NZ620302B2 - A grinding tool for machining brittle materials and a method of making a grinding tool - Google Patents

Abstract

The specification relates to a grinding tool 1 for machining brittle materials. The grinding tool 1 has a core 2 and an abrasive rim 4. The abrasive rim 4 comprises abrasive particles 5 embedded in a matrix 6. The matrix 6 comprises a sintered bronze alloy. The alloy comprises 50 to 100% of the volume of the matrix. 0.02% -5.0 % by volume of the alloy is silicon nitride in the shape of grains having an average grain size which is between 1 ?m and 10?m. The invention also relates to a method of manufacturing the grinding tool. In the method, abrasive particles are mixed with metal powder and silicon nitride and the mixture is sintered. me of the matrix. 0.02% -5.0 % by volume of the alloy is silicon nitride in the shape of grains having an average grain size which is between 1 ?m and 10?m. The invention also relates to a method of manufacturing the grinding tool. In the method, abrasive particles are mixed with metal powder and silicon nitride and the mixture is sintered.

Description

A GRINDING TOOL FOR MACHINING BRITTLE MATERIALS AND A METHOD OF MAKING A GRINDING TOOL FIELD OF THE INVENTION The invention relates to a ng tool, in particular a grinding tool for grinding hard and/or brittle materials such as tungsten carbide. The grinding tool may in ular be a grinding wheel. The invention also relates to a method of making such a grinding tool.

BACKGROUND OF THE INVENTION Grinding tools such as grinding wheels are used for machining of brittle materials. One area where such grinding tools are used is machining of tools that are made of hard metal (tungsten carbide). For example, grinding tools may be used for machining ions in which drills or milling tools are shaped by grinding. If the work piece which is to be shaped is made of a hard material such as tungsten carbide, the ve tool must have abrasive particles of a very hard material. In practice, this normally means that the abrasive particles are diamond les or grains of cubic boron nitride.

Diamonds or cubic boron nitride grains for this purpose are commercially available and can be considered as rd components. Diamonds for this purpose may typically have an average or mean particle size of 50pm (the size of the particles is of course varying) and have a plurality of sharp edges that can cut hard materials such as tungsten carbide.

A known type of grinding tool for this purpose is a grinding wheel with a core which may be made of, for example, a metallic material such as steel or aluminum. The core may also be made of a non-metallic material such as a ric material. The core can be shaped as a disc which can be mounted on a tool spindle for rotation about the axis of the disc-shaped metal core. An abrasive rim surrounds the core and is joined to the core. The abrasive rim may se abrasive particles embedded in a matrix with one or more bonding agents. The material used in the abrasive rim is normally more ive than the material of the core. For this reason, the abrasive rim has a smaller extension in the radial direction than the core (i.e. the abrasive rim is normally a r part of the grinding wheel since it is more expensive).

During grinding, the abrasive rim is gradually worn down until it is consumed and the grinding wheel can no longer be used.

Known bonding agents for abrasive rims of grinding wheels include polymeric bonding agents such as, for example, Bakelite. Alternatively, the bonding agent may be a ceramic bonding agent. It is also known to use metallic bonding agents, in particular g agents of bronze that have been made by sintering. In such sintering operations, metal powder containing copper and tin is sintered er with abrasive particles such as diamond particles or grains of cubic boron nitride. Sometimes, silver can be added such that the bronze contains copper (Cu), tin (Sn) and silver (Ag). In the past, cal experience has showed that Cu/Sn/Ag alloys function well as bonding agents for abrasives and that such bonding agents function well during grinding. Although the precise reason for this is not entirely understood, it is believed by the ors that improved thermal conductivity caused by the addition of silver may explain why bronze alloys sing silver function well as bonding agents for abrasives. However, since silver is expensive, other bronze alloys may be used in order to reduce the cost and the present invention is applicable also to bronze alloys without silver.

Other known bronze compositions for this purpose e copper/tin/cobalt (Cu/Sn/Co) and /tin/nickel (Cu/Sn/Ni). It has also been suggested that bronze compositions for this purpose may include /tin/titanium (Cu/Sn/Ti).

Yet another known system includes hybrids of polymeric and metallic bonding agents in which metallic powder is sintered together with polymeric material such that a matrix is formed in which the polymeric bonding agent and the metallic bonding agent (typically a bronze alloy as described above) are closely intertwined with each other on a microscopic level. In such hybrids, the metal bonding agent and the polymeric bonding agent each forms a network and the respective networks of the bonding agents penetrate each other. Such a hybrid matrix that comprises both a metal g agent and a polymeric bonding agent is disclosed in for example US patent No. 6063148.

