NZ617527B2 - Functionalized polyorganosiloxanes or silanes for treating lignocellulosic materials - Google Patents

Abstract

Disclosed are functionalized polyorganosiloxanes or silanes containing 2-30 siloxy units of formula Q, T, D or M, wherein the substituents are as described in the specification. The polyorganosiloxanes or silanes are used in a single process step for the treatment of lignocellulosic materials (materials based on cellulose and/or lignin) to protect them against weather conditions, microorganisms, insects, and fungi. ials based on cellulose and/or lignin) to protect them against weather conditions, microorganisms, insects, and fungi.

Description

Functionalized polyorganosiloxanes or silanes for treating lignocellulosic als The present invention relates to functionalized polyorganosiloxanes or s for the treatment of lignocellulosic materials that are suitable to preserve wood and other materials based on cellulose and/or lignin, and particularly to protect them against weather conditions, microorganisms, insects and fungi. Furthermore, the water absorption of lignocellulosic materials, particularly wood, is increased, the shrinkage or of lignocellulosic materials, particularly wood, is improved, by the use of the ganosiloxanes or silanes according to the present invention.

Furthermore, by using the polyorganosiloxanes or silanes of the present invention an icidal equipment can be achieved, which makes the use of conventional insecticides unnecessary.

It is known to increase the resistance of wood against weather conditions by a coating of lacquer and color paints. Dimensional changes of the wood, for e caused by swelling and age due to water absorption or release, caused by external humidity changes, nevertheless lead to peeling of such paints.

It is further known, to protect the optical appearance and the resistance of wood against harmful rganisms, for example blueing fungi or white rot, brown rot and soft rot, by an impregnation with a mixture of arsenic, ionic copper and chromium VI.

Such wood preservatives are disadvantageous for the reason that at least chromium and arsenic are l and toxic for the environment. Even copper complexes and boron compounds are now seen as critical under the same aspects.

Furthermore, soluble wood preservatives are known which comprise a quaternary ammonium compound such as for example benzalkonium chloride. Such wood preservatives are disadvantageous as they are deposited only in the upper layers of the wood due to their immediate bonding to wood. r biocidal actives are 3-iodopropynyl butyl carbamate (IPBC) or triazoles (propiconazole, tebuconazole).

The known c wood preservatives are used in the application categories 1, 2 and 3 according to DIN EN 351 and do not lead to hydrophobing (10903736_1):MGH the wood so that the tendency of the wood to absorb water and therewith the dimensional stability remain unchanged.

To reduce the water absorption of wood, essentially compounds based on oils, fats and waxes (paraffins and silicones) were used.

Known wood preservatives, which are used for hydrophobing and which have a t of silicon nds, are known too. Thus, JP 48567 A describes wood preservatives, which consist of a mixture of different alkoxysilanes, including amino group containing alkoxysilanes and boric acid.

US 6294608 discloses aqueous emulsions for treating mineral construction materials and wood with a mixture of silanes which have alkyl and alkoxy groups or aminoalkyl groups. Polysiloxane compounds are not disclosed.

EP 0716127 discloses polyorganosiloxanes as well as aqueous mixtures thereof, which are particularly used for hydrophobing surfaces, e.g. in the impregnation of leather and textiles made from natural and/or artificial materials and in the field of organic and mineral construction als as well as building tion.

EP 8 discloses aminoalkyl alkoxysilanes which can be used among others for hobing cellulose products or as additives for paints and lacquers. Polyorganosiloxanes are not disclosed therein. 2O US 2002/0026881 describes a composition for hydrophobing surfaces which contains silicone among others.

US 4757106 discloses the combination of aminoorganosiloxanes with basic nitrogen ts of >0.5 % with siloxanes with a molecular weight of > 620 g/mol in substantially solvent-free formulations as equipment for l substrates.

DE 3447636 discloses the combination of aminoorganosiloxanes with basic nitrogen contents of >0.5 % with a second amino ne with basic nitrogen content of 0 to 0.5 % and ally a siloxane with molar masses <600 g/mol in the presence of solvents. 3O EP 0621115 and DE 4241727 disclose the combination of aminoorganosiloxanes with basic nitrogen contents of >0.5 % with repellent agents, e.g. siloxanes, optionally in the presence of a second compound with basic nitrogen in contents of 0 to 0.5 % for the treatment of wood.

DE10 2004 036918 proposes the use of aminoorganosiloxanes in wood preservatives. The siloxanes shall have a molecular weight of 500 to 0 g/mol and the degree of substitution of the siloxane units with amino groups shall be up to 50 %.

DE 4202320 describes the impregnation of wood with a non-functionalized polydimethylsiloxane by using supercritical carbon dioxide as a carrier medium. The disadvantage of this proposal is that the non-functionalized polydimethylsiloxane can be d from the wood.

EP 680810 describes the modification of wood by acetylation with acetic anhydride at elevated temperatures. The disadvantage of this procedure is an insufficient reduction of the water uptake of the modified wood.

The disadvantage of all of the above tions is that a long-lasting tion of wood in practice can only be achieved with a two-stage treatment of the wood so far. In the so-called Royal s the wood is first impregnated in a first step with an c copper salt (Cu-HDO) or an organic copper salt, and subsequently in a second step an impregnation with oil is carried out to prevent the leaching of the biocidal copper. nes having hydrolysable groups tend to condensation after contact with water and acids or bases, which s solubility, emulsifying capacity and penetration capacity of the wood. Impregnation with nes as disclosed in DE 10 2004 036918 is not long-lasting, as these siloxanes can be ed again after prolonged exposure to water.

The present invention therefore relates to impregnating wood long-lasting in a practicable one-step method, and thereby further reduce the tendency of wood to absorb water, to improve the dimensional stability in changing humidity conditions of the environment and to reduce the degradation of the wood by fungi, bacteria and insects, such as wood destroying insects, for example termites, house longhorn beetle, common furniture beetle, powder post beetle, effectively. At the same time yellowing and graying of the woods due to light and weather impact shall be ssed.

In a first aspect, the present invention provides use of polyorganosiloxanes or silanes for the treatment of ellulosic materials, characterized in that the polyorganosiloxanes are straight-chained, branched or cyclic polyorganosiloxanes, formed from a number average of 2 to 30 siloxy units, which are selected from the group consisting of AH26(11521684_1):EOR O R1 R1 R1 O Si O O Si O O Si O O Si R1 1/2 1/2 1/2 1/2 1/2 1/2 1/2 O O R1 R1 1/2 1/2 (Q) (T) (D) (M) - wherein the radicals R1 represent organic radicals as defined below, which may be the same or different, with the proviso that at least one of the radicals R1 is an organic radical RF, containing a functional group F, which is selected from the group of functional groups consisting of - an acyloxy group Si-bonded via O, and - optionally ed from the group of functional groups consisting of: - phosphonium group, - ine group, - epoxy group - carbonate group, - urethane group, - isocyanate group including blocked isocyanate group, - urea group, - amido group, - aldehyde group, - hemiacetal and acetal group, - enamine group, - imine group, - zwitterionic group, - carboxylic acid / ylate group, - sulfonic acid / sulfonate group, - sulfuric acid half-ester / te group, - phosphoric ester / phosphate group - phosphonic ester / phosphonate group, AH26(11521684_1):EOR - phosphorous ester / phosphite group, - xanthate / genate ester group, - organo amino group Si-bonded via N, - y group, - alkoxy group Si-bonded via O, and - lfato group and characterized in that the silanes are represented by the formula (I) Si (R1) 4 (I) wherein the radicals R1 are as defined below, with the proviso that at least one of the radicals R1 is a radical RF containing a functional group F, which is as defined above, and at least one of the radicals R1 is bonded to the silicon atom via a hetero atom and at least one of the radicals R1 is bonded to the n atom via a carbon atom, or by the formula (II) (R1) 3 Si R3 Si (R1) 3 (II) wherein R1 is the same or different and has the meaning as defined for formula (I), and R3 is a divalent, ht-chained, branched, cyclic, aliphatic, unsaturated, or aromatic hydrocarbon l having up to 30 carbon atoms, which may contain one or more groups selected from -O-, -NR4-, wherein R4 is hydrogen or C1alkyl, - C(O)- and -C(S)-, and which may optionally be substituted by hydroxy and is bonded to the silicon atom via carbon, and salts thereof, and wherein the substituents R1 are selected from the group consisting of: straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals having up to 100 carbon atoms, which may optionally contain one or more groups selected from –O–, (10903680_1):MGH –S–, –NR2–, wherein R2 represents hydrogen, a monovalent straight- chained, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 60 carbon atoms, which may contain one or more groups selected from -O-, -S-, -NH-, -C(O)- and -C(S)-, and which may optionally be substituted by one or more substituents selected from the group consisting of a hydroxyl group, an optionally tuted cyclic group, amino, alkylamino, dialkylamino, ammonium, her radicals and polyether ester ls, wherein in case that multiple groups -NR2 are present, these may be the same or different, R2 , wherein R2 is as defined above, P(R2) 2 , wherein R2 is as defined above, –C(O)– and –C(S)–, (10903680_1):MGH and may be substituted by one or more radicals selected from the group consisting - hydroxyl, - mercapto (-SH or-S-), - isocyanato, - halogen, - a polyether l having up to 60 carbon atoms, which may optionally contain one or more amino, mono- or dialkylamino, or arylamino groups, - a saccharide-containing organic radical, or two substituents R1 from different siloxy units together form a straight-chained, ed or cyclic alkandiyl radical having 2 to 20 carbon atoms between two silicon atoms, which is ally interrupted by -O-, -S-, -C(O)-, -NH- and is optionally tuted by OH, wherein the bonding to silicon may be via a carbon atom and/or a heteroatom and, wherein said treatment comprises coating or impregnating said lignocellulosic material with said polyorganosiloxanes or silanes .

