridinecarboxylic acid ethyl ester (7.1 g, 94%).
Physical property: H-NMR (CDCl ): 8.40 (d, 1H), 7.68 (d, 1H), 4.73 (s, 2H), 4.67 (s, 2H), 4.49 (q, 2H), 3.41 (s, 3H), 2.96 (q, 2H), 1.45 (t, 3H), 1.40 (t, 3H) Intermediate Production Example 6 Production method of t-butyl -ethylthio((2-hydroxy(trifluoromethylthio)phenyl)car bamoyl)nicotinate [Chem. 15] To a THF solution (100 mL) of 3-(ethylthio)pyridine-2,5-dicarboxylic acid di-t-butyl ester (6.5 g, 19.1 mmol), potassium t-butoxide (5.4 g, 47.8 mmol) and 2-amino(trifluoromethylthio)phenol (4.0 g, 19.1 mmol) were successively added slowly at room temperature, and the mixture was stirred for 1 hour. The reaction mixture was slowly added to a saturated ammonium chloride solution, and ethyl acetate extraction was performed. The organic layer was dried over anhydrous magnesium sulfate and then concentrated in vacuo.
The residue was purified by silica gel column chromatography to give the desired compound.
Intermediate Production Example 7 Production method of t-butyl -ethylthio(5-(trifluoromethylthio)benzo[d]oxazolyl)n icotinate [Chem. 16] To a THF solution (100 mL) of t-butyl -ethylthio((2-hydroxy(trifluoromethylthio)phenyl)car bamoyl)nicotinate, PPh (7.52 g, 28.7 mmol) and DEAD (diethyl azodicarboxylate) (14.3 mL, 28.7 mmol, 2.2 m) were successively added at room temperature. The mixture was heated to 60 C and stirred for 2 hours. After the completion of the reaction, a saturated aqueous sodium hydrogen carbonate solution was added, and ethyl acetate extraction was performed. The organic layer was dried over anhydrous magnesium sulfate and then concentrated in vacuo. The residue was purified by silica gel column chromatography to give the desired compound.
Intermediate Production Example 8 Production method of t-butyl 5-ethylsulfonyl(5-(trifluoromethylsulfonyl)benzo[d]oxazo lyl)nicotinate [Chem. 17] To a CHCl solution (100 mL) of t-butyl -ethylthio(5-(trifluoromethylthio)benzoxazolyl)nicot inate, m-CPBA (meta-chloroperbenzoic acid) (25.3 g, 95.6 mmol) was added under ice cooling, and the mixture was stirred at room temperature overnight. After the completion of the reaction, a saturated aqueous sodium hydrogen carbonate solution and a saturated aqueous sodium thiosulfate solution were added, and CHCl extraction was performed. The organic layer was dried over anhydrous magnesium sulfate and then concentrated in vacuo.
The residue was purified by silica gel column chromatography to give the desired compound (4.99 g, 9.59 mmol, 50%).
Intermediate Production Example 9 Production method of -ethylsulfonyl(5-(trifluoromethylsulfonyl)benzo[d]oxazo lyl)nicotinic acid [Chem. 18] Trifluoroacetic acid (50 mL) was added to t-butyl -ethylsulfonyl(5-(trifluoromethylsulfonyl)benzo[d]oxazo lyl)nicotinate (4.99 g, 9.59 mmol) at room temperature, and the mixture was stirred at room temperature overnight. After the completion of the reaction, the reaction mixture was concentrated in vacuo. Hexane was added to the residue, and the precipitated solid was collected by filtration. Thus, the desired compound was obtained (3.53 g, 7.61 mmol, 79%).
Intermediate Production Example 10 Production method of -ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylsulfonyl)benzo[d]oxazolyl)nicotinamide [Chem. 19] To a solution of -ethylsulfonyl(5-(trifluoromethylsulfonyl)benzo[d]oxazo lyl)nicotinic acid (4.34 g, 9.35 mmol), 2,2,2-trifluoroethoxyamine hydrochloride (1.83 g, 12.2 mmol), dimethylaminopyridine (3.4 g, 28.0 mmol) and EDCl ·HCl (2.33 g, 12.2 mmol) were successively added at room temperature, and the mixture was stirred at room temperature overnight. After the completion of the reaction, a 1 M aqueous HCl solution was added, and CHCl extraction was performed. The organic layer was dried over anhydrous magnesium sulfate and then concentrated in vacuo.
