NZ714551A - Low resistance electrode assemblies for production of metals - Google Patents

Abstract

electrode assembly for use in a reduction cell for the production of metal such as aluminum. The electrode comprises an electrically conductive carbon electrode block with an electrically conductive metal member connected thereto. At least one solid, conductive metal insert is at least partly received in the carbon electrode block with an interference fit, such that the insert exerts a lateral force on the carbon electrode block. The insert provides an improved electrically conductive connection between the carbon electrode block and the conductive metal member, with reduced resistance. The insert may provide a direct connection between the electrode block and the metal member, or the connection may be provided through a layer of cast iron or other metal element provided between the electrode block and the metal member. The electrode assembly may either comprise an anode or a cathode. eived in the carbon electrode block with an interference fit, such that the insert exerts a lateral force on the carbon electrode block. The insert provides an improved electrically conductive connection between the carbon electrode block and the conductive metal member, with reduced resistance. The insert may provide a direct connection between the electrode block and the metal member, or the connection may be provided through a layer of cast iron or other metal element provided between the electrode block and the metal member. The electrode assembly may either comprise an anode or a cathode.

Description

LOW RESISTANCE ELECTRODE ASSEMBLIES FOR PRODUCTION OF METALS CROSS-REFERENCE TO RELATED APPLICATIONS This application claims priority to and the benefit of Canadian Patent Application No. 2 838 113 filed er 16, 2013 and United States Provisional Patent Application No. 62/081,187 filed November 18, 2014, the contents of each are incorporated herein by reference.

CAL FIELD The present subject matter relates to electrode assemblies for use in the electrolytic reduction of refined materials, including, but not limited to, use in um reduction cells. The subject matter more specifically relates to the reduction of electrical resistance and improvement of the current distribution through the anode and cathode assemblies to reduce power consumption, to improve reduction cell performance and to improve operational life of the anodes and cathodes.

OUND The Hall—Heroult process is a well known process for aluminum synthesis by electrolytic reduction of alumina. The s uses either pre-baked or in-situ baked carbon anodes paired in a reduction cell with opposing carbon cathodes that are separated from the anodes by a molten electrolyte (‘bath’) that contains ved alumina, and a molten metal pad of conductive aluminum overlying the top of the cathode. During the s an ical current is passed between the anode and cathode to reduce the dissolved alumina into molten aluminum and to evolve carbon monoxide/or dioxide from the bottom of the anode.

The conductive molten aluminum sinks to the aluminum layer or ‘metal pad’ on top of the carbon cathode, thereby becoming part of the electrical circuit. Alumina is WO 2015089654 added to the bath from an overhead hopper, while the molten aluminum is withdrawn from the reduction cell by intermittent siphoning to a mobile crucible.

The pre-baked carbon anode is attached to, and supported by, the lower end of a vertical conductor rod, and the upper end of the conductor rod is clamped to an electric buss beam. The vertical conductor rod is made of aluminum or copper and is typically joined to the carbon anode through a lower, horizontal steel yoke and from one to eight (or more) round bar steel stubs ed to the yoke.

The carbon anodes are formed with prepared recesses (stub holes) in which the corresponding stubs are fitted. The stubs and anode are then joined by filling the space between them with cast iron or with carbon paste adhesive. When using cast iron for the bond the solidified iron annulus between the stub and carbon anode is referred to as a ‘thimble’. The carbon anodes are mostly consumed in the reduction process by combining with the evolved oxygen from the reduced alumina.

The anode assemblies have an operational duty life of typically 20-30 days in the reduction cell. A typical anode assembly of this type is disclosed in US Patent No. 3,398,081 to Bonfils et al.

Pre-baked e assemblies include a pre-baked carbon (carbonaceous or graphitic) cathode connected by cast iron or carbon paste to one or more steel current collector bars that are oned in slots in the underside of the e. The tor bars are longer than the cathode and protrude through the reduction cell sidewall for connection to an electric buss. The cathodes have an operational duty life of typically 5-10 years, during which period the carbon corrodes, preferentially in electrical paths of lowest resistance and highest current density. The cathode blocks undergo sodium absorption from the bath, aluminum infiltration and vertical heaving from thermal stresses due to uneven temperature profile throughout the carbon, which conditions gradually increase the ical ance of the cathode assembly. When the ance becomes too high or the WO 2015089654 drawn aluminum contains too much iron, that indicates dissolving collector bars, the reduction cell is removed from service to be relined with new material.

The electrical energy required to reduce alumina to aluminum and to heat the incoming alumina to the reduction temperature is a minor fraction of the total electrical energy typically ed between the anode buss to cathode buss connections. The e of energy consumed is from heat generated due to electrical resistance through the various components and connection aces of the ion cell circuit, which heat is removed to the environment. The factors influencing ical resistance at the interfaces include the ical resistance of the adjoining materials, the surface area and cleanliness of the interface, and the contact pressure between the adjoining materials. Although the cast iron connections used in the anode and e assemblies are electrically conductive, they still exhibit significant electrical resistance which generates ohmic g that does not ly contribute to the electrolytic reduction process. The high electrical resistance is at least partly due to the shrinkage which the iron undergoes during solidification. This problem can be exacerbated by differential thermal expansion of the various materials of the electrode assemblies when the cell is heated to operating temperature.

Past efforts to e the efficiency of electrolytic processes for metal production have either focused on improving the electrical current distribution through the anodes and cathodes, and/or reducing resistance between various components of the ode assemblies. For example, a number of patents and published patent applications disclose thimbles having extensions to increase surface contact area with the anode, improving current distribution and reducing resistance. Examples of such constructions are disclosed in US Patent Nos. 4,552,638, 817 and 4,824,543. Others have attempted to change vertical current bution through the thimble by adding undercuts or lateral extensions to the thimble (eg. US 4,621,674). Others have ted to modify the contact pressure between the carbon electrodes and other components of the electrode assemblies, for example by providing an ed graphite lining in the cathode WO 9654 2014/051178 collector bar slots (eg. US Patent No. 7,776,190 to Hiltmann et al.), or providing tapered, straight, or threaded connectors which are assembled with a low pressure fit with stress relief slots in the connection pin, or led with a loose fit, which pin expands and tightens only with increasing temperature (eg. US Patent Nos. 3,179,736, 3,390,071, 3,489,984 and 3,499,831). Others have used alternate als and methods to provide separate mechanical and electrically conductive connections between the stub and anode (e.g. International Publication No. WO 2009/099335).

Despite the past efforts to improve the efficiency of electrolytic processes, there remains a need for anode and cathode assemblies which will help to achieve further reductions in the amount of energy consumed per kilogram of produced metal, reduced carbon emissions and carbon losses, and longer electrode life.

SUMMARY OF THE DISCLOSURE In an embodiment, there is provided an electrode assembly for use in a reduction cell for the tion of metal, the electrode assembly comprising: (a) an electrically conductive carbon electrode block having a first surface and a second surface, wherein the first surface faces an interior of the reduction cell when the electrode assembly is in use; (b) an electrically conductive metal member having a first end and a second end, wherein the first end of the metal member is connected to the carbon ode block in an electrically conductive manner, and the second end of the metal member is adapted for connection to a buss bar in an ically conductive manner; (c) a solid, conductive metal insert at least partly received in the carbon electrode block, wherein the insert extends into the carbon electrode block from the second surface thereof; and n the metal insert is ed in the carbon electrode block with an interference fit, such that the insert exerts a lateral force on the carbon electrode block.

WO 2015089654 According to one aspect, the electrode is a pre-baked carbon anode, wherein the first surface of the carbon electrode block is a bottom surface thereof, and n the electrically conductive metal member comprises a vertical conductor rod. The electrically conductive metal member may further se a vertical stub at its first end, the carbon electrode block having a top surface opposite the bottom surface, a recess formed in the top e, with an end of the vertical stub being received in the recess. The second surface in which the insert extends may comprise an inner surface of the , the inner surface being selected from a bottom surface and a side surface of the recess. For example, the insert may extend into the bottom surface of the recess and extend vertically downwardly therefrom, and/or the insert may extend into the side surface of the recess and extend radially outwardly rom, with a portion of each said insert ally protruding from the bottom surface or the side surface of the recess, the protruding portion optionally including an enlarged head. The insert may be inclined downwardly and outwardly from said second surface. A plurality of said inserts may be provided in the bottom surface and/or the side surface of the recess, with each of said s being at least partly received in the carbon electrode block.

According to r aspect, the recess may be provided with a tive metal lining through which an electrically conductive connection is formed between the stub and the carbon electrode block, and wherein the insert or the plurality of inserts is in direct, electrically conductive contact with the conductive metal lining of the recess. At least a portion of the conductive metal lining may comprise a cast portion which is formed in situ between the stub and the carbon electrode block. For example, a portion of the conductive metal lining may comprise a solid preform which is combined with the cast portion during formation of the metal lining, and n the insert or the ity of inserts is in direct, electrically conductive contact with the preform prior to formation of the cast portion. The preform may comprise a bottom plate which is in contact with a bottom surface of the recess.

WO 9654 According to yet another aspect, the electrode assembly may further comprise a plurality of said al stubs at its first end, the stubs being spaced apart from one another, with the carbon electrode block having a plurality of said es formed in its top surface, with an end of each of the vertical stubs being received in a corresponding one of the recesses; and wherein each of the vertical stubs is secured to the vertical conductor rod through an ically conductive metal yoke. The electrode assembly may further comprise a plurality of electrically conductive bypass members, each of which bypasses the yoke and one of the vertical stubs, wherein each of the bypass members has a first end connected to the vertical conductor rod through an electrically conductive connection, and a second end connected to the carbon electrode block through an ically conductive connection. The carbon ode block is provided with a plurality of said inserts in the top surface thereof, and wherein the second end of each of the bypass members is connected to at least one of the inserts. The second end of each bypass member may be secured to the top e of the electrode by at least one of the inserts, and wherein the second end of each bypass member includes an expandable or flexible portion.

According to yet another aspect, the carbon electrode block has a top surface opposite the bottom surface, and is provided with a plurality of said inserts in the top surface thereof, wherein the electrode assembly further ses a collar-shaped tor having a side wall to receive the first end of the electrically conductive metal member and to provide an electrically conductive connection between the electrically conductive metal member and the carbon electrode block, and wherein the collar-shaped connector further comprises at least one attachment portion which is connected to the side wall and extends dly therefrom, each of the attachment portions being connected to at least one of the inserts to provide an electrically conductive connection n the attachment portion and the at least one of said inserts. The plurality of said inserts may be distributed across the top surface of the carbon electrode block, with the attachment portion(s) connected to each of the inserts. The electrically conductive metal member may further comprise a vertical stub at its first end, n each of the vertical stubs is WO 2015089654 secured to the vertical conductor rod through an ically conductive metal yoke; the electrode assembly further comprising a plurality of said collar-shaped connectors, and the sidewall of each collar-shaped connector receiving an end of one of the vertical stubs; and each of the ment portions is conductively connected to all of the vertical stubs through the collar-shaped connectors. ing to yet another aspect, carbon electrode block has a top surface opposite the bottom surface, and is provided with a plurality of said inserts in the top surface thereof, wherein the electrode assembly further comprises a yoke assembly through which an electrically conductive connection is ed between the ically conductive metal member and the carbon ode block; wherein the yoke assembly comprises a ity of curved metal struts, each having an upper end and an d lower end, the upper end being secured by an electrically conductive connection to the lower end of the electrically conductive metal member, the lower end being secured to the carbon electrode block with an electrically conductive connection by at least one of said inserts. The lower ends of the struts may extend outwardly away from one another and from the electrically conductive metal , and the yoke assembly may include a pair of said struts, oppositely disposed relative to one another.

