NZ624081B2 - Additives for use in wood preservation - Google Patents
Additives for use in wood preservation Download PDFInfo
- Publication number
- NZ624081B2 NZ624081B2 NZ624081A NZ62408112A NZ624081B2 NZ 624081 B2 NZ624081 B2 NZ 624081B2 NZ 624081 A NZ624081 A NZ 624081A NZ 62408112 A NZ62408112 A NZ 62408112A NZ 624081 B2 NZ624081 B2 NZ 624081B2
- Authority
- NZ
- New Zealand
- Prior art keywords
- wood
- copper
- cationic polymer
- amino compound
- wood preservative
- Prior art date
Links
- 239000002023 wood Substances 0.000 title claims abstract description 56
- 238000004321 preservation Methods 0.000 title claims description 7
- 239000000654 additive Substances 0.000 title description 21
- 239000000203 mixture Substances 0.000 claims abstract description 84
- -1 amino compound Chemical class 0.000 claims abstract description 67
- 229920000642 polymer Polymers 0.000 claims abstract description 55
- 125000002091 cationic group Chemical group 0.000 claims abstract description 48
- 238000009472 formulation Methods 0.000 claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 38
- 239000003171 wood protecting agent Substances 0.000 claims abstract description 38
- 239000003139 biocide Substances 0.000 claims abstract description 28
- JPVYNHNXODAKFH-UHFFFAOYSA-N cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims abstract description 26
- PTFCDOFLOPIGGS-UHFFFAOYSA-N zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 150000001412 amines Chemical class 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N ethanolamine Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 17
- 230000035515 penetration Effects 0.000 claims description 13
- 229920000768 polyamine Polymers 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 150000002500 ions Chemical class 0.000 claims description 11
- 125000003342 alkenyl group Chemical group 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 9
- 125000000304 alkynyl group Chemical group 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- 230000002708 enhancing Effects 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxyl anion Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 6
- 125000004433 nitrogen atoms Chemical group N* 0.000 claims description 6
- 229920000083 poly(allylamine) Polymers 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbamate Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- TXOJCSIIFFMREV-UHFFFAOYSA-L didecyl(dimethyl)azanium;carbonate Chemical compound [O-]C([O-])=O.CCCCCCCCCC[N+](C)(C)CCCCCCCCCC.CCCCCCCCCC[N+](C)(C)CCCCCCCCCC TXOJCSIIFFMREV-UHFFFAOYSA-L 0.000 claims description 4
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 claims description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 238000003860 storage Methods 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 3
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecan-1-amine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims description 3
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 3
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N N-ethenylformamide Chemical class C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- VUNGHBJEVBKTME-UHFFFAOYSA-N [NH-]C=C Chemical class [NH-]C=C VUNGHBJEVBKTME-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- YWFWDNVOPHGWMX-UHFFFAOYSA-N N,N-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims 1
- 150000003457 sulfones Chemical class 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 47
- 239000010949 copper Substances 0.000 description 24
- 229910052802 copper Inorganic materials 0.000 description 23
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 18
- 230000000996 additive Effects 0.000 description 16
- 239000000047 product Substances 0.000 description 12
- 230000003115 biocidal Effects 0.000 description 11
- 230000002335 preservative Effects 0.000 description 10
- 239000003755 preservative agent Substances 0.000 description 10
- 239000011701 zinc Substances 0.000 description 10
- 238000005470 impregnation Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 229940091251 Zinc Supplements Drugs 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 235000008582 Pinus sylvestris Nutrition 0.000 description 7
- 241000218626 Pinus sylvestris Species 0.000 description 7
- 229940027983 antiseptics and disinfectants Quaternary ammonium compounds Drugs 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 230000000855 fungicidal Effects 0.000 description 7
- 239000001839 pinus sylvestris Substances 0.000 description 7
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper(II) hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N Imidazole Chemical compound C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 239000008139 complexing agent Substances 0.000 description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 6
- 239000005749 Copper compound Substances 0.000 description 5
- 150000001880 copper compounds Chemical class 0.000 description 5
- 239000000417 fungicide Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- BERDEBHAJNAUOM-UHFFFAOYSA-N Copper(I) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 4
- OPQARKPSCNTWTJ-UHFFFAOYSA-L Copper(II) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 4
- OTPSWLRZXRHDNX-UHFFFAOYSA-L Zinc pyrithione Chemical compound S1C2=CC=CC=N2=O[Zn]21O=N1=CC=CC=C1S2 OTPSWLRZXRHDNX-UHFFFAOYSA-L 0.000 description 4
- 150000003851 azoles Chemical class 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- ZMMDPCMYTCRWFF-UHFFFAOYSA-J dicopper;carbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[O-]C([O-])=O ZMMDPCMYTCRWFF-UHFFFAOYSA-J 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- GCGGSVAWTYHZBI-CVQRFVFPSA-N 1-hydroxy-2-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxyanthracene-9,10-dione Chemical compound O[C@@H]1[C@@H](O)[C@H](O)CO[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](OC=2C(=C3C(=O)C4=CC=CC=C4C(=O)C3=CC=2)O)O1 GCGGSVAWTYHZBI-CVQRFVFPSA-N 0.000 description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical class OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atoms Chemical group C* 0.000 description 3
- 230000000536 complexating Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- 125000001174 sulfone group Chemical group 0.000 description 3
- 229940043810 zinc pyrithione Drugs 0.000 description 3
- 150000000178 1,2,4-triazoles Chemical class 0.000 description 2
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 1H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 2
- 229960000686 Benzalkonium Chloride Drugs 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N Benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- 229940001447 Lactate Drugs 0.000 description 2
- 239000005820 Prochloraz Substances 0.000 description 2
- UPMFZISCCZSDND-JJKGCWMISA-M Sodium gluconate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O UPMFZISCCZSDND-JJKGCWMISA-M 0.000 description 2
