NZ504369A - Spiral wound, externally mounted parallel heat exchanger tubes for water heater using heat pump - Google Patents

Spiral wound, externally mounted parallel heat exchanger tubes for water heater using heat pump

Info

Publication number
NZ504369A
NZ504369A NZ504369A NZ50436998A NZ504369A NZ 504369 A NZ504369 A NZ 504369A NZ 504369 A NZ504369 A NZ 504369A NZ 50436998 A NZ50436998 A NZ 50436998A NZ 504369 A NZ504369 A NZ 504369A
Authority
NZ
New Zealand
Prior art keywords
heat
tank
water heater
heat exchange
water
Prior art date
Application number
NZ504369A
Inventor
Rafiqul Islam
Original Assignee
Quantum Energy Systems Pty
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Quantum Energy Systems Pty filed Critical Quantum Energy Systems Pty
Publication of NZ504369A publication Critical patent/NZ504369A/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H4/00Fluid heaters characterised by the use of heat pumps
    • F24H4/02Water heaters
    • F24H4/04Storage heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/0005Details for water heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/06Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with the heat-exchange conduits forming part of, or being attached to, the tank containing the body of fluid
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B30/00Heat pumps
    • F25B30/02Heat pumps of the compression type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B39/00Evaporators; Condensers
    • F25B39/04Condensers

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Heat-Pump Type And Storage Water Heaters (AREA)
  • Resistance Heating (AREA)
  • Cookers (AREA)

Abstract

A water heater comprises a water tank and a heat pump system (20). The heat exchanger (26) includes an inlet manifold (27) connected to the compressor (22), an outlet manifold (28) connected to the evaporator (25) and a plurality of heat exchange tubes (29, 30) connected in parallel between the inlet and outlet manifolds (27, 28). The heat exchange tubes (29, 30) are wound helically around the water tank and secured to the tank wall (32) in a heat conductive relation with the tank. Heat from condensation of the refrigerant liquid circulating through the heat pump system (20) is transferred to water contained in the tank.