In a second aspect, the present invention provides use of a composition sing at least one polyorganosiloxane and/or silane, as defined in the first aspect, and at least one solvent and/or at least one biocidal agent for the treatment of lignocellulosic als.

In a third aspect, the present invention es a composition comprising a) at least one polyorganosiloxane and/or silane as defined in the first aspect, having a functional group F selected from the group of the acidic functional groups: - carboxylic acid/carboxylate group, b) at least one polyorganosiloxane and/or silane having a basic functional group selected from amino groups, ammonium groups, phosphonium groups and phosphine groups. 11822965v2:gcc In a fourth aspect, the present invention es a process for treating lignocellulosic material, comprising the treatment of the lignocellulosic material with at least one polyorganosiloxane or silane, as defined in the first aspect, or a ition as defined in the second or third aspect, by surface treatment, immersion treatment, or vacuum or pressure impregnation.

In a fifth aspect, the present invention provides use of a composition as defined in the second or third aspect for the treatment of lignocellulosic material and, wherein said treatment comprises coating or impregnating said lignocellulosic material with said polyorganosiloxanes or silanes.

In a sixth aspect, the present invention provides use of at least one polyorganosiloxane and/or silane, as defined in the first aspect, or a composition as defined in the second or third aspect for repelling es with or without additional insecticides for combating termites.

In a seventh aspect, the present invention provides lignocellulosic material, comprising at least one ganosiloxane and/or silane, as defined in the first aspect.

In an eighth aspect, the present invention provides lignocellulosic material, comprising a composition as defined in the second or third aspect.

The t invention relates to polyorganosiloxanes and s for the treatment of lignocellulosic materials, in particular wood and other lignocellulosic materials, to se their ance, for example against microbial degradation or degradation caused by fungi and/or weather ions such as sunlight (UV rays), rain and other ional variations of humidity. The Polyorganosiloxanes 11822965v2:gcc or silanes used in the present invention serve for use as a protective agent for Iignocellulosic materials against weather impact, fungi, es and insects.

Furthermore, the use of the ganosiloxanes or silanes in ance with the present ion leads to an improvement of the properties such as shrinkage and swelling of wood or Iignocellulosic materials by treating the Iignocellulosic materials therewith. in a further aspect, the t ion relates to Iignocellulosic materials, in particular wood, which has been treated with the polyorganosiloxanes and / or silanes used according to the present invention.

The polyorganosiloxanes and / or silanes used in the present invention may in particular be used for the treatment of Iignocellulosic materials such as wood and wood products, particleboards, medium density fiberboards, oriented beach boards (088), paper, cardboards, insulation boards based on Iignocellulose, plywood, veneers and packaging material with a content of biodegradable compounds (hereinafter tively referred to as "Iignocellulosic materials"). The ganosiloxanes and / or silanes used in the present invention further have a high resistance to leaching after nation.

As a further advantage the polyorganosiloxanes and / or silanes used in accordance with the present invention permit application, such as e.g. by impregnation, in a single process step. Surprisingly, the desired improvement is possible with n organo-functional radicals in short-chain ganosiloxanes or s. Amino-functionalized silicones are primarily not required.

The present invention thus relates to polyorganosiloxanes or silanes for the treatment of Iignocellulosic materials, characterized in that the polyorganosiloxanes are straight-chained, branched or cyclic polyorganosiloxanes, formed from a number average of 2 to 30 siloxy units, which are selected from the group consisting of: 01/2 I. 1'21 Ill 1T1 . . —OU§SI—R1. —o—Sl—ol/7 —01—/381—01/—2— —ol—/Esl—ol—E | | I l (Bl/2 $1/2 R1 R1 (Q) (T) (D) (M) wherein the radicals R1 represent organic radicals, which may be the same or different, with the proviso that at least one of the radicals R1 is a radical RF containing a functional group F, which is ed from the group of functional groups consisting of: - phosphonium group, - epoxy group - carbonate group, - urethanegroup, - nate group including blocked isocyanate group, - urea group, - amido group, - aldehyde group, - hemiacetal and acetal group, - an enamine group, or - imine group, - a zwitterionic group, - carboxylic acid / carboxylate group, - sulfonic acid / sulfonate group, - sulfuric acid half-ester/ sulphate group, - phosphoric ester/ phosphate group - onic esters / phosphonate group, - phosphorous ester / phosphite group, - xanthate / xanthogenate ester group, - organo amino group Si-bonded via N, - y group, - acyloxy group Si-bonded via 0, - alkoxy group Si-bonded via 0, and - thiosulfato group and terized in that the silanes are represented by the formula (I) SI._(R )4 wherein the radicals R1 are as defined above, with the proviso that at least one of the radicals R1 is a radical RF ning a functional group F, which is as defined above, and at least one of the ls R1 is bonded to the silicon atom via a hetero atom and at least one of the radicals R1 is bonded to the silicon atom via a carbon atom, or by the formula (II) (R1)3—Si—R§-Si—(R1)3 (II) wherein R1 is the same or different and has the meaning as defined for formula (I), and R3 is a divalent, straight-chained, ed, cyclic, aliphatic, unsaturated, or aromatic hydrocarbon radical having up to 30 carbon atoms, which may n one or more groups selected from -O-, -NH-, -C(O)- and , and which may optionally be substituted by hydroxy and is bonded to the silicon atom via carbon, and salts thereof.

Preferably, the group of functional groups consists of: - phosphonium group, — phosphine group, - epoxy group - carbonate group, - urethane group, - isocyanate group including blocked isocyanate group, - urea group, - amido group, - aldehyde group, - an enamine group, - a zwitterionic group, - ylic acid / carboxylate group, - sulfonic acid / sulfonate group, - sulfuric acid half-ester/ sulphate group, - phosphoric ester / phosphate group - phosphonic acd esters / phosphonate group, - phosphorous ester/ phosphite group, - xanthate / xanthogenat ester group, — organo amino group Si-bonded via N, - acyloxy group ded via 0, - alkoxy group Si-bonded via 0, and - thiosulfato group.

The polyorganosiloxanes and silanes of the present invention are in ular characterized in that the radicals R1 are selected from the group consisting of RF and RN, wherein the radicals RF are such radicals R1 which have the mentioned functional groups F and wherein the radicals RN are such radicals R1 which do not have the above functional groups F.

In a preferred embodiment of the ion, the polyorganosiloxanes used in the present invention have a molar t of the radicals RF, which comprise at least one functional group F, from 3.33 to 100 mol-%, based on the number of siloxy units. More preferably this content is from 5 to 100%, even more preferred to 50%, even more preferred 10 to 50% and most preferred 10 to 30 mol-%.

The polyorganosiloxanes used in the present invention suitably have a molar content of branched radicals T and Q of 0 to 50%, preferably 0 to 20%, more preferably 0 to 10%, especially 0 to 5%, very especially 0%, based on the total number of siloxy units .

The polyorganosiloxanes used in the t invention suitably have an average number of siloxy units (number of silicon atoms) of 2 to 30. The average number of siloxy units in the polyorganosiloxanes used in the present ion is for example determined by gel permeation chromatography (GPC) after appropriate calibration, particularly with polystyrene as standard. ably, the average number of siloxy units is 2 to 20, more ably 2 to 15, even more preferred 2 to 12, even more red 2 to 7. it is within the scope of the present invention to use mixtures of the polyorganosiloxanes used in the present invention with one another, as well as mixtures of polyorganosiloxanes used in the present invention with silanes. When using mixtures of polyorganosiloxanes bi-, tri- and higher modal butions are formed. In this case, binary mixtures with a bimodal distribution are preferred. A preferred ment is then the use of mixtures of short chain polyorganosiioxanes having an average of 2 to 15 siloxy units and long-chain polyorganosiioxanes having 16 to 30 siloxy units. The use of such mixtures is advantageous in that in the lignocelluiosic materials different sites of action are operated. Thus, the long-chain polyorganosiioxanes are preferably located in the ellular spaces (Iumens) while the short-chain polyorganosiioxanes are more accumulated in the cells or cell walls. Overall this leads to a higher active penetration and concentration, and thus an improved effect is achieved.

The functional groups F of the polyorganosiioxanes or silanes used in the t invention serve both to improve the solubility of the polyorganosiioxane or silanes in the preferably aqueous formulation, on the other hand to the ing of the polyorganosiioxanes or silanes in the lignocelluiose materials, in particular in the cells and cell walls of the mentioned materials, particularly for increasing the dimensional stability of the materials or of the shrinkage or in the presence of swelling ts, in particular humidity. From these points, the following functional groups F are ularly suitable: - epoxy group, - carbonate group, - isocyanate group including blocked isocyanate group, - xanthate / Xanthogenat ester group, - organo amino group Si-bonded via N, - y group Si-bonded via 0, — alkoxy group Si-bonded via 0, and - thiosulfato group.