- 229940005574 Sodium gluconate Drugs 0.000 description 2
- 239000005839 Tebuconazole Substances 0.000 description 2
- PXMNMQRDXWABCY-UHFFFAOYSA-N Tebuconazole Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 239000011111 cardboard Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 2
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 description 2
- LILHXQCLSOZSRO-UHFFFAOYSA-J dizinc;oxozinc;dicarbonate;tetrahydrate Chemical compound O.O.O.O.[Zn+2].[Zn+2].[Zn]=O.[Zn]=O.[Zn]=O.[O-]C([O-])=O.[O-]C([O-])=O LILHXQCLSOZSRO-UHFFFAOYSA-J 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N edta Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000002431 foraging Effects 0.000 description 2
- 229940050410 gluconate Drugs 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 125000001072 heteroaryl group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M methanoate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 2
- 239000000176 sodium gluconate Substances 0.000 description 2
- 235000012207 sodium gluconate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 2
- 239000011667 zinc carbonate Substances 0.000 description 2
- 235000004416 zinc carbonate Nutrition 0.000 description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 150000003752 zinc compounds Chemical class 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 description 1
- RYAUSSKQMZRMAI-ZACQAIPSSA-N (R)-fenpropimorph Chemical compound C([C@H](C)CC=1C=CC(=CC=1)C(C)(C)C)N1C[C@H](C)O[C@H](C)C1 RYAUSSKQMZRMAI-ZACQAIPSSA-N 0.000 description 1
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical class O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 1
- TUBQDCKAWGHZPF-UHFFFAOYSA-N 1,3-benzothiazol-2-ylsulfanylmethyl thiocyanate Chemical compound C1=CC=C2SC(SCSC#N)=NC2=C1 TUBQDCKAWGHZPF-UHFFFAOYSA-N 0.000 description 1
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 description 1
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 description 1
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 description 1
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 1
- SNUSZUYTMHKCPM-UHFFFAOYSA-N 1-hydroxypyridin-2-one Chemical compound ON1C=CC=CC1=O SNUSZUYTMHKCPM-UHFFFAOYSA-N 0.000 description 1
- PFFIDZXUXFLSSR-UHFFFAOYSA-N 1-methyl-N-[2-(4-methylpentan-2-yl)-3-thienyl]-3-(trifluoromethyl)pyrazole-4-carboxamide Chemical compound S1C=CC(NC(=O)C=2C(=NN(C)C=2)C(F)(F)F)=C1C(C)CC(C)C PFFIDZXUXFLSSR-UHFFFAOYSA-N 0.000 description 1
- ZHDBTKPXEJDTTQ-UHFFFAOYSA-N 1-oxido-2-[(1-oxidopyridin-1-ium-2-yl)disulfanyl]pyridin-1-ium Chemical compound [O-][N+]1=CC=CC=C1SSC1=CC=CC=[N+]1[O-] ZHDBTKPXEJDTTQ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-Methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 description 1
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 description 1
- FECDACOUYKFOOP-UHFFFAOYSA-N 2-ethylhexyl 2-hydroxypropanoate Chemical compound CCCCC(CC)COC(=O)C(C)O FECDACOUYKFOOP-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- NRAYWXLNSHEHQO-UHFFFAOYSA-N 3-(1-benzothiophen-2-yl)-5,6-dihydro-1,4,2-oxathiazine 4-oxide Chemical compound O=S1CCON=C1C1=CC2=CC=CC=C2S1 NRAYWXLNSHEHQO-UHFFFAOYSA-N 0.000 description 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N 3-acetyl-6-methylpyran-2,4-dione Chemical compound CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
- ZOMKCDYJHAQMCU-UHFFFAOYSA-N 4-butyl-1,2,4-triazole Chemical compound CCCCN1C=NN=C1 ZOMKCDYJHAQMCU-UHFFFAOYSA-N 0.000 description 1
- GOFJDXZZHFNFLV-UHFFFAOYSA-N 5-fluoro-1,3-dimethyl-N-[2-(4-methylpentan-2-yl)phenyl]pyrazole-4-carboxamide Chemical compound CC(C)CC(C)C1=CC=CC=C1NC(=O)C1=C(F)N(C)N=C1C GOFJDXZZHFNFLV-UHFFFAOYSA-N 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N 8-Hydroxyquinoline Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- RZOBLYBZQXQGFY-UHFFFAOYSA-N Ammonium lactate Chemical compound [NH4+].CC(O)C([O-])=O RZOBLYBZQXQGFY-UHFFFAOYSA-N 0.000 description 1
- 239000004251 Ammonium lactate Substances 0.000 description 1
- 229950000294 Azaconazole Drugs 0.000 description 1
- 239000005730 Azoxystrobin Substances 0.000 description 1
- WFDXOXNFNRHQEC-GHRIWEEISA-N Azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/22—Compounds of zinc or copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/4935—Impregnated naturally solid product [e.g., leather, stone, etc.]
- Y10T428/662—Wood timber product [e.g., piling, post, veneer, etc.]
Abstract
The present disclosure relates to a wood preservative formulation comprising a biocidal agent which is a copper or zinc ion complexed with an amino compound selected from the group consisting of ammonia, a water soluble amine or aikanoiamine and an aminocarboxyiic acid and a cationic polymer, as well as to aqueous treatment solutions comprising such a formulation and methods of treating wood or other cellulosic material utilising said formulation. Examples of a cationic polymer include compounds of formula (I), (II) and (III). l as to aqueous treatment solutions comprising such a formulation and methods of treating wood or other cellulosic material utilising said formulation. Examples of a cationic polymer include compounds of formula (I), (II) and (III).
Description
ADDITIVES FOR USE IN WOOD PRESERVATION
Field of the Invention
The present invention relates to wood preservative formulations and
methods of treating wood and other cellulosic material. In particular it relates to
formulations which contain a positively charged polymer which enhances the
penetration of the active ingredients also present in the formulation into the wood or
other cellulosic material.
Background of the Invention
Any discussion of the prior art throughout the specification should in no way
be considered as an admission that such prior art is widely known or forms part of
common general knowledge in the field.
Many types of wood preservative treatments exist on the market today.
These can be applied directly to the surface, paint-on, or by vacuum pressure
immersion treatments. During industrial application of preservatives, timber is
typically impregnated with the treatment solution to achieve either shell or full cell
type penetration into the substrate.
Depending on the wood species being treated and the end use, the depth of
penetration of the preservative solution into the timber can have a significant
bearing on the useful service life of the treated timber.
A typical industrial treatment plant will consist of a storage tank to hold the
treatment solution and an autoclave. Timber is charged into the autoclave and this
is then flooded with treatment solution. Combinations of vacuum and pressure are
applied to achieve the required penetration of preservative into the timber.
During the treatment process, an amount of preservative solution is
consumed by way of being absorbed into the timber. This typically represents a
relatively small amount of the total volume of solution used to flood the autoclave.