Description

WO 99/24764 PCT/AU98/00922 " HEAT EXCHANGER FOR WATER HEATER USING HEAT PUMP FIELD OF THE INVENTION This invention relates to improvements in water heaters, and more particularly to an improved heat exchange arrangement for a water tank of a water heater.
BACKGROUND TO THE INVENTION The use of solar energy to supplement water heating systems is becoming increasingly practical with developments in technology.
For example, in Australian Patent No. 509,901 there is described a solar boosted heat pump system which converts solar energy particularly efficiently and transfers l o that energy by the use of a refrigerant heat pump.
In European Patent No. 0 336 751 there is disclosed a water heater comprising a water tank having a cold water inlet adjacent one end and a hot water outlet adjacent the other end, a heat exchange tube adapted to carry a refrigerant fluid and wound around the water tank by a heat-conductive bonding, an evaporator for absorbing heat 15 energy from ambient conditions and a compressor for circulating refrigerant fluid through the heat exchange tube and to the evaporator. The heat exchange tube is secured exterrfaliyto the wall of the water tank by a heat-conductive bonding material and the tube is under applied tension when it is secured to the tank to reduce the likelihood of the heat-conductive bonding material breaking during expansion or 20 contraction of the tube and tank during use.
The heat exchange arrangement of European Patent No. 0 336 751 operates quite effectively to heat water in the water tank For example, it is possible to heat water in a 340 litre tank to about 60°C in approximately four hours. It is, however, Printed from Mimosa WO 99/24764 PCT/AU98/00922' - desirable to provide an improved heat exchange arrangement which can heat water in a water tank more efficiently than the arrangement of European Patent No. 0 336 751 It is an object of the present invention to overcome or ameliorate at least one of the disadvantages of the prior art, or to provide a useful alternative.
SUMMARY OF THE INVENTION Accordingly, the present invention provides a water heater including. a water tank having a tank wall formed from a material having heat transfer properties; and a heat pump system including a heat exchanger for transferring heat to the water 10 tank, an evaporator, and a compressor for circulating refrigerant fluid to the evaporator via the heat exchanger, wherein the heat exchanger includes an inlet manifold connected to the compressor, an outlet manifold and a plurality of heat exchange tubes connected in parallel between the inlet and outlet manifolds, said plurality of heat exchange tubes being wrapped around the water tank and secured to the tank wall in 15 heat-conductive relation with the tank wall to transfer heat from condensation of the refrigerant liquid within the tubes through the tank wall to water contained in the tank.
In a more particular form, the present invention provides a water heater including: a water tank having a tank wall formed from a material having heat transfer 20 properties; and a heat pump system including a heat exchanger for transferring heat to the water tank, an evaporator, and a compressor for circulating refrigerant fluid to the evaporator via the heat exchanger, Printed from Mimosa WO 99/24764 PCT/AU98/00922 " - wherein the heat exchanger includes an inlet manifold connected to the compressor, an outlet manifold and a plurality of heat exchange tubes connected in parallel between the inlet and outlet manifolds, said plurality of heat exchange tubes being wrapped around the water tank and secured to the tank wall in a heat-conductive 5 relation with the tank wall in order to transfer heat from the refrigerant due to de-superheating and condensing of the refrigerant within the tubes through the tank wall to water contained in the tank.
Preferably, the heat exchange tubes are secured to the tank wall by a heat-conductive bonding material It is further preferable for the heat exchange tubes to be 10 under applied tension upon being secured to the tank wall. This tension reduces the likelihood of the heat-conductive bonding material breaking during expansion and contraction of the tube and tank due to changes in temperature during use.
Preferably the heat exchange tubes are wound helically around the water tank. It is further preferable that a pair of heat exchange tubes are provided which are wound 15 helically around the water tank. The tubes preferably extend from a position adjacent a lower end of the tank close to the cold water inlet level to a position adjacent, and preferably as close as possible, to the hot water outlet at the top side wall of the tank.
The upper ends of the heat exchange tubes are conveniently connected to the inlet manifold and the lower ends of the heat exchange tubes are connected to the 20 outlet manifold, preferably by one or more riser tubes.
Preferably the one or more riser tubes include a "U" bend or the like before rising vertically. The "U" bend acts as an oil trap to catch, accumulate and draw oil back to the compressor through the riser(s). Additionally, the bottom of the "U" bend Printed from Mimosa "WO 99/24764 PCT/AU98/00922 should be below the bottom of the lowest point of the lowest turn of the respective tube.
Preferably, the water tank and the heat exchange tubes are made from the same matenal, or materials with substantially the same co-efficient of expansion. This helps 5 to reduce the likelihood of heat transferring contact being lost due to different coefficients of expansion between the tank and tube.
In one preferred form of the invention the water tank and the heat exchange tubes are made from steel.
Preferably the lengths of the parallel tubes are substantially the same and are 10 constructed from the same matenal. It is also preferable for the tubes to have substantially the same intenor surface finish.
Preferably, the spacing between the consecutive pair of windings is preferably uniform from the bottom to the top of the tank.