The residue was purified by silica gel column chromatography to give the desired compound (4.96 g, 8.84 mmol, 95%).
Intermediate Production Example 11 Production method of -ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylsulfonyl)benzo[d]oxazolyl)nicotinimidoyl bromide [Chem. 20] To a THF solution (65 mL) of -ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylsulfonyl)benzo[d]oxazolyl)nicotinamide (3.64 g, 6.48 mmol), PPh (3.40 g, 13.0 mmol) and CBr (4.30 g, 13.0 mmol) were successively added at room temperature, and the mixture was stirred at room temperature overnight. After the completion of the reaction, Celite filtration was performed, and the residue was washed with ethyl acetate. The filtrate was concentrated in vacuo, and the concentrated residue was purified by silica gel column chromatography to give the desired compound (3.77 g, 6.04 mmol, 93%).
Reference Example 1 Production method of 3-ethylthio(methoxymethoxy)-N-(2-hydroxy(trifluoromet hylthio)phenyl)pyridine-carboxylic acid amide [Chem. 21] To a THF solution (10 mL) of 3-ethylthiomethoxymethylpyridine-carboxylic acid ethyl ester (0.64 g), which compound was produced according to Production Method of Intermediate (2a) above, NaH (0.36 g) and a THF solution (2 mL) of 2-amino(trifluoromethylthio)phenol (0.4 g) were added at 0 C, and the mixture was stirred at 50 C for 2 hours. After the completion of the reaction, a saturated aqueous NH Cl solution was added, and ethyl acetate extraction was performed. The organic layer was washed with a saturated aqueous sodium chloride solution, dried over anhydrous magnesium sulfate, and then dried in vacuo. The residue was purified by silica gel chromatography to give 3-ethylthio(methoxymethoxy)-N-(2-hydroxy(trifluoromet hylthio)phenyl)pyridine-carboxylic acid amide (0.73 g, 60%).
Physical property: m.p. 135 to 136 C Reference Example 2 Production method of 2-(3-ethylthio(methoxymethoxy)pyridinyl)(trifluoro methylthio)benzo[d]oxazole [Chem. 22] To a THF solution (5 mL) of 3-ethylthio(methoxymethoxy)-N-(2-hydroxy(trifluoromet hylthio)phenyl)pyridine-carboxylic acid amide (0.73 g), PPh3 (1.04 g) and bis(2-methoxyethyl) azodicarboxylate (0.93 g) were added, and the mixture was stirred at 60 C for 1 hour.
After the completion of the reaction, H O was added, and ethyl acetate extraction was performed. The organic layer was washed with a saturated aqueous sodium chloride solution, dried over anhydrous magnesium sulfate, and then dried in vacuo. The residue was purified by silica gel chromatography to give 2-(3-ethylthio(methoxymethoxy)pyridinyl)(trifluoro methylthio)benzo[d]oxazole (0.70 g, quantitative).
Physical property: m.p. 145 to 146 C Reference Example 3 Production method of 2-(5-methoxymethoxyethylsulfonyl-pyridinyl)(triflu oromethylthio)benzo[d]oxazole [Chem. 23] To an ethyl acetate solution (15 mL) of 2-(3-ethylthio(methoxymethoxymethyl)pyridinyl)(tri fluoromethylthio)benzo[d]oxazole (0.68 g), m-chloroperoxybenzoic acid (0.74 g) was added at room temperature, and the mixture was stirred for 2 hours. After the completion of the reaction, a saturated aqueous sodium hydrogen carbonate solution and a saturated aqueous sodium thiosulfate solution were added, and ethyl acetate extraction was performed. The organic layer was washed with a saturated aqueous sodium chloride solution, dried over anhydrous magnesium sulfate, and then dried in vacuo. The residue was purified by silica gel chromatography to give 2-(5-methoxymethoxyethylsulfonyl-pyridinyl)(triflu oromethylthio)benzo[d]oxazole (0.40 g, 60%).