This generates a scenario whereby treatment solution is repeatedly exposed to
timber. The average treatment solution age increases as a function of solution
refresh rates. This can extend from several days to many months. Therefore the
solution is repeatedly exposed to timber.
It has been observed that the ability of the preservative to penetrate into the
timber substrate as the solution is repeatedly exposed to timber can deteriorate
very significantly. This can have significant consequences to the useful service life
of the treated article.
Wood preservatives tend to be neutral or alkaline and the high pHs can
solubilise chemical substances found in timber and during the impregnation process
the timber generates anionic by-products. This combination of anionic by-products
and timber extractives can then hinder penetration of the wood preservatives
through the timber.
, and Nikiforova et al. in the Russian
Journal of Applied Chemistry (201 0) vol. 83, no 7, pp 1170-1175 describe formulations
with one or more of the components of the formulations of the present invention, but
they do not describe or suggest the formulations of the present invention or their
ability to enhance uptake of biocides contained therein.
It is an object of the present invention to overcome or ameliorate at least
one of the disadvantages of the prior art, or to provide a useful alternative.
Unless the context clearly requires otherwise, throughout the description
and the claims, the words “comprise”, “comprising”, and the like are to be construed
in an inclusive sense as opposed to an exclusive or exhaustive sense; that is to
say, in the sense of “including, but not limited to”.
Although the invention will be described with reference to specific examples
it will be appreciated by those skilled in the art that the invention may be embodied
in many other forms.
Summary of the Invention
According to a first aspect of the present invention there is provided a wood
preservative formulation comprising a biocidal agent which is a copper or zinc ion
complexed with an amino compound selected from the group consisting of
ammonia, a water soluble amine or alkanolamine and an aminocarboxylic acid, and
a cationic polymer selected from the group consisting of:
(i) a compound of formula (I)
(CH )n
n (CH ) (CH )n
1 2 2 1
(I)
(ii) a compound of formula (II)
(II)
; and
(iii) a compound of formula (III)
n (CH )
N(R )n
(III)
in which:
n = 3 to 5000;
n = 0, 1 or 2;
n = 0 or 1;
n = 2 or 3 and when n = 3 the nitrogen atom carries a positive charge and a
counter ion X is present;
R groups, which can be identical or different, are hydrogen or a straight
chain, branched or cyclic alkyl, alkenyl, alkynyl, alkanoxyl, aryl,
-(C=O)H, -(C=O)R , -CO H -CO R , -CH CO H, -CH CO R , CH NR R ,
n 2 2 n 2 2 2 2 n 2 n n
-(C=O)NR R , -CN, -(CH )n -O-R , in which;
n n 2 4 n
R groups, which can be identical or different, are hydrogen or a straight
chain, branched or cyclic alkyl, alkenyl, alkynyl, alkanoxyl or aryl;
n = 2 or 3;
R is of the formula (IV)
H O H H
R R R
z z z
a b c d
(IV)
in which;
R = H or OH;
a = 0 to 10;
b = 0 or 1;
c = 0 to 10;
d = 0 to 10;
X is any anion selected from chloride, bromide, iodide, fluoride, sulphate,
phosphate, carboxylate especially propionate and lactate, carbonate,
bicarbonate, nitrate, nitrite, hydroxide, cyanide; and
* represents the bonds connecting the repeating units within the backbone
of the polymer.
According to a second aspect of the present invention there is provided a
combined wood preservative product comprising
(a) a biocidal agent which is a copper or zinc ion complexed with an
amino compound wherein said amino compound is as defined according to
any one of claims 1, 6 or 7; and
(b) a cationic polymer as defined in any one of claims 1 to 12.
According to a third aspect of the present invention there is provided an
aqueous wood preservative treatment solution comprising a wood preservative
formulation as defined in claim 1 or claim 2 or any one of claims 6 to 11, said
solution containing 10 to 1000 ppm of cationic polymer.
According to a fourth aspect of the present invention there is provided a
method of preserving wood or other cellulosic material which comprises applying to
the wood or other cellulosic material a formulation or solution as defined in any
preceding claim or applying
(a) a biocidal agent which is a copper or zinc ion complexed with an
amino compound wherein said amino compound is as defined according to
any one of claims 1, 6 or 7; and
(b) a cationic polymer as defined in any one of claims 1 to 12;
to the wood/material such that the wood/material effectively receives a
formulation as defined in any one of the preceding aspects of the invention.
According to a fifth aspect of the present invention there is provided a wood
treatment system comprising a storage tank adapted to receive the wood to be
treated and in said tank a volume of treatment solution comprising
(a) a biocidal agent which is a copper or zinc ion complexed with an
amino compound wherein said amino compound is as defined according to
any one of claims 1, 6 or 7; and
(b) a cationic polymer as defined in any one of claims 1 to 12.
According to a sixth aspect of the present invention there is provided a
substrate of wood or other cellulosic material containing:
(a) a biocidal agent which is a copper or zinc ion complexed with an
amino compound wherein said amino compound is as defined according to
any one of claims 1, 6 or 7; and
(b) a cationic polymer as defined in any one of claims 1 to 12.
According to a seventh aspect of the present invention there is provided a
method of making a wood preservative formulation which comprises admixing:
(a) a biocidal agent which is a copper or zinc ion complexed with an
amino compound wherein said amino compound is as defined according to
any one of claims 1, 6 or 7; and
(b) a cationic polymer as defined in any one of claims 1 to 12.
According to an eighth aspect of the present invention there is provided the
use of a cationic polymer as defined in any one of the preceding claims to enhance
the penetration into wood or other cellulosic material of
(a) a biocidal agent which is a copper or zinc ion complexed with an
amino compound wherein said amino compound is as defined according to
any one of claims 1, 6 or 7; and
(b) a cationic polymer as defined in any one of claims 1 to 12
which is co-administered to the wood or other cellulosic material in a
method of preservation.
It has been found that addition of certain highly cationic polymers to the
wood preservative solutions can significantly improve preservative solution uptakes
and penetration into the wood being treated.