] According to yet another aspect, the electrode is a pre-baked carbon cathode, wherein the first surface of the carbon electrode block is a top surface thereof and the carbon electrode block has a bottom surface opposite the top surface, and wherein the electrically conductive metal member comprises a current collector bar having an end received in a slot in the bottom surface, the current collector bar and the bottom surface being substantially parallel. A cast iron layer may be provided in the slot, between the current tor bar and the carbon ode block. The second surface in which the insert extends may comprise an inner surface of the slot, the inner surface of the slot being ed from a top surface and a side surface of the slot. The insert may have a flat head which is received between the cast iron layer and the carbon electrode block, and a WO 9654 conductive metal liner and/or a conductive metal washer may be received n the flat head of the insert and the carbon electrode block.

According to yet another aspect, the current tor bar is provided with one or more collector bar anchors, each said anchor having a first end attached to the collector bar and a second end embedded in the cast iron layer. For example, the first end of each said anchor comprises a threaded shank which is received in a threaded bore in the collector bar.

According to yet another aspect, the second surface in which the insert is received comprises the bottom surface of the carbon electrode block, the t collector bar having a flat bottom surface which is substantially co—planar with the bottom surface of the carbon ode block. An electrically conductive metal connector may be attached to the bottom surface of the carbon electrode block and to the flat bottom surface of the t collector bar, to provide an ically conductive connection between the current collector bar and the carbon electrode block. The electrically conductive metal connector may be attached to the top surface of the carbon ode block by said insert, and is in electrically conductive contact with said insert. The ically conductive metal connector is in the form of one or more layers of flat metal strap. The strap may have an able portion to permit deformation of the electrically conductive metal connector in response to differential thermal ion of the current collector bar and the carbon electrode block, along an axis defined by the current collector bar.

Alternatively, the electrically conductive metal connector may comprise a flexible cable connector, which may be provided with lug ends.

According to yet another aspect, the electrode assembly may comprise a plurality of said inserts provided in the bottom surface of the carbon electrode block, with each of said inserts being at least partly received in the carbon electrode block, and the electrode assembly may further comprise a plurality of said electrically conductive metal connectors, each providing an electrically conductive connection between the current collector bar and at least one of the inserts. The WO 9654 inserts may be spaced apart along a length of the carbon electrode block, and/or the inserts may be of different dimension to control the resistance of the top surface of the carbon block ve to the external portion of the collector bar.

According to yet another aspect, a thickness of the insert and the width of the bore are sized ve to one another such that an interface contact pressure between the insert and the adjoining carbon electrode block is at least about 1 kPa. For example, the interface contact pressure may be less than about MPa, and/or the interface contact pressure may be between about 1 MPa and about 10 MPa. A maximum interface contact pressure may be less than about one half of the breaking pressure required to break the surrounding carbon electrode block. ing to yet another aspect, the second end of the metal member, which is adapted for connection to the buss bar, includes a connecting surface which is adapted to mate with the buss bar, and wherein the connecting surface is electroplated or clad with corrosion ant conductive material.

According to yet another aspect, the insert is received in a bore either pre—drilled or formed in the carbon electrode block.

According to yet another aspect, the electrode is pre-baked and the insert is inserted into the carbon electrode block either before or after the ode is pre-baked.

According to yet another aspect, the current collector bar is supported within the slot of the carbon electrode block by at least one hanger ly comprising a tongue portion ly received in a slot portion. The slot portion may be secured to the carbon electrode block by one or more of said conductive metal inserts, and the tongue portion is secured to the current collector bar.

WO 2015089654 According to yet another , there is provided a ic mounted cooling fin for removable attachment to a steel potshell of a reduction cell for the production of metal. The magnetic mounted cooling fin comprises: (a) a bottom plate having a bottom e and a top e, wherein the bottom surface is adapted to be received against the potshell; (b) one or more fins extending from the top surface of the bottom plate; (c) one or more magnets having a curie point of at least about five hundred degrees s, said one or more magnets being secured to said bottom plate.

According to yet another , the magnets of the magnetic mounted cooling fin may comprise rare earth magnets and/or rrous magnets.

For example, the magnets may comprise Samarium—Cobalt or Aluminum—Nickel— Cobalt (Alnico) alloyed magnets.

According to yet another aspect, the magnetic mounted cooling fin may further comprise a thermal break attached to the bottom surface of the magnet, situated between the magnet and the potshell, wherein the l break comprises a thin layer of a non flammable material with low thermal conductivity.

According to yet another aspect, there is provided a magnetic mounted blanket for removable attachment to a steel potshell of a reduction cell for the production of metal. The magnetic mounted blanket ses: (a) one or more layers of a flexible, high temperature resistant material having a melting point of at least about 600 degrees Celsius; and (b) a plurality of magnets are attached to said material to hold the blanket to the potshell.

According to yet another aspect, the magnets of the magnetic mounted blanket have a curie point and holding power such that they lose adequate holding power at a predetermined temperature which corresponds to an unacceptably high temperature of said steel ll. The magnets may be sed of a ferrous, or nonferrous or rare earth alloy.

According to yet another aspect, the material of the magnetic mounted blanket may comprise flexible glass or ceramic fibre cloth.

BRIEF DESCRIPTION OF THE DRAWINGS In order that the claimed subject matter may be more fully understood, reference will be made to the accompanying drawings, in which: Figure 1 is a cross section through a prior art reduction cell; Figures 2 and 3 are perspective views showing the stubs of a prior art anode assembly before and after insertion into the stub holes of the anode block; Figures 4 and 5 are perspective views g the casting of the thimble in the prior art anode of Figures 2 and 3; Figure 5a is an enlarged, partial vertical sectional view through the stub, thimble and anode block of the prior art anode of Figure 5; Figures 6 and 7 are perspective views showing the electrode of Figure provided with electrically conductive bypass members; Figure 8 is a partial, perspective sectional view, showing a recess for ing a stub according to an embodiment described herein; ] Figure 8a is a close-up, cut-away view of an insert embedded in the wall of the stub hole shown in Figure 8; Figure 9 is a partial, ctive cross-sectional view, showing a recess for receiving a stub according to another embodiment described herein; Figure 9a shows a preform for formation of a thimble according to an embodiment described herein; Figure 10 is a cut-away side ion view showing an ode with thimble anchors; Figures 11 and 12 show an electrode assembly including an assembly for attaching the stubs to the top e of the anode block; Figure 13 is a perspective view of an electrode assembly having a low resistance yoke assembly as described herein; Figures 14a to 14e are side views of various types of conductive inserts and connections as bed herein; Figures 15 and 16 are perspective views showing the casting of a cast iron layer in a prior art cathode ly; Figure 17 is a perspective view showing a cathode block in which the connection to the collector bar is provided by a plurality of strap connectors; Figure 18 is a side view of the cathode block of Figure 17; Figure 19 is a partial transverse cross-section h a cathode block g an embodiment in which the connection to the collector bar is provided by an alternate form of strap tor; Figure 20 is a partial perspective view of a cathode block, partly in cross—section, showing another embodiment in which the connection to the current collector bar is provided by an alternate form of strap connectors; Figure 21 is a perspective view of a steel cathode collector bar with a conductive metal e cladding; Figure 22 is a partial view of the slot of a cathode assembly according to an embodiment disclosed herein; Figure 23 is a perspective view showing a portion of a conductive lining for a cathode slot; Figure 24 is a partial view of the slot of a cathode assembly ing to r embodiment disclosed herein; Figures 25 to 28 are views of e assemblies, showing alternate methods for connecting the current collector bar to the cathode block; Figure 29 is a partial cross-section through a cathode assembly according to r embodiment disclosed herein; ] Figure 30 is a up of area A of Figure 29; Figure 31 is a perspective view g an end of a cathode block according to another embodiment disclosed herein; Figure 32 is a longitudinal cross-section through a cathode assembly according to another embodiment disclosed herein; Figure 33 shows the cathode assembly of Figure 32, along with possible locations of slot anchors; Figure 34 is an isolated view of a magnetic mounted cooling fin according to an embodiment disclosed herein; and WO 2015089654 Figure 35 is an ed view of a magnetic mounted blanket according to an embodiment disclosed herein.

DETAILED DESCRIPTION OF EMBODIMENTS Certain embodiments are now described below with reference to the Hall-Heroult process for aluminum synthesis by electrolytic reduction of alumina.

However, it will be appreciated that the embodiments described herein may be modified for use in other electrolytic reduction or electrolysis processes for the production of metals or als that may also use metal electrodes joined to carbon anodes or cathodes, including but not limited to the electrolytic reduction of Lithium, Sodium and Magnesium.

Although pre—baked anode technology has developed over time to larger anodes with larger or more stubs, and to larger reduction cells with higher applied amperage, the subject matter disclosed herein may be d to all forms and configurations of pre-baked carbon anodes and pre-baked carbon cathodes.

Furthermore, the subject matter disclosed herein for the thimble anchors or preform may be applied either before or after the anode is baked, the carbon material of the anode being referred to herein as “green” prior to baking.

Figure 1 is a cross—sectional view showing the components of a ion cell 10 for um production. The reduction cell 10 includes a plurality of opposed electrode assemblies, including a ity of anode assemblies 12, of which two are shown in Figure 1, and a plurality of cathode assemblies 14, of which one is shown in Figure 1.

Each ode assembly 12, 14 comprises an electrically conductive carbon electrode block having a first surface and a second surface, n the first surface faces the interior 16 of the reduction cell 10 when in use. In this regard, each anode ly 12 includes a carbon anode electrode block 18 (also referred to herein as the “anode block 18”) and each cathode assembly includes a carbon WO 2015089654 cathode ode block 20 (also referred to herein as the de block 20”), which are described in more detail below. The first surface of each anode block 18 is the lower surface 22, and the first surface of each e block 20 is the upper surface 30. As shown in Figure 1, the surfaces 22, 3O face one another and face the interior 16 of the reduction cell 10.

The interior 16 of ion cell 10 contains a molten electrolyte bath 26 which contains dissolved alumina, and a molten metal pad 28 of conductive aluminum ing the top surface 30 of the cathode block 20. As alumina is d to aluminum, it sinks into the molten pad 28 and becomes part of the electrical circuit. Alumina is added to the bath 26 from an overhead hopper 32, while the molten aluminum is withdrawn from the metal pad 28 by intermittent siphoning to a mobile crucible (not shown). The interior 16 of reduction cell 10 is enclosed by sidewall refractories 34 and bottom refractory 36. The cell 10 further comprises an outer metal shell 11 (referred to herein as the “potshell”) which encloses the refractories 34, 36.