In addition to metallic and polymeric bonding agents, such hybrids normally include one or several flllers. One such flller may be graphite which is used for its lubricating properties.

The abrasive particles used may have ent ties. For example, the eness of diamonds may vary depending on the purpose for which the grinding tool is to be used. The properties of different diamonds may be matched to meet the properties of different g agents (or hybrids of bonding agents).

In a good grinding tool, the abrasive particles should be bonded in its matrix in such a way that the ng tool fiinctions as desired. It is desirable that the grinding tool have a good resistance to wear such that it can be used over an extended period. However, good wear resistance is not the only desired property and the grinding tool with the highest resistance to wear is not necessarily the best choice. Other desirable properties include low energy consumption (i.e. that the power required to drive the grinding tool is not excessively high) and constant or at least predictable mance properties. If the grinding effect of the abrasive rim varies too much over time, this causes problems.

This is especially the case if the performance of the ng tool varies in a way that is unpredictable.

The extent of wear of the grinding tool under given circumstances depends to a very high degree on the properties of the matrix in which the abrasive particles are embedded. Therefore, the ition of the matrix is important.

When a grinding tool is used for machining a work piece, sharp corners and edges on the abrasive particles act on the work piece. Thereby, force is exerted on abrasive particles embedded in the matrix. During the grinding, the abrasive particles are damaged. Gradually, small pieces break loose from the abrasive particles such that the abrasive particles are gradually worn down. When the abrasive particles in one area of the ve rim have been completely worn down, the work piece meets the matrix directly. The matrix as such is less hard than the work piece and it is quickly worn down. As a result, fresh abrasive particles come to the surface of the abrasive rim and can start to act on the work piece.

However, if the matrix that holds the ve particles is too weak, ve particles may be torn away from the matrix before they have been worn down. When this happens in part of the surface of the abrasive rim, the work piece will come into direct contact with the relatively brittle matrix and wear down the matrix prematurely. When this happens, power ption drops momentarily until so much of the matrix has been worn down that fresh abrasive particles come to the surface. As a result, the abrasive rim of the grinding tool is worn out faster than it would otherwise have been. If the ion of the grinding tool has been programmed in advance, the consequence thereof may be that the grinding operation does not function properly since the grinding tool is set to operate based on an tion of tool diameter that is now incorrect. This m becomes more serious if the abrasive rim is worn out in a way that is difficult to predict, for example if wear occurs in sudden steps that come in irregular intervals.

WO 15737 It is also desirable that the required power for the grinding operation can be kept low such that the energy consumption during grinding can be minimized.

Another desirable property of grinding tools is a high G—ratio. The G—ratio expresses the ratio between the volume of the al removed by the grinding tool from a work piece and the volume lost by the grinding tool (the wear on the tool). A good grinding tool has a high G—ratio.

Therefore, it is an object of the t invention to provide a grinding tool that has a good resistance to wear. Further objects of the invention are to provide a tool that is worn out in a r and predictable way, which has a low power requirement and a high G—ratio. These objects are ed by means of the present ion as will be explained in the following.

SUMIVIARY OF THE ION The invention relates to a grinding tool. The grinding tool is especially intended as a grinding tool for machining hard and/or brittle materials, such as tungsten carbide but the inventive grinding tool could also be used for grinding other materials. The grinding tool comprises a core and an abrasive rim. The abrasive rim comprises abrasive particles embedded in a matrix and the matrix comprises a metallic bonding agent which is a sintered bronze alloy. The metallic bonding agent constitutes 50 % - 100 % by volume of the matrix. According to the invention, the metallic bonding agent contains silicon nitride in an amount that constitutes 0.02 % - 5.0 % by volume of the ic bonding agent or optionally 0.1 % by volume — 5.0 % by volume of the metallic g agent.

In embodiments of the invention, the matrix may further optionally comprise a polymeric bonding agent that has been ed together with the metallic bonding agent such that the polymeric bonding agent and the metallic bonding agent form a connected network.

In embodiments of the invention, the silicon nitride constitutes 0.3 % - 5.0 % by volume of the ic bonding agent. For e, it may constitute 0.5 % - 5.0 % by volume of the metallic bonding agent, 1.0 % - 5.0 % by volume of the metallic bonding agent, or 0.5 % - 3.0 % by volume or 0.5 % - 2.0 % by volume.

The silicon e is present in the shape of grains having an average grain size which is less than 10μm but also above 1μm. Such particles may be 1250 Tyler mesh particles.

The particles may thus include particles up to 10μm even though average grain size is smaller.

When a polymeric bonding agent is part of the matrix, the polymeric bonding agent may comprise polyimide or be made entirely or almost entirely of ide.

