NZ543497A - Method and apparatus for acquiring heat from multiple heat sources - Google Patents

Abstract

Disclosed are systems and methods for implementing a closed loop thermodynamic cycle utilizing a multi-component working fluid to acquire heat from two or more external heat source stream in an efficient manner utilizing countercurrent exchange. The liquid multi-component working stream is heated by a first external heat source stream at a first heat exchanger and is subsequently divided into a first substream and a second substream. The first substream is heated by the first working stream at a second external heat source stream at a second heat exchanger. The second substream is heated by the second working stream at a third heat exchanger. The first substream and the second substream are then recombined into a single working stream. The recombined working stream is heated by the second external heat source stream at a fourth heat exchanger.

Description

^3^9*7 ;WO 2004/102082 PCT/US2004/014496 ;1 ;METHOD AND APPARATUS FOR ACQUIRING HEAT FROM MULTIPLE ;HEAT SOURCES BACKGROUND OF THE INVENTION ;1. The Field of the Invention ;5 The invention relates to implementing a thermodynamic cycle utilizing countercurrent heat exchange. In more particular, the invention relates to methods and apparatuses for utilizing a multi-component working fluid to acquire heat from multiple external heat source streams. ;2. The Relevant Technology ;10 Thermal energy can be usefully converted into mechanical and then electrical form. Methods of converting the thermal energy of low and high temperature heat sources into electric power present an important area of energy generation. There is a need for increasing the efficiency of the conversion of such low temperature heat to electric power. ;15 Thermal energy from a heat source can be transformed into mechanical and then electrical form using a working fluid that is expanded and regenerated in a closed system operating on a thermodynamic cycle. The working fluid can include components of different boiling temperatures, and the composition of the working fluid can be modified at different places within the system to improve the efficiency 20 of energy conversion operation. ;Typically multi-component working fluids include a low boiling point component and higher boiling point component. By utilizing the combination of the low boiling point component and a higher boiling point component, an external heat source stream such as industrial waste heat can be more efficiently utilized for 25 electricity production. In applications where there are two or more heat sources available for electricity production, multi-component working fluids can be further utilized to improve the efficacy of heat acquisition and electricity generation. The two or more heat sources can be utilized to heat the low boiling point component to convert the low boiling point component from a liquid state to a vapor state. By 30 heating the low boiling point component to the vapor state, heat energy from the external heat source stream is converted to kinetic energy which can more easily be converted to useful energy such as electricity. ;2 (followed by page 2a) ;BRIEF SUMMARY OF THE INVENTION In a first aspect, the present invention as claimed broadly consists in a method for implementing a thermodynamic cycle comprising expanding a multi-component gaseous working stream transforming its energy into a usable form and producing a spent stream; condensing the 5 spent stream producing a condensed stream; pressurizing the condensed stream and producing a working stream; and heating the working stream utilizing multiple external heat source streams. ;In a second aspect, the present invention as claimed broadly consists in a method for implementing a thermodynamic cycle comprising: transforming energy from a gaseous multi-component working stream into a usable form and producing a spent stream; condensing the 10 spent stream to produce a liquid working stream; heating the liquid working stream to the bubble point; heating the working stream from the bubble point at least to the boiling region utilizing overlapping same-temperature regions of a plurality of external heat source streams to increase the heating capacity at the boiling region; and heating the working stream to above the boiling point to create a heated gaseous working stream. ;15 In a third aspect, the present invention as claimed broadly consists in an apparatus for implementing a thermodynamic cycle comprising: an expander that is connected to receive a multi-component gaseous working stream and that is adapted to transform the energy of the multi-component gaseous working stream into a usable form and producing a precondensed stream; a condenser adapted to condense the pre-condensed stream producing a liquid working 20 stream; a pump configured to pressurize the condensed stream to produce a working stream; and a means for transferring heat to the working stream utilizing multiple sources of external heat. ;In a fourth aspect, the present invention as claimed broadly consists in an apparatus for implementing a thermodynamic cycle comprising: an expander adapted to expand a multi-component gaseous working stream transforming its energy into a usable form and producing a 25 spent stream; a condenser for converting the spent stream to produce a condensed stream; a pump for pressurizing condensed stream to produce a working stream; a first heat exchanger to heat the working stream utilizing a first external heat source stream; a divider to form a first substream and a second substream form a working stream; a second heat exchanger to heat the first substream utilizing the first external heat source stream; a third heat exchanger to heat the second 30 substream utilizing a second external heat source stream; a recombiner to form a recombined stream from the first substream and the second substream; and a fourth heat exchanger to heat the recombined stream to form a heated gaseous working stream. ;-7 MA.R 2 ;2a (followed by page 3) ;The present invention relates to systems and methods for implementing a closed loop thermodynamic cycle utilizing a multi-component working fluid to acquire heat from two or more external heat source streams in an efficient manner utilizing countercurrent exchange. Typically multi-component working fluids include a low boiling point component and higher boiling point component. Where the multi-component working fluid is heated, utilizing two or more external heat source streams, the heat acquisition process can be further optimized to improve electricity generation. In one embodiment, the heat acquisition process is utilized to convert both the low boiling point component and the higher boiling point component to a vapor state. ;Where the temperature of the external heat source stream is sufficient to