Each electrode assembly 12, 14 further comprises an electrically conductive metal member having a first end and a second end, wherein the first end of the metal member is ted to the carbon electrode block 18 or 20 in an electrically conductive manner, and the second end of the metal member is d for connection to a buss bar in an electrically conductive manner.

In this regard, the electrically conductive metal member 37 of each anode assembly 12 comprises a vertical conductor rod 38 which is typically made of aluminum or copper, the first (lower) end 40 of conductor rod 38 being connected to the top surface 42 of the anode block 18, and the second (upper) end 44 of which is connected to an anode buss bar 46, for example by clamping or the like.

It will be iated that the electrically conductive metal member 37 carries electric current from the anode buss bar 46 to the anode block 18, and also suspends the anode block 18 in the bath 26.

WO 2015089654 The electrically conductive metal member 37 of each anode assembly 12 further comprises one or more vertical stubs 48 at its first end 40. In the reduction cell shown in Figure 1 the anode assemblies 12 each have two stubs 48 which are spaced apart from one another along the top surface 42 of the anode block 18. However, it will be appreciated that the anode assembly may comprise a single stub 48, or more than two stubs 48. The stubs 48 are typically sed of steel and typically have a cylindrical shape, although the stubs 48 may have other cross-sectional shapes, such as square or rectangular.

The electrically conductive metal member 37 of each anode assembly 12 further comprises an electrically conductive metal yoke 50 through which the stubs 48 are connected to the lower end 40 of the vertical conductor rod 38. The yoke 50 comprises a horizontal member such as a thick conductive plate of steel or other conductive metal. atively, the yoke 50 may be integrally formed with the stubs 48.

The electrically tive metal member of each cathode assembly 14 comprises a current collector bar 52. A section of the collector bar 52 is located within the cell 10 and is ted to the e block 20. One or both ends of the tor bar 52 are located external of the cell 10 and connected to a cathode buss 24 located outside the cell 10. Therefore, as shown in Figure 1, the collector bar 52 extends through the sidewall refractory 34 on one or both sides of the cell . The e block 20 has a bottom surface 54 opposite the top surface 30.

The collector bar 52 may be split in two pieces (not shown) and ted in the middle of the cathode block 20, each piece having one end and a portion of the collector bar 52 connected to the cathode block 20 and the opposite end protruding h the refractory sidewall 34 of ion cell 10 and connected to the cathode buss 24 located outside the cell 10.

As shown most clearly in the isolated views of Figures 15 and 16, the bottom surface 54 of the cathode block 20 has an elongate slot 56, open at the bottom surface 54, in which the end of the current collector bar 52 is received. The WO 9654 slot 56 shown in Figures 15 and 16 is of constant shape and cross-sectional area along its . However, in other embodiments, the slot 56 may be interrupted or may vary in cross-sectional area along its length.

] The cathode block 20 and the current collector bar 52 may be ted by a layer of cast iron 57 or carbon paste provided between the interior surfaces of the slot 56 and the current collector bar 52. In the illustrated embodiment, the layer 57 of cast iron or carbon paste is provided over the top surface 55 and the two side surfaces 59 of collector bar 52 which are received within slot 56, with the bottom surface being free of layer 57. In another embodiment, the layer 57 of cast iron or carbon paste may also be provided over the bottom surface 53 of current collector bar 52, so as to join both sides of layer 57 across the bottom surface 53 of the collector bar 52.

During operation, the cathode blocks 20 undergo sodium absorption from the bath 26, aluminum infiltration from the metal pad 28, and thermal stresses between the top and bottom surfaces 30, 54 due to uneven temperature profile throughout the carbon, which conditions gradually cause an upward bowing of the cathode block 20 which increases the electrical resistance of the cathode ly 14. When the resistance becomes too high, or the cathode block 20 corrodes to the extent of ng aluminum contact with the collector bars 52, the reduction cell 10 is removed from service to be relined with new material.

Figures 2 to 5 illustrate a conventional anode assembly 12 having an anode block 18 of lly gular shape, a vertical tor rod 38 of rectangular cross-section and a horizontal yoke 50 integrally formed with a pair of vertical stubs 48, the yoke 50 being conductively ted to the lower end of the conductor rod 38 by welding, brazing or the like and typically on either side of a bimetallic transition joint 51. After the anode assembly 12 is clamped and suspended from the anode buss 46, the top surface 42 of the anode block 18 is covered with a layer consisting of a combination of frozen crystalline bath and powdered alumina, called a “bath cover” 25, (Fig. 1) to prevent air contact with the WO 9654 top surface 42 of the anode block 18 and to insulate the anode 12 from excess heat loss.

Figures 2 and 3 illustrate the insertion of the lower ends of vertical stubs 48 into recesses 58 formed in the top e 42 of the anode block 18, the es 58 sometimes being referred to herein as “stub holes”. As best seen in the enlarged views of Figures 8, 8a and 9, the recesses 58 have a generally cylindrical shape to match that of the stubs 48, the inner surface of each recess 58 comprising a flat, horizontal, circular bottom surface 60, and a generally cylindrical side surface 62, which may be tapered to have a smaller diameter at its bottom than at its top. The side surface 62 may be provided with helical grooves 66, as disclosed in above—mentioned US Patent No. 3,398,081 to Bonfils et al.

The stubs 48 and recesses 58 have diameters such that an annular gap is provided between the vertical side surface of each stub 48 and the cylindrical side surface 62 of each recess 58. Figures 4 and 5 illustrate the ion of a conductive metal lining 64, also referred to herein as a “thimble”, in the gap n the stub 48 and the inner surface of the recess 58, to provide an electrically conductive connection n each stub 48 and the anode block 18.

The metal lining 64 is at least partially cast in situ, i.e. with the stub 48 received in the recess 58, and with the bottom of the stub either in contact with or in close proximity to the bottom surface 60, where molten metal 27 such as cast iron is poured into the annular recess between the stub 48 and the inner surface of recess 58. The metal lining 64 is typically formed from cast iron, the brittle nature of which makes it easy to remove from the steel stubs 48 during anode 12 recycling procedures.

Upon rapidly freezing the thimble 64 in situ from molten iron, the iron undergoes solidification age. As shown in Figure 5a, the iron fies with freeze isotherms 29 primarily parallel to the vertical surface of the stub 48, which acts as a heat sink, and further undergoes three dimensional thermal shrinkage of the solid iron upon cooling of the thimble 64 from its freezing temperature down to WO 2015089654 its lower operating ature. The shrinkage of the iron causes a vertical gap 31 and a loose fit between the outer surface of the thimble 64 and inner e of recess 58.

Similarly, with reference to Figures 15 and 16, the cathode collector bar 52 is received in the slot 56 of the cathode block 20 with a space provided between the collector bar 52 and the walls of slot 56. This space is filled with a layer 57 of cast iron formed in situ against the collector bar 52 by pouring molten metal 27 into the space n the collector bar 52 and the walls of slot. For the same reasons described above with reference to the anode 12, a gap may form between the surfaces of the slot 56 and the outer surface of the cast iron layer 57 due to shrinkage of the metal of layer 57. During initial heatup of the reduction cell , the steel stub 48, collector bar 52, cast iron tions 57, 64 and carbon electrode blocks 18, 20 expand at ent rates, and a high carbon cast iron may expand slightly by undergoing phase transition, all providing a tighter fit of the ly than when cold, however still with erable electrical resistance through each of the electrode assemblies 12 and 14.

The electrical current distribution through the anodes and cathodes follow the paths of least resistance, passing from the power connection points at the anode buss 46 to the external ends of the collector bars 52. This electrical current behavior results in uneven electrical resistance and t density across the first surfaces of the blocks 22, 30 to the bars 38 and 52 respectively, which in turn may cause uneven anode consumption and uneven cathode wear and corrosion. The uneven electrical resistance across the top surface 30 of the cathode block 20 may also contribute to horizontal electrical flow through the um metal pad 28 due to the aluminum’s very low electrical ance, which horizontal electrical flow generates electromagnetic flow currents and turbulence (waves) in the metal pad 28. This turbulence may force a larger than normal anode to cathode distance (ACD) to be maintained to avoid short circuits between the bottom surface of anode block 18 and the top surface 30 of cathode block 20, which WO 9654 additional ACD incurs extra electrical resistance through the bath 26, consuming more electrical energy than otherwise required for the reduction process.

The present subject matter addresses the above problems by providing solid conductive metal s 76 received in the carbon electrode blocks 18 and/or 20 of the electrode assemblies 12, 14, with an interference fit, and with or without accompanying bores 68 (also referred to herein as “boreholes”) in the carbon electrode blocks 18 and/or 20. One end of each insert 76 is embedded into the carbon of the electrode block 18 or 20, with a llable lateral interface contact pressure between the insert 76 and the carbon, which pressure provides a low resistance ical path into the carbon, thereby reducing power consumption.

The application of the interference fit inserts 76 varies between the anode 12 and cathode 14, but follows the same l ple.

As defined herein, an interference fit is one which produces a high al’ interface pressure between the insert 76 and the carbon material of the electrode block 18 or 20, Le. the pressure being directed radially outwardly against the carbon material. The high lateral interface pressure reduces the electrical resistance across the ‘lateral’ interface between the insert 76 and the carbon material. atively, or in addition to the high lateral interface pressure, the erence fit may provide an axial (i.e. along an axis defined by insert 76) compression or interference fit with high contact re between the outer surface of the insert 76 and the carbon material. To produce an erence fit the inserts 76 must be inserted into the solid carbon material, as opposed to being formed by solidifying a molten metal poured or injected into a recess or cavity, which would be subject to shrinkage upon solidification and which, in any event, would not achieve significant ace pressure to provide an interference fit.

The controlled, high t pressure between the insert 76 and the carbon electrode block 18 or 20 may cause minor carbon material failure local to the interface (by crushing or scaling), which limited carbon failure is acceptable provided that such carbon failure does not extend to cracks through the carbon WO 9654 2014/051178 electrode block 18 or 20 which may introduce high electrical resistance areas across the crack, or which cracks may propagate during operation causing the anode or cathode ode block 18 or 20 to physically break apart. Use of inserts 76 providing an interference fit therefore requires consideration of the mechanical stresses induced by thermal ion of the insert within the carbon anode or cathode electrode block 18 or 20 when placed in operation, and the strength of the anode or cathode electrode block 18 or 20 relative to the location of the insert 76 determined by the lateral thickness of carbon surrounding the insert 76. The interface pressure may change during the operational life of the anode 12 or cathode 14 due to al creep, ing on the temperature and thermal behaviour of the adjoining materials. The breaking strength of the anode 12 or cathode 14 may also change due to its temperature and condition over its operational life. The interface pressure and resulting electrical resistance of the connection can be lled by adjusting the external dimensions of the insert 76 and/or the dimensions of bores 68 (e.g. drilled pilot holes, etc.) in the carbon material, in order to control the amount of interference fit, contact area and resulting contact pressure.

