NZ619238B2 - Use of aldehyde scavengers in interior building products - Google Patents
Use of aldehyde scavengers in interior building products Download PDFInfo
- Publication number
- NZ619238B2 NZ619238B2 NZ619238A NZ61923812A NZ619238B2 NZ 619238 B2 NZ619238 B2 NZ 619238B2 NZ 619238 A NZ619238 A NZ 619238A NZ 61923812 A NZ61923812 A NZ 61923812A NZ 619238 B2 NZ619238 B2 NZ 619238B2
- Authority
- NZ
- New Zealand
- Prior art keywords
- ammonium
- building product
- interior building
- phosphate
- approximately
- Prior art date
Links
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title claims abstract description 35
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 20
- 239000010452 phosphate Substances 0.000 claims abstract description 20
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 19
- 238000009472 formulation Methods 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000002516 radical scavenger Substances 0.000 claims abstract description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 17
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims abstract description 16
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 14
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical group OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims abstract description 6
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims abstract description 6
- 229910000342 sodium bisulfate Inorganic materials 0.000 claims abstract description 6
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229940001584 sodium metabisulfite Drugs 0.000 claims abstract description 5
- 235000010262 sodium metabisulphite Nutrition 0.000 claims abstract description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims abstract description 4
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940080818 propionamide Drugs 0.000 claims abstract description 4
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000945 filler Substances 0.000 claims description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- GCBGNGBXQQLAFD-UHFFFAOYSA-N hexanedioyl diazide Chemical compound [N-]=[N+]=NC(=O)CCCCC(=O)N=[N+]=[N-] GCBGNGBXQQLAFD-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 3
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 235000010265 sodium sulphite Nutrition 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000012855 volatile organic compound Substances 0.000 description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- LQVXSNNAFNGRAH-QHCPKHFHSA-N BMS-754807 Chemical compound C([C@@]1(C)C(=O)NC=2C=NC(F)=CC=2)CCN1C(=NN1C=CC=C11)N=C1NC(=NN1)C=C1C1CC1 LQVXSNNAFNGRAH-QHCPKHFHSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- -1 dehyde Chemical class 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- NHWGPUVJQFTOQX-UHFFFAOYSA-N ethyl-[2-[2-[ethyl(dimethyl)azaniumyl]ethyl-methylamino]ethyl]-dimethylazanium Chemical compound CC[N+](C)(C)CCN(C)CC[N+](C)(C)CC NHWGPUVJQFTOQX-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/33—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by chemical fixing the harmful substance, e.g. by chelation or complexation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
Provided is a coating for application to the surface of an interior building product comprising a resin formulation, preferably including a melamine formaldehyde resin, and an aldehyde scavenger selected from the group consisting of: tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide, and a combination of a polyvinyl alcohol and adipic dihydrazide. xide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide, and a combination of a polyvinyl alcohol and adipic dihydrazide.
Description
USE OF ALDEHYDE SCAVENGERS IN INTERIOR NG PRODUCTS FIELD OF THE ION The present invention in general concerns coatings that are applied to interior building products, such as ceiling tile for example, wherein the coatings e an aldehyde ger that possesses the ability to tie-up any aldehydes, including formaldehyde, and/or other volatile organic compounds that may tend to be emitted from the basic or building products themselves and/or the coatings.
OUND OF THE INVENTION Many interior building products such as ceiling tiles, fiber panels and gypsum wallboard and other types of ard, for example, following their lation, can exhibit a tendency to emit aldehyde, including dehyde, vapors and/or other kinds of volatile organic compounds ("VOCs") to their surroundings. The sources of the aldehydes and other VOC’s may reside in the basic or building product itself or in coverings, coatings and other adjuncts applied to the basic interior building t.
The emission of the aldehydes and other VOCs can be undesirable and efforts can be undertaken to avoid their release into their surroundings because of their deleterious effects on human and animal health, as well as on the general comfort of humans and animals exposed to the emissions. In this regard, formaldehyde and certain other VOC’s that can be emitted fiom interior building products have been classified as cancer-causing agents.