Thus, in another aspect, the present invention provides a wood preservative
formulation comprising a biocidal agent and a cationic polymer selected from the
group consisting of:
(i) a compound of formula (I)
(CH )n
(CH )n
n (CH )
(ii) a compound of formula (II)
(II)
; and
(iii) a compound of formula (III)
n (CH )
N(R )n
(III)
in which:
n = 3 to 5000;
n = 0, 1 or 2;
n = 0 or 1;
n = 2 or 3 and when n = 3 the nitrogen atom carries a positive charge and a
counter ion X is present;
R groups, which can be identical or different, are hydrogen or a straight
chain, branched or cyclic alkyl, alkenyl, alkynyl, alkanoxyl, aryl,
-(C=O)H, -(C=O)R , -CO H -CO R , -CH CO H, -CH CO R , CH NR R ,
n 2 2 n 2 2 2 2 n 2 n n
-(C=O)NR R , -CN, -(CH )n -O-R , in which;
n n 2 4 n
R groups, which can be identical or different, are hydrogen or a straight
chain, branched or cyclic alkyl, alkenyl, alkynyl, alkanoxyl or aryl;
n = 2 or 3;
R is of the formula (IV)
H O H H
R R R
z z z
b c d
(IV)
in which;
R = H or OH;
a = 0 to 10;
b = 0 or 1;
c = 0 to 10;
d = 0 to 10;
X is any anion selected from chloride, bromide, iodide, fluoride, sulphate,
phosphate, carboxylate especially propionate and lactate, carbonate,
bicarbonate, nitrate, nitrite, hydroxide, cyanide; and
* represents the bonds connecting the repeating units within the backbone
of the polymer.
R groups are preferably C , more preferably C , e.g. C alkyl, alkenyl,
x 1-22 1-16 1-8
alkynyl or alkanoxyl, or C , more preferably C aryl.
-22 6-10
Likewise R groups are preferably C , more preferably C , e.g. C alkyl,
n 1-22 1-16 1-8
alkenyl, alkynyl or alkanoxyl, or C , more preferably C aryl. Aryl groups may
-22 6-10
be heteroaromatic.
The molecular weight of the above polymers is typically up to 1,000,000,
preferably up to 500,000, preferably at least 1,000, more preferably between 1,000
and 50,000.
As discussed in more detail below, many wood preservatives contain
biocidal metal compounds, such as copper compounds, in which the metal ion acts
as the primary fungicide. It is known in the art to use nitrogen containing
compounds, such as monoethanolamine, as a complexing agent for the metal ion to
enhance delivery of the metal into the wood. In such systems the complexing
nitrogen compound is typically present at between 5 and 25% by weight of
ingredients in the concentrated wood preservative formulation which is
manufactured. In contrast, according to the present invention, where the cationic
polymers are not included for the purposes of complexing a copper or other metal
ion but to manage negatively charged extractives and by-products, the wood
preservative formulation preferably contains 0.01 to 4%, more likely 0.05 to 2% by
weight of a cationic polymer as defined above, more preferably 0.1 to 1%, most
preferably 0.15 to 0.6%. These values refer to the amount of cationic polymer
present in the wood preservative concentrate as manufactured and supplied to the
treatment site. Such formulations are typically diluted with water to form treatment
solutions which are 2-6% solutions on a m/v basis. The amount of cationic polymer
applied to the wood will thus be correspondingly less in terms of the weight
percentage of the impregnation solution.
The wood preservative formulations of the invention may comprise one or
more of the following active agents; boron containing biocides such as boric acid,
oxides and salts thereof and organic fungicides including fungicidal amides such as
prochloraz, penthiopyrad, dichlofluanid and tolylfluanid; anilide fungicides such as
sedaxane and penflufen; anilinopyrimidine fungicides such as pyrimethanil,
cyprodinil or mepanipyrim; fungicidal aromatic compounds such as chlorthalonil,
cresol, dicloran, pentachlorophenol, sodium pentachlorophenol, 2-
(thiocyanatomethylthio)-1,3-benzothiazole (TCMBC), dichlorophen, fludioxonil and
8-hydroxyquinoline; fungicidal heterocyclic compounds such as dazomet,
fenpropimorph, bethoxazin and dehydroacetic acid; strobilurins such as
azoxystrobin; quaternary ammonium compounds; azoles; isothiazolones;
Potassium HDO (cyclohexylhydroxydiazene 1-oxide, potassium salt); pyrion
compounds such as sodium pyrithione, zinc pyrithione, copper pyrithione, 1-
hydroxypyridinone and pyrion disulfide and mixtures thereof. Particularly
preferred organic fungicidal agents are quaternary ammonium compounds, azoles,
and mixtures thereof.
Preferred quaternary ammonium compounds are trimethyl alkyl quaternary
ammonium compounds such as cocotrimethyl ammonium chloride; dialkyldimethyl
quaternary ammonium compounds such as didecyl dimethyl ammonium chloride,
didecyl dimethyl ammonium carbonate, didecyl dimethyl ammonium bicarbonate,
dioctyl dimethyl ammonium chloride and octyl decyl dimethyl ammonium chloride,
or mixtures thereof; alkyl dimethyl or diethyl benzyl ammonium salts such as
benzalkonium chloride and benzalkonium hydroxide; polyethoxylated quaternary
ammonium compounds such as N,N-didecyl-N-methyl- poly(oxyethyl) ammonium
propionate (Bardap 26) or N,N-didecyl-N-methyl-poly(oxyethyl) ammonium lactate;
and N-substituted pyridinium compounds such as cetyl pyridinium chloride.
Particularly preferred quaternary ammonium compounds are benzalkonium
chloride, didecyl dimethyl ammonium chloride and didecyl dimethyl ammonium
carbonate, with didecyl dimethyl ammonium chloride and didecyl dimethyl
ammonium carbonate being the most preferred.
The azole compound, i.e. a compound comprising an azole group, may be
an imidazole or a 1,2,4-triazole and is preferably represented by the general
formula (V)
wherein
X denotes CR or N;
R denotes hydrogen or a linear, branched, cyclic, aromatic or any
combination thereof, saturated or unsaturated, substituted or unsubstituted C to
C group
wherein any of the carbon atoms other than those bound to the nitrogen
atom shown in formula (V) may be replaced with an optionally substituted hetero
atom;
R denotes hydrogen, C -C alkyl, C -C alkenyl, C -C aromatic, C -C
1 8 2 8 6 10 5 10
heteroaromatic or C -C alkyl carbamate; and
R and R denote hydrogen; or
3 4 3 4
together R and R may provide a benzimidazole group (i.e. R and R may
combine to form -(CH) -).