convert both the low boiling point component and the higher boiling point component to a vapor state, the heat energy from the external heat source streams can be optimally converted in both a high energy state and the low energy state. For example, when the external heat source stream is at a lower temperature, the low boiling point component can be converted to the vapor state. Where the external heat source stream is at a higher temperature, the higher boiling point component can be converted to the vapor state. Where the temperature of an external source of energy exceeds the temperature needed to convert the higher boiling point component to the vapor state, the external heat source stream can be utilized to super heat the vapor working stream. ;According to one embodiment of the present invention, a liquid multi-component working stream is heated by a first external heat source stream at a first heat exchanger and subsequently heated by second external heat source stream at a second heat exchanger in series with the first heat exchanger. In another embodiment, the liquid multi-component working stream is heated by a first external heat source stream at a first heat exchanger and is subsequently divided into a first substream and a second substream. The first substream is heated by the first external heat source stream at a second heat exchanger. The second substream is heated by the second external heat source stream at a third heat exchanger. The first substream and the second substream are then recombined into a recombined working stream. The ;WO 2004/102082 ;PCT/US2004/014496 ;3 ;recombined working stream is heated by the second external heat source stream at a fourth heat exchanger to form a heated gaseous working stream. According to one embodiment of the present invention, subsequent to being heated by the fourth heat exchanger, the heated gaseous working stream is expanded to transform the energy of 5 the heated gaseous working stream to a usable form. Expanding the heated gaseous working stream transforms it into a spent stream which is sent to a distillation/condensation subsystem to convert the spent stream into a condensed stream. ;According to-one embodiment of the present invention, the first external heat 10 source stream is of a different temperature than the second external heat source stream. In one embodiment, the first external heat source stream and the second external heat source stream have overlapping same temperature regions. In one embodiment, subsequent to being pumped to a higher pressurization, the liquid working stream comprises a sub-cooled liquid. In the embodiment, the working fluid 15 is heated to a point at or near the bubble point in the first heat exchanger. Subsequent to being divided, the first substream and the second substream are heated to near the dew point. After the first substream and the second substream are recombined, the recombined working fluid is superheated to a heated gaseous working stream. ;In another embodiment, more than two heat sources are utilized to heat the 20 working fluid. For example, in one embodiment three external heat source streams are utilized to heat the working fluid. In one embodiment, two or more Heat Recovery Vapor Generators (HRVG) having separate expansion turbines, or an expansion turbine having first and second stages, are utilized to convert energy from the heated gaseous working stream. In another embodiment, one of the external heat 25 source streams is a low temperature source and the other external heat source stream is a higher temperature source. In one embodiment, the low temperature source and the high temperature source have overlapping same temperature regions. In another embodiment, the low temperature source and the higher temperature source do not have overlapping same temperature regions. ;30 These and other objects and features of the present invention will become more fully apparent from the following description and appended claims, or may be learned by the practice of the invention as set forth hereinafter. ;WO 2004/102082 ;PCT/US2004/014496 ;4 ;BRIEF DESCRIPTION OF THE DRAWINGS ;To further clarify the above and other advantages and features of the present invention, a more particular description of the invention will be rendered by reference to specific embodiments thereof which are illustrated in the appended drawings. It is 5 appreciated that these drawings depict only typical embodiments of the invention and are therefore not to be considered limiting of its scope. The invention will be described and explained with additional specificity and detail through the use of the accompanying drawings in which: ;Figure 1 illustrates a thermodynamic system for acquiring heat from a first 10 external heat source stream and a second external heat source stream according to one embodiment of the present invention. ;Figure 2 illustrates a thermodynamic system for acquiring heat from a first external heat source stream and a second external heat source stream having overlapping temperature regions according to one embodiment of the present 15 invention. ;Figure 3 illustrates a thermodynamic system for acquiring heat from a first external heat source stream and a second external heat source stream positioned in series according to one embodiment of the present invention. ;Figure 4 illustrates a thermodynamic system for acquiring heat from a first 20 external heat source stream and a second external heat source stream having overlapping same temperature regions in which the first external heat source stream comprises a higher temperature source. ;Figure 5 illustrates a thermodynamic system for acquiring heat from a first external heat source stream using a first heat recovery vapor generator at a high 25 working fluid pressure and a second external heat source stream utilizing a second heat recovery vapor generator at a low working fluid pressure according to one embodiment of the present invention. ;Figure 6 illustrates a thennodynamic system for acquiring heat from more than two external heat source streams according to one embodiment of the present 30 invention. ;WO 2004/102082 ;PCT/US2004/014496 ;5 ;DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS ;The present invention relates to systems and methods for implementing a closed loop thermodynamic cycle utilizing a multi-component working fluid to acquire heat from two or more external heat source streams in an efficient manner 5 utilizing countercurrent exchange. Typically multi-component working fluids include a low boiling point component and higher boiling point component. Where the multi-component working fluid is heated utilizing two or more external heat source streams, the heat transfer can be optimized to convert both the low boiling point component and the higher boiling point component to a vapor state for more efficient