Therefore, a need exists to l the emission of aldehydes, including formaldehyde, and other VOC’s from these interior building products. One method of doing so involves incorporating with the interior building products a substance that will tie-up the aldehydes and other VOC’s and prevent them from being released from the interior building products into the surrounding environment. Such substances can be incorporated into the interior building products either when the interior building products are ctured, at the time the interior building ts are installed or after the interior building products are installed for example.
One consideration in determining the suitability of any particular substance for the purpose of tying-up aldehydes and other VOC’s can be the effect the compo site that is formed as a result of the substance tying-up an aldehyde or another VOC has on the interior building 4246 product. That is to say that the composite should not adversely affect the physical or chemical properties or esthetic values of the interior building product.
SIJhdhdfidiHI()F'TIIEZIIJVHEIJII()}J As used herein the sion "aldehyde scavenger" is intended to refer to any substance used for the purpose of tying-up aldehydes and other VOC’s whether, for example, by covalent chemical bonding, ionic interaction, improved incorporation of the aldehydes and/or other VOC’s to the substrate at which the aldehydes and/ or other VOC’s are present, phase transformation, hydrogen bonding or otherwise.
According to one , the present invention concerns a coating for application to the surface of an interior building product, including a resin formulation characterized by its ability to strengthen the interior building product when d as a coating to the building product er with an aldehyde scavenger.
According to another aspect of the invention, the de ger is selected fiom the group consisting of; tetraethylene pentamine, namide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, um primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium ary phosphate and a sulfite, a polyvinyl alcohol, adipic azide and a combination of a polyvinyl alcohol and adipic dihydrazide.
In a fiarther aspect of the invention, the resin formulation includes a melamine formaldehyde resin and the aldehyde scavenger ses dually, or in combination, a polyvinyl alcohol and adipic dihydrazide.
In an additional aspect of the invention, the melamine formaldehyde resin formulation comprises by weight: approximately 10% to 20% of a melamine formaldehyde resin; approximately 20% to 60% of a calcium carbonate filler and approximately 0% to 10% of a clay filler; approximately 20% to 80% water; an ammonium chloride and/or magnesium catalyst; and sufficient defoamer to suppress the formation of any foam in the resin formulation. In a particular embodiment of this additional aspect, the melamine dehyde resin formulation comprises by weight: approximately 10% to 20% of a melamine formaldehyde resin; 4246 approximately 35% of a calcium carbonate filler and approximately 5% of a clay filler; and approximately 40% water.
In yet another aspect of the invention, the interior building product to which the coating is applied can comprise ceiling tile.
DETAILED DESCRIPTIONS OF EXAMPLES OF THE INVENTION Examples of embodiments that incorporate one or more aspects of the present invention are described below. These examples are not intended to be limitations on the present invention.
Thus, for example, in some instances, one or more examples of the present invention described with reference to one aspect or embodiment can be utilized in other s and embodiments. In addition, certain terminology is used herein for convenience only and is not to be taken as limiting the present ion.
The present invention has application to a variety of interior building ts including, for example, ceiling tiles, fiber panels and gypsum wallboard and other types of wallboard and ses coatings that are applied to at least one surface of the interior building products. In a particular employment of the invention, the coating is applied to the back of a ceiling tile; that is, the surface of the ceiling tile that is not exposed. In an embodiment of the invention, the gs include a resin formulation characterized by its ability to then the interior ng products when applied as a coating to the building products together with an aldehyde scavenger.
The coatings can be applied to the surface of the ceiling tiles by employing spraying techniques or rollers that hold the coatings, for example, and can be applied at the tion of the tile- cturing process, at the time the ceiling tiles are installed or following the installation of the ceiling tiles for example.
In an embodiment of the ion, the resin formulation includes a ne formaldehyde resin such as, for e, a butylated form of the resin that is ved in n- butanol and xylene and then cross-linked with alkyd, epoxy, acrylic and polyester resins. The melamine formaldehyde resin forms a hard covering on the ceiling tile and provides the ceiling tile with the strength ed for the ceiling tile to remain intact while being suspended from open gridwork typically installed at the ceilings of interior structures for e.