The matrix may optionally additionally comprise filler materials such as graphite.

Graphite has lubricating properties which may be desirable during grinding.

The metallic bonding agent is preferably a bronze alloy that comprises copper, tin and silver.

The abrasive particles may be, for example, diamond particles or cubic boron nitride particles. For both diamonds and cubic boron nitride, the abrasive particles may have a mean particle size in the range of 4μm – 181μm. In many realistic embodiments, the ve particles may have a size in the range of 46μm – 91μm. In ments of the invention, the abrasive particles may have a coating of copper or nickel.

The invention also s to a method of making the inventive grinding tool comprising a core and an abrasive rim. The method comprises sintering ve particles together with metallic powder such that the sintering results in a matrix in which the abrasive particles are embedded. The matrix will thereby comprise a ic bonding agent. The metallic powder comprises copper and tin such that the metallic bonding agent will be a sintered bronze alloy. According to the invention, silicon nitride in the form of a powder is added to the ic powder before sintering and to such an extent that the silicon nitride will tute 0.02 % - 5.0 % by volume of the metallic bonding agent and preferably 0.1% - 5.0% by volume of the metallic bonding agent.

In embodiments of the inventive method, the metallic powder may additionally comprise silver.

When reference is made to the relative proportion of silicon nitride in the metal g agent, it should be understood that this refers to the volume proportion of the powder used in the manufacturing process. In other words, the method of manufacturing is such that, in the powder added before sintering, silicon e will constitute 0.02 % - 5.0% by volume of the metallic bonding agent (the n nitride being counted as part of the metal bonding . It is d that the silicon carbide particles will retain the same relative proportion of total volume also after sintering. ally, a polymer is added to the metallic powder before sintering, preferably in the form of polyimide powder, such that also a polymeric bonding agent is formed which is a part of the matrix.

The method may be carried out in such a way that the powder material for the bonding agents of the matrix is mixed with the abrasive les to form a mixture. The mixture is then compacted in a cold press. The compacted e is then cured in a kiln at a temperature in the range of380°C - 520°C, preferably 400°C - 500°C, for a period of 120 — 150 minutes. Thereafter, the compacted and cured mixture is placed in a press and subjected to a pressure of 1500 — 2000 kg/cmz. The pressure is then held until the mixture has reached a temperature below 300°C.

Optionally, filler material is added to the mixture of metallic powder and ve particles before the ing operation. The filler material may optionally comprise graphite.

The matrix of the inventive grinding tool may advantageously be a matrix which is a hybrid, i.e. a matrix having both a metal g agent and a polymeric bonding agent.

Hybrid bonding solutions can combine the best properties of metal bonding agents with the best properties of polymeric bonding agents. If re-sharpening by a sharpening tool is needed, a grinding tool with a hybrid matrix can be re-sharpened easier than a pure metal matrix. At the same time, a grinding tool with a hybrid matrix has better resistance to wear than a matrix using only a polymeric g agent.

BRIEF DESCRIPTION OF THE DRAWINGS Figure l is a schematic representation of a grinding tool.

Figure 2 is a schematic cross sectional representation of abrasive particles embedded in the abrasive rim of a grinding tool.

Figure 3 is a schematic cross sectional representation of a grinding tool that acts on a work piece.

Figure 4 is a diagram that represents the power consumption for two different grinding tools.

Figure 5 is a schematic cross sectional representation of a first embodiment of the inventive grinding tool.

Figure 6 is a schematic cross nal representation of a second embodiment of the inventive ng tool.

Figure 7 is a diagram that shows wear of a grinding tool as a function of n nitride content.

Figure 8 is a diagram that shows the G—ration of a grinding tool as a function of silicon nitride content.

DETAILED DESCRIPTION OF THE INVENTION With reference to Figure l, a grinding tool 1 is shown. The grinding tool may in particular be a grinding wheel which is intended for machining hard and/or brittle als such as tungsten carbide. Such materials may be present in work pieces for tools such as for e drills or milling tools and the grinding tool 1 of the present invention may be a grinding wheel that is used for shaping such tools. The grinding tool 1 comprises a core 2 and an abrasive rim 4. The core 2 may be made of a less expensive material such as steel or some other metal. Alternatively, the core could be made of, for example, a polymeric material. The core could also comprise more than one material.