] The interference fit between the insert 76 and the carbon al of the electrode block 18 or 20 is such that an interface contact pressure n the insert 76 and the carbon material of the adjoining electrode block 18 or 20 is at least about 0.1 kPa. For example, the interface contact pressure is typically up to about 10 MPa, and/or between about 1 MPa and about 10 MPa. Interface contact pressures in excess of 10 MPa, although possible, do not significantly r reduce the electrical resistance across the interface and increase the risk of cracking of the carbon substrate.

To avoid cracking the carbon electrode block 18 or 20, the pressure applied by the interference fit may be less than about one half of the stress required to break the carbon electrode block 18 or 20. The breaking pressure depends on the strength of the carbon material of the carbon electrode block 18 or and the minimum width and thickness of carbon material surrounding the insert WO 9654 76. It will be appreciated that the breaking pressure may vary in different regions of the electrode block 18 or 20, being higher in the middle of the block than near its edges.

The total applied pressure caused between the insert and the surrounding carbon material of the ode block 18 or 20 depends on the contact area between them. Limiting the surface area of the insert 76 within the carbon material, with or t a bore 68, can enable a high interface pressure with a limited total applied pressure. Selecting a maximum applied re of less than approximately one half of the minimum yield strength of the surrounding carbon should provide an adequate margin of error, such that the anode or cathode electrode block 18 or 20 does not break from extra pressure that may result during anode and cathode operation, possibly due to greater thermal expansion of the inserts 76 versus the carbon of the carbon electrode block 18 or 20, and the ial weakening of the carbon electrode block 18 or 20 from bath tion and air burn during its operational cycle. In the ative, the interface pressure for each insert 76, with or without a bore 68, may be theoretically determined using Lames equation for interference fit. The selection of dimensions, locations and quantity of inserts 76 are to take into consideration an acceptable current density through the inserts 76 and desired current distribution through the anode or e electrode block 18 or 20. The maximum interface re may also be tested experimentally for each insert 76 location prior to implementation in the reduction cell 10.

The inserts 76 will typically be inserted into the electrode block 18 or after it has been formed and baked to a hardened state, producing an interference fit as described above. However, it will be appreciated that the inserts 76 may be inserted into the electrode block 18 or 20 after it has been formed, and while it is in a green state, i.e. prior to baking. Where an insert 76 is installed into the carbon of the electrode block 18 or 20 prior to , the carbon is relatively soft and the interface contact pressure between the insert 76 and the surrounding carbon will initially be low. The ode block 18 or 20 will then be hardened by WO 2015089654 baking, with the insert 76 installed therein, and a good electrical bond between the insert 76 and the surrounding carbon of the electrode block 18 or 20 will result.

The current density and resistance through the inserts 76 and between the inserts 76 and the surrounding carbon material of electrode block 18 or 20 will generate ohmic heating that will heat the inserts 76, which temperature should be maintained below the point at which the yield strength of the heated insert 76 falls below two times the desired interface contact pressure between the insert 76 and the surrounding carbon material, taking into account any additional load that any insert 76 may carry, for example due to the mass of the suspended carbon block 18 in the case of anode 12.

When the inserts 76 are used within the anode assembly 12, specifically n the anode block 18 and the cast iron e 64, the insert 76 is mes referred to herein as a ‘thimble anchor’. The thimble anchor 76 enhances the mechanical and electrical connections between the thimble 64 and the anode block 18. A portion of the thimble anchor 76 is embedded in the anode block 18 with an interference fit, as d above, between the thimble anchor 76 and the nding carbon al of the anode block 18. The total interface contact area between the insert and the anode block 18 depends on the diameter, embedded length and quantity of the inserts 76 used. When using large diameter inserts 76, then a predrilled borehole 68 may be provided for the insert 76 to be embedded into, in order to limit the maximum lateral interface t pressure to avoid fracture of the carbon of the anode block 18. The inserts 76 may be impact driven if nail style, or screwed into the carbon if screw or bolt style, either with or t a borehole 68 to provide the desired interface contact pressure. The inserts 76 may also be in the form of expansion anchors that are loose fit inserted into predrilled boreholes 68 and then tightened to impose the d lateral interface t pressure between the insert 76 and the inner surface 74 of the borehole 68 WO 9654 When used as thimble s, the inserts 76 perform two functions, firstly that of providing an electrical conductor between the cast iron thimble 64, which is cast in-situ from molten iron around the non-embedded end of the thimble anchor 76, and the anode block 18. Secondly, because one end of the thimble anchor 76 protrudes from a surface of the anode block 18 into the stub hole 58, the thimble anchor 76 modifies the freeze profile of the cast iron thimble 64 by providing a heat sink on the inner wall of stub hole 58 which promotes the solidification or freezing of the iron across the full width of the space between the stub 48 outer surface and the inner wall of stub hole 58 at the locations of the inserts 76, while there is molten metal above the insert 76 to fill in for the solidification shrinkage. This modified freeze e will reduce or eliminate the usual shrinkage gap between the thimble 64 and the inner wall of stub hole 58 at those locations, thereby enabling a tighter contact and lower electrical resistance n the stub 48, e 64 and wall of stub hole 58 when the assembly 12 heats up in the reduction cell 10.

In the embodiments shown in Figures 8, 8a, 9 and 10, the inserts 76 are similar in appearance to nails, having a pointed end, a smooth shank and a single, enlarged head. It will be appreciated that the inserts 76 do not necessarily have this configuration, and that heads and pointed ends are not necessarily required. However, to enhance the function of the protruding n of thimble anchor 76 as a heat sink, it is cial to provide the thimble anchor 76 with an enlarged head, as further discussed below. The thimble anchors 76 may, for example, have a single head or a duplex head.

Figure 8 is a ned view through a portion of anode block 18, showing the interior of one of the stub holes 58, and with the lower end of a stub 48 shown above the block 18. As shown, the anode electrode block 18 is provided with a plurality of impact driven, nail style thimble anchors 76 which, in this embodiment, are of cylindrical shape, and extend partially into the anode block 18 from a second surface thereof. In this embodiment, the second surface is the inner surface of the stub hole 58, sing the flat bottom surface 60, the side surface WO 9654 62, and/or in the helical grooves 66. Although only a single thimble anchor 76 may be required, improved results may be obtained by providing a plurality of e anchors 76. As shown in Figure 8a, a first end 78 of each thimble anchor 76 protrudes from the inner surface of the stub hole 58, and a second end 80 of each thimble anchor 76 is embedded in the inner surface of stub hole 58 with an interference fit. The protruding first end 78 of the thimble anchor 76 may have an enlarged head to enhance its on as a heat sink during the pouring and solidification of the molten metal in the gap between the stub hole 58 and stub 48, to form the thimble 64. It will be appreciated that the additional e area provided by the enlarged head at the first end 78 of thimble anchor 76 will provide an enhanced ical bond with the thimble 64, as well as an enhanced electrical connection with the e 64. Thus, with the provision of thimble anchors 76 as disclosed herein, better mechanical and electrical connections are formed between the stubs 48, the thimble 64, and the inner surface of stub hole Depending on the diameter and type of thimble anchor 76, it may be necessary to provide the inner surface of the stub hole 58 of Figure 8 with boreholes 68 corresponding in number to the e anchors 76, in order to achieve an interference fit with the desired amount of lateral ace contact pressure discussed above. This possibility is also illustrated in the close—up of Figure 8a, which shows one of the impact driven, nail style thimble anchors 76 of Figure 8 partially embedded in a pre-formed borehole 68 in the side surface 62 of the stub hole 58. The borehole 68 is pre-drilled in the substrate and has a first open end 70 at the second surface (i.e. the inner e) of the anode block 18, and a second closed end 72 inside the anode block 18. The borehole 68 also has an inner wall 74, a width (in the case of the rical bore 68, the same as diameter), and a length extending from the first end 70 to the second end 72 of bore 68 Except where the thimble anchor 76 is an expansion type anchor, the diameter of the borehole 68 is sized less than the diameter of the thimble anchor 76 in order to provide the desired lateral ace contact pressure between the thimble anchor 76 and the inner wall 74 of the borehole 68. As shown in Figure 8a, WO 2015089654 the first end 78 of thimble anchor 76 is proximate to the first end 70 of borehole 68 and spaced therefrom, while the second end 80 of thimble anchor 76 received inside borehole 68 ate to the second end 72 thereof. It can be seen from Figure 8a that the initial diameter of borehole 68, as shown at the second end 72 of borehole 68, is smaller than the diameter of the thimble anchor 76, the relative ers of borehole 68 and thimble anchor 76 being selected to provide an interference fit having the desired amount of l interface contact pressure.

As shown, the thimble anchors 76 embedded lly in the bottom e 60 of stub hole 58 may extend vertically downwardly from the bottom surface 60, although the thimble anchors 76 in bottom surface 60 may instead be sloped ve to the vertical. The partially embedded thimble anchors 76 in the side e 62 may extend horizontally and radially outwardly from the side e 62. Alternatively, the thimble anchors 76 in the side surface 62 may be sloped relative to the horizontal, extending downwardly and outwardly from the side surface 62, and one such sloped anchor 76 is shown in Figure 10.

In this embodiment, where the inserts 76 comprise thimble anchors, they will be formed of a material such as cast iron or carbon steel which can be recycled with the metal comprising the thimble 64.

The thimble anchors 76 provide the electrical connection between the thimble 64 and the anode block 18, while the cast iron thimble 64 will bond the anode block 18 to the stub 48. The thimble anchors 76 and stub 48 together create a good electrical connection through those components of the electrode assembly 12 even when it is cold. Further, the provision of at least one thimble anchor 76 in the bottom e 60 of stub hole 58 with a cast iron bond will enable current distribution through the bottom surface 60 of the stub hole 58 through the stub 48.

This typically does not occur when the stubs 48 sit ly on the bottom surface 60 of the stub hole 58 during iron pouring, which prevents a cast iron connection forming between the bottom of the stub 48 and the bottom surface 60 of stub hole WO 2015089654 Care must be taken if the thickness of the cast iron under the stub 48 is too great, thereby preventing the thimble stripping press from breaking and stripping the thimble 64 from the stub 48. To t this from happening, the bottom surface of the thimble 64 can be provided with a weaker breaking area. For e, as shown in Figure 9, the bottom surface 60 of stub hole 58 may be provided with one or more raised ridges 86 of carbon, extending wholly or partially across the diameter of bottom surface 60. The height of ridges 86 is below the tops of the inserts 76 provided in the bottom surface 60, such that the ridges 86 will allow the cast iron 27 to flow over the ridges during casting to fill the space between the bottom surface 60 and the bottom of the stub 48 while ng the necessary weakness in that layer to enable the thimble stripping press to break and strip the cast iron metal lining 64 from the stub 48. The ridges 86 may be formed by altering the shape of the anode forming press mold by removing material from the bottom of the stub hole form in the shape and ation suited to the needs of the thimble stripping press.