The c substituents R1 of the polyorganosiioxanes or silanes used in the present invention are suitably selected from the group consisting of: straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals having up to 100 carbon atoms, which may optionally contain one or more groups selected from _O_’ _s_, —NR2—, wherein R2 ents hydrogen, a lent straight- chained, cyclic or branched, saturated, unsaturated or ic hydrocarbon radical having up to 60 carbon atoms, which may contain one or more groups selected from -O-, -S-, -NH-, -C(O)- and -C(S)-, and which may optionally be substituted by one or more substituents selected from the group consisting of a hydroxyl group, an optionally substituted heterocyclic group, ably containing one or more nitrogen atoms, amino, alkylamino, dialkylamino, ammonium, polyether radicals and polyether ester radicals, wherein in case that multiple groups -N R2 are present, these may be the same or different, may comprise , wherein R2 is as defined above, _P<R )2 , wherein R2 is as defined above, —C(O)— and -C(S)-. and may be substituted by one or more radicals selected from the group consisting of: - hydroxyl, - mercapto (-SH or-S'), - isocyanato, - halogen (such as chlorine, fluorine), - a polyether radical having up to 60 carbon atoms, which may optionally n one or more amino, mono- or dialkylamino, or arylamino groups, - a saccharide-containing organic radical, or two tuents R1 from different siloxy units together form a straight-chained, branched or cyclic alkandiyl radical having 2 to 20 carbon atoms between two silicon atoms, which is ally interrupted by -O-, -S-, -C(O)—, -NH- and is optionally substituted by OH, wherein the bonding to n may be via a carbon atom and / or a heteroatom.

As mentioned above, these radicals R1 are selected from the group consisting of the radicals RF and RN, wherein the radicals RF are radicals R1 having the mentioned functional groups F and the radicals RN are radicals R1 not having the ned functional groups F.

Preferably, the radicals R1, R2 and R3 in the polyorganosiloxanes or silanes used in the present invention, including RF and RN, have no amino groups. Except for such amino group-containing radicals having a zwitterionic group such as a betaine or a sulfobetaine group, or such radicals wherein the amino group is bonded to the silicon atom via the nitrogen atom.

Preferably, R2 is en, a saturated arbon radical having up to 24 carbon atoms, which may contain one or two groups selected from -O-, -S-, -NH-, ,-C(O)— and -C(S)—, and which may optionally be substituted by one or two hydroxyl groups.

Preferably, R3 is a divalent saturated aliphatic arbon radical having up to carbon atoms, which may contain one or two groups, and which may ally be substituted by hydroxy, and which is bonded to the silicon atom via carbon.

The radicals RN preferably include: n-, iso-, or tert.-C1-ng-alkyl, 02-sz- alkoxyalkyl, -cycloalkyl, Ce-Cgo-aryl, Ce-Cgo-aryl(C1-Ce)alkyl, C6-C30- alkylaryl, C2-C22-alkenyl, C2-sz-alkenyloxyalkyl, which may all be substituted by one or more (such as one to five) substituents, such as hydroxyl, halogen (particularly fluorine), and which may have one or more ether groups, such as HsC-, CHsCH2-, CH3CH20H2-, (CH3)2CH-, C3H17- and C10H21-, HzC=CH-O-(CH2)1- 6, cycloaliphatic radicals such as cyclohexylethyl, limonyl, norbonenyl, , tolyl, xylyl, benzyl and 2-phenylethyl, halogen(C1-C1o)alkyl, such as Cfan+1CH2CH2' n f = 1 to 8, such as CF3CH2CH2-, C4F9CH20H2-, CeF13CHzCH2-, CzF5—O(CF2—CF2—O)1-1oCF2—, F3)—CF2—O]1-5—(CF2)0-2—, F(CF3)— and C3F7—OCF(CF3)—CF2—OCF(CF3)—.

Particularly preferred are methyl, vinyl, phenyl, 3,3,3-trifluoropropyl, and most preferred is RN = Methyl.

In the polyorganosiioxanes or silanes used in the present invention the radicals RF are ably selected from the group consisting of: - quaternary phosphonium groups containing radicals of the formula: 2O —R3—P+(R2)3 wherein R3 is as defined above and is bonded to the silicon atom via , the radicals R2 may be the same or ent and are as defined above, and preferably at least one of R2 is not hydrogen, —R3—P(R2>2 wherein R3 is as defined above and is bonded to the silicon atom via carbon, the radicals R2 may be the same or different and the radicals R2 are as defined above, - epoxy groups containing radicals selected from: carbonate groups containing radicals ed from: —\/\O/fi___‘ O 0 urethane groups containing radicals selected from: —R3—OC(O)NH-R2 wherein R2 and R3 are as described above, isocyanate groups containing radicals selected from: —-R3—NCO wherein R3 is as described above, urea groups containing radicals ed from: —R3—NHC(O)NHR2, wherein R2 and R3 are as defined above, amid or amido groups containing radicals selected from: —R3—NHC(O)—R2 or O)NH-R2, wherein R2 and R3 are as defined above, - enamine groups containing radicals selected from: —-gi/ \N/ 2 I R (imine form) which may be present as a tautomer when one of the radicals R2 is a hydrogen atom in B-position to the nitrogen atom: —Si/ \NHl l R , wherein the radical R2* from the radical R2 formally results from shifting of a hydrogen atom, and wherein R2 are the same or different and R2 and R3 are each as defined above, which are particularly obtainable by reaction of amino-functional ganosiloxanes with ketones, such as tic or aromatic ketones having up to 14 carbon atoms, such as C3-C14 aliphatic ketones, aromatic C8 to C12 ketones, further enamines of the formula wherein R2 and R3 are as defined above, which are particularly obtainable by reaction of amino-functional polyorganosiloxanes with monoaldehydes, such as aliphatic or aromatic aldehydes having up to 14 carbon atoms, for example, dehyde, butyraldehyde, furfural, acrolein, crotanaldehyde, glycolaldehyde , dol, aromatic C7 to C11 aldehydes, for example benzaldehyde, anisaldehyde, vanillin, salizylaldehyde, aldehyde groups containing radicals, such as selected from: n R3 are the same or different and R2 and R3 are as defined above, which are particularly obtainable by reaction of aminofunctional polyorganosiloxanes with dialdehydes, such as glyoxal, malonaldehyde, aldehyde, phthalaldehyde, isophthalaldehyde, terephthalaldehyde, i0 — hemiacetal and acetal group containing radicals such as those resulting from the reaction of aldehyde groups containing polysiloxanes or silanes with monovalent or polyvalent alcohols, such as methanol, ethanol, glycol zwitterionic group containing radicals such as carbobetaine groups containing ls selected from: —-—R§-lTl—R3—COO_ IIRZ R2 —R3—N—R3-COOH or its neutral form: and salts thereof, wherein R2 and R3 are the same or different and are as defined above, sulfobetaine groups containing radicals ed from: if 2 —R§-lTl—R3—SO3+ _ Fl? 2 3_ R __ L _R N R or its neutral form: SO3H and salts thereof, n R2 and R3 are the same or different and are as defined above, carboxylic acid/carboxylate groups containing radicals selected from: -R3-COOR2, -R3-COO' wherein R2 and R3 each are as defined above, sulfonic acid / sulfonate groups containing radicals selected from: -R3-SO3R2, -R3-sog' wherein R2 and R3 each are as defined above, - ic acid halfesters / sulfate groups containing radicals selected from: 2, -oso3' wherein R2 is as defined above, oric ester/ phosphate groups containing radicals selected from: wherein R2 and R3 are as defined above, and fluorophosphoric ester selected from: F OR2 0' --R3—O—ll3—OR2 —R3—o—I|=—F -—R§—O-F"—F n n n o o 0 , and wherein R2 and R3 are as defined above, phosphonic esters / phosphonate groups containing radicals selected from: or the protonated forms thereof, wherein R2 and R3 are as defined above, in R3 is bonded to the phosphorus atom via a carbon atom), and wherein R3 is as defined above, phosphorous ester/ phosphite groups containing radicals, OR2 OR2 0' I I i 3 2 3 - 3 — —R—o—P——0R —O lO , and —R—O—P—Ol wherein R2 and R3 are as defined above (and are bonded to the oxygen atom of the phosphorous ester/ phosphite groups via carbon), l5 te/ xanthogenate ester groups containing radicals S S n n —R3—O-C—S—R2 —R3—O—C—S' wherein R2 and R3 each are as defined above, amino groups Si-bonded via N, selected from: -N(R2)2, wherein R2 is as d above, with the proviso that at least one radical R2 is not hydrogen, hydroxy group, acyloxy groups Si-bonded via 0, selected from: _O—C_R wherein R2 is as defined above. - alkoxy groups Si-bonded via 0, selected from: -OR2, wherein R2 is as defined above, and the cations, which neutralize the anionic functional groups, are selected from the group consisting of: ammonium groups (N+(R2)4, wherein R2 is as d , phosphonium groups (P+(R2)4, wherein R2 is as defined above) and mono- to trivalent metal cations, and the anions, which neutralize the cationic functional groups, are selected from the group consisting of: halide, hydroxide, borate, sulphate, phosphate, nitrate and carboxylate.