energy 10 conversion. ;Where the temperature of the external heat source stream is sufficient to convert both the low boiling point component and the higher boiling point component to a vapor state, the heat energy from the external heat source streams can be optimally converted in both a high energy state and a low energy state. For example, 15 when the external heat source stream is at a lower temperature the low boiling point component can be converted to the vapor state. Where the external heat source stream is at a higher temperature, the higher boiling point component can be converted to the vapor state. Where the temperature of an external source of energy exceeds the temperature needed to convert the higher boiling point component to the 20 vapor state, the external heat source stream can be utilized to super heat the vapor working stream. ;According to one embodiment of the present invention, a liquid multi-component working stream is heated by a first external heat source stream at a first heat exchanger and subsequently heated by a second external heat source stream at a 25 second heat exchanger in series with the first heat exchanger. In another embodiment, the liquid multi-component working stream is heated by a first external heat source stream at a first heat exchanger and is subsequently divided into a first substream and a second substream. The first substream is heated by the first external heat source stream at a second heat exchanger. The second substream is heated by the second 30 external heat source stream at a third heat exchanger. The first substream and the second substream are then recombined into a recombined working stream. The recombined working stream is heated by the second external heat source stream at a fourth heat exchanger to form a heated gaseous working stream. According to one ;WO 2004/102082 ;PCT/US2004/014496 ;6 ;embodiment of the present invention, subsequent to being heated by the fourth heat exchanger the heated gaseous working stream expanding transforms it into a spent stream which is sent to a distillation/condensation subsystem to convert the spent ;I ;stream into a condensed stream. ;5 According to one embodiment of the present invention, subsequent to being combined with a second partial working stream a partial heated gaseous working stream is expanded to transform the energy of the partial heated gaseous working stream to a usable form. Expanding the heated gaseous working stream transforms it into a spent stream which is sent to a distillation/condensation subsystem to convert 10 the spent stream into a condensed stream. ;According to one embodiment of the present invention, the first external heat source stream is of a different temperature than the second external heat source stream. In one embodiment, the first external heat source stream and the second external heat source stream have overlapping same temperature regions. In one 15 embodiment, subsequent to being pumped to a higher pressurization, the liquid working stream comprises a sub-cooled liquid. In the embodiment, the working fluid is heated to a point at or near the bubble point in the first heat exchanger. Subsequent to being divided, the first substream and the second substream are heated to near the dew point. After the first substream and the second substream are recombined, the 20 recombined working fluid is superheated to a heated gaseous working stream. ;In another embodiment, more than two heat sources are utilized to heat the working fluid. For example, in one embodiment three external heat source streams are utilized to heat the working fluid. In one embodiment, two or more Heat Recovery Vapor Generators (HRVG) having separate expansion turbines, or an 25 expansion turbine having first and second stages, are utilized to convert energy from the heated gaseous working stream. In another embodiment, one of the external heat source streams is a low temperature source and the other external heat source stream is a higher temperature source. In one embodiment, the low temperature source and the high temperature source have overlapping same temperature regions. In another 30 embodiment, the low temperature source and the higher temperature source do not have overlapping same temperature regions. ;Figure 1 illustrates a thermodynamic system for acquiring heat from a first external heat source stream and a second external heat source stream according to one ;WO 2004/102082 PCT/US2004/014496 ;7 ;embodiment of the present invention. In the illustrated embodiment, a spent stream 38 is condensed in distillation/condensation subsystem 10 forming a condensed stream 14. Condensed stream 14 is pressurized by pump P to form a liquid working stream 21. Liquid working stream 21 comprises a low boiling point component and a 5 higher boiling point component and is configured to be heated with two or more external heat source streams to produce a heated gaseous working stream. In one embodiment of the present invention, the liquid working stream 21 is still in a sub-cooled state. ;A number of different types and configurations of multi-component working 10 streams can be utilized without departing from the scope and spirit of the present invention. For example, in one embodiment the working stream comprises an ammonia-water mixture. In another embodiment, 1he working stream is selected from the group comprising two or more hydrocarbons, two or more freons, mixtures of hydrocarbons and freons, or other multi-component working streams having a low 15 boiling point component and a higher boiling point component. In yet another embodiment, the multi-component working stream is a mixture of any number of compounds with favorable thermodynamic characteristics and solubility. As will be appreciated by those skilled in the art, a variety of different types and configurations of distillation/condensation subsystems are known in the art and can be utilized 20 without departing from the scope and spirit of the present invention. ;The first external heat source stream 43-46 heats the liquid working stream 22-42 in a heat exchanger HE-1 in the path 45-46. Heating of liquid working stream 22-42 increases the temperature of liquid working stream 22-42 commensurate with the temperature of first external heat source stream in path 45-46. In one embodiment of 25 the present invention, the temperature of the working stream at point 42 approximates the bubble point of the low boiling point component. Where the temperature of the working stream at point 42 is less than the bubble point, the working stream comprises a liquid working stream in which both the low boiling point component and the high bubble point component are in a liquid state. ;30 As will be appreciated by those skilled in the art, a variety of different types and configurations of external heat source streams can be utilized without