In another aspect, also shown in Figure 9a, only a portion of thimble 64 comprises a cast structure, and the remainder comprises a preform 82. The preform 82 is in the form of a circular disc, of the same material as the thimble 64, which is sized to fit inside the bottom of stub hole 58, against the bottom surface 60 thereof. The preform 82 becomes incorporated in the structure of the e 64 when the molten iron is cast, and helps to maintain a desired spacing between the bottom of stub 48 and the bottom surface 60 of stub hole 58. As shown in Figure 9a, the preform 82 may have apertures h which inserts 76 can be driven or threaded into the bottom surface 60 of stub hole 58. The preform 82 may be formed with grooves 84 on its lower or upper surface to allow the preform to be easily fractured when it is desired to remove the stub 48 and the thimble 64 from the stub hole 58 during anode ing.

The preform 82 described above will lly be fastened to the bottom surface 60 of stub hole 58 after baking of the anode block 18. However, WO 2015089654 according to an alternate embodiment, the preform 82 may be ed into the stub hole 58 while the anode block 18 is in a relatively soft, green state, in which case the m 82 may be partially embedded in the bottom surface 60 of stub hole 58. In such an embodiment, the preform 82 may be formed into the anode block 18 during the anode forming process, i.e. at the time that the stub hole 58 is formed. Alternatively, the preform 82 may be ed into the stub hole 58 after it is . Where the preform 82 is inserted into the green anode block 18, the inserts 76 may optionally be integrally formed with the preform 82.

Although Figures 8 to 10 illustrate the use of impact driven, nail style thimble anchors 76, other types of inserts 76 may be used in this embodiment, or in other embodiments described herein. For example, the inserts may be similar in appearance and/or function to conventional fasteners, such as friction fit or press fit nails, rods or spikes, screws or lag bolts, expansion anchors (including but not limited to lag shields, sleeve or wedge type expansion anchors, etc.), or other mechanically installed fasteners that produce a controlled lateral and/or axial pressure. For example, Figures 14a to 14c show three forms of inserts, labelled 76a, 76b and 76c. Insert 76a is in the form of a nail having a d tip, smooth shank and circular, enlarged head, similar to that shown in Figures 8 to 10. Insert 76b is in the form of a lag screw or lag bolt, having a hexagonal head, a pointed tip and a threaded shank. s 14a and 14b each shows insert 76a or 76b optionally being inserted into a pre-drilled bore 68 which is r in diameter than the shank of the insert 76a or 76b, the bore 68 being deformed radially outwardly by the insertion of insert 76a or 76b. However, it will be tood that the bores 68 are not always necessary, depending at least partly on the diameter of the insert 76a or 76b.

Insert 76c shown in Figure 14c is in the form of an expansion anchor having an inner ed screw portion and an outer split sleeve n. The insert 76c is initially inserted into a pre-drilled bore 68 with a relatively loose fit and, when the screw portion is threaded into the sleeve portion and tightened, the WO 2015089654 sleeve portion is forced outwardly against the inner wall 74 of bore 68 as the insert 76c, causing radially outward deformation of the bore 68.

Although the inserts 76 described and shown herein generally have cylindrical , it will be appreciated that this is not necessary. Rather, the inserts may be of any convenient cross-section, including square-shaped, rectangular-shaped, star-shaped, fluted, etc.

In another embodiment now described with reference to Figures 6 and 7, the conductive metal inserts 76 are used to augment the existing cast iron connected assemblies, by adding one or more additional electrical paths n the al tor rod 38 and the anode block 18 using one or more electrically conductive bypass members, resulting in lower overall electrical resistance of the anode assembly 12.

The embodiment shown in Figures 6 and 7 includes a plurality of “external” electrically conductive bypass members 88, meaning that they form an electrically tive tion from the vertical conductor rod 38 to the carbon material of the anode block 18, without forming a connection through the metal lining 64 of recess 58. Each of the bypass members 88 has a first end 90 connected to the vertical conductor rod 38 through an electrically conductive connection, and a second end 92 ted to the anode block 18 through an electrically conductive connection.

The anode block 18 is provided with a plurality of conductive metal inserts 76 in its top surface 42, forming an interference fit as defined above with the carbon al of the anode block 18. As discussed above, the inserts 76 are provided with or without bores 68, depending on the diameters of the inserts 76 and the strength of the substrate material.

] The inserts 76 are at least partly received in the top surface 42. It can be seen from the drawings that the s 76 are located in top surface 42 such WO 2015089654 2014/051178 that the second ends 92 of the bypass members 88 are connected to the anode block 18 by at least one of the inserts 76. In the illustrated embodiment, each of the second ends is connected to the anode block 18 by two of the inserts 76. High pressure contact between the second ends 92 and the inserts 76 may be ed by using inserts 76 provided with compression s 77 to maintain interface pressure, or using other conductive connections, including but not limited to brazing, welding or use of a nut 79 welded to the second end 92, or a locking thread 81 in the second end 92, ensuring an electrical connection with the insert 76. These latter two options are illustrated in Figuresl4d and 14e, respectively.

It will be appreciated that the attachment of the bypass members 88 to inserts 76 also results in the second ends 92 of the bypass members 88 being secured to the top surface 42 of the anode block 18 with an electrically conductive connection.

The first ends 90 of the bypass members 88 are ed to the vertical conductor rod 38 by means of fusion welding, soldering, brazing, interference fit er, screw, bolt, rivet, clamp or other mechanical or fusion connection which forms an electrical conduction path from the vertical conductor rod component 38 to the bypass member 88. In the embodiment of Figures 6 and 7, the first ends 90 of bypass members 88 are connected to the conductor rod 38 by mechanical ing means 83a and 83b, including nuts and bolts, each pass through or adjacent to the conductor rod 38.

Although Figures 6 and 7 show bypass members having a ic configuration, it will be iated that the bypass members may instead comprise flexible conductors such as wire cables with lug ends for the attachment of the inserts 76.

According to another embodiment, the inserts 76 are used in combination with conductive connectors similar to the bypass members 88 WO 2015089654 described above, to replace and eliminate the conventional iron connection without, r, ng the main basis of the shapes of the electrodes, to allow a user to transition from ional assemblies to the low resistance assemblies disclosed herein. Small changes to the shape of the carbon electrode block 18, 20 may be included in this embodiment to enable the use of the inserts 76, with or without bores 68.

Figures 11 and 12 illustrate an anode assembly 12 according to this embodiment, including a al conductor rod 38, yoke 50 and stubs 48 similar to those rated in the embodiments described above. However, in the present embodiment, the lower end of each stub 48 is secured to the top surface 42 of the anode block 18 in an electrically tive manner by a collar-shaped tor 94. Each connector 94 has a vertical sidewall 96 which receives the lower end of a stub 48. Because the stub 48 is cylindrical, the sidewall 96 in the illustrated ment of connector 94 is also cylindrical, and has an inside diameter slightly greater than the outside diameter of the stub 48, so as to closely receive the lower end of stub 48 in its hollow interior. The sidewall 96 is electrically connected to the stub 48 by welding, brazing or electrically conductive mechanical fasteners. It will be appreciated that the ll 96 may have any desired shape which provides an ically conductive connection with the end of stub 48. Although the sidewall 96 is shown as being continuous, this is not necessarily the case. It will be appreciated that the sidewall 96 may instead be discontinuous, or comprise a plurality of te pieces each attached mechanically and electrically to the stub The connector 94 also has at least one attachment portion 98 which is connected to the sidewall 96 in an electrically conductive manner, and may be ally formed therewith. Each attachment portion 98 extends outwardly from the sidewall 96 of connector 94 and is secured and conductively connected to the top surface 42 of the anode block 18 by one or more conductive inserts 76, with or without a bore 68. High pressure contact between the connector 98 and the insert 76 may be provided by the same means described above with reference to Figures WO 2015089654 6 and 7 and 14a to 14e, for example by using inserts 76 provided with compression washers 77, to maintain interface pressure, or using other tive connections, including but not limited to brazing, welding or use of a backing plate, ng an electrical tion.

In the embodiment of Figures 11 and 12, the collar-shaped tor 94 includes a plurality of attachment portions 98, in the form of radially projecting tabs, each of which is secured to the top surface 42 by at least one insert 76. Each one of the attachment portions 98 es means for permitting differential thermal expansion thereof in on to the anode block 18. In the illustrated embodiment, the means for permitting expansion comprise folds or bends 100 in the attachment portion 98, so as to permit the attachment portion 98 to expand, contract or flex in response to differential thermal expansion or contraction while supporting the load of the anode. Although bends 100 are shown as the means for permitting thermal expansion, other means may be used instead. For example, the attachment portions 98 may have expansion slits cut or formed into the attachment portion 98, providing a serpentine ical path that enables different thermal expansion of the ment portions 98 between inserts 76 relative to the thermal ion of the top surface 42 of the anode block 18 between inserts 76.

As discussed above, the inserts 76 are used to connect components such as the collar-shaped connector 94 to the top surface 42 of the anode block 18, and also to conduct electricity into the block 18 through the inserts 76 themselves.

The use of inserts 76 allows for modification of electrical resistance and t distribution through the anode assembly 12 by adjusting the material of inserts 76, as well as the length, diameter, contact e area, ty, location and interference fit or contact pressure between the insert 76 and the anode block 18.

These adjustments may enable a more consistent electrical resistance from the vertical conductor rod 38 to any point on the bottom surface 22 of the block 18, which promotes consistent current density, lower overall electrical resistance, more consistent anode consumption ing in a flatter bottom surface 22 of the block 18 during its operational life. The r anode bottom surface 22 may enable a WO 2015089654 higher portion of the block 18 to be consumed before it is necessary to remove the anode 12 from operation, thus reducing recycle s and reducing the ongoing replacement costs of anode replacement.

The use of inserts 76, with or without bores 68, may also be applied in a cathode assembly 14, between the cathode block 20 and the current collector bar 52. The collector bar 52 is typically bonded to the cathode block 20 by a layer of cast iron 57 between the collector bar 52 and the corresponding recess 56 (also referred to in this embodiment as “slot 56”), in the bottom surface 54 of carbon cathode collector block 20. The t collector bar 52 is bonded to the carbon cathode collector block 20 with molten cast iron 27 while it is upside down (See Fig. ) prior to assembly into the reduction cell 10. Bonding may instead be done using a carbon adhesive paste. The following embodiments apply to both cast iron and carbon adhesive collector bar connections.