Physical property: m.p. 127 to 128 C Reference Example 4 Production method of 2-(3-ethylsulfonyl(hydroxymethyl)pyridinyl)(triflu oromethylthio)benzo[d]oxazole [Chem. 24] To a methanol solution (7 mL) of 2-(5-methoxymethoxyethylsulfonyl-pyridinyl)(triflu oromethylthio)benzo[d]oxazole (0.55 g), concentrated hydrochloric acid (2 mL) was added, and the mixture was stirred at room temperature overnight. After the completion of the reaction, the reaction mixture was dried in vacuo. A saturated aqueous sodium hydrogen carbonate solution was added to the residue, and ethyl acetate extraction was performed. The organic layer was washed with a saturated aqueous sodium chloride solution, dried over anhydrous magnesium sulfate, and then concentrated in vacuo. The residue was purified by silica gel chromatography to give 2-(3-ethylsulfonyl(hydroxymethyl)pyridinyl)(triflu oromethylthio)benzo[d]oxazole (0.34 g, 70%).
Physical property: m.p. 156 to 157 C id="p-199" id="p-199" id="p-199" id="p-199" id="p-199"
id="p-199"
[0199] Reference Example 5 Production method of (5-ethylsulfonyl)(trifluoromethylthio)benzo[d]oxazoly l)nicotinaldehyde [Chem. 25] To a CHCl solution (7 mL) of 2-(3-ethylsulfonyl(hydroxymethyl)pyridinyl)(triflu oromethylthio)benzo[d]oxazole (0.34 g), BAIB ([bis(acetoxy)iodo]benzene) (0.32 g) and TEMPO (2,2,6,6-tetramethylpiperidine 1-oxyl free radical) (0.028 g) were added, and the mixture was stirred at room temperature overnight. After the completion of the reaction, a saturated aqueous sodium thiosulfate solution was added, and ethyl acetate extraction was performed. The organic layer was washed with a saturated aqueous sodium chloride solution, dried over anhydrous magnesium sulfate, and then concentrated in vacuo.
The residue was purified by silica gel chromatography to give -ethylsulfonyl(trifluoromethylthio)benzo[d]oxazolyl) nicotinaldehyde (0.26 g, 75%).
Physical property: m.p. 150 to 151 C id="p-200" id="p-200" id="p-200" id="p-200" id="p-200"
id="p-200"
[0200] Reference Example 6 Production method of -ethylsulfonyl(5-trifluoromethylthio)benzo[d]oxazoly l)nicotinaldehyde oxime [Chem. 26] To a EtOH solution (12 mL) of -ethylsulfonyl(trifluoromethylthio)benzo[d]oxazolyl) nicotinaldehyde (0.51 g), 0.13 g of hydroxylamine hydrochloride and 0.15 g of AcONa were added, and the mixture was heated under reflux for 2 hours. After the completion of the reaction, the reaction mixture was concentrated in vacuo. The residue was purified by silica gel chromatography to give 0.47 g (87%) of -ethylsulfonyl(5-trifluoromethylthio)benzo[d]oxazoly l)nicotinaldehyde oxime.
Physical property: m.p. 213 to 214 C Production Example 1 Production method of chloro 5-ethylsulfonyl-N-hydroxy(5-trifluoromethylthio)benzo[d] oxazolyl)nicotin imidate [Chem. 27] To a MeOH solution (4 mL) of 5-ethylsulfonyl(5-trifluoromethylthio)benzo[d]oxazoly l)nicotinaldehyde oxime (0.05 g), 0.015 mL of t-BuOCl was added at 0 C, and the mixture was stirred for 1 hour. After the completion of the reaction, the reaction mixture was concentrated in vacuo to quantitatively give chloro 5-ethylsulfonyl-N-hydroxy(5-trifluoromethylthio)benzo[d] oxazolyl)nicotin imidate.
Physical property: H-NMR (CDCl ): 9.45 (d, 1H), 8.98 (d, 1H), 8.21 (d, 1H), 7.78 (d, 1H), 7.77 (d, 1H), 3.51 (q, 2H), 1.47 (t, 3H) id="p-202" id="p-202" id="p-202" id="p-202" id="p-202"
id="p-202"
[0202] Production Example 2 Production method of methyl -ethylsulfonyl-N-hydroxy(5-trifluoromethylthio)benzo[d] oxazolyl)nicotin imidate [Chem. 28] To chloro -ethylsulfonyl-N-hydroxy(5-trifluoromethylthio)benzo[d] oxazolyl)nicotin imidate, which was obtained in Production Example 1 above, MeOH (2 mL) and NaOMe (28% solution in MeOH) were added at 0 C, and the mixture was stirred for 1 hour. After the completion of the reaction, water was added, and ethyl acetate extraction was performed. The organic layer was washed with a saturated aqueous sodium chloride solution, dried over anhydrous magnesium sulfate, and then concentrated in vacuo.