For example, it could be made partially by metal such as steel or aluminum and partially be a polymeric material. The core 2 may be provided with a through-hole or cavity 3 such that the grinding tool 1 may be mounted on a spindle (not shown) for rotary movement. With nce to Figure 2, the abrasive rim 4 comprises abrasive particles 5 embedded in a matrix 6. The matrix 6 in turn comprises a ic bonding agent which is a sintered bronze alloy. The metallic bonding agent constitutes 50 % - lOO % by volume of the matrix 6 and embodiments are thus conceivable in which the entire matrix 6 is made up of the metallic bonding agent. r, the matrix 6 normally ses at least some other component. For example, it may comprise flller such as graphite that has lubricating properties. In most embodiments, the matrix 6 would also comprise a polymeric g agent that may be formed by polyimide.

If the matrix 6 holds the abrasive particles 5 well, the abrasive particles 5 will emit small fragments and be worn down gradually. As a , the wear on the abrasive rim 4 will be relatively slow such that the diameter of the grinding tool 1 can be kept substantially constant during a longer period. Moreover, wear on the abrasive rim 4 will be kept at an even pace and the power during operation will not vary so much.

If the matrix 6 is instead incapable of holding the abrasive particles 5 firmly, it may happen that abrasive particles come loose well before they have been fragmented. As a consequence, they will be lost before their entire abrasive potential has been used. The abrasive tool 1 will be worn out faster and the diameter of the grinding tool (such as a grinding wheel) will decrease faster. A smaller diameter of the grinding tool 1 may result in a less accurate machining of the work pieces.

With nce to Figure 3, a grinding tool 1 acts on a work piece 7. The work piece 7 may be, for example, a work piece that shall be shaped to a drill. The grinding tool 1 is rotated by means of a power source acting through for example a spindle (not shown). y, the abrasive rim 4 of the grinding tool acts on the work piece 7 to cut a groove in the work piece. In Figure 3, the work piece has a core diameter CD which is determined by the action of the grinding tool 1. If the grinding tool 1 is worn down such that its diameter decreases, the core diameter CD will grow unless the wear is compensated (for e by repositioning of the grinding tool 1 in relation to the work piece 7). It is ore very desirable that the wear can be kept low and that the wear that does take place does not come in sudden unpredictable leaps.

It can be added that, when the abrasive particles 5 are properly fragmented piece by piece, this is good for the free-cutting properties of the grinding tool 1, i.e. the ability of the grinding tool to re-sharpen itself. When the ve particles 5 become nted step by step, the wear on the matrix 6 can occur smoothly and the surface of the ve rim 4 does not become clogged so easily. If abrasive particles are instead torn away suddenly before they have been properly fragmented, this tends to lead to increased ng of the surface, the surface of the abrasive rim 4 may become clogged to a greater extent by small particles 5 from the work piece 7. This may necessitate temporary removal of the grinding tool 1 from operation such that the grinding tool 1 may be re-sharpened. If the ve particles 5 are gradually fragmented, the risk of such clogging is r. When abrasive particles have been completely worn out, new abrasive particles 5 may come to surface in a smoother process which in itself contributes to rpening of the grinding tool (or rather the abrasive rim 4 of the grinding tool 1).

When abrasive particles are torn away from the abrasive rim before they have been completely fragmented, this tends to show itself in the power consumption of the grinding tool, the power suddenly drops and then starts to rise again after a while. If the abrasive les are held properly by the matrix so that they are allowed to fragment as they should, also this can be seen on the power consumption. In such a case, the power tends to remain relatively nt over time (it should be noted, however, that there is normally always a gradual increase in the power requirement from the first work pieces such that less power is required for the very first work pieces).

It has been suggested in an article by E. D. Kizikov and P. Kebko (“Microaddilions l0 alloys ofthe system T1'”, Institute of Superhard Materials, Academy of Science of the Ukrainian SSR, Kiev, in translation from Metallovedenie I Termicheskaya Obrabotka Metallov, No. 1, pp 50 — 53, January 1987) that an alloy of Cu/Sn/Ti which is to be used as binder for diamond-abrasive tools be reinforced with 0.01% silicon nitride (Si3N4). According to the authors of that article, this addition resulted in improved yield strength.

The inventors of the present invention have considered what steps can be taken to e the ability of the matrix to hold the abrasive particles. Without g to be bound by theory, the inventors e that one reason that metal bonding agents e the abrasive particles embedded n may be that dislocations inside the metal g agent weaken the metallic bonding agent. Assuming this theory to be correct, the inventors first speculated that it should be possible to improve the matrix by reinforcing it with particles blocking dislocations in the metal bonding agent.

Consequently, the inventors tried different additions to the metal powder that was used for sintering the metal bonding agent. One additive that was tried was aluminum oxide which was added to an extent corresponding to 1.0 % by volume of the metal bonding agent. This resulted in a certain ement but the improvement was not as good as the inventors had hoped. The inventors also tried addition of 0.01 % by volume of silicon nitride. The improvement of that addition was even less than the ement achieved by the aluminum oxide.