As will be iated, there may be le current collector bars 52 connected to each cathode block 20. Each block 20 is led across the width of the reduction cell 10 and multiple blocks 20 are installed beside each other to line the bottom floor of the reduction cell 10. As shown in Figures 15 and 16, the current collector bar 52 has a flat bottom surface 53 which is substantially co- planar with the bottom surface 54 of the cathode block 20, a top surface 55 which is opposed to the bottom surface 53, a pair of side surfaces 59 extending between the top and bottom surfaces 55, 53, and a pair of end es 61. 6] In accordance with an embodiments shown in Figures 17 to 19, there may be provided one or more electrically conductive metal connectors 112 in the form of a flat, elongated strap which is attached to the bottom surface 54 of carbon e collector block 20 by inserts 76, with or without bores 68. The inserts 76 are received in the bottom surface 54, nt to slot 56. Each strap connector 112 extends substantially transversely across the bottom surface 54, extending across the slot 56 and having each of its ends d to the bottom surface 54 by at least one insert 76. The middle portion of each strap connector 112 is WO 2015089654 electrically connected to the current collector bar 52 by means of fusion weld, solder, braze, friction fit pin, screw, bolt or other mechanical or fusion connection which forms an ical conduction path from the collector bar 52 to the strap connector 112. The strap connectors 112 of Figure 17 are connected to the bottom surface 53 of each collector bar 52 by a fusion connection, whereas Figure 19 shows a variant in which mechanical connections are formed n the strap connectors and collector bar 52. If protrusion of strap connector 112 below the plane of bottom surface 54 is undesirable, it is possible to machine grooves 114 (Figure 19) or clearance cavities into the bottom surface 54 of the cathode block 20 to provide the necessary clearance.

Although the strap connectors 112 are shown in Figure 17 as extending across both sides of the slot 58, this is not arily the case. Rather, as shown in Figure 19, the strap tors 112 may be shorter pieces, having one end electrically connected by an insert 76 to the bottom e of cathode block 20 and the other end ically connected to the collector bar 52. For example, Figure 19 shows an insert 76 in the form of a bolt with a lock washer 77 compressed between the bolt head and one end of the strap connector 112. The other end of strap connector 112 is bolted to the bottom surface 53 of the current tor bar 52 by a bolt and washer, which are similarly labelled 76 and 77, but which are not necessarily the same as the insert 76 and lock washer 77.

Alternately, as shown in Figure 20, the connectors 112 may be comprised of flexible electrical conductors such as wire cable 113 with lugs 115 at one or both ends thereof, to attach to the inserts 76. A small amount of extra wire cable 113 may be provided to allow for differential ion between the collector bar 52 and the cathode block 20.

It will be appreciated that the use of strap connector 112 allows the layer 57 of cast iron or carbon paste to be bypassed or eliminated, as the strap connector provides a direct, electrically conductive connection between the current WO 2015089654 collector bar 52 and the bottom surface 54 of the cathode block 20. As shown in Figure 17, a plurality of spaced strap connectors 112 may be provided along the length of block 20, each secured by inserts 76, so as to provide multiple electrical connections between the block 20 and the current collector bar 52. This es an improved current distribution across the length and the width of the block 20.

As with the anode assemblies discussed above, the use of inserts 76 allows modification of the electrical resistance and current distribution of the e assembly 14 from the end of the collector bar 52, where it exits the reduction cell 10, to the top surface 30 of the cathode block 20, by adjusting the insert material, length, diameter, quantity, position and interference fit or contact pressure relative to the carbon material of the cathode block 20. For example, the current distribution and resistance profile of the cathode assembly 14 may be made more even across the top surface 30 by using longer or more inserts 76 towards the centre of block 20, in relation to its ends as illustrated in Figure 18. The actual lengths and positions of the inserts 76 may be ined during e assembly outside of the reduction cell 10, using a suitable ohmmeter to measure the resistance from the top surface 30 to the end of the collector bar 52. These modifications promote consistent current density, lower overall electrical resistance, more even e wear, a longer cathode life, and a flatter cathode top surface 30 during its operational life.

Due to differential l ion of the current collector bar 52 it is also desirable to provide strap connectors 112 with means for permitting differential l expansion. As shown in s 18 and 19, the means for permitting expansion comprise folds or corrugations 100 in the connector 112, so as to provide a bellows-like arrangement which can expand or contract in response to differential l expansion or contraction.

It is appreciated that the strap connectors 112 may not be limited to singular pieces of conductor but may be sed of multiple layers of thin straps WO 2015089654 2014/051178 which flex more easily than solid pieces while providing a similar electrical resistance. For example, the strap connectors 112 in Figure 19 are shown as comprising two layers 117.

According to another embodiment, illustrated in Figure 13, a low resistance yoke assembly 126 is provided for forming a connection between the lower end of a vertical conductor rod 38 and the top surface 42 of an anode block The yoke assembly 126 comprises a pair of curved metal struts 128, which may be identical to one another. Each of the struts has an upper end 130 and an opposed lower end 132. The upper end 130 of each strut 128 is bonded through mechanically and ically conducting attachment to opposing side surfaces of the lower end of the vertical conductor rod 38, which is shown as having a rectangular cross section with four vertical side surfaces. The mating surface of the struts 128 and the rod 38 may be electroplated, or bonded with suitable surface material to enable uent bonding of the strut 128 to the rod 38 by welding, brazing or other electrical connection. Following attachment of the struts 128 to the rod 38, one or more mechanical through fasteners 136, such as but not limited to bolts with washers and nuts, are inserted through the struts 128 and rod 38, and are adequately ned to remove cyclical physical stress on the electrical joint due to loading and unloading the weight of suspended anode block 18 from the rod The two struts 128 are arranged in opposed, face-to—face on with each other. In this ment they are joined er by one curved connector or brace 134, which contributes to the mechanical strength of the struts 128 while enabling some flexure of the struts 128 under thermal expansion stress. The struts 128 may be made of a single alloy of metal or clad or cored with ent conductive metal.

WO 2015089654 2014/051178 The lower ends 132 of the struts 128 are curved outwardly away from the vertical tor rod 38 and may be formed with multiple sections, separated by slits 138. The lower ends 132 mate with the top surface 42 of the anode block 18, and for this purpose the lower ends 132 are provided with one or more holes to enable the installation of one or more inserts 76 through the lower ends 132 and into the top e 42 of the anode block 18, with or without bores 68. The inserts 76 therefore carry the weight of the anode block 18 from the struts 128 and provide an electrical connection from the vertical conductor rod 38 to the anode block 18. To provide added ance against awal of the inserts 76, at least some of the bores 68 may be angled from the vertical, toward the al conductor rod 38, so that the inserts 76 received in these bores 68 will be “toed in” toward one another. Other inserts 76 may be angled from the vertical in other directions to provide improved current distribution within the anode block 18. If, as shown in Figure 13, multiple holes are provided within the same section of strut 128, such that one section is secured by two or more inserts 76, then an expansion fold 101 is ed in between the holes and inserts 76 to enable differential expansion of the strut 128 versus the anode block 18, with minimal stress imposed on the anode block 18 due to the flexing of the curved struts 128.

It is appreciated that the lower ends 132 of the struts 128 may be connected to the vertical conductor rod 38 by other means than mechanical fasteners 136, provided that electrical conduction is maintained between the two parts during operation.

As compared to the traditional rod assembly, the configuration of the low ance yoke assembly 126 eliminates one fusion weld on the bimetallic transition joint, increases the ical contact surface area of the strut 128 to rod 38 connection through connection on both sides of the rod 38, it removes the physical stresses in the bimetallic connection from the weight of the suspended load by use of the through bolt connections, it eliminates the yoke to stub welded connection, it eliminates the condition of stub toe-in that the ional yoke & stub assembly suffers due to repeated thermal stress and material creep at high WO 2015089654 temperatures, it enables the use of inserts 76 with toed in orientation to carry high loads h the cross section of the inserts 76. These benefits provide a low electrical resistance configuration with long life.

According to convention, the upper end 44 of the aluminum or copper vertical conductor rod 38 is temporarily attached to anode buss bar 46 with a buss clamp (not shown). The electrical resistance through the mating surface(s) of the rod 38 and buss 46 is dependent on the cleanliness, surface area and clamp pressure between the mating es. Over ed use the surfaces of the rod 38 and buss 46 may become oxidized or pitted from arcing which introduces surface roughness and a surface oxide layer of relatively high ical resistance.

The electrical resistance of the rod 38 to buss 46 connection may be reduced by coating (for example by cladding or oplating) the mating surface 140 of the buss 46 (Figure 11) and/or the mating surface 142 of rod 38 (Figure 11) with an electrically tive corrosion resistant metal such as, but not limited to, , platinum or gold. Although this surface treatment may add a small amount of electrical ance compared to a clean metal interface (aluminum rod to aluminum bus or copper rod to aluminum bus) this clad or electroplated surface will maintain its electrical resistance at levels less than those of oxidized aluminum or ed copper over the life of the rod assembly.

One or both ends of each steel current collector bar 52 are connected by a bolted connection to the e buss 24 flex connectors (not . Also, a portion of each collector bar 52 is in electrical contact with the cathode block 20 through the cast iron layer 57, as explained above with reference to Figure 3. The mating surface(s) of tor bar 52 which are in electrical contact with the cast iron layer 57 may oxidize and develop an electrically resistant oxide layer due to the high temperature of the collector bar during operation. Similarly, the mating surface(s) of collector bar 52 which are in contact with the flex connectors of the cathode buss 24 may develop oxidation. For this reason, the mating surface(s) of the current collector bar 52 which are in contact with the cathode buss flex connectors and/or the cast iron layer 57 may be coated (for example clad or WO 2015089654 electroplated) with electrically conductive corrosion resistant material, such as any of the electrically conductive corrosion resistant metals mentioned above.

Figure 21 shows a n of a current collector bar 52 in which a ng 141 of the electrically conductive corrosion resistant metal is ed on the top, bottom and side es 55, 53 and 59 of the bar 52. The cladding 141 may instead be applied only to the mating surfaces which are in contact with the cast iron layer 57 or the cathode buss 24. Alternatively, the current tor bar 52 may be ed with a coating of the electrically conductive corrosion resistant metal, for example by electroplating. The coating or cladding may have a thickness in a range from imately 0.05 to 10 mm.

The current collector bars 52 are typically comprised of an electrically conductive metal such as steel, which has a g point which is substantially higher than the maximum operating temperature of the reduction cell. However, typical steel collector bars have higher electrical resistance than the ical resistance of the aluminum metal pad, and therefore the current entering from the bath into the metal pad will preferentially conduct itself horizontally through the metal pad toward the sidewall of the cell before conducting downward through the cathode assembly 14 to the external busbar connection.

To reduce electrical resistance within the cathode assembly and horizontal electrical currents in the metal pad, an embodiment of a cathode ly 14 shown in Figure 29 provides includes a current collector bar 52 having a core 170 comprised of a metal with a lower ical resistance than steel, and an outer casing 172 nding core 170, the casing being comprised of a metal having a melting point substantially higher than the highest operating temperature of the reduction cell. For example, the core 170 may comprise copper or an alloy thereof, and the casing 172 may comprise steel, nickel or alloys such as stainless steel. The core 170 provides the current collector bar 52 with reduced electrical resistance, while the metal casing reduces potential corrosion of the outer surface of collector bar 52. Furthermore, the melting point and the thickness of the casing WO 2015089654 172 are sufficient to contain the metal of the core 170 should it temporarily melt during operation in which there is excessive heat generation. Where the core 170 may melt during operation, it will be iated that the casing 172 will comprise a sealed enclosure which surrounds the core 170 on all sides (i.e. top e 55, bottom surface 53, side surfaces 59, and end surfaces 61) within the potshell 11.