The residue was purified by silica gel chromatography to give methyl -ethylsulfonyl-N-hydroxy(5-trifluoromethylthio)benzo[d] oxazolyl)nicotin imidate (0.029 g, 54%).
Physical property: H-NMR (CDCl ): 9.34 (d, 1H), 8.85 (d, 1H), 8.19 (d, 1H), 7.83 (s, 1H), 7.78 (dd, 1H), 7.74 (dd, 1H), 4.29 (s, 3H), 4.06 (q, 2H), 1.45 (t, 3H) Production Example 3 Production method of methyl -ethylsulfonyl-N-(2,2,2-trifluoroethoxy(5-trifluorometh ylthio)benzo[d]oxazolyl)nicotin imidate (compound number 3-76) [Chem. 29] To a DMF solution (1 mL) of methyl 5-ethylsulfonyl-N-hydroxy(5-trifluoromethylthio)benzo[d] oxazolyl)nicotin imidate (0.029 g), 0.04 g of Cs CO and 0.02 mg of 2,2,2-trifluoroethyl trifluoromethanesulfonate were added, and the mixture was stirred at room temperature for 1 hour. After the completion of the reaction, an aqueous ammonium chloride solution was added, and ethyl acetate extraction was performed. The organic layer was dried over anhydrous magnesium sulfate and then concentrated in vacuo. The residue was purified by silica gel column chromatography to give methyl -ethylsulfonyl-N-(2,2,2-trifluoroethoxy(5-trifluorometh ylthio)benzo[d]oxazolyl)nicotin imidate (0.022 g, 65%).
Physical property: m.p. 135 to 136 C Production Example 4 Production method of propyl 5-ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylsulfinyl)benzo[d]oxazolyl)nicotin imidate (compound number 3-282) [Chem. 30] To a toluene solution (1 mL) of -ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylsulfinyl)benzo[d]oxazolyl)nicotinimidoyl bromide (0.050 g, 0.082 mmol), n-propanol (1 mL) and RockPhos Pd G3 (0.005 g) were successively added at room temperature, and the mixture was stirred at 50 C for 10 minutes. After the completion of the reaction, the reaction mixture was concentrated in vacuo, and the residue was purified by silica gel column chromatography to give the desired compound (0.007 g, 0.012 mmol, 14%).
Production Example 5 Production method of methyl -ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylthio)benzo[d]oxazolyl)pyridinecarboimide thioate (compound number 3-288) [Chem. 31] To a MeOH solution (1 mL) of -ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylthio)benzo[d]oxazolyl)nicotinimidoyl bromide (0.050 g, 0.084 mmol), NaSMe (0.08 g, 0.13 mmol) was added at room temperature, and the mixture was stirred for 1 hour. After the completion of the reaction, a saturated aqueous ammonium chloride solution was added, and ethyl acetate extraction was performed. The organic layer was dried over anhydrous magnesium sulfate and then concentrated in vacuo. The residue was purified by silica gel column chromatography to give the desired compound (0.018 g, 0.032 mmol, 38%).
Production Example 6 Production method of N-(5-ethylsulfonyl(5-(trifluoromethylsulfinyl)benzo[d]ox azolyl)pyridinyl)((2,2,2-trifluoroethoxyimino)methyl acetamide (compound number 3-291) [Chem. 32] To a toluene solution (1 mL) of -ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylsulfinyl)benzo[d]oxazolyl)nicotinimidoyl bromide (0.050 g, 0.082 mmol), acetamide (0.08 g, 0.12 mmol), Xantphos (0.011 g, 0.020 mmol), Cs CO (0.080 g, 0.25 mmol) and Pd (dba) 2 3 2 3 (0.008 g, 0.008 mmol) were added at room temperature, and the mixture was heated under reflux for 2 hours. After the completion of the reaction, the reaction mixture was concentrated in vacuo, and the residue was purified by silica gel column chromatography to give the desired compound (0.024 g, 0.041 mmol, 50%).