departing from the scope and spirit of the present invention. For example, in one embodiment at least one of the external heat source streams comprises a liquid stream. In another ;WO 2004/102082 ;PCT/US2004/014496 ;embodiment, at least one of the external heat source streams comprises a gaseous stream. In yet another embodiment, at least one of the external heat source streams comprises a combined liquid and gaseous stream. In one embodiment, the external heat source stream in path 45-46 comprises low temperature waste heat water. In 5 another embodiment, heat exchanger HE-1 comprises an economizer preheater. ;The working stream at point 42 is divided into first substream 61 and second substream 60. In one embodiment of the present invention, the working fluid is split between substream 61 and substream 60 in a ratio approximately proportional to the heat that flows from each source. In another embodiment, first substream 61 and 10 second substream 60 are at the bubble point and have substantially similar parameters except for flow rates. The first external heat source stream flows from point 43 to point 44 to heat the first substream 61-65 in the heat exchanger HE-2. The temperature of first external heat source stream in path 43-44 is greater than the temperature of first external heat source stream in path 45-46 due to heat exchange 15 that occurs in heat exchanger HE-2. The higher temperature of first external heat source stream in path 43-44 heats the first substream 61-65 to a higher temperature than the working fluid 22-42, which is heated by first external heat source stream in path 45-46. In one embodiment, the first substream is heated past the boiling point region of the low boiling point component but below the boiling point region of the 20 higher boiling point component. In the embodiment, the first substream has undergone partial vaporization and includes a vapor portion and a liquid portion. ;The second external heat source stream 25-26 flows from point 53 to point 54 to heat the second substream 60-64 in the heat exchanger HE-3. In the illustrated embodiment, the second external heat source stream in path 53-54 shares a same 25 temperature region with the first external heat source stream in path 43-44. As a result, the temperature of the second heat source in path 53-54 and first external heat source stream in path 43-44 is approximately the same. Similarly, the heat exchange that occurs in heat exchangers HE-2 and HE-3 is similar due to the similar temperatures of second external heat source stream in path 53-54 and first external 30 heat source stream in path 43-44. As a result, second substream 60-64 approximates the temperature of first substream 61-65. Second substream 60-64 is heated to a higher temperature than the working fluid 22-42. In one embodiment, the second substream is heated past the boiling point region of the low boiling point component ;WO 2004/102082 ;PCT/US2004/014496 ;but below the boiling point region of the higher boiling point component. In the embodiment, the second substream has undergone partial vaporization and includes a vapor portion and a liquid portion. ;First substream 65 and second substream 64 are recombined into a recombined 5 working fluid 63. Where the first substream 65 and the second substream 64 are heated past the boiling point of the low boiling point component but below the boiling point of the higher boiling point component, the recombined working fluid is partially vaporized and includes a vapor portion and a liquid portion. The second external heat source stream flows in path 25-52 to heat recombined working fluid 62-30 in heat 10 exchanger HE-4. ;The temperature of second external heat source stream in path 25-52 is greater than the temperature of second external heat source stream in path 53-54 due to heat exchange that occurs in heat exchanger HE-4. The higher temperature of second external heat source stream in path 25-52 heats the recombined working stream 62-30 15 to a higher temperature than the recombined working stream 63. In one embodiment, the recombined working stream 62-30 is heated past the boiling point region of both the low boiling point component and the boiling point of the higher boiling point component to form a heated gaseous working stream 31. In the embodiment, the heated gaseous working stream 31 has undergone total vaporization and includes only 20 a vapor portion. In another embodiment, the heated gaseous working stream 31 has not undergone total vaporization and includes a vapor portion and a liquid portion. ;By utilizing first and second substreams for overlapping same temperature regions of the first and second external heat source streams, the increased heat requirement of the working fluid boiling region can be transferred in an efficient a 25 manner that increases the power production capacity of the thermodynamic system so that more power can be generated than would be 1he case if the two heat sources were used in separate generating systems. In one embodiment of the present invention heat exchanger HE-1, heat exchanger HE-2, heat exchanger HE-3, and heat exchanger HE-4 comprise a Heat Recovery Vapor Generator (HRVG). The function of the HRVG is 30 to heat working fluid at a high pressure from sub-cooled liquid to a superheated vapor to acquire heat from waste heat sources (typically hot gases or liquids). The superheated vapors are admitted into a power generating turbine to convert the vapor into useful energy. ;WO 2004/102082 ;PCT/US2004/014496 ;10 ;For the type of working fluid under discussion, the ranges of sensible heat acquisition include sub-cooled liquid up to the bubble point and the dew point up through superheated vapor. The working fluids have a heat capacity which varies relatively little with temperature. In other words, in each region the working fluid 5 gains about the same amount of temperature for an equal amount of heat input, though the temperature gain is somewhat larger in the vapor than in the liquid. Between the bubble point and the dew point lies the boiling region, which for a multiple-component working fluid spans a range of temperatures. In this region, much more heat is utilized for each unit of working fluid temperature gain, and the amount can be 10 variable. As will be appreciated by those skilled in the art, the type of working fluid utilized, the degree to which it is heated, and the amount of vaporization can vary without departing from the scope and spirit of the present invention. For example, in one embodiment, the parameters of the working fluid are dependent on the type and temperature of external heat source stream utilized. In another embodiment, the 15 parameters of the working fluid are dependent on the configuration and juxtaposition of components of the HRVG. ;In one embodiment the working fluid is a high-pressure sub-cooled liquid at point 