The formulations of the invention may contain one or more azole
compounds, such as mixtures of an imidazole and a 1,2,4-triazole, or mixtures of
two or more 1,2,4-triazoles. However, it is preferred to use 1,2,4-triazoles in the
formulations of the invention.
The imidazole compound incorporates a five-membered diunsaturated ring
composed of three carbon atoms and two nitrogen atoms at non-adjacent positions.
The imidazole compound may be a benzimidazole. Preferred compounds include
thiabendazole, imazalil, carbendazim and prochloraz.
The 1,2,4-triazole compound incorporates a five-membered diunsaturated
ring composed of three nitrogen atoms and two carbon atoms at non-adjacent
positions.
Preferred triazole compounds include a triazole compound selected from
compounds of formula (VI):
R C C R
(VI)
wherein R represents a branched or straight chain C alkyl group (e.g. t-
butyl) and R represents a phenyl group optionally substituted by one or more
substituents selected from halogen (e.g. chlorine, fluorine or bromine) atoms or C
alkyl (e.g. methyl), C alkoxy (e.g. methoxy), phenyl or nitro groups.
Alternatively, the triazole compound is advantageously selected from
compounds of formula (VII):
(VII)
7 6 8
wherein R is as defined for R above and R represents a hydrogen atom or
a branched or straight chain C alkyl group (e.g. n-propyl).
Particularly preferred triazoles include, but are not limited to, triadimefon,
triadimenol, triazbutil, propiconazole, cyproconazole, difenoconazole,
fluquinconazole, tebuconazole, flusilazole, uniconazole, diniconazole, bitertanol,
hexaconazole, azaconazole, flutriafol, epoxyconazole, tetraconazole, penconazole,
ipconazole, prothioconazole and mixtures thereof.
Particularly preferably the wood preservative formulation comprises a
biocidal copper ion. The biocidal copper may advantageously be incorporated into
the formulation in the form of inorganic copper salts, such as carbonate,
bicarbonate, sulphate, nitrate, chloride, hydroxide, borate, fluoride or oxide.
Alternatively, the copper may be in the form of a simple organic salt, such as
formate or acetate, or as a complex such as N-nitroso-N-cyclohexyl-hydroxylamine-
copper (copper-HDO) or copper pyrithione (bis(2-pyridylthio)copper 1,1'-dioxide,
CAS number 149158).
Preferably, the biocidal copper ion is a copper (II) ion. Preferred forms of
copper (II) include basic copper carbonate (CuCO .Cu(OH) ), copper (II) acetate,
copper (II) hydroxide, copper (II) oxide and copper (II) sulphate pentahydrate, with
basic copper carbonate being the most preferred. Preferred copper (I) compounds
that can be used are copper (I) oxide and copper-HDO.
Particularly preferred biocidal copper compounds are selected from basic
copper carbonate, copper (II) acetate, copper (II) sulphate pentahydrate, copper (II)
hydroxide, copper (II) oxide, copper (I) oxide, and copper-HDO.
In alternative preferred embodiments, the biocidal metal ion may be a
biocidal zinc ion. The biocidal zinc may advantageously be incorporated into the
formulation in the form of inorganic zinc salts, such as carbonate, bicarbonate,
chloride, hydroxide, borate, oxide or phosphate. Alternatively, the zinc may be in
the form of a an organozinc compound such as a simple organic salt, such as
formate or acetate, or as a complex such as N-nitroso-N-cyclohexyl-hydroxylamine-
zinc (zinc-HDO), zinc naphthenate or zinc pyrithione (bis(2-pyridylthio)zinc 1,1'-
dioxide - CAS number 134637).
Preferred zinc compounds include zinc oxide, zinc carbonate, zinc chloride,
zinc borate and zinc pyrithione, with zinc oxide, zinc carbonate and zinc borate
being the most preferred.
The metal is present in the formulation of the invention as a solubilised
metal ion. Suitable methods for solubilising metal ions such as copper and zinc are
known in the art, for example from WO93/02557. Suitable complexing agents for
the copper or zinc ion are ammonia; water soluble amines and alkanolamines
capable of complexing with copper or zinc cations; and aminocarboxylic acids such
as glycine, glutamic acid, ethylenediaminetetraacetic acid (EDTA),
hydroxyethyldiamine triacetic acid, nitrilotriacetic acid and N-dihydroxy ethylglycine.
Where the complexing agents are acidic in nature they may be employed either as
free acids or as their alkali metal or ammonium salts. These complexing agents
may be used either alone or in combination with each other. Preferred complexing
agents are selected from alkanolamines, such as monoethanolamine,
diethanolamine, triethanolamine, monopropanolamine, dipropanolamine, and
tripropanolamine. Ethanolamines are preferred, with monoethanolamine being
particularly preferred.
Formulations of the invention comprise a biocidal agent which is a copper or
zinc ion complexed with an amino compound selected from the group consisting of
ammonia, a water soluble amine or alkanolamine and an aminocarboxylic acid.
Preferred amino compounds are discussed herein and particularly preferred amino
compounds are ammonia, monoethanolamine and primary, secondary or tertiary
amines incorporating a C alkyl, preferably C alkyl, e.g. laurylamine or dimethyl
8-14 12
laurylamine.
Alternatively viewed, preferred formulations contain a zinc or copper
compound and an amino compound selected from the group consisting of
ammonia, a water soluble amine or alkanolamine and an aminocarboxylic acid.
The amino compound complexes with the metal ion to solubilise it.
In some embodiments, particularly where the formulation contains zinc, it
may be advantageous to have two solubilising and/or complexing agents, for
example an amino compound as discussed above and a gluconate salt such as
sodium gluconate.
Preferred wood preservative formulations of the invention are known as
alkaline copper quaternary systems, comprising a copper compound and a
quaternary ammonium compound, for example as defined above. Further preferred
wood preservative formulations contain an azole as defined above. More preferred
formulations contain a copper compound and a triazole, preferably together with an
alkanolamine. Particularly preferred formulations contain copper carbonate present
as an ethanolamine complex and tebuconazole, e.g. as sold under the Tanalith
brands.
Preferred cationic polymers for use in the formulations of the invention
include:
Poly vinyl formamides,
Poly amides,
Poly vinyl amides,
Polyamines, branched and linear, specifically polyamines derived from
epihalohydrin,
Poly vinyl amines (PVAm),
Poly DADMAC’s,
Poly allyl amines (PAAm),
Poly DADMAC Sulphones, and
Vinyl amine/ vinyl formamide copolymers.