Production Example 7 Production method of -ethylsulfonyl(5-(trifluoromethylsulfinyl)benzo[d]oxazo lyl)pyridinyl)(1H-1,2,4-triazolyl)methanone O-(2,2,2-trifluoroethyl)oxime (compound number 3-289) [Chem. 33] To a DMF solution (1 mL) of -ethylsulfonyl-N-(2,2,2-trifluoroethoxy)(5-(trifluorome thylsulfinyl)benzo[d]oxazolyl)nicotinimidoyl bromide (0.050 g, 0.082 mmol), 1,2,4-triazole (0.028 g, 0.40 mmol) and NaH (0.016 g, 0.040 mmol) were successively added under ice cooling, and the mixture was stirred at room temperature for 1 hour. After the completion of the reaction, a saturated aqueous ammonium chloride solution was added, and ethyl acetate extraction was performed. The organic layer was dried over anhydrous magnesium sulfate and then concentrated in vacuo.
The residue was purified by silica gel column chromatography to give the desired compound (0.036 g, 0.061 mmol, 74%).
Hereinafter, formulation examples are shown, but the present invention is not limited thereto. In the formulation examples, "part" means part by weight.
Formulation Example 1 Compound of the present invention 10 parts Xylene 70 parts N-methylpyrrolidone 10 parts Mixture of polyoxyethylene nonylphenyl ether 10 parts and calcium alkylbenzene sulfonate (weight ratio of 1:1) The above ingredients are uniformly mixed for dissolution to give an emulsifiable concentrate formulation.
Formulation Example 2 Compound of the present invention 3 parts Clay powder 82 parts Diatomite powder 15 parts The above ingredients are uniformly mixed and then pulverized to give a dust formulation.
Formulation Example 3 Compound of the present invention 5 parts Mixture of bentonite powder and clay powder 90 parts Calcium lignosulfonate 5 parts The above ingredients are uniformly mixed. After addition of an appropriate volume of water, the mixture is kneaded, granulated and dried to give a granular formulation.
Formulation Example 4 Compound of the present invention 20 parts Kaolin and synthetic high-dispersion silicic 75 parts acid Mixture of polyoxyethylene nonylphenyl ether 5 parts and calcium alkylbenzene sulfonate (weight ratio of 1:1) The above ingredients are uniformly mixed and then pulverized to give a wettable powder formulation.
Hereinafter, test examples in connection with the present invention are shown, but the present invention is not limited thereto.
Test Example 1 Test for control efficacy on Myzus persicae Chinese cabbage plants were planted in plastic pots (diameter: 8 cm, height: 8 cm), Green peach aphids (Myzus persicae) were propagated on the plants, and the number of surviving Green peach aphids in each pot was counted. The oxime group-containing condensed heterocyclic compounds represented by the general formula (1) of the present invention or salts thereof were separately dispersed in water and diluted to 500 ppm. The agrochemical dispersions were applied to the foliage of the potted Chinese cabbage plants. After the plants were air-dried, the pots were kept in a greenhouse. At 6 days after the foliar application, the number of surviving Green peach aphids on the Chinese cabbage plant in each pot was counted, the control rate was calculated according to the formula shown below, and the control efficacy was evaluated according to the criteria shown below.
[Math. 1] Control rate = 100 - {(T × Ca)/(Ta × C)} × 100 Ta: the number of survivors before the foliar application in a treatment plot T: the number of survivors after the foliar application in a treatment plot Ca: the number of survivors before the foliar application in a non-treatment plot C: the number of survivors after the foliar application in a non-treatment plot Criteria A: the control rate is 100%.
B: the control rate is 90 to 99%.
C: the control rate is 80 to 89%.
D: the control rate is 50 to 79%.
As a result, the compounds 1-6, 1-10, 1-66, 1-71, 2-6, 3-6, 3-76, 3-86, 3-126, 3-133, 3-146, 3-216, 3-275, 3-276, 3-281, 3-282, 3-283, 3-284, 3-285, 3-286, 3-287, 3-288, 3-289, 3-290, 3-291, 3-292, 3-293 and 3-294 of the present invention showed the activity level evaluated as A.