21. The stream continues to point 22, which maybe at a slightly lower pressure due to piping and control valve losses. In the embodiment, the first external heat 20 source stream 43-46 comprises a low temperature source and the second external heat source stream comprises a higher temperature external heat source stream. At point 22 the liquid working stream enters heat exchanger HE-1 where it is heated by the low temperature part of the low temperature source 45-46, emerging at point 42 still slightly sub-cooled. (It is also possible that mechanical considerations would allow 25 working fluid 42 to be somewhat above the bubble point as long as its vapor fraction is small enough so that the working fluid still flows smoothly through the 60/61 split. In another embodiment it can be desireable to begin to boil only in the presence of both heat source streams.) ;In the illustrated embodiment the working fluid 42 splits into substreams 60 30 and 61 in a ratio approximately proportional to the heat flows from the first and second external heat source stream. Substreams 60 and 61 are at the bubble points, and have parameters that are substantially the same except for flow rates. The substreams 61-65 and 60-64 continue through heat exchangers HE-2 and HE-3, ;WO 2004/102082 PCT/US2004/014496 ;11 ;absorbing heat from the higher-temperature and lower-temperature external heat source streams respectively, attaining warmer and preferably similar parameters at points 64 and 65 to where the streams are recombined at point 63. Point 63 may be above or below the dew point. The superheating of the recombined working fluid is 5 finished in HE-4 by heating from the higher-temperature heat source stream, attaining the parameters of point 30. ;Once the heated gaseous working stream 30 has left the heat exchanger HE-4 it moves to turbine T. The turbine T expands the heated gaseous working stream to transform the energy of the heated gaseous working stream into a useable form. 10 When the heated gaseous working stream is expanded it moves to a lesser pressure providing useful mechanical energy to turbine T to generate electricity or other useful energy and produces a spent stream. As the cycle is closed, the spent stream moves to the distillation/condensation subsystem where the expanded spent stream is condensed into a condensed stream in preparation for being pumped to a higher 15 pressurizationbypumpP. ;Figure 2 illustrates a thermodynamic system for acquiring heat from a first external heat source stream 43-45 and a second external heat source stream 25-26 having overlapping temperature regions according to one embodiment of the present invention. In the illustrated embodiment, the liquid working stream 22 is divided to 20 form a first substream 61 and a second substream 60 rather than being heated at a heat exchanger HE-1 (see Fig. 1). As a result, liquid working stream 22 is heated from a sub-cooled liquid past the boiling point utilizing heat exchanger HE-2 and heat exchanger HE-3. First substream 61-65 is heated in heat exchanger HE-2. Second substream 60-64 is heated in heat exchanger HE-3. First substream 61-65 and second 25 substream 60-64 are recombined at point 63 in a recombined stream. The recombined stream is superheated at heat exchanger HE-4. ;As will be appreciated by those skilled in the art, different configurations of closed loop thermodynamic systems can be utilized without departing from the scope and spirit of the present invention. The use of additional heat exchangers can 30 optimize heat transfer within the system to maximize the amount of heat exchange that can be acquired from external heat source streams. However, additional components can add additional cost and complexity in the system while providing unnecessary optimization. ;WO 2004/102082 PCT/US2004/014496 ;12 ;Where the temperature of the external heat source streams is sufficient to produce desired temperatures of the working fluid, such optimization may not be required. Alternatively, where the desired temperatures of the working fluid are sufficiently low that optimization is not required, a system may not require additional 5 heat exchangers. For example, in some prospective heat sources the temperature of the higher temperatures source (second external heat source stream 25-26) must be a good deal higher than ambient because of flue gas acid dew point corrosion requirements. In such systems, optimization provided by the use of heat exchanger HE-1 may be necessary. Where there is no such constraint, as in the illustrated 10 embodiment, additional cost associated with the inclusion of heat exchanger HE-1 may not be required. ;Figure 3 illustrates a thermodynamic system for acquiring heat from a first heat source and a second heat source having non-overlapping temperature regions according to one embodiment of the present invention. In the illustrated embodiment, 15 the liquid working stream moves from point 22 to heat exchanger HE-1. Liquid working stream 60-63 is heated by first external heat source stream 43-45 at heat exchanger HE-1. From point 63 working stream moves to heat exchanger HE-3. Working stream 62-30 is heated by second external heat source stream 25-26 at heat exchanger HE-3. ;20 In the illustrated embodiment, the multi-component working stream is heated without dividing the multi-component working stream into a first and second substream. The first external heat source stream 43-45 and the second external heat source stream 25-26 do not share overlapping same temperature regions. The first external heat source stream 43-45 comprises a low temperature source and the second 25 external heat source stream 25-26 comprises a higher temperature source. The illustrated system can be utilized where the temperature of point 26 must be of a value not far above the temperature of point 43. Where the optimization required by heat exchanger HE-2 is not required or where the use of heat exchanger HE-2 would not be economical, two heat exchangers in series as illustrated in Figure 3 can be utilized. 