The inventors then investigated whether increased amounts of silicon nitride would produce better results. This was confirmed in testes carried out by the inventors. When silicon nitride was added in quantities significantly larger than 0.01 % by volume of the metal g agent, it was discovered that a very substantial improvement was obtained.

For example, the inventors tested a composition in which the metal bonding agent ned 1.0 % by volume of silicon nitride (Si3N4). A grinding tool with this ition was then compared to a standard grinding tool using a hybrid matrix and 2012/050842 which did not contain n nitride (Si3N4). The grinding tools were both grinding wheels in which the abrasive rim 4 was shaped as a ring surrounding the core 2. Under comparable conditions, the diameter of the standard tool was worn down by 136um while the diameter of the ng tool with the experimental composition was worn down by only 58um. The G—ratio for the tool with 1.0 % silicon nitride was 2335. By ison, a tool using 0.01 % by volume of silicon nitride was worn down 94pm while a tool using 1.0 % by volume aluminum oxide was worn down 84pm.

A test was made with a composition where silicon nitride constituted 5 % by volume of the metal bonding agent. The resistance to wear was still good but not quite as good as for the ng tool with 1.0% by volume silicon nitride. Moreover, the tool with 5.0 % silicon nitride had higher power consumption. The G—ratio was good but not quite as good as for the tools with 1.0% and 0.1 % by volume.

The ors have also tested a grinding wheel which had a shape and a composition similar to the other tools tested but in which the silicon nitride tuted 0.1 % by volume of the metal bonding agent. It was found that, under the same test conditions as the other tools that were tested, the wear of the tool with 0.1 % by volume silicon nitride was 62pm and the G—ration was 2084. While this was inferior to the results obtained at 1 % by volume, it was still a very substantial improvement compared to the standard grinding tool.

The inventors have also tested a grinding wheel which had a silicon nitride content of 0.02 % by volume of the metal bonding agent but which was otherwise similar to the other grinding wheels tested. Under similar test conditions, the grinding wheel with 0.02 % by volume of silicon e has a wear (diameter ion) of 58um and a G—ratio of 2283. The results were thus slightly better than the results obtained at a ratio of 0.1 % by volume.

The results lead to the conclusion that significantly better results are obtained in the range of 0.02 % - 5.0 % by volume silicon nitride ). In this range, both G—ratio and resistance to wear has been found to be significantly better than at 0% or 0.01 %.

Tests of resistance to wear and test of G—ratio have been carried out at 0 % by volume, 0.01 % by volume, 0.02 % by volume, 1.0 % by volume and 5.0 % by volume silicon nitride.

The tools that were tested were grinding wheels of substantially the kind shown in Figure 5, i.e. grinding tools with an abrasive rim 4 that surrounds a core 2 and where the grinding tool 1 rotates about the axis A during ion. Resistance to wear as a function of n nitride content can be seen in Figure 7. The resistance to wear is expressed in Figure 7 as a resistance to diameter reduction. As can be seen in Figure 7, resistance to wear increased significantly when the content of silicon nitride was increased from 0.01 % to 0.02 %. The wear ance continued to be high up to a silicon nitride content of 5.0 % by volume of the metallic bonding agent. However, at .0 % by volume silicon nitride, the resistance to wear was somewhat lower compared to the ance observed at a content of 0.02 % - 1.0 %. The inventors have therefore concluded that the best wear resistance is obtained in the range of 0.02 % - 5.0 % by volume.

The G-ratio as a on of silicon nitride content can be seen in Figure 8. As can be seen in the figure, the best values are ed at a silicon nitride content in the range of 0.02 % - 5.0%. From Figure 8, it can also be derived that the G-ratio is sinking towards the right in the figure even though the G-ratio at 5.0% by volume is still good.

Therefore, the inventors have concluded that the metallic bonding agent may contain silicon e in an amount that constitutes 0.02 % - 5.0 % by volume of the metallic bonding agent. Since power ption was higher at 5.0 % by volume, the inventors have concluded that values lower than 5.0% will have good resistance to wear but lower power consumption compared to tools with a silicon nitride content of 5% by volume.

Therefore, a preferred range may be 0.02 % by volume to 3.0% by volume, 0.5 % - 3.0 % by volume, 0.5 % - 2.0 % by volume or 1.0 % - 2.0 % by volume of the metallic bonding agent.

At 0.1 % by volume, power consumption was generally lower than at 0.02 % by volume. At a silicon nitride of 5.0 % by volume, power consumption was higher than at a content of 0.02 % but the power consumption at 5.0 % by volume was more even, the power consumption was more predictable than at 0.02 % by volume.