Particularly preferred are polyvinylamines, poly DADMAC and poly
DADMAC-sulphone and polyamines (both high and low MW polyamines). Most
preferred is a polyamine, in particular a polyamine with a molecular weight of about
1,000 to 10,000, for example 2,000 to 4,000.
In some instances it is preferable to prepare the wood preservative
formulation from two or more products shortly before administration, thus in a
further aspect, the present invention provides a combined wood preservative
product comprising,
(a) a biocidal agent which is a copper or zinc ion complexed with an
amino compound wherein said amino compound is as defined according to any one
of claims 1, 6 or 7; and
(b) a cationic polymer as defined herein.
The product will typically contain a first compartment or container containing
a formulation comprising (a) and a second compartment or container containing the
polymer (b). The product may be supplied with written instructions for mixing and
diluting (in any order) the two parts.
The formulation or product is typically diluted prior to application to the
timber as an impregnation or treatment solution, the copper or zinc biocidal agent
containing part may be diluted first before addition of the polymer. Dilution is
preferably with water, e.g. at a ratio of water:concentrate v/v of 10:1 to 200:1,
preferably 20:1 to 100:1, more preferably 20:1 to 50:1.
The treatment solution will preferably contain 10 or 50 to 1000 ppm of
cationic polymer, more preferably 50 or 100 to 500 ppm (ppm = parts per million by
weight).
In a further aspect, the invention provides a method of preserving wood or
other cellulosic material which comprises applying to the wood or other cellulosic
material a formulation of the invention as described above or applying the individual
components to the wood/material such that the wood/material effectively receives a
formulation of the invention.
Reference to "individual components" is not to be understood as requiring
separate application of each active ingredient but as indicating that the whole
complement of active and other ingredients are not simultaneously applied. Thus,
the material is treated in such a way which means that it effectively receives a wood
preservative formulation of the invention.
Types of wood which can benefit from treatment with the formulations of the
invention include sawn timber, logs, glulam, plywood, laminated veneer lumber
(LVL), wood based composite products such as oriented strand board (OSB),
medium density fibreboard (MDF), fibreboard, hardboard and particle board.
It will be understood that "wood" in the context of this invention does not
encompass living trees or other plants.
Other cellulosic materials which can benefit from treatment with the
formulations of the invention are lignocellulosic substrates, wood plastic
composites, cardboard and cardboard faced building products such as
plasterboard, and cellulosic material such as cotton. Also, leather, textile materials
and even synthetic fibres, hessian, rope and cordage as well as composite wood
materials. For convenience, the invention is described with reference to the
treatment of wood but it will be appreciated that other cellulosic materials may be
treated analogously. The reference to treatment of "wood" or "timber" applies
mutatis mutandis to such substrates, unless it is clear from the context. Preferably,
though not exclusively, the formulations are applied to sawn timber, logs or
laminated veneer lumber, OSB or MDF. Most preferably, the formulations are
applied to unseasoned timber.
Conveniently, the formulations of the present invention are applied as a
liquid composition. They may also be applied as a solid implant or paste.
Preferably, the formulations are applied as a liquid composition, e.g. in the form of
an emulsion made up of solubilised liquid droplets. Preferably, the emulsions are in
the form of a micro-emulsion. The person skilled in the art of making emulsions
knows how to make an emulsion according to the invention by the use of suitable
solvents and emulsifying agents.
Preferably, when applied in liquid form, this is in an aqueous solution, but
one or more organic solvents or a mixture of water and an organic solvent could
also be used. Suitable organic solvents include both aromatic and aliphatic
hydrocarbon solvents such as white spirit, petroleum distillate, kerosene, diesel oils
and naphthas. Also, glycol ethers, benzyl alcohol, 2-phenoxy ethanol, methyl
carbitol, propylene carbonate, benzyl benzoate, ethyl lactate and 2-ethyl hexyl
lactate.
The application of these formulations may be by one or more of dipping,
deluging, spraying, brushing or other surface coating means or by impregnation
methods, e.g. high pressure or double vacuum impregnation into the body of the
wood or other material, all being techniques well known to the man skilled in the art.
Impregnation under pressure is particularly advantageous when the substrate is
wood or a wood composite material which is made to become wet during its life, for
example, wood for window frames, timber used above ground in exposed
environments such as decking and timber used in ground contact or fresh water or
salt water environments.
The formulations of the invention are preferably used in immersion
treatments of wood, in particular immersion treatments which utilise a vacuum
and/or pressure. Thus, in a further aspect, the present invention provides a wood
treatment system comprising a storage tank adapted to receive the wood to be
treated and in said tank a volume of treatment solution comprising a biocidal agent
comprising a copper or zinc ion as defined herein and a cationic polymer as defined
herein. Optionally the system further comprises an autoclave. Optionally the
system comprises means to apply a vacuum or pressure, e.g. 25-95% of a full
vacuum and 8-12 Bar pressure.
Substrates made of wood or cellulosic material which have been treated
with a formulation or product or by a method according to the invention as
described herein, comprise further aspects of the present invention. Additionally,
substrates made of wood or other cellulosic material containing a biocidal agent
comprising a copper or zinc ion as defined herein and a cationic polymer (e.g. a
formulation) according to the invention comprise a further aspect of the present
invention.
Also described is the use of formulations and products of the present
invention in the treatment or preservation of wood or other cellulosic material.
In yet a further aspect, the invention provides a method of making a wood
preservative formulation which comprises admixing a biocidal agent comprising a
copper or zinc ion as defined herein and a cationic polymer as defined herein.
As described above, the cationic polymers defined herein improve the
penetration of biocidal agents into the treated wood; thus in a further aspect, the
present invention provides the use of a cationic polymer as defined herein to
enhance the penetration into wood or other cellulosic material of biocidal agents
comprising a copper or zinc ion as defined herein which are co-administered to the
wood or other material in a method of preservation. "Preservation" (and preserving)
refers to the protection of wood or other material against fungal decay, borers and
termites. Also described is the use of a cationic polymer as defined herein to
ameliorate the impact on penetration into wood (or other cellulosic material) of
biocidal agents which is caused by anionic by-products and timber extractives, as
part of a method of preserving wood or other cellulosic material. Preferred methods
of application and biocides are described above.