Particularly preferred groups RF include: - quaternary phosphonium groups containing radicals of the formula: -R3—P*(R2)3 n R3 is as defined above, bonded to the silicon atom via carbon, the ls R2 may be the same or ent and the radicals R2 are as defined above, and preferably at least one of the radicals R2 is not hydrogen, phosphine groups containing radicals of the formula: —R3—P (R2)2 wherein R3 is as defined above, bonded to the silicon atom via carbon, the radicals R2 may be the same or different and the ls R2 are as defined above, isocyanate groups ning radicals, selected from: —R3—NCO Wherein R3 is as bed above, and blocked derivatives thereof, such as lactams, oximes, pyrazoles, sterically hindered amines or malonic acid ester (C. Githler, M. Homann M. Mager, M. Schelhaas, T. Stingl, Farbe & , Lack, 110. Volume, 12/2004, 34-37), epoxy groups containing radicals, ed from: Mo/% carbonate groups containing radicals selected from: LR‘LCOO' R2 3 3 or its neutral form: _R_N—R_COOH wherein R2 and R3 are the same or different and are as defined above, sulfobetain groups containing radicals selected from: * 2 —R3—lTl—R3—SO3+ _ if or its neutral form —R3—N-R3—803H wherein R2 and R3 are the same or different and are as defined above, ylic acid / carboxylate groups ning radicals selected from: -R3-COOR2, -R3-COO' wherein R2 and R3 each are as defined above, sulfonic acid / sulfonate groups ning radicals selected from: 423-303 R2,, -R3-sog' wherein R2 and R3 each are as defined above, - phosphonic acid esters / phosphonate groups containing ls selected from: 9H 9H 9 —R3—l[=|’—OH l’—O' —R3—IIDI—0' O O o , and wherein R3 are as defined above, - phosphorous ester/ phosphite groups ning radicals 9H 9H —R§—o—P—0H 9' —R3—o-P—0’ and —-R3—O—P-O'l wherein R3 is as defined above, - xanthate / xanthogenate ester groups containing radicals S S n n —R3—O—C—S—R2 —R3—o—c—S' wherein R2 and R3 each are as defined above, amino groups Si-bonded via N, selected from: -N(R2)2, wherein R2 is as d above, with the proviso that at least one radical R2 is not hydrogen acyloxy groups Si-bonded via 0, selected from: —-O—C—R , wherein R2 is as defined above, - alkoxy groups Si-bonded via 0, selected from: -OR2, wherein R2 is as defined above, except hydrogen.

Preferred cations which neutralize the anionic functional groups are selected from the group consisting of: Ammonium groups )4, wherein R2 is as d above), phosphonium groups (P+(R2)4, n R2 is as defined above), and mono- to trivalent metal cations, such as for example Na+, K”, Fe”, Fe 3+, Al“, Cu”, Zn2+ und Cr3+.

Preferred anions which neutralize the cationic functional groups are selected from the group consisting of: halide, hydroxide, borate, sulfate, phosphate, nitrate and carboxylate.

Polyorganosiloxanes according to the present invention preferably contain at least one radical of the formula MF: —o,—,2—Si—RF , wherein R1 is as defined above, preferably RN as defined above, and RF as d above.

In a further preferred embodiment polyorganosiloxanes are used having the formula: (lll) wherein n1 + n2 = 1 to 28, preferably 1 to 20, more preferably 1 to 15, more preferably 5 to 15, and n2 2 0, preferably 1 to 28, more preferably 1 to 10, more preferably 1 to 5, and R1 and RF are as defined above. ularly preferred are polyorganosiloxanes according to the present invention having the formula R1 R R F l I R—sl—o F si—o si—R R1 R1 R1 (VI) n n is in number average 0 to 28, preferably 0 to 20, more preferably 0 to , more preferably 5 to 15, and R1 is as defined above, preferably RN as defined above, and RF is as defined above.

In a further preferred embodiment polyorganosiloxanes are used having the formula: R1l T1 R F|{1 RLsu-o si—o slsi—R1 1 1 sl—o 1 1 R R R n1 n2R (IV) n n1 + n2 = 1 to 28, and n2 2 1, preferably 1 to 28, more preferably 1 to 10, more preferably 1 to 5 and R1 and RF are as defined above.

In a further preferred embodiment cyclic polyorganosiloxanes are used having the formula: wherein n1 + n2 = 3 to 7 and n2 2 1, preferably 1 to 7, more preferably 1 to 5, particularly preferably 1 to 3 and R1 and RF are as defined above.

It is r possible that the radical RF is located on a silicon atom, which forms a In a further red embodiment of the invention, several types of the inventive compounds are used simultaneously.

The polyorganosiloxanes or silanes of the present invention may be used in combination with other polyorganosiloxanes or silanes different from those of the present invention. Such polyorganosiloxanes or silanes, which are ent from the polyorganosiloxanes or silanes according to the present invention, may for example also comprise functional groups which are ent from RF, and which for e comprise amino groups (NH2, NHR1, NR12, wherein R1 represents an organic radical) or ammonium groups (NH4+, NR1H3+, NR12H2+, NR13H+ and NR1 +, wherein R1 represents an organic radical).

Therein, a combination of polyorganosiloxanes or silanes with basic functional polyorganosiloxanes or silanes with acidic functional groups and groups are particularly preferred. Herein, the term "basic" includes both the basic functional groups, such as amino groups, as well as their salts or protonated forms, such as ammonium groups. hangeably the term "cationic" polyorganosiloxanes or silanes is used. The term c" includes both an acidic onal group, such as carboxyl groups, as well as their salts, such as carboxylates. lnterchangeably the term "anionic" polyorganosiloxanes or silanes is used.

Especially red are: combinations of led cationic polyorganosiloxanes or silanes, which se for example, amino groups (such as mentioned above), ammonium groups (such as mentioned above), quaternary ammonium groups (such as mentioned above), quaternary phosphonium groups (such as ned above), with so-called anionic polyorganosiloxanes or silanes, which comprise for example carboxylic acid groups / carboxylate groups, sulfonic acid / ate groups, sulfuric acid half ester groups / sulfate groups, phosphoric ester / phosphate groups, phosphonic ester / phosphonate groups, phosphorig ester groups / phosphite groups, xanthate / xanthogenate ester groups.

The molar ratio of the cationic to the anionic groups in the polyorganosiloxane or silanes is preferably selected as follows: cationic : anionic = 90 : 10 to 10 : 90, preferably 70 : 30 to 30 : 70, particularly 60 : 40 to 40 : 60.

Accordingly the present invention further relates to a composition sing: a) at least one polysiloxane and / or silane as defined in any of claims 1 to 10 having a functional group F selected from the group of the acidic functional groups: - a zwitterionic group, — carboxylic acid / carboxylate group, - sulfonic acid / sulfonate group, - sulfuric acid half-ester/ sulphate group, - phosphoric ester/ phosphate group - phosphonic ester/ phosphonate group, - phosphorous ester/ ite group, (each as previously defined) b) at least one polysiloxane and / or silane having a basic functional group selected from amino groups, ammonium , phosphonium groups and phosphine groups (each as defined above and below).

The molar ratio of cationic groups (corresponding to component b)) to the anionic groups (corresponding to component a)) in the ganosiloxanes or s is preferably selected as follows: cationic : anionic = 90 : 10 to 10 : 90, preferably 70 : 30 to 30 : 70, particularly 60 : 40 to 40 : 60.

The content of the cationic component b) is for example 1-90 wt -%, ably 5- 80 wt -% based on the total amount of component a) and b).

It is also within the scope of the present invention, to substitute the cationic and / or anionic polyorganosiloxanes or silanes partially by cationic and / or anionic hydrocarbon compounds, wherein the the terms cationic and c must be understood as described above. Examples are cationic or anionic tants, such as long-chain alkyl or aryl sulphonates, long-chain alkyl ammonium compounds.

According to the present invention it is also possible to combine the rionic, ularly betainic polyorganosiloxanes or silanes with the cationic or anionic polyorganosiloxanes or silanes.

In a preferred embodiment, the polyorganosiloxanes or silanes according to the invention have a lar weight of <2000 g / mol, preferably of <1500 g / mol, more preferably of <1000 g / mol.

For the said polyorganosiloxanes of formulas (III), (IV) and (VI), n1 + n2 is preferably 0 to 18, more preferably 0 to 13, even more preferably 0 to 10, even more preferably 0 to 5, wherein at least one siloxy group with RF must be present.

The synthesis of thiosulfate groups containing polysiloxane or silane compounds is also known (Silicones, Chemistry and Technology, Vulkan Verlag Essen 1989, p 121).

Phosphine groups containing polysiloxane or silane compounds are for example obtainable by alkylation of dialkyl or diaryl phosphines with the haloalkyl- substituted siloxanes or silanes. (Organikum VEB Deutscher Verlag der Wissenschaften 1988, 17. edition, p. 203).

Phosphonium groups containing polysiloxane or silane compounds are for example obtainable by alkylation of yl or triaryl phosphines with kyl- substituted siloxanes or s or by alkylation of the aforementioned phosphine groups containing polysiloxane or silane nds (Organikum VEB Deutscher Verlag der Wissenschaften, 1988, 17. edition, p. 203).

Epoxy—polyorganosiloxanes or -silanes are advantageously prepared by hydrosilylation of unsaturated epoxy-functional compounds, such as allyl yl ether and vinyl cyclohexene oxide, with SiH functional precursors under Pt catalysis (Silicones, Chemistry and Technology, Vulkan Verlag Essen 1989, p. 90). ate-functional polyorganosiloxanes or -silanes are obtainable either by hydrosilylation of unsaturated carbonate-functional compounds, such as allyl carbonate, with SiH-functional sors under Pt catalysis (US 5672338, US 5686547). Alternatively, they may be prepared from the ponding es by insertion of 002 (DE 19505892) or by reacting rganosiloxanes or 2O silanes with bifunctional carbonate coupling agents ().

Polyorganosiloxanes or silanes modified with isocyanate groups, including blocked isocyanate groups, are obtainable by reacting polyorganosiloxanes which are functionalized with CH-acidic groups, such as hydroxyl or amino functional polyorganosiloxane or silanes, with an excess of di— or higher functional isocyanates, or by reaction of amino-functional polyorganosiloxanes or silanes with COCI2, or by pyrolysis of carbamato-functional polyorganosiloxanes or Urea groups containing polyorganosiloxanes or silanes are obtainable, for example, by reaction of the above mentioned isocyanate-functional polyorganosiloxanes or silanes with .