The silicon nitride particles should preferably have a size up to 10μm (1250 Tyler mesh). For sieved particles, this will normally mean that e grain size is less than 10μm. The average le size (D50) of the silicon nitride particles may then be about 2μm - 3μm (depending on how average particle size is measured). The ic e area of the silicon nitride particles may advantageously be in the range of 5 m2/g – 6 m2/g. If the particles used are too small, this may result in clogging and difficulties 2012/050842 during manufacturing. Moreover, for giving zed strength to the metal bonding agent, it is believed by the inventors that particles up to lOum should preferably be included.

Normally, the matrix 6 should further se a polymeric g agent that has been sintered er with the metallic bonding agent such that the polymeric bonding agent and the metallic bonding agent form a connected k (even though such a polymeric bonding agent is optional). The use of a polymeric agent makes it possible to fine tune the ties of the matrix and adapt it to different kinds of abrasive particles.

The polymeric bonding agent may suitably be polyimide or comprise polyimide. The reason for this is that polyimide is heat resistant and can withstand the high temperatures during sintering. If a polymeric bonding agent is used, the ric bonding agent may be present in an amount of up to 50% by volume of the matrix (i.e. the amount of polymeric bonding agent is in the range of 0% - 50% by volume of the matrix). For example, the polymeric bonding agent may represent 10 % - 40 % or 10% - % by volume of the .

Possibly, the polymeric bonding agent could be formed by some other polymeric material. For example, it could be formed by polyamide-imide which is also capable of withstanding high atures. However, polyimide is preferred since it has better grinding ties than polyamide-imide.

The metallic bonding agent is a preferably a bronze alloy that comprises copper, tin and silver. Silver improves the desirable properties of the metal bonding agent.

The abrasive particles 5 may be either diamond particles or cubic boron nitride particles.

Diamonds are harder and have better abrasive properties but cubic boron nitride is more temperature resistant. Moreover, diamonds may react chemically with certain materials.

The abrasive particles 5 may be are diamond particles or particles of cubic boron nitride. The particles may be in the range of 4pm - 181 um even though particles outside this range may be considered depending on the requirements in each specific case. In many realistic embodiments, the abrasive les 5 may have a mean particle size in the range of 46pm — 91 um which is a range that is suitable for many grinding operations.

The abrasive les 5 may optionally have a coating of copper or nickel. A coating of copper or nickel can improve the bond between the abrasive particles 5 and the matrix 6. However, the abrasive properties of the particles 5 will be somewhat reduced if the particles have such a coating.

The relative proportion of abrasive particles 5 in relation to the bonding agents and fillers in the matrix 6 may vary depending on the requirements in each case. In many realistic embodiments, the amount of abrasive particles may represent a 10 % - 50 % of the total volume of the abrasive rim (i.e. the total volume of the abrasive particles and the ). If the relative proportion of ve particles is higher than 50 %, there is a substantial danger that the matrix will no longer be able to hold the ve particles. If the relative proportion of abrasive particles is less than 10 %, the grinding effect may become too small. The relative proportion of abrasive particles may ably be in the range of 15 % - 30 % and a suitable value may be 25 %.

The silicon nitride is present in the shape of grains having an average grain size which is equal to or less than 10μm but above 1 μm. For example, they may have a mean size in the range of 1μm - 10μm or 2μm - 9μm. It is ed by the inventors that n nitride particles smaller than 0.1μm may result in clogging of the silicon nitride particles which reduces their reinforcing effect.

The silicon nitride particles may have three different crystallographic ures designated as α, β and γ phases (also known as trigonal phase, hexagonal phase and cubic phase). The α and β phases are the most common. The γ phase can only be synthesized under high pressure and high temperature. Any of these phases can be used.

Preferably, the phase used is the α phase. The silicon nitride particles added may also be a mixture of particles of different .

With reference to Figure 4, a grinding tool according to the invention is compared with a standard grinding tool. The vertical axis represents power consumption while the horizontal axis ents number of work pieces upon which the respective grinding tool has acted. In Figure 4, B5 ents a grinding tool according to the invention while EZ represents a standard grinding tool. As can be seen in Figure 4, the tool represented as B5 has a power consumption that first rises steeply and thereafter remains substantially nt. The conventional tool as represented by EZ has a power consumption that rises steeply and then ly drops before it rises again. This indicates that the abrasive particles of the B5 tool are slowly fragmented while EZ represents a grinding tool where the abrasive les are suddenly torn away. The wear on the tool will therefore be faster.