In a particular aspect of the present invention, the melamine formaldehyde resin can be included in a melamine formaldehyde resin formulation included in the coatings of the invention 4246 comprising by weight: imately 10% to 20% of the melamine formaldehyde resin; approximately 20% to 60% of a calcium carbonate filler and approximately 0% to 10% of a clay filler; approximately 20% to 80% water; an effective amount of an ammonium chloride and/or magnesium chloride catalyst; and sufficient defoamer to suppress the formation of any foam in the resin formulation. In an embodiment of this particular aspect of the invention, the melamine dehyde resin can be included in a melamine formaldehyde resin formulation comprising by weight: imately 10% to 20% of a melamine formaldehyde resin; approximately 35% of a calcium carbonate filler and approximately 5% of a clay filler; and approximately 40% water.
In addition to the resin formulation, the coatings of the present invention include an aldehyde scavenger. The primary function of the aldehyde scavenger is to tie-up any aldehydes and other VOC’s that may tend be emitted from the ceiling tiles lves and/or coatings applied to the ceiling tiles and t such aldehydes and other VOC’s fiom being emitted into the surroundings where the g tiles have been installed. The tying-up of any aldehydes and other VOC’s can occur, for example, as a result of covalent al bonding, ionic ction, improved incorporation of the aldehydes and/or other VOC’s to the ceiling tiles at which the aldehydes and/or other VOC’s are present, phase transformation, hydrogen bonding or ise.
When a formaldehyde resin formulation is employed in the coatings, typically the emission of aldehydes will arise from that formulation. However, the aldehydes and any other VOC’s that may tend to be emitted can arise from any of the components that go into the manufacture of the ceiling tile. The coatings, including the aldehyde scavenger, can be applied to the ceiling tiles either when the ceiling tiles are manufactured, at the time the ceiling tiles are installed or after the ceiling tiles are installed.
In accordance with one aspect of the invention, the aldehyde scavenger can comprise a scavenger selected from the group consisting of; thylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and um secondary phosphate, a combination of ammonium primary ate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol, adipic azide and a combination of a polyvinyl alcohol and adipic dihydrazide. In particular embodiments of the present invention, the aldehyde scavenger can comprise a polyvinyl alcohol such as Celvol® 2058 or Celvol® 2035 having a Chemical Abstracts Service registry number ("CAS Number") 4246 of 25213—24-5, adipic azide, and a combination of a polyvinyl alcohol such as Celvol® 2058 or Celvol® 2038 having a Chemical Abstracts Service ry number ("CAS Number") of 252135 and adipic dihydrazide.
While the present invention has been described above and illustrated with reference to certain embodiments thereof, it is to be understood that the invention is not so limited. In addition, modifications and alterations of the aspects of the invention described herein will occur to those skilled in the art upon reading and tanding the specification, including the drawings. The present invention is intended to cover and include any and all such modifications and ions to the described embodiments that are encompassed by the following claims.
Claims (9)
1. An interior building product including at least two exterior surfaces and a coating applied to at least one of the at least two exterior es, the coating comprising: a resin formulation ing a melamine dehyde resin characterized by its ability to strengthen the interior building product when applied as a coating to the building product; and an aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary ate, a combination of um primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl l; adipic azide and a combination of a polyvinyl alcohol and adipic dihydrazide.
2. The interior building product of claim 1 wherein the de scavenger ses a polyvinyl alcohol.
3. The interior building product of claim 1 wherein the de scavenger comprises adipic dihydrazide.
4. The interior building product of claim 1 wherein the melamine formaldehyde resin formulation ses by weight: approximately 10% to 20% of a melamine formaldehyde resin; approximately 20% to 60% of a calcium ate filler and approximately 0% to 10% of a clay filler; approximately 20% to 80% water; a st selected from the group consisting of; ammonium chloride, magnesium chloride and a combination of ammonium chloride and magnesium chloride; and sufficient defoamer to suppress the formation of any foam in the resin formulation.