Urethane and urea-units containing ganosiloxanes or silanes are on the one hand obtainable by reaction of hydroxyl- or amino-functional precursors with isocyanates (Organikum VEB Deutscher Verlag der Wissenschaften 1988, 17. edition, p. 429). Alternatively, urethanes can also be obtained by reaction of aminoorganosiloxanes or silanes with for e cyclocarbonates or ate- functional siloxanes or silanes with amines (US 8).

Amide-functional siloxanes or silanes are, for example, obtainable by reaction of aminoorganosiloxanes or silanes with lactones (DE 6, Example 22).

Schiff base, imine, and enamine groups containing siloxanes or silanes are, for example, obtainable by reaction of aminosiloxanes or s with aldehydes or ketones, as demonstrated, for example, in W02008113820, Example 1, and DE 4318536, Example 20a.

Hemiacetal and acetal groups containing siloxanes and silanes are, for example, able by reaction of hydroxyI-functional (COH functional) siloxanes with aldehydes to form structures, which contain hemiacetal or acetal functions (Organikum German VEB Deutscher Verlag der Wissenschaften 1988, 17. edition, p. 398-400) or, as described above, by reaction of aldehyde groups containing polyorganosiloxanes or silanes with mono- or lent (particularly divalent) alcohols.

Aldehyde groups containing siloxanes or silanes are, for example, obtainable by reaction of aminosiloxanes with dialdehydes, for e C2 to 05 dialdehydes, with the formation of structures which, for example, contain the combination of Schiff bases with aldehyde functions or enamines and aldehyde functions. Alternatively, hydroxy-functional (COH functional) siloxanes can react with dialdehydes to form structures, which contain etal and aldehyde or acetal and aldehyde functions. (Organikum German VEB Deutscher Verlag der Wissenschaften 1988, 17. edition, p. 390-400). Further, hydroxyl-functional (COH functional) siloxanes can react with epoxy aldehydes to these end products. It is also possible, to convert hydroxy-functional (COH functional) siloxanes by catalytic dehydrogenation on Cu and Ag catalysts into aldehydes. A further preferred group of aldehyde-functional siloxanes are compounds which can be obtained by reaction of functional siloxanes, for example on the basis of the addition of allyl glycidyl ether or vinyl cyclohexene oxide and SiH sors, with aldehyde carboxylic acids, for example glyoxylic acid HC(=O)C(= O)OH. The preparation can, for e be carried out in accordance with US 8, Example 3.

Siloxane or silane-based carbobetaines are, for example, obtainable by on of tertiary amino structures with oroacetate (Silicones, Chemistry and logy, Vulkan Verlag Essen 1989, p 121). On the other hand, they can be obtained by reaction of epoxy siloxanes or silanes with the alkaline salts of amino acids (DE 10036532, Example 1).

Siloxane or silane—based sulfobetaines are, for example, obtainable by reaction of tertiary amino structures with sultones (DE 4140447, Example 1).

Alternatively, they may be obtained by reaction of epoxy nes or silanes with the alkaline salts of amino sulfonic acids, such as taurine, in analogy to the corresponding carbobetaines.

Siloxane or silane-based carboxylic acids are, for example, obtainable by reaction of hydroxyl- or amino-functional precursors with a carboxylic acid anhydrides, such as phthalic anhydride, succinic anhydride and maleic anhydride (DE 9, Example 1).

Acetoxy—functional siloxanes or silanes, for example with acyloxy groups Si-bonded via 0, are, for example, obtainable by reaction of silanoles with acetoxy silanes (Silicones, Chemistry and Technology, Vulkan Verlag Essen 1989, p 58). Alternatively, for example, silanols and alkoxysilanes can react with acid anhydrides to form these end products. For the synthesis of such compounds it is also possible to cleave siloxane bonds in the presence of acid anhydrides and catalysts (V. Bazant, Organosilicon Compounds, Volume 1, Academic Press New York, 1965, pp. 61-64).

Siloxane or silane-based sulfonic acid derivatives are, for example, obtainable by reaction of epoxy-functional precursors with sodium bisulfite (Silicones, Chemistry and Technology, Vulkan Verlag Essen 1989, p 121).

Siloxane or silane-based e derivatives are, for e, obtainable by reaction of hydroxyl-functional sors with amido ic acid (DE 9, Example 3).

The synthesis of silicone-based phosphate derivatives or derivatives of phosphoric acid is, for example, bed in US 1 and US 6175028.

Alkoxy-functional siloxanes are, for example, obtainable by alkaline equilibration of silanes with cyclosiloxanes (Silicones, Chemistry and Technology, Vulkan Verlag Essen 1989, p 5).

Phosphonic esters / phosphonate group-containing polyorganosiloxanes or silanes are, for example, obtainable by reaction of alkenyl- polyorganosiloxanes or silanes with phosphorous esters.

Phosphorous ester/ phosphite groups containing polyorganosiloxanes and silanes are, for example, able by reaction of hydroxyalkyl- polyorganosiloxanes or silanes with phosphorous esters or phosphites.

Xanthate / xanthogenate ester groups containing polyorganosiloxanes or s are, for example, obtainable by reaction of alcolates of the alkoxy polyorganosiloxanes or silanes with carbon disulfide and optionally uent reaction with alkyl halides to form xanthogenate ester.

Via N to Si bonded organoamino groups containing polyorganosiloxanes or silanes are, for example, obtainable by reaction of halogen- polyorganosiloxanes or silanes with .

The invention r relates to compositions comprising at least one polyorganosiloxane and / or silane, as defined above, and at least one solvent and / or at least one biocidal agent for the treatment of ellulosic als.

The compositions of the present invention comprising at least one onalized polyorganosiloxane and / or silane, as defined above, may for example comprise a solubilizer and / or an emulsifier which particularly leads to an increase in stability of the compositions of this invention, such as for example an aqueous composition, such as an emulsion or a solution or a dispersion in a solvent.

Suitable solubilizer or emulsifier are particularly amino-modified silicones, quaternary fatty aminalkoholate, especially a quaternary fatty hanolat. le ts, depending on the method of ation, are: carbon dioxide, alcohol, water, ethane, ethylene, propane, butane, sulfur hexafluoride, nitrogen oxides, ionic s, chlorotrifluoromethane, monofluoromethane, methanol, ethanol, DMSO, isopropanol, acetone, THF, acetic acid, ethylene glycol, polyethylene glycol, acetic anhydride, N,N-dimethyl aniline, methane, e, hexane, cyclohexane, toluene, heptane, benzene, ammonia, propanol etc. and mixtures thereof, more preferably water, organic solvents, such as polyalcohols, such as in particular propylene glycol, ethylene glycol or butyl diglycol, ethanol, propanol, isopropanol, n-butanol, furfuryl alcohol, THF, DMSO, dioxane, aliphatic and / or nated hydrocarbons, etc., or mixtures f.

A preferred emulsion of the functionalized polyorganosiloxane and / or silanes as defined in the present invention contains: a) at least one functionalized polyorganosiloxane and / or silane as defined according to the invention (optionally in combination with one or more non- inventive polyorganosiloxanes and / or silanes) in a concentration of 1-80 wt -%, ably 5—60 wt-%, most preferred from 10-50 wt-% (wherein this amount includes the total amount of the onalized polyorganosiloxanes and/or silanes as defined according to the present invention and of the non-inventive polyorganosiloxanes and / or silanes), b) water in an amount of 99 to 20 wt-%, ably 95 to 40 wt -%, most preferred 90 to 50 wt -%, in each case based on the total amount of components a) and b), and optionally: 0) one or more emulsifiers in an amount of 0-20 wt -%, preferably 0.5-20 wt - 2O %, more preferably 1-15 wt -%, most preferred from 2-10 -%, preferably selected from ionic or non-ionic emulsifiers d) one or more compounds for controlling the pH of the emulsion, such as a base or an acid, preferably an acid such as acetic acid, e) one or more solvents in a range of 0-50 —%, preferably 1 —50 wt -%, preferably 1-20 wt -%, wherein the amounts of the optionally present components 0) to e) refer to the total amount of the emulsion.

The weight ratio of the components [a) + b)] to [c) + d) + e)] is from 100 : 0 to 100 : 70, preferably from 100 : 1 to 100 : 30.

The pH of such an emulsion is preferably in the range of 2-12, ably 2-7, most preferred 3-5, which generally increases the stability of the emulsion.

Optionally, the amount of component d) is accordingly selected.

Examples of biocides, which may optionally be present in the compositions of the t invention comprise for example: Boron compounds, such as borax, borate, boric acid, boric acid ester, Copper compounds, such as water-soluble copper compounds such as copper (ll) salts (copper (ll) oxide, micronized copper, copper (ll) sulfate, copper (ll) hydroxide ate, bis (N-cyclohexyldiazeniumdioxy) copper (ll), mixtures of boron compounds and copper compounds organic biocidal compounds, such as triazoles (as azaconazole, cyproconazole, propiconazole, tebuconazole, TCMTB) sulfamide (such as dichlorofluanid, tolylfluanid), carbamates (such as IPBC, carbendazim), aromatic fungicides (such as ortho-phenylphenol, chlorothalonil) and other ides (such as bethoxazin, isothiazolone), synthetic pyrethroids (such as permethrin, ethrin, cyfluthrin, deltamethrin, silafluofen), insecticides (such as imidacloprid, flufenoxuron, chlorpyrifos, fenoxycarb).

The boron compounds are usually used in an amount of 0.1 to 300 parts by weight per 100 parts by weight of the total amount of polysiloxane and / or silane.