30 The use of two heat exchangers in series can be desirable where the first and second heat source flows are comparable. ;As will be appreciated by those skilled in the art, a variety of types and configurations of multiple heat exchangers in series can be utilized without departing ;WO 2004/102082 ;PCT/US2004/014496 ;13 ;from the scope and spirit of the present invention. For example, in one embodiment, a third heat exchanger in series can be utilized. In another embodiment, more than three heat exchangers can be utilized without departing from the scope and spirit of the present invention. ;5 As will be appreciated by those skilled in the art, a variety of types and configurations of heat exchangers can be utilized with the thermodynamic systems of the present invention without departing from the scope and spirit of the present invention. For example, in one embodiment one or more of the multiple heat exchangers comprises a boiler. In another embodiment, one or more of the multiple 10 heat exchangers comprise an evaporator. In another embodiment, one or more of the multiple heat exchangers comprise an economizer preheater. In another embodiment, another type of heat exchanger that allows the transfer of heat from an external heat source stream to a working fluid stream is utilized. Jh yet another embodiment, the type of heat exchanger utilized is determined by its placement and/or junction in the 15 system. The heat exchanger is one example of a means for transferring heat to a working stream. ;Figure 4 illustrates a thermodynamic system for acquiring heat from a first external heat source stream and a second external heat source stream having overlapping temperature regions in which the first external heat source stream is the 20 higher temperature source. In the embodiment, working stream 22-40 is heated by first external heat source stream 43-46 in path 45-46 in heat exchanger HE-1. The working stream 40 is divided into first substream 61 and second substream 60. First substream 61-65 is heated in heat exchanger HE-2 by first external heat source stream 43-46 in path 42-44. Second substream 60-64 is heated in heat exchanger HE-3 by 25 second external heat source stream 25-26. ;Subsequent to heating in heat exchanger HE-2 and heat exchanger HE-3, the first and second substreams are recombined into a recombined stream 63. The recombined stream 63-30 is heated in heat exchanger HE-5 to transfer heat from first external heat source stream 43-46 in path 63-30. Where the temperature of first 30 external heat source stream 43-46 at point 43 is higher than the temperature of second heat source 25-26 at point 25, the superheating of working stream 63-30 is accomplished by the first external heat source stream 43-46 at heat exchanger HE-5 in ;WO 2004/102082 ;PCT/US2004/014496 ;14 ;path 43-41. In the embodiment, second heat source stream 25-26 is used primarily to add heat in the boiling region. ;In the embodiment, heat from the first and second external heat source streams is optimized utilizing the overlapping same temperature regions of the external heat 5 source streams even where the first external heat source stream is the high temperature source. The first external heat source stream is utilized both to preheat the liquid working stream and to superheat the recombined working stream in addition to providing heat in the boiling region. As will be appreciated by those skilled in the art, a variety of types and configurations methods and apparatuses for utilizing two 10 working streams to heat a multi-component working stream in a single HRVG can be utilized without departing from the scope and spirit of the present invention. ;Figure 5 illustrates a thermodynamic system for acquiring heat from a first heat source using a first heat recovery generator and a second heat source utilizing a second heat recovery vapor generator according to one embodiment of the present 15 invention. In the illustrated embodiment, the condensed stream 14 is pumped to a higher pressurization at pump PI to form a liquid working stream 21. The liquid working stream is split at point 29 into a first substream 66 and a second substream 32. First substream 66-65 is heated by the first external heat source stream 43-45 in the heat exchanger HE-1. Once the first substream is heated in the heat exchanger 20 HE-1 it is converted into a heated gaseous working stream 65 which is sent an intermediate pressure turbine IPT without being recombined with the second substream. Second substream 32 is pumped to yet a higher pressurization at pump P2. After being pumped to a higher pressurization, working fluid 22-30 is heated by a second heat source 25-26 in heat exchanger HE-3 and becomes a heated gaseous 25 working stream 30. Heated gaseous working stream 30 is sent to a high pressure turbine turbine HPT to be expanded at a high pressure and recombined with stream 67 to form stream 44. In the illustrated embodiment, the first external heat source stream 43-45 comprises a low temperature source and the second external heat source stream 25-26 comprises a higher temperature source. Additionally, each of the substreams is 30 heated in a separate HRVG rather than recombining the streams within a single HRVG system. ;In the embodiment, the working fluid parameters at point 65 contain too much non-vaporized liquid to transport practically at the pressure necessary for the turbine ;15 ;HPT inlet. Accordingly, the working fluid 66-67 and associated heat exchanger HE-1 are pressurized to a lower pressurization while the working fluid 22-30 and associated heat exchanger HE-3 are pressurized to a higher pressurization with a second pump P2. The two separate working streams are not recombined before being expanded. ;5 Instead, the lower-pressure working fluid 65 is admitted to a secondary turbine, or a secondary component of the same turbine, at an appropriate later stage. The illustrated configuration preserves much of the advantage of using two heat sources in parallel. ;10 two external heat source streams according to one embodiment of the present invention. In the illustrated embodiment, aspects of the systems of Figure 1 and Figure 5 are utilized in combination. A first heat source 25-26 and a second heat source 43-46 are utilized in a first HRVG in a system similar to that shown in Figure 1. A third external heat source 85-88 is utilized to heat a first working stream 69-66 15 in path 68-67 at a heat source HE-6 in path 86-87 in a second HRVG at a lower pressurization similar to that shown in Figure 5. As will be appreciated by those skilled in the art, aspects of different embodiments of the present invention can be combined without departing from the scope and spirit of the present invention. ;20 departing from its spirit or essential characteristics. The described embodiments are to be considered in all respects only as illustrative and not restrictive. The scope of the invention is, therefore, indicated by the appended claims rather than by the foregoing description. All changes which come within the meaning and range of equivalency of the claims are to be embraced within their scope. ;25 The term "comprising" as used in this specification means "consisting at least in part of'. When interpreting each statement in this specification that includes the term "comprising", features other than that or those prefaced by the term may also be present. Related terms such as "comprise" and "comprises" are to be interpreted in the same manner. ;Figure 6 illustrates a thermodynamic system for acquiring heat from more than ;The present invention may be embodied in other specific forms without ;INTELLECTUAL PROPIHT* OFRCP OP N.Z -7 MAR 2008 PcCPtVED