5. The interior building product of claim 4 wherein the melamine formaldehyde resin formulation comprises by weight: approximately 10% to 20% of a melamine formaldehyde resin; approximately 35% of a calcium carbonate filler and approximately 5% of a clay filler; approximately 40% water.
6. The interior building product of claim 5 wherein the aldehyde scavenger comprises a polyvinyl alcohol.
7. The interior building product of any one of claims 1 to 6 wherein the interior ng t comprises ceiling tile.
8. The coating of claim 5 wherein the aldehyde scavenger comprises a combination of a polyvinyl alcohol and adipic dihydrazide.
9. An interior building product including at least two exterior surfaces and a component that emits one or more volatile organic nds that can be tied-up and prevented from being released from the interior building product by an aldehyde scavenger, a coating applied to at least one of the at least two exterior es, the coating comprising: a resin formulation including a melamine formaldehyde resin characterized by its y to strengthen the interior building product when applied as a coating to the building product; and an aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, um hydroxide, sodium bisulfate, sodium sulfite, um primary phosphate, ammonium secondary phosphate, a ation of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, um secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide and a ation of a polyvinyl alcohol and adipic dihydrazide.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161510109P | 2011-07-21 | 2011-07-21 | |
| US61/510,109 | 2011-07-21 | ||
| US13/490,595 | 2012-06-07 | ||
| US13/490,595 US20130023612A1 (en) | 2011-07-21 | 2012-06-07 | Use of aldehyde scavengers in interior building products |
| PCT/US2012/046985 WO2013012828A1 (en) | 2011-07-21 | 2012-07-17 | Use of aldehyde scavengers in interior building products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NZ619238A NZ619238A (en) | 2016-02-26 |
| NZ619238B2 true NZ619238B2 (en) | 2016-05-27 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9334410B2 (en) | Use of aldehyde scavengers in interior building products | |
| JP5270981B2 (en) | Formaldehyde scavenger and woody material using the same | |
| WO2008045500A2 (en) | Laminate fire retardant systems and uses | |
| US9249312B2 (en) | Eco-friendly water-based paint composition for interior finishing materials of buildings | |
| NZ619238B2 (en) | Use of aldehyde scavengers in interior building products | |
| JP2020509951A (en) | Composition and method for producing the same | |
| WO2007083578A1 (en) | Formaldehyde scavenger, deodorant composition, deodorant solution and wooden material | |
| JP2009023095A (en) | Method for producing wood board | |
| KR102103908B1 (en) | Natural water-based paint composition having flame-retardant and fire-retardant and preparing the same | |
| KR20190029827A (en) | Flame retardant epoxy flooring and waterproof composition | |
| KR101942559B1 (en) | A Method of Manufacturing Aggregate Panel Filled with Polyphenol Resin | |
| AU2003292252A1 (en) | Intumescent body | |
| EP0993938A1 (en) | Backer Laminate | |
| RU2198193C2 (en) | Fire-retardant foaming coating composition | |
| JP2005023673A (en) | Outgas suppressing method | |
| US20210189153A1 (en) | Improved apparatus and uses and methods relating thereto | |
| WO2015020510A1 (en) | Ecological, corrosion-resistant, water-based fireproof coating with resistance to the elements | |
| JP2021102673A (en) | Water-based wood coating for exterior facing | |
| JP2009220518A (en) | Coated metal plate | |
| GB2407832A (en) | Fire resistant wall material | |
| JP2005066903A (en) | Sawn wood product or woody material suppressing dissipation of acetaldehyde and its manufacturing method | |
| TH90896B (en) | Thermosetting agent for the primary coating and the pre-coated metal plate. | |
| JPH1142603A (en) | Manufacture of wood board | |
| WO2015051062A1 (en) | Coatings for attenuating ionizing radiation, coated substrates and associated methods |