The collector bar 52 of Figure 29 may have a preformed core 170, with the casing 172 being applied to the core 170 by any suitable means, such as by electroplating, hot dip, sputtering or as a clad layer by bonding. Alternatively, the casing 172 may comprise a preformed shell and the core 170 may be formed by casting of metal into the casing 172. In the former case, the preformed core 170 defines the shape of the exterior surface of the collector bar 52, while in the latter case the preformed casing 172 defines the shape of the collector bar 52. The cross sectional shape of the collector bar 52 may be square, rectangular or round or a combination of profiles. The outer surface of the collector bar 52 may be smooth, or it may be textured to increase the contact area between the collector bar 52 and cast iron layer 57. For example, the outer surface of the current collector bar 52 may be ed by ribs and/or s.

The collector bars 52 remove heat from the cell to the environment through thermal tion through the collector bar 52 and by convective, radiation and conductive cooling of the d portion of the collector bar 52 situated outside of the cell. This heat loss must be taken into account when balancing the heat loss of the cell. In an embodiment illustrated in Figure 31, the cross nal area of at least one end portion 174 of collector bar 52, located outside of slot 56 and outside the cell, is altered in order to alter the l conductivity and electrical resistance of the tor bar 52. As shown in Figure 31, the end portion 174 of collector bar 52 is reduced in cross-sectional area relative to portions of collector bar 52 which are received inside the slot 56 of cathode block 20. The reduction of the cross sectional area of end portion 174 reduces heat loss from the cell. The collector bar 52 shown in Figure 31 includes a core 170 and casing 172 as discussed above with reference to Figure 29.

WO 2015089654 The following ments described with reference to Figures 22 to 26, 31 and 32 relate to reducing electrical resistance n the t collector bar 52, the cast iron layer 57 and the carbon of the cathode block 20. Some of these embodiments are similar to the means for reducing electrical resistance in the anode 12, discussed above, using conductive inserts 76. However, some differences are necessitated by the fact that the thermal expansion of stubs 48 and thimbles 64 in the anode 12 is primarily radial without relative movement between the components, whereas the thermal expansion of the collector bar 52 and cast iron layer 57 in the cathode 14 is primarily axial and with ve movement between the components due to different cients of thermal expansion. 7] Figure 24 is a partial, cross-sectional view of a cathode assembly 14, showing the cathode block 20 having a slot 56 in its bottom surface 54, with a cast iron layer 57 and current collector bar 52 received in the slot 56. As shown, the interior surfaces of slot 56 are provided with a plurality of conductive inserts 76 which are received in the carbon of cathode block 20 with an erence fit, as sed above with reference to the anode 12. The above discussion of the embedding of inserts 76 into the anode block 18 applies equally to the t embodiments, except where otherwise discussed below.

The conductive inserts 76 embedded in the surfaces of slot 56 do not significantly protrude into the cast iron layer 57. Rather, the heads of inserts 76 in Figures 24 and 25 are intended to be flat, optionally having rounded edges, so as to permit axial ion movement of the cast iron layer 57 relative to the cathode block 20. It will be appreciated that embedment of the heads of inserts 76 in the cast iron layer 57 could result in damage to the carbon material when the cast iron layer expands axially relative to the cathode block 20. Furthermore, to prevent a bond forming between the inserts 76 and the cast iron layer 57, the heads of inserts may be provided with a thin g of graphite powder, or other electrically conductive non-stick material which will not icantly increase electrical resistance between the inserts 76 and the cast iron layer 57.

WO 2015089654 9] An alternate arrangement for permitting axial expansion movement of the cast iron layer 57 relative to the cathode block 20 is now described with reference to Figure 30, which is an enlarged view of the circled n of Figure 29.

According to this embodiment, conductive inserts 76 embedded in the side surfaces and/or the top surface of slot 56 are provided with heads which protrude into the cast iron layer 57. The heads may become embedded therein during casting of the iron layer 57, thereby providing a good electrical conduction path between the cathode block 20 and the cast iron layer 57. In this embodiment, the s 76 are installed through formed cavities 182 in the side surface of slot 56, wherein the cavity 182 is sealed from filling with the molten cast iron by a metal shield or washer 184 which may be attached to the shank of the insert 176. During operation of the cell, the collector bar 52 and cast iron layer 57 may move a small distance relative to the cathode block 20 due to differential thermal ion between the e block 20 and collector bar 52, or due to deformation of the cathode block 20. The shank of the metal insert 76 may flex or bend within the cavity 182, and/or the shank may partially pull out of the cathode block 20, while maintaining good electrical conduction between the cast iron layer 57 and the cathode block 20 due to the embedded heads of inserts 76.

As shown in Figure 22, a conductive metal slot liner 144 may be provided between the cast iron layer 57 and the interior surfaces of slot 56. The conductive slot liner comprises a thin sheet of metal through which the inserts 76 extend into the cathode block 20, the heads of the s 76 holding the liner in place as shown in Figure 22. As shown in Figure 23, the liner 144 may have expansion slits 146 between the insert locations, shown as holes 148, to allow for differential thermal expansion of the liner 144 ve to the cathode block 20. The liner 144 may alternately be comprised of a plurality of close fitting or overlapping plates of tive metal with each piece attached to the inside surface of the cathode slot 56 by means of at least one insert 76. It will be appreciated that the provision of liner 144 may improve t distribution through the cathode block WO 2015089654 2014/051178 by improving the electrical connection between the cast iron layer 57 and the e of the cathode slot 56.

Instead of using a liner, the current distribution may be enhanced by providing more inserts 76 or, as shown in Figure 24, by providing the inserts 76 with larger heads and/or conductive metallic s 150. For example, inserts 76 with enlarged heads 78 having rounded edges 78, which may be partially embedded in the carbon of block 20, are shown in Figure 25, which will be discussed below.

In the case of the anode 12, the inserts 76 embedded in the anode block 18 have heads which protrude into the stub hole 58 and are embedded in the thimble 64, to modify the shape of the freezing iron to reduce shrinkage gap between the cast iron and the stub hole wall. This reduces the electrical resistance between those components. As shown in Figure 25, this effect can be attained in the cathode 14 by providing one or more tive collector bar anchors 152, the collector bar anchors 152 having one end ed to the collector bar 52 and another end protruding into the slot 56. The ends of the collector bar anchors 152 protruding into slot 56 will become embedded in the cast iron layer 57and provide heat sinks during casting of layer 57. This will reduce the solidification shrinkage gap local to the tor bar anchors, between the cast iron layer 57 and the inner surfaces of slot 56 for the same reasons as discussed above, by modifying the freeze profile of the cast iron layer 57 to promote solidification of the iron across the full width of the space between the collector bar 52 and the cathode block 20, as illustrated by the freeze isotherms 29 in Figure 26. This provides a “tighter” fit of the collector bar 52 and the cast iron layer 57 within the cathode slot 56, thereby reducing ical resistance between the cathode block 20, the tor bar 52 and the cast iron layer 57. 3] The quantity, depth, dimensions and ons of the collector bar anchors 152 may be modified to adjust the electrical resistance between the top surface 30 of the cathode block 20 and the collector bar 52 in order to make the WO 2015089654 electrical resistance as consistent as possible. In order to enhance the heat sink effect, the collector bar anchors 152 may be provided with ed heads, as shown in Figure 25. Also, the anchors 152 and the holes 154 in which they are ed may be threaded, to permit the amount of protrusion of the anchor 152 to be adjusted. For example, the degree of protrusion can be adjusted so that the heads of the anchors 152 contact the heads of the conductive inserts 76 embedded in the cathode block 20. This will further e the electrical connection n collector bar 52 and cathode block 20.

Figure 26 illustrates a e assembly 14 according to a variant of the embodiment shown in Figure 25. The cathode assembly of Figure 26 includes inserts 76 having enlarged, rounded heads 78 which are impact driven into the carbon of cathode block 20, rather than being driven into pre-formed bores 68.

The right hand side of current collector bar 52 is provided with threaded collector bar anchors 152 adjustably received in threaded holes 154, the collector bar anchors 152 being in the form of threaded studs or rods, not having enlarged heads, the protruding ends optionally being tapered. The protruding ends of the collector bar anchors 152 may or may not be in contact with the heads 78 of inserts ] The left hand side of current collector bar 52 is provided with fixed collector bar anchors 156 which are secured to the outer surface of current tor bar by fusion bonding, such as by welding, g or soldering. The fixed anchors 156 may be in the form of rical studs or rods, and the protruding ends may be tapered as shown. The fixed anchors 156 will act as heat sinks, and have a similar effect on the freeze profile of the cast iron layer 57, as indicated by the freeze isotherms 29 on the left hand side of Figure 26.

Figures 32 and 33 illustrate embodiments of a cathode assembly 14 in which the current distribution is improved by providing a lower and more uniform electrical resistance across the top surface 30 of cathode block 20 as compared to a traditional cathode assembly as seen in Figs. 15-16. This will reduce power WO 2015089654 consumption, reduce uneven erosion of the cathode block 20, and reduce horizontal electrical currents in the metal pad. According to this ment the electrical resistance of the cathode assembly is reduced by use of the copper collector bar 170. According to this embodiment, the electrical resistance across the top surface of cathode block 20 is made more uniform by varying the distance from the top edge of cast iron layer 57 to the top surface 55 of the collector bar 52, and to the top surface of the slot 56 of cathode block 20, along the length of slot 56.

As shown in Figure 32, the collector bar 52 is bonded to the e block 20 by means of cast iron layers 57 on the two l ng side surfaces 59 of the tor bar 52 that reside within the cathode slot 56. In contrast to the embodiment shown in Figures 15 and 16, no cast iron layer 57 is provided between the top surface 55 of the collector bar 52 and the top e of the slot 56. This space may be optionally filled with an electrically and thermally insulating refractory material 178.

In addition, the cast iron layer 57 along each side surface 59 of collector bar 52 varies in height along the length of the collector bar 52, being higher in the middle portion of tor bar 52 and slot 56, and lower proximate to the ends of collector bar 52 and slot 56. Accordingly, each cast iron layer 57 has a top edge 180 which varies in distance from the top surface 55 of collector bar 52 along the length of slot 56, where any spaces caused by the profiling of the top edge 180 may be filled with insulating refractory material 178. In the illustrated embodiment, the top edge 180 of cast iron layer 57 is shaped in an approximate arc profile, however, the shape can be varied from that which is shown, such as straight or polygonal profiles. Also, in this embodiment, the top edge 180 of cast iron layer 57 is substantially level with the top surface 55 of collector bar 52 at the midpoint of cathode block 20.