The invention will now be further described with reference to the following
non-limiting Examples and Figures in which:
Figure 1 is a graph showing % gains in solution uptake achieved during
impregnation of a copper MEA solution into Pinus sylvestris with various cationic
polymer additives of the invention.
Figure 2 is a graph showing % gains in solution uptake achieved during
impregnation of a copper MEA solution into Pinus sylvestris with various
concentrations of a cationic polymer additive of the invention.
Figure 3 is a graph showing % gain in solution uptake achieved during
impregnation of a zinc/gluconate/MEA solution into Pinus sylvestris with a cationic
polymer additive of the invention.
Example 1
Materials and methods
An aqueous solution of copper 2 ions was prepared by reacting basic
copper carbonate with mono ethanolamine (MEA) to give a copper concentration of
%w/w and MEA concentration of 19.2%w/w, equivalent to an MEA:Copper molar
ratio of 4:1.
3%w/v aqueous solutions of the copper amine complex were prepared with
separate solutions dosed with 200ppm of the cationic polymeric additives of the
present invention. Additives 1 to 6 as incorporated are as follows:
Product
Physical Properties
Viscosity,
Additive Chemical Solution Approximate
CAS No. cps, 22°C
S.G., Freeze Flash
No. Group Strength, Mw
Sp 2, Sp 60
g/cm point, °C point, °C
Poly vinyl 913068
1 24 10 1,000-4,000* 4 - 6 1.12 - 1.14 < 0 N/A
amine 7
Low Mw Poly
2 259880 50 12 2,000-4,000* 4 - 7 1.12 - 1.16 -3 >100
amine
High Mw Poly 500,000-
3 259880 55 147 4 - 7 1.12 - 1.16 -3 >100
amine 1,000,000*
,000-
4 poly DADMAC 260623 40 45 3 - 4 1.1 -3 N/A
50,000
poly DADMAC
264706 40 6 4,000 3 1.14 -5 N/A
Sulphone
Poly allyl
6 305514 20 15 3,000 12 1.03 -5 N/A
amine
* are estimates based on viscosity
Additive 1
Polyvinylamine, CAS 9130687, 2-propenaminium, N,N-dimethyl-N
propenyl-, chloride (1:1), polymer with 2-propenamide, decarboxylated,
hydrochlorides
Additive 2
Polyamine, Poly(2-hydroxypropyldimethylammonium chloride) CAS 25988-
97-0, low MW
Additive 3
Polyamine, Poly(2-hydroxypropyldimethylammonium chloride) CAS 25988-
97-0, High MW
Additive 4
PolyDADMAC (Diallyldimethylammoniumchloride), CAS 260623
Additive 5
PolyDADMAC-Sulphone, CAS 264706
Additive 6
Polyallylamine, CAS 305514
The 3%w/v aqueous solutions of the copper amine complex containing
active substance were aged, to replicate commercial treatment plant solutions, by
the addition of Pinus Sylvestris sapwood sawdust, 3.5%w/v, and stirred for 1 hour.
The sawdust was filtered from of the aqueous the copper amine solution prior to
treatment of matched blocks being undertaken.
Sections of kiln dried Pinus Sylvestris (12cmx12cmx2.75cm) were then
impregnated with a 3%w/v solution of the copper amine complex, using a double
vacuum process.
Treatment Process:
Weigh timber sample prior to treatment.
Place timber sample in vacuum desiccator, apply vacuum to timber,
760 mm Hg, hold under vacuum for 20 minutes.
Flood vessel under vacuum.
Release vacuum, and soak at atmospheric pressure for 1 hour.
Remove sample from solution, remove residual surface solution,
then re-weigh timber sample.
Uptakes were determined and these expressed as a weight gain for the
timber section. Retentions were also calculated as Kg/m3, (Weight of treatment
solution per m3 of pine sapwood).
The depth of penetration was observed by cross cutting the samples and
spraying with a reagent that reacts with copper to generate a dark coloration (dark
blue to black).
Copper Spray reagent:
% Sodium acetate solution
0.5% Alcoholic Rubianic acid (Dithio-oxamide) solution
Dissolve 5g of sodium acetate in 100ml of deionised water.
Dissolve 0.5g of Rubianic acid in 100ml of ethanol or methanol.
The sodium acetate solution was sprayed onto a fresh cross cut face of
timber and then the Rubianic acid solution was sprayed onto the fresh cross cut
face of timber. The copper penetrated timber turns a dark blue to black colour
instantly.
Results
Chemical Pre Post Uptake % Uptake
Uptake/g
Group Treatment Treatment Kg/m vs no
Wt, g wt/g additive
No additive 162.83 225.85 63.02 204.0 0
Polyvinylamine 161.09 348.05 186.96 605.3 197
Polyamine 156.37 286.96 130.59 422.8 107
Polyamine 161.83 246.19 84.36 273.1 34
PolyDADMAC 156.46 295.36 138.9 449.7 120
PolyDADMAC- 158.29 282.61 124.32 402.5 97
Sulphone
Polyallylamine 158.62 243.70 85.08 275.4 35
For all products tested, gains in solution uptake (also reflected in the depth
of penetration of the preservative in the timber) increased ~20-200% vs a solution
with no additive. Results are also shown in Figure 1.
Example 2
The copper MEA solution, with 5%w/w copper concentration and an
MEA:Copper molar ratio of 4:1 was prepared in accordance with the method in
example 1.
Six 3%w/v aqueous solutions of the copper amine complex were prepared,
with separate solutions dosed with 0, 10, 20, 30, 50 and 200 ppm of the cationic
polymeric additive, additive no. 1 of the present invention, respectively.
The methods for aging the solution and treating matched blocks of Pinus
Sylvestris was in accordance with those given in example 1.
Results are shown in Figure 2.
Example 3
An aqueous solution of zinc ions was prepared by reacting zinc chloride
with sodium gluconate and mono ethanolamine to give a zinc concentration of
0.50%w/v and a Gluconate:Zn molar ratio of 2:1, and an MEA:Zn molar ratio of 2:1.
To separate aqueous solutions of the zinc gluconate/amine complex
prepared was dosed 0 and 200 ppm of the cationic polymeric additive, additive no.
1 of the present invention, respectively.
The methods for aging the solution and treating matched blocks of Pinus
Sylvestris was in accordance with those given in example 1.