The boron compounds stop microbial decomposition and allow for repelling insects such as termites. Suitable boron compounds include boric acid, borax, boric esters, such as trialkyl borate, such as hyl , triethyl , tripropyl borate and tributyl borate, borates as NangO13 x 4H20 or Timbor (R) available from U.S. Borax |nc., borax and borates such as Timbor (R) are preferred. An amount of boron of more than 300 parts by weight deteriorates the ity of the emulsions. When boron nds are used, they are preferably used in a concentration of at least 10 wt% based on the total amount of the polyorganosiloxanes and silanes.

Further auxiliaries which can be used in the compositions of the invention include for example: emulsifiers, as mentioned above, thickener, pigments, dyes, antistatic agents, defoaming agents, flame retardants, etc.

Preferred compositions of the invention contain 2 5 weight -%, preferably 210 wt -%, more preferably 215 wt -°/o, most preferred 230 wt -% functionalized polysiloxane and / or onalized , as defined above.

Preferred compositions of the invention contain: to 50, preferably 15 to 50 parts by weight of onalized polyorganosiloxane and / or functionalized silane, as defined above, to 95, preferably 40 to 80 parts by weight solvent, such as the above- mentioned, as defined above, 0 to 100, preferably 0 to 80 parts by weight of r es, such as the above-mentioned O to 100, preferably 1 to 80 parts by weight of other aries, such as the above-mentioned, such as in particular emulsifiers.

The present application further relates to a process for treating Iignocellulosic material, comprising the treatment of the ellulosic material with at least one polysiloxane or silane, as defined above, or a composition as defined above, by surface treatment, immersion treatment, or vacuum or pressure nation.

In the method according to the present inventive the Iignocellulosic materials may be coated or impregnated with the itions of the invention by all methods for introducing aqueous solutions, common in wood treatment and known from the literature, such as coating or impregnation, for example by brushing, spraying, dipping, flow coating, hutch soaking, vessel pressure impregnation, vacuum impregnation, vacuum pressure impregnation, borehole impregnation or by the sap displacement method, see also "Encyclopedia of Wood AZ" (Volumes | and II), Ulf Lohmann, DRW Verlag, ld-Echterdingen, 2003, see, inter alia "Einbringungsverfahren" Volume l, pages 289 to 292.

Preferably a vessel pressure impregnation or a surface treatment method is carried out, such as brushing, spraying, dipping or flow coating. It is ularly red to carry out a vacuum-pressure impregnation in the method of the present invention. The substrate to be impregnated can be placed in a pressure- resistant impregnation reactor and subjected to a first absolute pressure of 10 to 500 mbar, preferably 50 to 200 mbar abs., particularly about 100 mbar abs. for 5 minutes to 8 hours, preferably 15 minutes to 2 hours, particularly about one half to one hour, maintaining this pressure, and then immersing the substrate in the impregnating agent or covering the substrate with the impregnating agent and increasing the pressure to 1.5 to 20 bar abs. for 0.5 to 4 hours, preferably to 5 to bar abs. for 1 to 3 hours, particularly preferred to 10 to 12 bar abs. for about 2 to 3 hours. Subsequently, the re can be lowered to atmospheric pressure.

The substrate is taken from the impregnating solution, ally affects subsequent vacuum or drains and then conveys the vacuum pressure IO impregnated substrate to drying. Advantageously, a ic drying process is carried out after the impregnation step. A specific air drying and/or a ic technical drying method should follow the nation step, for example a microwave , infrared drying, fresh / exhaust air drying, hot air drying, vacuum drying, freeze drying, or a combination of these methods, such as described, for example, in "Holzlexikon von A-Z" (Volume | and II), Ulf Lohmann, DRW Verlag, lden-Echterdingen, 2003, see, "Holztrocknung", Volume I, page 605).

The combination of the polyorganosiloxanes or silanes used in the present invention with copper and / or boron and / or biocidal organic preservatives can be used both in a preferred one-step process or in a less preferred two-step process. One-step processes are for e brushing, dipping or impregnating with formulations of polyorganosiloxanes or silanes used in the present invention in organic solvents or as aqueous emulsions. In two-step processes, preferably the copper and / or boron compounds and / or c biocidal preservatives are applied first, for example by brushing, dipping or impregnating, and then the polyorganosiloxanes or s used in the t invention.

In a preferred embodiment, the polyorganosiloxanes or silanes used in the present invention are present as an aqueous emulsion. For the preparation and / or stabilization of such an aqueous on, an emulsifier may be added, wherein the emulsifier may also be an amino-modified silicone.

It is believed that the mechanism by which the polyorganosiloxanes or s used in the present ion achieve an increased resistance of wood and other lignocellulosic materials against weather and / or humidity deviations is at least partially effected from hydrophobing the surface, preferably the layers adjoining the surface up to the entire volume, of the wood or lignocellulosic material. Regarding wood, it is assumed that the polyorganosiloxanes or silanes used in the present invention lead to a d absorption of liquid water and a reduced moisture on (gaseous water), which in turn leads to less variation in the dimensions in the rain or with changing environmental humidity. Thus, polyorganosiloxanes or silanes used in the present ion therefore achieve a better dimensional stability of wood, because they penetrate into the cell wall of the wood and remain there permanently, apparently by reason of their functionalization. Therefore, the wooden cell wall is also in the dry state in a form of a pre-swollen state and therefore absorbs less water than untreated wood. The penetration of the polyorganosiloxanes or silanes used in the present invention is particularly achieved with so-called microemulsions, for example with an e particle size of 10 to 100 nm. Such microemulsions may penetrate into the pores of wood cell walls and even between the cellulose s, thus permanently reducing the further uptake of water. In this way, the dimensional change, such 2O as age during the drying of the wood, is reduced when the moisture content of the environment ses. In case of macroemulsions, for example having a le size of greater than 50 to 100 nm, it is assumed that the polyorganosiloxanes or s used in the present invention at least partially coat the inner surfaces of the wood cells and penetrate into the pores of the wood cell wall. The polyorganosiloxanes or s used in the present invention on the one hand allow a greater association with the lignocellulosic material and on the other hand provide a growth-inhibiting effect on microorganisms. The treatment especially effects resistance against fungi, so that lignocellulosic materials such as wood, treated with the polyorganosiloxanes or silanes used in the present invention, are less affected by staining, for example ””6“" fungi, or molds, or destructive fungi (white rot, brown rot) , and therefore have a greater resistance against microbial degradation. It is ed that impregnation with the polyorganosiloxanes or silanes used in the present invention presses the moisture t in the wood below the level required for growth of the fungi. By means of the polyorganosiloxanes or silanes of the invention it is surprisingly possible to permanently impregnate wood in a practical one—step process, and thus to further reduce the tendency of the wood to absorb water, to improve the dimensional stability in changing moisture contents of the environment and to reduce the degradation of wood by fungi, bacteria and insects, such as wood- destroying insects, such as termites, house longhorn , common furniture beetle, powder post beetles effectively. At the same time yellowing and graying of the wood by light and weather impact is suppressed.

In a further particularly preferred embodiment of the present invention, the functionalized ganosiloxanes or silanes are incorporated into the lignocellulosic material in a method using supercritical carbon dioxide, or other preferably gaseous ts (such as the above-mentioned) as a carrier medium.

In case of the particularly preferred use of carbon dioxide this method comprises a pressure impact of, for example, about 10 to 400 bar at about 0 to 180°C, especially from 50 to 300 bar at 32 to 100°C, very specifically 70 to 300 bar at 32 to 70°C. This s often requires special decompression methods for not damaging the lignocellulosic al during ression. During decompression the lly gaseous carrier medium, such as particularly carbon dioxide, excapes and the polysiloxanes or silanes used in the present invention remain in the lignocellulosic material, wherein generally cell walls and intercellular spaces are filled with the polysiloxanes or silanes used in the present ion. For more details on supercritical fluid treatments of wood materials reference can be made to DE 4202320, , EP 1128939, EP 1146969, EP 1501664 and Morrell & Levien: "Entwicklung Neuer Behandlungsverfahren zum Holzschutz" Conference report from "Konferenz fiir Holzschutz in den 90er Jahren und er hinaus", Savannah, a, USA, September 26-28,1994. 3O in a further particularly red embodiment of the present invention alkoxy and / or acyloxy, preferably acetoxy-functionalized polysiloxanes and / or silanes are introduced into the lignocellulosic material by means of a method using carboxylic acid anhydrides, especially acetic anhydride, as a solvent and reactant. Preferably, for this purpose the wood is placed in a vacuum and pressure-resistant reactor and first set under , then a mixture comprising acetic anhydride and aikoxy and / or acetoxy-functionalized poiysiloxanes and / or silanes are . Preferably, at elevated pressure and temperature the wood impregnation is ed over several hours. Thereafter, excess impregnating liquid is discharged. By applying a vacuum and optionally vapor tion volatile compounds are removed from the wood. It is preferred to use alkoxy and / or acetoxy-functionalized poiysiloxanes and / or silanes in an amount of 0.01 to wt -%, preferably 0.1 to 10%, more preferably 0.1 to 5 wt -% based on the weight of the wood. More technical details about impregnation in the presence of acetic anhydride can be found in EP 680 810. In this procedure, the weight ratio of aikoxy and / or acetoxy-functionalized poiysiloxanes and / or silanes to carboxylic acid anhydrides, especially acetic anhydride, is preferably from 0.1 : 100 to 20: 100, ably 1 : 100 to 10 : 100.

The aikoxy and / or acetoxy-functionalized poiysiloxanes and / or silanes, especially acetoxypolysiloxane may also be prepared in-situ by using polyorganosiloxanols, in particular erminated polyorganosiloxane, in particular hydroxy-terminated polydimethylsiloxane in the presence of di, tri or tetraalkoxysilanes, so that they can react with the polyorganosiloxanols to form 2O among others alkoxy and / or acetoxypolysiloxanes. Generally, poiysiloxanes with acyloxy groups Si-bonded via 0, such as the acetoxy group, may be ed in- situ from the corresponding polyorganosiloxanols, in particular SiOH terminated polyorganosiloxanes, in particular hydroxy—terminated polydimethylsiloxanes and the corresponding anhydrides.