It can be added that B5 represents a tool with both a metal g agent and a polymeric bonding agent. The metal bonding agent is a bronze that has copper, tin and silver. It has been sintered using a metal powder that ns 45 % by volume copper, 45 % by volume tin and 10 % by volume silver. In the tool according to B5, the polymeric bonding agent constitutes 1.0 % by volume of the total amount of bonding agent.

The grinding tool of Figure 1 may have a cross section as shown in Figure 5. In such an embodiment, the abrasive rim 4 is placed radially outside the core 2 such that the rim 4 completely surrounds the core 2. The tests explained with reference to Figure 4, Figure 7 and Figure 8 have been d out on such a grinding tool. However, the invention is not limited to such an embodiment. With reference to Figure 6, it should be understood that the core 2 may extend at least as much in the radial direction as the abrasive rim 4.

In Figure 6, the grinding tool has an abrasive rim 4 that does not extend beyond the core 2 in the radial direction. Instead, the abrasive rim 4 has an extension in the axial direction that is different from that of the core 2 (the axial direction being the axis of rotation A of the grinding tool 1 when it is driven by a spindle, see Figure 5 and Figure 6). It should also be understood that the grinding tool 1 is not arily ed for rotation. Instead, it could act on work pieces in a reciprocating movement. In the context of the claims, the term “core” should thus be understood broadly as any kind of carrier body for the ve rim. Likewise, the term “rim” should also be understood broadly as any kind of layer secured to the core 2 such that abrasive particles can act on a work piece.

The invention further comprises a method of making the ive grinding tool. The method comprises sintering abrasive les together with metallic powder that comprises copper and tin such that the sintering results in a matrix in which the abrasive particles 5 are embedded. The matrix comprises a metallic bonding agent which is a sintered bronze alloy. According to the invention, silicon nitride in the form of a powder is added to the metallic powder before sintering to such an extent that the silicon nitride will constitute 0.1% - 5.0% by volume of the metallic bonding agent.

The metal powder used is preferably metal powder with les that are smaller than 44pm but they should preferably be larger than the silicon nitride particles. Preferably 2012/050842 they should be at least twice as large. An average size in the range of 15um — 44um may be suitable.

The metallic powder may optionally also comprise silver.

The metal powder may come in the shape of loyed particles or as particles of pure copper, pure tin, pure silver etc.

A polymer may be added to the metallic powder before sintering, preferably in the form of polyimide powder, such that also a polymeric bonding agent is formed which is a part of the matrix 6.

The sintering method may be carried out such that the powder material for the bonding agents of the matrix 6 is mixed with the abrasive particles 5. The mixture is compacted in a cold press. Thereafter the compacted is mixture is cured in a kiln at a temperature in the range of380°C - 520°C, preferably 400°C - 500°C or 440°C - 460°C, for a period of 120 — 150 s. The time required depends on size. In a larger press form, more time is required. Thereafter (preferably immediately thereafter) the compacted and cured mixture is placed in a press and subjected to a pressure of 1500 — 2000 kg/cmz‘ The pressure is then maintained until the mixture has reached a temperature below 300°C.

For example, the ors have made ng tools according to this method in a process where the ature in the kiln was 450°C.

The ve rim 4 may also be manufactured by means of spark plasma sintering (SPS). By this technique, the abrasive rim 4 may be manufactured very fast.

The rim with the matrix containing ve particles may be sintered separately and subsequently fastened (e. g. glued) onto the core 2. Alternatively, the abrasive rim 5 may be sintered directly onto the core 2 such that it is bonded to the core as it is formed.

Before sintering, the core 2 may be electrolytically plated with copper on at least one surface of the core which will meet the abrasive rim 4. The abrasive rim 4 can then be sintered onto the copper-plated surface such that a seam is formed.

Filler material may optionally be added to the mixture of metallic powder and abrasive particles 5 before the sintering operation. As previously explained, the filler material may comprise graphite. Other possible filler als may include, for example, spheres of aluminum oxide.

Preferably, the bronze used in the metal bonding agent is selected from the group including copper — tin (Cu/Sn), copper — tin — cobalt /Co), copper — tin — nickel (Cu/Sn/Ni) or copper — tin — silver (Cu/Sn/Ag). Even more preferred, the bronze is a copper — tin — silver bronze. Other bronze alloys can also be considered.

The inventive grinding tool can be used for machining hard and/or brittle materials.

This does not exclude the ility that the grinding tool can be used also for other materials.