Test Example 2 Insecticidal test on Laodelphax striatellus The oxime group-containing condensed heterocyclic compounds represented by the general formula (1) of the present invention or salts thereof were separately dispersed in water and diluted to 500 ppm. Rice plant seedlings (variety: Nihonbare) were dipped in the agrochemical dispersions for 30 seconds. After air-dried, each seedling was put into a separate glass test tube and inoculated with ten 3rd-instar larvae of Laodelphax striatellus, and then the glass test tubes were capped with cotton plugs. At 8 days after the inoculation, the numbers of surviving larvae and dead larvae were counted, the corrected mortality rate was calculated according to the formula shown below, and the insecticidal efficacy was evaluated according to the criteria shown below.
[Math. 2] Corrected mortality rate (%) = 100 × (Survival rate in a non-treatment plot - Survival rate in a treatment plot)/Survival rate in a non-treatment plot Corrected mortality rate A: the corrected mortality rate is 100%.
B: the corrected mortality rate is 90 to 99%.
C: the corrected mortality rate is 80 to 89%.
D: the corrected mortality rate is 50 to 79%.
As a result, the compounds 1-6, 1-10, 1-66, 1-71, 2-6, 3-6, 3-76, 3-86, 3-126, 3-133, 3-146, 3-216, 3-275, 3-276, 3-281, 3-282, 3-283, 3-284, 3-285, 3-286, 3-287, 3-288, 3-289, 3-290, 3-291, 3-292, 3-293 and 3-294 of the present invention showed the activity level evaluated as A.
Test Example 3 Insecticidal test on Plutella xylostella Adults of Plutella xylostella were released onto Chinese cabbage seedlings and allowed to lay eggs thereon. At 2 days after the release of the adults, the Chinese cabbage seedlings with laid eggs were dipped for about 30 seconds in agrochemical dispersions diluted to 500 ppm, each of which contained a different kind of oxime group-containing condensed heterocyclic compound represented by the general formula (1) of the present invention as an active ingredient. After air-dried, the seedlings were kept in a thermostatic chamber at 25 C. At 6 days after the dip treatment, the number of hatched larvae per plot was counted, the mortality rate was calculated according to the formula shown below, and the insecticidal efficacy was evaluated according to the criteria of Test Example 2. This test was conducted in triplicate using 10 adults of Plutella xylostella per plot.
[Math. 3] Corrected mortality rate (%) = 100 × (Number of hatched larvae in a non-treatment plot - Number of hatched larvae in a treatment plot)/Number of hatched larvae in a non-treatment plot As a result, the compounds 1-6, 1-10, 1-66, 1-71, 2-6, 3-6, 3-76, 3-86, 3-126, 3-133, 3-146, 3-216, 3-275, 3-276, 3-281, 3-282, 3-283, 3-284, 3-285, 3-286, 3-287, 3-288, 3-289, 3-290, 3-291, 3-292, 3-293 and 3-294 of the present invention showed the activity level evaluated as A.
INDUSTRIAL APPLICABILITY The compound of the present invention is highly effective for the control of a wide range of agricultural and horticultural pests and thus is useful. 3 3 1
Claims (7)
1. An oxime group-containing condensed heterocyclic compound represented by the general formula (1): {wherein R represents (a1) a halogen atom; (a2) a (C1-C6) alkoxy group; (a3) a (C -C ) alkenyloxy group; (a4) a (C -C ) alkynyloxy group; (a5) a (C -C ) alkylthio group; (a6) a (C -C ) alkenylthio group; (a7) a (C -C ) alkynylthio group; (a8) an imidazole group; (a9) an imidazole group having, on the ring, 1 to 3 substituting groups which may be the same or different and are selected from (a) a halogen atom, (b) a cyano group, (c) a nitro group, (d) a formyl group, (e) a (C -C ) alkyl group, (f) a halo (C1-C6) alkyl group, (g) a (C1-C6) alkoxy group, (h) a halo (C1-C6) alkoxy group, (i) a (C3-C6) cycloalkyl (C -C ) alkoxy group, (j) a (C -C ) alkylthio 1 6 1 6 group, (k) a halo (C -C ) alkylthio group, (l) a (C -C ) 1 6 1 6 alkylsulfinyl group, (m) a halo (C -C ) alkylsulfinyl group, (n) a (C -C ) alkylsulfonyl group and (o) a halo (C - 1 6 1 C ) alkylsulfonyl group; (a10) a triazole group; (a11) a triazole group having, on the ring, 1 or 2 substituting groups which may be the same or different and are selected from (a) a halogen atom, (b) a cyano group, (c) a nitro group, (d) a formyl group, (e) a (C -C ) alkyl group, (f) a halo (C -C ) alkyl group, (g) a (C -C ) alkoxy 1 6 1 6 group, (h) a halo (C1-C6) alkoxy group, (i) a (C3-C6) 1 4 3 cycloalkyl (C -C ) alkoxy group, (j) a (C -C ) alkylthio 1 6 1 6 group, (k) a halo (C -C ) alkylthio group, (l) a (C -C ) 1 6 1 6 alkylsulfinyl group, (m) a halo (C -C ) alkylsulfinyl group, (n) a (C -C ) alkylsulfonyl group and (o) a halo (C - 1 6 1 C ) alkylsulfonyl group; (a12) a (C -C ) alkoxy (C -C ) alkyl group; 1 6 1 6 (a13) a (C -C ) alkyl-CO-NH- group; (a14) a (C -C ) alkoxy-CO-NH- group; (a15) a (C -C ) alkylcarbonyl ((C -C ) alkyl)amino group; or 1 6 1 6 (a16) a (C -C ) alkoxy (C -C ) alkoxy group, 1 6 1 6 R represents (b1) a hydrogen atom; (b2) a (C -C ) alkyl group; (b3) a (C -C ) alkenyl group; (b4) a (C -C ) alkynyl group; (b5) a (C -C ) cycloalkyl group; (b6) a (C -C ) cycloalkyl (C -C ) alkyl group; 3 6 1 6 (b7) a (C -C ) alkoxy (C -C ) alkyl group; 1 6 1 6 (b8) a halo (C -C ) alkyl group; (b9) a halo (C -C ) alkenyl group; (b10) a halo (C -C ) alkynyl group; or (b11) a (C -C ) alkylthio (C -C ) alkyl group, 1 6 1 6 R represents (c1) a halogen atom; (c2) a halo (C -C ) alkyl group; (c3) a halo (C -C ) alkoxy group; (c4) a halo (C -C ) alkylthio group; (c5) a halo (C -C ) alkylsulfinyl group; or (c6) a halo (C -C ) alkylsulfonyl group, A represents an oxygen atom or N-R (wherein R represents (e1) a (C -C ) alkyl group; (e2) a (C -C ) cycloalkyl group; (e3) a (C -C ) alkenyl group; or (e4) a (C -C ) alkynyl group), A represents a CH group or a nitrogen atom, 1 5 3 m represents 0, 1 or 2, and n represents 0, 1 or 2}, or a salt thereof.
2. The oxime group-containing condensed heterocyclic compound or the salt thereof according to claim 1, wherein A is an oxygen atom and A is a CH group.
3. The oxime compound or the salt thereof according to claim 1, wherein A is N-R (wherein R is as defined above).
4. An agricultural or horticultural insecticide comprising the oxime group-containing condensed heterocyclic compound or the salt thereof according to any one of claims 1 to 3 as an active ingredient.
5. A method for using an agricultural or horticultural insecticide, comprising treating plants or soil with an effective amount of the oxime group-containing condensed heterocyclic compound or the salt thereof according to any one of claims 1 to 3.
6. An animal ectoparasite control agent comprising the oxime group-containing condensed heterocyclic compound or the salt thereof according to any one of claims 1 to 3 as an active ingredient.
7. The oxime group-containing condensed heterocyclic compound of claim 1, substantially as herein described with reference to any one of the Examples thereof.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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JP2016253824 | 2016-12-27 | ||
JP2016-253824 | 2016-12-27 | ||
PCT/JP2017/046772 WO2018124129A1 (en) | 2016-12-27 | 2017-12-26 | Fused heterocyclic compound having oxime group or salts thereof, agricultural/horticultural insecticide containing said compounds, and method for using said insecticide |
Publications (2)
Publication Number | Publication Date |
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NZ755504A NZ755504A (en) | 2021-05-28 |
NZ755504B2 true NZ755504B2 (en) | 2021-08-31 |
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