According to the invention, it is preferred to achieve contents of the polyorganosiloxanes or s used in the present invention by the method of application or introduction of said ganosiloxanes or silanes of up to 20 wt- %, preferably up to 10 wt.-%, more preferably up to 7 wt -%, ally 1 to 7 wt- %, especially about 2 to 5 wt-%, based on the total mass of the dried treated lignocellulosic material.

Using the ganosiloxanes or silanes used in the t invention it is possible to achieve a m protection of the lignocellulosic material with a very low content of the same.

According to the invention, the content of the polyorganosiloxanes or silanes used in the present invention in the lignocellulosic materials can be increased by using a very concentrated aqueous emulsion of the polyorganosiloxanes or silanes. Therefore, preferred concentrations of said s emulsions are at least about 5, preferably at least about 10, more preferably at least about 15 wt -%, based on the total amount of the emulsion.

Alternatively, polyorganosiloxanes or s can be used, wherein the preferred concentrations correspond to those of the emulsion.

The use of the microemulsions (average droplet diameter of the polyorganosiloxanes or silanes less than 200 nm) is particularly red, since T5 the uptake into the lignocellulosic material occurs very easily. According to the invention it has been found that the penetration depth and therefore the effectiveness of the functionalized polyorganosiloxanes or silanes of the present invention also depends from the molecular weight and the wettability of the lignocellulosic material with said functionalized polyorganosiloxanes or silanes. It is shown that ally the chained or low molecular weight ganosiloxanes or silanes of the present invention, which are used according to the invention are preferred herein. The polyorganosiloxanes used in the present invention, for example, have number average molecular weights Mn of less than 3000 g/mol, preferably less than 2000 g/mol, more preferably less than 1000 g/mol (in each case determined by gel permeation chromatography on polystyrene as the standard). The silanes of the present invention are low molecular weight compounds per se and in general have a molecular weight of less than 500 g/mol, more preferably less than 400 g/mol, more preferably less than 300 g/mol.

Examples Example 1: Test items of size 25 * 25 * 10 mm3 l * tangential * longitudinal) of the wood types pine splint (Pinus sylvestris L.) and beech (Fagus sylvatica L.) were kiln dried at 103 °C to constant mass. Subsequently, a vacuum impregnation was carried out with an aqueous on containing 10 wt -% of a sarcosin- functionalized silicon having a chain length D10 (10 D units), prepared ing to Example 1 of DE 10036532, having the structure KO+>/\N K+ OMS?CH3 H3 CH3S|i\/\/OVi/Nw: Kiln drying was d out for 4 days at temperatures rising up to 103 °C.

Subsequently, a washout has been carried out according to EN 84 to remove extractable siloxanes and other materials.

This was a 14-days e in water with multiple water exchanges. A percentage weight increase of about 9% in e, relating to the initial weight of each dried on-treated wood resulted.

To determine the water absorption the samples were loaded with bars and poured with about 300 ml of water. From the weight gain after 2, 4 6 and 24 , hours, the water absorption in % was calculated. In each case, the water content was related to the initial weight of the (still) untreated test items, in order to exclude an influence of the weight gain due to the treatment. wnass_ Wtrbeh Water absorption = wtrunbeh *100 [0/0] wnass: weight of wet test items wtrbeh: weight of dry test items after treatment wirunbeh: weight of dry test items before treatment It was found that the wood samples treated with the zwitterionic functional siloxanes showed a reduced water absorption of about 36 wt-% after 24 hours compared to the respective untreated reference.

Example 2: Test items of size 25 * 25 * 10 mm3 (radial * tangential * longitudinal) of the wood types pine splint (Pinus tris L.) and beech (Fagus sylvatica L.) were kiln dried at 103 °C to constant mass. Subsequently, a vacuum impregnation was carried out with an aqueous emulsion containing 30 wt -% of propyltriacetoxysilane in acetic acid, additionally containing 0.07 wt-% H2804.

The test items were subjected to a vacuum of 7 mbar for about 15 min in a vacuum vessel. Then the impregnation solution was sprayed and normal pressure ed (impregnation according to EN 113).

The test items were heated in the on for 5 hours at 120 °C under reflux and in the absence of moisture (CaClz tube). The test items were then ted with acetic acid in a Soxhlet extractor to soluble silane or siloxane and extracted with ethanol, to remove the acetic acid. The test items were then dried at 103 °C to constant mass. Then immersion in water was d out as described in Example 1. The test items showed a strongly retarded absorption of water, compared to the untreated wood samples (control). After 24 hours, this was approximately 25 % lower ed to the control. In addition, a permanent swelling of the cell wall was ed. The cross-sectional area was increased by 7% (bulking).

The g could not be undone by leaching with water. The average weight increase in the kiln dry state was about 14 wt - % based on the initial weights of the 10 samples. The swelling - shrinkage efficiency (ASE = anti shrink efficiency) was calculated using the following formula: ASE = au- at locu *100 [%] ocu = swelling coefficient of the controls at = swelling coefficient of the untreated samples ASE = “u x100 [%] [9|u = swelling coefficient of the controls t = swelling coefficient of the treated samples.

Wherein the swelling coefficients were calculated using the ing formula: swelling coefficient ct = Adry- Awet /Adry *100 [%] n nass n X1 00 [0/0] Ad -A swelling coefficientoc= ry—wet x100[%] Adry = cross-sectional area dry Awet= cross-sectional area wet The achieved swelling - age efficiency (ASE) was in average about 50 % compared to the untreated reference.

Example 3: Test items of size 25 * 25 * 10 mm3 l * tangential * longitudinal) of the wood types pine splint (Pinus sylvestris L.) and beech (Fagus sylvatica L.) were kiln dried at 103 °C to constant mass. Subsequently, a vacuum impregnation (as described in Example 2) was carried out with an 100 % of propyltriacetoxysilane.

The test items impregnated in such manner were heated in propyltriacetoxysilane at 90 °C for 5 hours, the removed from the propyltriacetoxysilane solution and stored at ambient condition 25 °C and 50 % relative humidity for 24 hours. Then a kiln drying at 103 °C to constant mass followed and subsequently te immersion in water at 25 °C. This was carried out as described in Example 1. The weight increase after anew kiln drying was in average imately 68 % compared to the initial weight of the 10 test items. Compared to the untreated wood s a strongly retarded absorption of water was shown; after 24 hours, this was reduced by about 70 wt-% in average. e 4: Reference Example without siloxane (,, acetylated wood“ ) 8 samples of pine splint (20 * 20 * 10 mm 3; radial * tangential * longitudinal) were kiln dried at 103 °C and subsequently impregnated with acetic anhydride according to EN 113. The samples were then heated to 120 °C when lying in the chemical product and this temperature was maintained for 5 hours. After the reaction time, the samples were placed in deionized water to stop the reaction and to remove the excess acetic ide. The s were left in the water for 2 days, after a day the water was exchanged. Subsequently, the samples were dried, first at room temperature then at 103 °C.

The water absorption was tested in the kiln dried samples, by loading the samples in a vessel and pouring with about 300 ml of water. After 2, 4, 6 and 24 hours, the weight was determined after a brief dabbing of the samples, which were then rapidly put back into the vessel. The relative water absorption was calculated based on the dry weight of the s prior to acetylation. Then, a reduction of water absorption after 24 hours was calculated by relating the reduction of the water absorption after 24 hours, compared to the control, to the value of the control. In the first water absorption his reduction was -12,8 % and increased to -34.9 % in the 4th water absorption.

Example 5: Synthesis of an acetoxy—functionalized polydimethylsiloxane 234 g (1 mol) ethyltriacetoxysilane were introduced into a round bottom flask and 231 g (0.5 mol) of a SiOH-stopped polydimethylsiloxane of the average structure l l | HO/TiO/TiO/TKOH with a chain length distribution of 2 to 10 and remaining cyclodimethylsiloxanes were added dropwise. During the dropwise addition, the ature rose from °C to about 38 °C. After 5 hours reaction the product was igated by 1H NMR and it was found that no free ethyltriacetoxysilane exists any longer.

The product has the following average structure: e I Et [Acoi' a a s o’ I 0’ {‘OAc] 2 2 Example 6: lmpregnation with acetic anhydride acetoxy—functional loxane-mixture according to Example 5 Each of 16 pine splint samples (20 * 20 * 10 mm3; radial * tangential * udinal) were kiln dried at 103 °C and then impregnated with acetic anhydride mixed with various amounts of acetoxy-functional polysiloxane (0%, 1%, 3%, 6 %, 10%, 20 wt -%) according to EN 113. The samples were then heated to 120 °C when lying in the chemical product and this temperature was ined for 5 hours. After the reaction time, the samples were placed in deionized water to stop the reaction and to remove the excess chemical product.

The samples were left in the water for 2 days, after a day the water was exchanged. Subsequently, the samples were dried, first at room temperature then at 103 °C.

As can be seen from Figure 1, the Weight Percent Gain (WPG), i.e. the percentage weight gain, sharply increases by treatment with increasing content of acetoxyfunctional siloxane. The WPG was calculated based on the dry weight using the ing formula: weightafter treatment WPG [%] = -1 • 100 weightbefore treatment But even the g, the permanent ng in dry state due to the treatment, rises.