Claims (41)

16

1. A method for implementing a thermodynamic cycle comprising: expanding a multi-component gaseous working stream transforming its energy into a usable form and producing a spent stream; condensing the spent stream producing a condensed stream; 5 pressurizing the condensed stream and producing a working stream; and heating the working stream utilizing multiple external heat source streams. 10

2. The method of claim 1, wherein the multiple external heat source streams have different temperatures.

3. The method of claim 2, wherein two or more of the multiple external heat source streams share a same temperature region. 15

4. The method of claim 1, wherein heating the working stream comprises acquiring heat from two or more external heat source streams.

5. The method of claim 1, further comprising splitting the working stream 20 into a first substream and a second substream.

6. The method of claim 5, wherein the first substream is heated utilizing at least a first external heat source stream. 25

7. The method of claim 6, wherein the second substream is heated utilizing at least a second external heat source stream. 17

8. A method for implementing a thermodynamic cycle comprising: transforming energy from a gaseous multi-component working stream into a usable form and producing a spent stream; condensing the spent stream to produce a liquid working stream; 5 heating the liquid working stream to the bubble point; heating the working stream from the bubble point at least to the boiling region utilizing overlapping same-temperature regions of a plurality of external heat source streams to increase the heating capacity at the boiling region; and 10 heating the working stream to above the boiling point to create a heated gaseous working stream.

9. The method of claim 8, wherein condensing the spent stream to produce a liquid working stream comprises condensing the spent stream to form a condensed 15 stream and pressurizing the condensed stream to produce a liquid working stream.

10. The method of claim 8, wherein heating the liquid working stream is conducted in a heat exchanger. 20

11. The method of claim 10, wherein the heating the liquid working stream is conducted in a heat exchanger comprising an economizer preheater.