Results are shown in Figure 3.
Claims (20)
1. A wood preservative formulation comprising a biocidal agent which is a copper or zinc ion complexed with an amino compound selected from the group 5 consisting of ammonia, a water soluble amine or alkanolamine and an aminocarboxylic acid, and a cationic polymer selected from the group consisting of: (i) a compound of formula (I) (CH )n (CH )n n (CH ) 10 (I) (ii) a compound of formula (II) (II) ; and (iii) a compound of formula (III) n (CH ) N(R )n (III) in which: n = 3 to 5000; n = 0, 1 or 2; n = 0 or 1; n = 2 or 3 and when n = 3 the nitrogen atom carries a positive charge and a 5 counter ion X is present; R groups, which can be identical or different, are hydrogen or a straight chain, branched or cyclic alkyl, alkenyl, alkynyl, alkanoxyl, aryl, -(C=O)H, -(C=O)R , -CO H -CO R , -CH CO H, -CH CO R , CH NR R , n 2 2 n 2 2 2 2 n 2 n n -(C=O)NR R , -CN, -(CH )n -O-R , in which; n n 2 4 n 10 R groups, which can be identical or different, are hydrogen or a straight chain, branched or cyclic alkyl, alkenyl, alkynyl, alkanoxyl or aryl; n = 2 or 3; R is of the formula (IV) H O H H R R R z z z b c d 15 (IV) in which; R = H or OH; a = 0 to 10; b = 0 or 1; 20 c = 0 to 10; d = 0 to 10; X is any anion selected from chloride, bromide, iodide, fluoride, sulphate, phosphate, carboxylate especially propionate and lactate, carbonate, bicarbonate, nitrate, nitrite, hydroxide, cyanide; and 25 * represents the bonds connecting the repeating units within the backbone of the polymer.
2. A wood preservative formulation according to claim 1, wherein the polymer has a molecular weight between 1,000 and 100,000.
3. A wood preservative formulation according to claim 2, wherein the polymer has a molecular weight between 1,000 and 50,000.
4. A wood preservative formulation according to any one of the preceding claims, wherein the formulation contains 0.01 to 4% by weight of the cationic 5 polymer.
5. A wood preservative formulation according to claim 4, wherein the formulation contains 0.1 to 1% by weight of the cationic polymer. 10
6. A wood preservative formulation according to any one of the preceding claims, wherein the amino compound is monoethanolamine or ammonia.
7. A wood preservative formulation according to any one of claims 1 to 4, wherein the amino compound is laurylamine or dimethyl laurylamine.
8. A wood preservative formulation according to any one of the preceding claims, further comprising an azole compound.
9. A wood preservative formulation according to any one of the preceding 20 claims, further comprising didecyl dimethyl ammonium chloride or carbonate.
10. A wood preservative formulation according to any one of the preceding claims, wherein the cationic polymer is selected from the group consisting of: poly vinyl formamides, 25 poly amides, poly vinyl amides, polyamines, poly vinyl amines (PVAm), poly DADMAC’s, 30 poly allyl amines (PAAm), poly DADMAC sulfones, and Vinyl amine/ vinyl formamide copolymers.
11. A wood preservative formulation according to claim 10, wherein the cationic 35 polymer is a polyamine, preferably with a molecular weight of 2,000 to 4,000.
12. A wood preservative formulation according to claim 11, wherein the cationic polymer is a polyamine, preferably with a molecular weight of 2,000 to 4,000. 5
13. A combined wood preservative product comprising (a) a biocidal agent which is a copper or zinc ion complexed with an amino compound wherein said amino compound is as defined according to any one of claims 1, 6 or 7; and (b) a cationic polymer as defined in any one of claims 1 to 12.
14. An aqueous wood preservative treatment solution comprising a wood preservative formulation as defined in claim 1 or claim 2 or any one of claims 6 to 11, said solution containing 10 to 1000 ppm of cationic polymer.
15 15. A wood preservative treatment solution according to claim 14, which contains 50 to 1000 ppm of cationic polymer.
16. A method of preserving wood or other cellulosic material which comprises applying to the wood or other cellulosic material a formulation or solution as defined 20 in any preceding claim or applying (a) a biocidal agent which is a copper or zinc ion complexed with an amino compound wherein said amino compound is as defined according to any one of claims 1, 6 or 7; and (b) a cationic polymer as defined in any one of claims 1 to 12; 25 to the wood/material such that the wood/material effectively receives a formulation as defined in any one of the preceding claims.
17. A wood treatment system comprising a storage tank adapted to receive the wood to be treated and in said tank a volume of treatment solution comprising 30 (a) a biocidal agent which is a copper or zinc ion complexed with an amino compound wherein said amino compound is as defined according to any one of claims 1, 6 or 7; and (b) a cationic polymer as defined in any one of claims 1 to 12.
18. A substrate of wood or other cellulosic material containing: (a) a biocidal agent which is a copper or zinc ion complexed with an amino compound wherein said amino compound is as defined according to any one of claims 1, 6 or 7; and 5 (b) a cationic polymer as defined in any one of claims 1 to 12.
19. A method of making a wood preservative formulation which comprises admixing: (a) a biocidal agent which is a copper or zinc ion complexed with an 10 amino compound wherein said amino compound is as defined according to any one of claims 1, 6 or 7; and (b) a cationic polymer as defined in any one of claims 1 to 12.
20. The use of a cationic polymer as defined in any one of the preceding claims 15 to enhance the penetration into wood or other cellulosic material of (a) a biocidal agent which is a copper or zinc ion complexed with an amino compound wherein said amino compound is as defined according to any one of claims 1, 6 or 7; and (b) a cationic polymer as defined in any one of claims 1 to 12 20 which is co-administered to the wood or other cellulosic material in a method of preservation. 25 Dated this 20 day of October 2015 Shelston IP Attorneys for: Arch Timber Protection Limited
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1119139.2 | 2011-11-04 | ||
GB201119139A GB201119139D0 (en) | 2011-11-04 | 2011-11-04 | Additives for use in wood preservation |
PCT/GB2012/000826 WO2013064798A1 (en) | 2011-11-04 | 2012-11-01 | Additives for use in wood preservation |
Publications (2)
Publication Number | Publication Date |
---|---|
NZ624081A NZ624081A (en) | 2015-12-24 |
NZ624081B2 true NZ624081B2 (en) | 2016-03-30 |
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