With pure acetylation (0% siloxane) it is 7.9% and significantly increases with 20% admixture of siloxane to 8.7%. The Bulking was calculated based on the dry dimensions using the following formula: radafter treatment • tanafter treatment bulking [%] = -1 • 100 radbefore treatment • tanbefore treatment The water tion (Figure 2) was determined in the samples by placing in each case 8 test items per treatment in a vessel, loading and pouring with about 300 ml of water. After 2, 4, 6 and 24 hours, the weight of the samples was determined and the relative water absorption based on the dry weight of the s prior to (10903027_1):MGH acetylation calculated. Based on the 24-hour values a water absorption reduction (Reduct. WA) ed to the controls and the acetylated samples was calculated.

For this purpose the reduction of the relative water absorption in percentage points was related to the relative water absorption of the controls and the acetylated samples. In the first contact with water, the water absorption of the combinations with polysiloxane was significantly reduced compared to the purely acetylated samples.

However, the maximum reduction of water absorption was ed with an admixture of 6% polysiloxane. In the 4th water absorption hardly any differences between the different combinations with polysiloxanes were recognizable. This means that even an addition of 1% acetoxy-functional polysiloxane may effect a maximum reduction of water tion. Compared to the pure ation the combination with loxane shows much better hydrophobing.

Figure 2 shows reduction of Water absorption compared to non-acetylated wood (black bars) and acetylated wood (shaded bars (top: 1th water absorption, bottom: 2nd water tion).

Example 7 (Reference): (10903027_1):MGH Pine splint samples 20*20*1Omm3 (radial*tangential*longitudinal) were impregnated with an aqueous emulsion consisting of 10 wt -% (m/m) of amino- onal polysiloxane having an average chain length of 12 siloxy units of the formula: O H l I H H2N/\/N\j\/O\/\/Si[o//Ii 00’’ISi\/\/O\)\/N\/\NH2 3 wt-% acetic acid, 5 wt-% of a e of three emulsifiers, (isotridecyl alcohol C13-polyethylene oxide with different polyethylene oxide chain s such as in ®) and 82 % of water. The amino-functional polysiloxane was prepared according to Example 22a in DE 4318536 by reaction of epoxy-functional siloxane with nediamine.

Subsequently, the ination of the water absorption was carried out as described in Example 6. In the first water absorption, the reduction of water absorption after 24 hours was only -8.2%, this is probably due to the high emulsifier content, which supported a water absorption. In the second water absorption, the reduction was -18.6 %.

In the fungi test, as described below, the samples treated with this material showed a weight loss upon incubation with Coniophora puteana of 9.7% (pine) and 26.9 % (beech), and upon incubation with Trametes olor of 6.3% (beech). The values of the controls are listed in the table below.

Example 8: Pine splint samples 20*20*10 mm3 (radial*tangential*longitudinal) were impregnated with an aqueous emulsion consisting of 10 wt -% (m/m) of carboxy- functional polysiloxane having an average chain length of 12 of the formula: wt-% emulsifiers (as in Example 7) and 80% water.

Subsequently, the water absorption was carried out as described in Example 6.

In the first water absorption, the reduction of water absorption after 24 hours was -11.2%, in the second water absorption an increase of water absorption by +4.7% occurred, compared to the control.

In the fungi test, as described below, the samples treated with this material showed a weight loss upon incubation with hora puteana of 2.7% (pine) and 14.1 % ), and upon incubation with Trametes versicolor of 2.7% (beech). The values of the ls are listed in the table below. e 9: Pine splint samples 20*20*10 mm3 l*tangential*longitudinal) were impregnated with an aqueous emulsion consisting of 10 wt -% (m/m) of a mixture of the amino-functional polysiloxane as described in Example 7 (80 wt.-%) with the carboxy-functional polysiloxane as described in e 8 (20 wt.-%), 3 % acetic acid, 5 % emulsifier and 82 % water.

Subsequently, the water absorption was carried out as described in Example 6.

In the first water absorption, the reduction of water absorption after 24 hours was -16.5% and was increased in the second water absorption to .

Accordingly, by combining the two functional polysiloxanes an improvement of the water repellency of the treated wood can be achieved compared to the two pure products. This is particularly interesting under the aspect, that the carboxy- functional polysiloxane has a very good efficiency against wood-destroying fungi, whereas the absorption of water is increased and t to heavy ng. By a combination with the amino-functional polysiloxane the leaching can be the hydrophobicity can be improved. Mixtures of amino-functional polysiloxane to carboxy—functional polysiloxane of 50:50 and 20:80 showed better results in some cases in the first water absorption, but in the second water absorption the combination of 80:20 was superior. fungi test A fungi test was carried out in ance with EN 113, wherein, deviating from the standard, in each case 2 treated and 2 untreated samples were incubated in a Kolle flask. The table below shows the results.

Control 1 (Ref. ) amino/ carbo- _—_-8 2 -36 absorption __— Coniophora puteana on 2,7 52,4 orne fungi-. Coniophora reSIstance pubteana on (weight-loss eech [%]) Trametes on beech )5: will be provided later The examples show that functionalized polysiloxanes or silanes of the present invention lower the water absorption in wood bodies. The sed water absorption allows to use the functionalized polysiloxanes or silanes of the invention as a protective agent for wood and other ellulosic materials, wherein wood etc. may be made more resistant to weather influences such as changes in the moisture content of the nment.

It has further been shown that wood, treated with functionalized polysiloxanes or silanes according to the invention as a tive agent, is subjected to a significantly lower surface infestation by mold and blue stain fungi.

As a further advantage, the functionalized polysiloxanes or s of the present invention used as a protective agent for lignocellulosic materials, such as wood, offer an increased resistance to infestation with harmful algae and marine organisms, such as piddock. As a further advantage, the functionalized polysiloxanes or silanes of the invention used as a protective agent for wood, offer an increased ance to infestation with algae.

Further, the onalized polysiloxanes or silanes of the present invention can increase the resistance of wood against wood-destroying insects, such as es, house longhorn beetles, common furniture beetles, powder post beetles.

Furthermore, ation experiments, i.e. measurement of mass loss of beech and pine in contact with the white rot fungus Trametes versicolor and the brown rot fungus Coniophora puteana, that functionalized polysiloxanes or silanes according to the invention se resistance of wood and other ellulosic materials against these wood destroying fungi.

Experiments on the swelling and shrinkage behaviour of beech and spruce wood samples show that the functionalized polysiloxanes or silanes of the present invention provide wood with an increased dimensional stability when d to water or humidity of the environment. This is a d property, as swelling and shrinkage is a major disadvantage when using wood. For example, the increase in the dimensional stability leads to a significantly reduced cracking, as has been demonstrated in weathering tests.

Experiments in outdoor exposure ed that wood samples treated with the functionalized loxanes or silanes according to the invention, exhibit an increased color stability. This protection can be ascribed to the fact that in particular the lignin degradation in the upper layers of the cell walls of the wood takes place less rapidly than in untreated wood.

The leaching experiments with boric acid as a co-biocidal agent for determining the fixation of hydrophilic substances by the functionalized loxanes or silanes of the present invention in lignocellulosic als show that the functionalized polysiloxanes or silanes of the present invention achieve a fixation or retention of hydrophilic substances in wood or lignocellulose materials. The fixation or retention even of lipophilic substances in lignocellulosic materials by the functionalized polysiloxanes or silanes according to the invention derive from the general lipophilic properties of these silicone derivatives. Therefore, the functionalized polysiloxanes or silanes of the t invention are also le for fixation of conventional wood treatment agents, such as flame retardants, fungicides, insecticides or dyes. This particularly s to such conventional compounds which are poorly retained in the matrix of the lignocellulosic material and are easily washed out by water.

To detect a reduction of flammability, pine wood impregnated with the onalized polysiloxanes or silanes according to the invention are examined using a thermo-balance (TGA). Therefore, pine wood samples of the size 5 x 10 x mm3 are treated with the functionalized polysiloxanes or silanes of the t invention as well as with a commercial flame retardant for wood (lmpralit F3/66 , Ruetgers cs). The wood samples are then ground. By means of a thermo- balance (STA 409 PC, Netzsch), the wood flour is continuously heated from 0 °C to 800 °C under oxygen as a shielding gas with a heating rate of 20 °C / min, and the weight changes are measured. The thermogravimetric analysis shows that the functionalized polysiloxanes or s of the present invention, lead to a higher flame resistance or fire ance of the so treated lignocellulosic materials, as demonstrated on the example of wood. This is particularly the case if in addition to the functionalized polysiloxanes or silanes of the present invention, conventional flame retardants are applied to the lignocellulosic material, such as those of or nds (phosphates, polyphosphates), magnesium compounds (magnesium hydroxide), aluminum nds (aluminum hydroxide), bromine / chlorine compounds (hydrogen halides) and flame retardant systems with expanding materials.

The functionalized polysiloxanes or silanes of the present invention may also be used for the physical and / or chemical bonding of conventional treatment agents for wood and other cellulose-based materials, thus increasing its ance. This ularly related to the combination of functionalized polysiloxanes or silanes according to the invention with flame retardants, insecticides or dyes, especially those compounds, which are particularly stable in a hydrophobic environment or retained n.

Furthermore, wood treated with functionalized polysiloxanes or silanes according to the ion may comprise more resilient surfaces, i.e. for example harder and / or abrasion resistant surfaces.

I

Claims (1)

/WE CLAIM:

1. Use of polyorganosiloxanes or silanes for the treatment of lignocellulosic materials, characterized in that the ganosiloxanes are straight-chained, branched or cyclic polyorganosiloxanes, formed from a number average of 2 to 30 siloxy units, which are selected from the group consisting of O R1 R1 R1 O Si O O Si O O Si O O Si R1