In embodiments of the ion, the matrix 6 may optionally also comprise at least one ceramic component in the shape of ceramic particles. The c component may be, for example, frit and contain SlOz. c particles for the matrix may be frit in the shape of cal particles having a particle size of 50pm - SOOum depending on the size of the abrasive particles. For larger abrasive particles, larger ceramic particles will be used. The abrasive particles may be embedded in the ceramic particles while the ceramic particles are embedded in a hybrid matrix with a ic bonding agent and a polymeric bonding agent. The ceramic particles may be held stronger by the matrix than the abrasive particles would be held. The free-cutting properties of the abrasive rim are thus improved. The ceramic component does not have such a good resistance to wear as the metallic g agent. By combining ceramics, metal and polymeric bonding agents, it is possible to combine the best properties of these bonding agents.

Claims (24)

1. A grinding tool for machining hard and/or brittle materials which grinding tool comprises a core and an abrasive rim, the abrasive rim comprising ve les embedded in a matrix, the matrix comprising a metallic bonding agent which is 5 a sintered bronze alloy, the metallic bonding agent tuting 50 % - 100 % by volume of the matrix, the metallic bonding agent containing silicon nitride in an amount that constitutes 0.02 % - 5.0 % by volume of the metallic bonding agent characterized in that the silicon nitride is present in the shape of grains having an average grain size which is n 1 µm and 10μm. 10

2. A grinding tool according to claim 1, wherein the silicon nitride is crystalline.

3. A grinding tool according to claim 1 or claim 2, wherein the matrix further comprises a polymeric bonding agent that has been sintered together with the metallic bonding agent such that the polymeric bonding agent and the metallic bonding agent 15 form a connected network.

4. A grinding tool according to any one of claims 1 – 3, wherein the silicon e constitutes 0.3 % - 5.0 % by volume of the metallic bonding agent.

5. A ng tool according to any one of claims 1 – 4, wherein the silicon nitride constitutes 0.5 % - 3 % by volume of the metallic bonding agent. 20

6. A grinding tool according to any one of claims 1 – 5, wherein the silicon nitride constitutes 0.5 % - 2 % by volume of the ic bonding agent.

7. A ng tool according to claim 3, wherein the polymeric bonding agent comprises polyimide.

8. A grinding tool according to any one of claims 1 – 3, wherein the matrix 25 additionally comprises filler materials.

9. A grinding tool according to claim 8, n the filler material is graphite.

10. A grinding tool according to any one of claims 1 – 9, wherein the ic bonding agent is a bronze alloy that comprises copper, tin and silver. 30

11. A grinding tool according to any one of claims 1 – 10, wherein the abrasive particles are diamond particles or cubic boron nitride particles.

12. A grinding tool according to claim 11, wherein the abrasive particles have a mean particle size in the range of 4μm - 181μm.

13. A grinding tool ing to claim 11 or 12, wherein the abrasive particles have a mean particle size in the range of 46μm – 91μm. 5

14. A grinding tool according to claim 12 or claim 13, wherein the ve particles have a coating of copper or nickel.

15. A method of making a grinding tool comprising a core and an abrasive rim, which method comprises ing abrasive particles together with metallic powder that comprises copper and tin such that the sintering results in a matrix in which the 10 abrasive particles are embedded, the matrix comprising a metallic bonding agent which is a sintered bronze alloy, characterized in that silicon nitride in the form of a powder is added to the metallic powder before sintering and to such an extent that the silicon nitride will constitute 0.02 % - 5.0% by volume of the metallic bonding agent and wherein the silicon nitride which is added is in the shape of grains having an average 15 grain size which is between 1 µm and 10μm.

16. A method ing to claim 15, n the silicon nitride is crystalline.

17. A method according to claim 15 or claim 16, wherein the metallic powder additionally comprises silver.

18. A method according to any one of claims 15 – 17, wherein a polymer is 20 added to the metallic powder before sintering.

19. A method ing to claim 18, wherein the polymer is in the form of ide powder, such that also a polymeric bonding agent is formed which is a part of the matrix.

20. A method ing to any one of claims 15 – 19, wherein the method 25 comprises; mixing the powder material for the bonding agents of the matrix with the abrasive particles; compacting the mixture in a cold press; curing the compacted mixture in a kiln at a temperature in the range of 380°C - 520°C, for a period of 120 – 150 minutes; thereafter placing the compacted and cured e in a press and subjecting it to a pressure of 1500 – 2000 kg/cm2; and holding the pressure until the 30 mixture has reached a temperature below 300°C.

21. A method according to claim 20, n the compacted mixture is cured at a temperature in the range of 400°C - 500°C.

22. A method according to any one of claims 15 – 21, n filler material is added to the mixture of metallic powder and abrasive particles before the sintering operation and wherein the filler material comprises graphite.

23. A grinding tool substantially as herein described or exemplified, with 5 reference to the accompanying gs.

24. A method according to claim 15, substantially as herein described or exemplified.