With the profiled top edge 180 of cast iron layers 57, the resistance of the cathode carbon between the top surface 30 of the cathode block 20 and the ting surface of the iron layers 57 presents a changing electrical resistance WO 2015089654 along the length of the cathode block 20 that is offset by the changing electrical resistance along the length of the tor bar 52, thereby presenting a near uniform electrical resistance from re along the length of the top surface 30 of the cathode block 20 to the external end of the collector bar 52. The current distribution across the width of the top surface 30 of the cathode block 20 may be made more uniform by the altering the dimensions of the slot 56 and the iron connection surface between the e block 20 and collector bar 52. The shape profiles of the top edges 180 of the iron layers 57, and the distance from the top edge 180 of the iron layers 57 to the top e 55 of the collector bar 52, may also be varied in adjacent cathode assemblies 14 so as to e the current distribution across the width of the reduction cell 10. Cast iron may be substituted equally with carbon paste used to connect the cathode block and the collector bar.

The insulating refractory material 178 between the cathode block 20 and the collector bar 52 serves to reduce the rate of heat transfer from the cathode block 20 to the collector bar 52. This material 178 may be castable, using a temporary form, or may be preformed and positioned into the cathode slot 56 prior to positioning of the tor bar 52 and casting of the iron layer 57.

As shown in Figure 33, inserts 76 such as those shown in Figure 30 may be provided along the length of the collector bar 52.

Figures 27 and 28 show an alternate ment of a cathode assembly 14 in which no cast iron layer 57 is provided in the space n the current tor bar 52 and the cathode block 20. The cathode block 20 is conductively connected to the collector bar by a strap connector 112 comprising a wire cable 113 with lugs 115, one of the lug ends 115 being conductively connected to the bottom surface 54 of cathode block 20 by a conductive insert 76, the opposite lug end 115 being conductively connected to the bottom surface 53 of collector bar 52 by a bolt 176. Alternatively, a plurality of any of the strap connectors 112 described above may be provided.

WO 2015089654 In the embodiment of Figures 27 and 28, the current collector bar 52 is held in place by one or more conductive hanger assemblies 160, one of which is shown in the gs, comprising a tongue portion 162 and a slot portion 164, the tongue portion 162 being slidably received in the slot portion 164 along the longitudinal axis of the collector bar 52, as best seen in the cross—sectional side elevation of Figure 29. In the illustrated embodiment, the tongue portion 162 has an attachment flange 166 which is secured to the top surface 55 of collector bar 52 (opposite the bottom surface 53) by one or more bolts 176, although other mechanical or fusion connections may be used instead. The slot portion has a pair of attachment flanges 168 along its l edges, the flanges being attached to the inner surface of slot 56 by tive inserts 76 inserted in the carbon of cathode block 20. It will be appreciated that the positions of the tongue portion 162 and slot portion 164 could be reversed, i.e. with the slot portion 164 attached to collector bar 52 and the tongue portion 162 attached to the cathode block 20.

With the conductive hanger assembly 160, ve thermal expansion of the tor bar 52 and the cathode block 20 results in axial longitudinal movement of the tongue portion 162 within slot n 164, y providing support for the collector bar 52 while avoiding the creation of thermal stresses.

If eliminating the layer 57 of cast iron or paste the gap remaining between the collector bar 52 and the inner surface of the cathode slot 56 may be filled with thermal insulation to reduce heat transfer between the cathode block 20 and the collector bar 52. 6] The thermal balance of the cell must be maintained hout the life of the cell, so as to maintain the bath at about 25-50 degrees Celsius above its freezing ature, while enabling the bath to freeze against the sidewall for corrosion protection of the sidewall refractory, and to prevent excessive freezing of the bath on the anode and cathode surfaces. However, the thermal conductivity of the cell changes over time due to ion wear of the sidewall and the cathode blocks 20, and the energy(watts) input to the cell may change with the cell’s WO 2015089654 electrical resistance. According to the embodiments shown in Figures 34 and 35, the outer surface of ll 11 (shown in Fig. 1) may be provided with removable means for preventing the potshell 11 from becoming too hot or too cold throughout the operational life of the cell 10.

In accordance with the embodiment of Figure 34, the thermal conductivity through the potshell 11 can be increased in selected locations by use of cooling fins 186 attached to the outside of the potshell 11, with or without forced cooling. Cooling fins 186 absorb heat from the potshell 11 and cool the potshell 11 by convection of heat to the air and/or heat radiation to the environment. The increase in cooling rate provided by fins 186 will reduce the temperature of the refractory lining 34, 36 (shown in Fig. 1) on the inside of the potshell 11, thereby ncing the thickness of the frozen bath layer.

Each cooling fin 186 may comprise an extruded um shape with a bottom plate 188 that es a bottom surface 190 and a top surface 192, where the bottom surface 190 contacts the potshell 11. Extending from the top surface 192 are one or more fins 194. The cooling fins 186 may be comprised of aluminum, and may e a surface treatment of ation, such as a coloured anodization, which increases the emissivity of the g fin material in order to increase its ability to e heat to the environment compared to a non-anodized aluminum g fin.

The cooling fins 186 may be magnetically held against the potshell 11 by one or more rare earth and/or non-ferrous magnets 196 having a curie point of at least about five hundred degrees Celsius. For example, the s 196 may comprise Samarium—Cobalt or Aluminum—Nickel—Cobalt (Alnico) alloyed magnets.

Such magnets 196 in their magnetic force at high temperatures, and hold the cooling fin 186 against the side of the steel potshell 11 when it has heated beyond normal design parameters due to the wear of the internal refractory lining.

WO 2015089654 2014/051178 The magnets 196 are retained in the bottom plate 188. For example, the bottom surface 190 of the bottom plate 188 may be provided with one or more cavities 198 for retaining magnets 196, and the magnets 196 may be retained therein by retaining screws 200 or other mechanical means, and/or by bonding.

The bottom plate 188 may have a groove 202 along an edge of the bottom surface 190 of plate 188 to enable prying the cooling fin 186 off of the potshell 11 for removal.

The cooling fins 186 may further comprise a thin thermal break 204 between the magnets 196 and the steel potshell 11, through which the heat transfer into the magnets 196 will be reduced but the magnetic force will be maintained. The thermal break 204 may be attached to the external surfaces 197 of magnets 196, and may comprise a non flammable material with low thermal conductivity. The thermal break 204 es the performance of the magnets 196 by keeping them at a cooler temperature than without the thermal break 204. For clarity, the thermal break 204 is shown as being removed from the external surface of the lower magnet 196 in Figure 34.

In accordance with the embodiment of Figure 35, the thermal conductivity through the potshell 11 can be decreased in selected locations by the use of external insulation on the potshell 11, which insulation reduces the convective and ion cooling of the ll 11. Due to the wear (thinning) of the internal refractory in the cell over its ional life the potshell 11 may change from being too cold to being too hot, so it is desirable to have insulation that can easily be removed if the local potshell temperature exceeds a certain level.

According to the present embodiment, the ary l insulation is applied to the exterior of the ll 11 in the form of one or more ically mounted blankets 206, one of which is shown in Figure 35. The blanket 206 is comprised of a non-flammable, high ature resistant material 210 having a melting point of at least about 600 degrees s, such as one or more layers of a woven or unwoven, flexible glass or ceramic fibre cloth. Filler WO 2015089654 material may ally be quilted between layers of the cloth. The blankets 206 reduce the cooling rate of the ll 11 to the environment, thereby increasing the internal temperature of the potshell 11 nt to the blanket location. ts 206 may be overlapped and/or layered so as to cover nt areas and/or to enhance reduction of the cooling rate in specified regions of the potshell 11. The flexibility of blankets 206 allows them to be positioned over structural elements of the potshell 11.

A plurality of magnets 208 are attached to or captured within the construct of the blanket 206, in adequate location and ty to hold the blanket 206 against the potshell 11 and thereby reduce the convective and radiation cooling of the potshell 11 to the environment. The magnets 208 may be ferrous, nonferrous or may be comprised of a rare earth alloy. The magnets 208 may be selected by strength and curie point to lose holding power in the event that the temperature of the potshell 11, or a portion thereof, reaches an unacceptably high level. Also, the magnets 208 are of low enough magnetic force to enable manual l of the blankets 206 from the potshell 11.

] Although specific embodiments have been described herein, the claims are not limited to these embodiments. Rather, the disclosure includes all embodiments which may fall within the scope of the following claims.

WO 9654

Claims (13)

What is claimed is:

1. An electrode assembly for use in a reduction cell for the production of metal, the electrode assembly comprising: (a) an electrically conductive carbon electrode block having a first surface and a second surface, wherein the first surface faces an interior of the reduction cell when the electrode assembly is in use; (b) an electrically conductive metal member having a first end and a second end, wherein the first end of the metal member is connected to the carbon electrode block in an electrically tive , and the second end of the metal member is adapted for connection to a buss bar in an electrically conductive manner; (c) a solid, conductive metal insert at least partly received in the carbon ode block, wherein the insert s into the carbon electrode block from the second surface thereof; and wherein the metal insert is received in the carbon electrode block with an erence fit, such that the insert exerts a lateral force on the carbon electrode block.

2. The electrode assembly of claim 1, wherein the electrode is a pre—baked carbon anode, wherein the first surface of the carbon electrode block is a bottom e thereof, and n the electrically conductive metal member comprises a vertical conductor rod.

3. The electrode assembly of claim 2, wherein the electrically conductive metal member further comprises a vertical stub at its first end, the carbon electrode block has a top surface opposite the bottom surface, a recess is formed in the top surface, with an end of the vertical stub being received in the recess.

4. The electrode assembly of claim 3, wherein the second surface in which the insert extends comprises an inner surface of the recess, the inner surface being selected from a bottom surface and a side surface of the recess. WO 2015089654

5. The electrode ly of claim 4, wherein the insert extends into the bottom e of the recess and s vertically downwardly therefrom.

6. The electrode assembly of claim 4, wherein the insert extends into the side surface of the recess and extends ly outwardly therefrom.

7. The electrode assembly of claim 4, wherein the insert is inclined downwardly and outwardly from said second surface.

8. The electrode assembly of any one of claims 4 to 7, comprising a plurality of said inserts provided in the bottom surface and/or the side surface of the recess, with each of said inserts being at least partly received in the carbon electrode block.

9. The electrode assembly of claim 8, wherein a portion of each of said inserts protrudes from the bottom e or the side surface of the recess.

10. The ode assembly of claim 9, wherein the portion of each insert which protrudes from the bottom surface or the side surface includes an enlarged head.

11. The electrode assembly of any one of claims 4 to 10, wherein the recess is ed with a conductive metal lining through which an electrically conductive connection is formed between the stub and the carbon ode block, and wherein the insert or the plurality of inserts is in direct, electrically conductive contact with the conductive metal lining of the recess.

12. The electrode assembly of claim 11, wherein at least a portion of the conductive metal lining comprises a cast portion which is formed in situ between the stub and the carbon electrode block.

13. The electrode ly of claim 12, wherein a portion of the conductive metal lining comprises a solid preform which is combined with the cast portion WO 2015089654