12. The method of claim 8, further comprising splitting the liquid working stream into a first substream and a second substream. 25

13. The method of claim 12, wherein the first substream is heated utilizing an overlapping same temperature region of a first external heat source stream. 7mtpi I FCTUAL PROPER OFFICE OF N.2. - ( MAR 2008 18

14. The method of claim 12, wherein the second substream is heated utilizing an overlapping same temperature region of a second external heat source stream. 5

15. The method of claim 8, wherein the plurality of external heat source streams comprises two or more external heat source streams.

16. The method of claim 8, wherein the plurality of external heat source streams comprise more than two external heat source streams. 10

17. The method of claim 7, wherein the working stream produced by pressurizing the condensed stream is a liquid working stream.

18. The method of claim 17, wherein the first substream is heated in a first 15 heat recovery vapor generator.

19. The method of claim 18, wherein the second substream is heated in a second heat recovery vapor generator.

20 20. The method of claim 19, wherein the second substream is pressurized at a greater pressurization than the first substream.

21. The method of claim 19, wherein the first substream and the second substream are expanded without being recombined. 25

22. The method of claim 17, wherein the first substream and the second substream are expanded after being recombined.

23. The method of claim 22, wherein the first substream and the second 30 substream are heated in a single vapor recovery generator. PROPeFrrY OFFICE OF N.Z - ( MAR 2088 19

24. The method of claim 17, wherein the second substream is split creating additional substreams, the additional substreams of the second substream being heated by first and second external heat source streams and the first substream is heated in a 5 first heat recovery generator utilizing a third external heat source stream.

25. The method of claim 24, wherein the first substream is heated at a lower pressurization than the substreams of the second substream. 10

26. An apparatus for implementing a thermodynamic cycle comprising: an expander that is connected to receive a multi-component gaseous working stream and that is adapted to transform the energy of the multi-component gaseous working stream into a usable form and producing a precondensed stream; 15 a condenser adapted to condense the pre-condensed stream producing a liquid working stream; a pump configured to pressurize the condensed stream to produce a working stream; and a means for transferring heat to the working stream utilizing 20 multiple sources of external heat.

27. The apparatus of claim 26, wherein the expander comprises a turbine.

28. The apparatus of claim 27, wherein the turbine includes a first 25 component and a second component.

29. The apparatus of claim 26, wherein the expander comprises a first turbine and a second turbine. INTELLECTUAL PROFB^ QFFiCF OF N2. ~ I MAR 2808 RECELYJE.Pl 20

30. The apparatus of claim 26, wherein the condenser comprises a distillation/condensation subsystem.

31. The apparatus of claim 26, wherein the means for transferring heat 5 comprises a heat exchanger.

32. The apparatus of claim 31, wherein the heat exchanger comprises a plurality of heat exchangers. 10

33. The apparatus of claim 32, wherein a first heat exchanger comprises an economizer preheater which heats the liquid working stream to near the bubble point.

34. The apparatus of claim 33, wherein at least a second heat exchanger heats the working stream in the boiling point region. 15

35. The apparatus of claim 34, wherein at least a third heat exchanger superheats the working stream to a heated gaseous working stream.

36. An apparatus for implementing a thermodynamic cycle comprising: 20 an expander adapted to expand a multi-component gaseous working stream transforming its energy into a usable form and producing a spent stream; a condenser for converting the spent stream to produce a condensed stream; 25 a pump for pressurizing condensed stream to produce a working stream; a first heat exchanger to heat the working stream utilizing a first external heat source stream; a divider to form a first substream and a second substream form a 30 working stream; 7 um 2008 n 21 * a second heat exchanger to heat the first substream utilizing the first external heat source stream; a third heat exchanger to heat the second substream utilizing a second external heat source stream; a recombiner to form a recombined stream from the first substream and the second substream; and a fourth heat exchanger to heat the recombined stream to form a heated gaseous working stream. 10 37. The method of claim 1, wherein the step of heating the working stream utilizing multiple heat source streams comprises: heating the working stream utilizing a first external heat source stream; splitting the working stream to form a first substream and a 15 second substream; heating the first substream utilizing the first external heat source stream; heating the second substream utilizing a second external heat source stream; 20 recombining the first substream and the second substream to form a recombined stream; and heating the recombined stream to form a heated gaseous working stream. 25 38. The method of claim 1, wherein the step of heating the working stream utilizing multiple heat source streams comprises splitting the working stream into a first substream and a second substream; heating the first substream utilizing at least a first external heat source stream; and heating the second substream utilizing at least a second external heat source stream.

INTELLECTUAL PROPERTY OFFICE OF N-7.

( MAR 2008 V 22 5 %

39. The method of claim 1 or 8, and substantially as herein described with reference to any embodiment disclosed.

40. The apparatus of claim 26 or 36, and substantially as herein described with reference to any embodiment disclosed.

41. An apparatus for implementing a thermodynamic cycle substantially as herein described with reference to any embodiment shown in the accompanying drawings.