BRIEF DESCRIPTION OF THE DRAWINGS 15 A preferred embodiment of the present invention will now be described, by way of example only, with reference to the accompanying drawings, in which: Figure 1 is a schematic diagram of a solar boosted heat pump system for heating water, Figure 1A is an enlarged fragmentary sectional elevation of a portion of a water 20 tank of the system showing the attachment of a heat exchange tube thereof; and Figure 2 is a schematic diagram of a heat pump system incorporating a water tank with an improved heat exchanger in accordance with the invention.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENT Printed from Mimosa WO 99/24764 PCT/AU98/00922 " ~~ Referring to Figure 1, there is shown a solar boosted heat pump system as disclosed in European Patent No 0 336 751, the contents of which are incorporated herein by reference. The heat pump system comprises a water tank 1, a heat exchange tube 8 carrying refrigerant wrapped around the water tank 1, a compressor 12, a 5 receiver/filter/drier 13 and a series of solar evaporator plates 15. Each evaporator plate 15 contains a number of refrigerant passages 16 arranged in a serpentine configuration. The water tank 1 and heat exchange tube 8 are enclosed in a housing 10 containing insulating foam 11, and the compressor 12 and receiver/filter/drier 13 are mounted on top of a refrigeration chassis 14 located on top of the tank housing 10. 10 The system has a thermostat control system including a thermostat T. The system also has a thermostatic expansion valve, Tx, in the liquid line between the receiver/filter/drier 13 and the evaporator plates 15.
The water tank 1 has a cylindrical wall 2, a bottom wall 3, a convex top wall 4, a cold water inlet 5 adjacent the bottom wall 3, incorporating a diffiiser or diverter 6 and 15 a hot water outlet 7 adjacent the top wall 4. While the bottom wall 3 is shown to be concave, it may be convex if desired. The heat exchange tube 8 carrying a refrigerant B, such as refrigerant R12 or R22, is wrapped around the external surface of the tank wall 2. The tube 8 is preferably flattened as shown in Figure 1 A, so that it is D-shaped in cross-section, and the flattened portion is heat conductively bonded to the surface of 20 the wall 2 by means of a thin film of solder 9 or the like between the outer surface of the wall 2 of the tank 1 and the flat face of the tube 8. To ensure the best possible contact during soldering and during expansion and contraction of the tube and tank wall 2 in use, the tube 8 is wound around the tank 1 under an applied tension of the Printed from Mimosa WO 99/24764 PCT/AU98/00922 order of 1200 to 1300 N, and is secured to the tank 1 while under tension. This may be achieved in the manner described in European Patent No. 0 336 751.
It will be appreciated that by attaching the refrigerant carrying tube 8 to the external surface of the tank 1, a double-wall effect is automatically achieved and the 5 protection required by the relevant water authorities, which stipulates a double walled tube where a refrigerant carrying tube is associated with water, is satisfied. Both the tube 8 and the tank 1 are preferably made from a similar material, or at least from materials having similar co-efficients of thermal expansion.
In the present case, the tube 8 and the tank 1 are fabricated from steel or 10 stainless steel. For example, the tube may be Bundyweld steel tubing while the tank 1 may be made from mild steel. As mentioned above, the thermal bond between the tube 8 and the tank 1 is maintained by the winding of the tube 8 around the tank 1 under tension. Where materials having slightly different co-efficients of thermal expansion are used, the different rates of expansion and contraction of the materials 15 may be compensated for by increasing the winding tension of the tube 8. In any event, the winding of the tube under tension ensures that the thermal bond is maintained notwithstanding the flexing of the materials caused by expansion and contraction in use.
In use, the compressor 12 supplies refrigerant gas under pressure to the heat 20 exchange tube 8 and as the refrigerant B condenses in the tube 8, heat is transferred through the tank wall 2 to the water contained in the tank 1. The condensed refrigerant then passes through the receiver/filter/drier 13 and thermostatic expansion valve Tx to the evaporator plates 15 which are preferably mounted in a position Printed from Mimosa WO 99/24764 PCT/AU98/00922" - exposed to the sun so that the refrigerant in the passages 16 of the plates 15 can absorb heat from the ambient conditions before the refrigerant is returned via supply line 12G to the compressor 12.
While the evaporator plates are shown in the above embodiment as being 5 mounted in a position exposed to the sun, the plates may be mounted even in shaded locations in areas where the ambient temperature is high. In such a situation, the heat pump operates at least partly as an air source heat pump.
Referring to Figure 2, there is shown a heat pump system 20 for a water tank 21 similar to that of Figure 1 but incorporating an improved heat exchange arrangement. 10 The heat pump system 20 includes a compressor 22, a receiver/filter/drier 23, a thermostatic (Tx) expansion valve 24, an evaporator 25 and a heat exchanger 26 connected between the compressor 22 and the receiver/filter/drier 23 The evaporator 25 preferably comprises at least one solar collector panel 15 as described with reference to Figure 1. The number of solar panels 15 may vary depending upon the 15 size of the compressor and the climatic region for which the heat pump system is designed.
The heat exchanger 26 comprises an inlet manifold 27 connected to the compressor 22, an outlet manifold 28 connected to the receiver/filter/drier 23 and a pair of heat exchange tubes 29 and 30 wrapped around the water tank 21 and 20 connected in parallel between the inlet and outlet manifolds 27 and 28.
Whereas the outlet manifold was shown to be at the same level as the inlet manifold, the outlet manifold 28 can be positioned anywhere between the ends of the wound tubes and the top of the tank.
Printed from Mimosa WO 99/24764 PCT/AU98/00922 " - The water tank 21 is similar to the tank of Figure 1 in that it has a cylindrical wall 32, a bottom wall 33, a convex top wall 34, a cold water inlet 35 adjacent the bottom wall 33 incorporating a diffiiser or diverter 36 and a hot water outlet 37 adjacent the top wall 34. The heat exchange tubes 29 and 30 are preferably flattened 5 so as to the D-shaped in cross-section similar to the tube 8 of Figure 1 A. The flattened portions of the heat exchange tubes 29 and 30 are secured to the external surface of the cylindrical wall 32 of the water tank 21 by a heat-conductive bonding material, such as a thin film of solder.
To ensure the best possible contact during soldering and during expansion and 10 contraction of the tube and tank wall 2 in use, the tube 8 is wound around the tank 1 under an applied tension, preferably of the order of 1200 to 1300 N, and is secured to the tank 1 while under tension. This may be achieved in the manner described in European Patent No. 0 336 751.
In a preferred embodiment, the heat exchange tubes 29 and 30 are formed from 15 Bundyweld steel tubing having an internal diameter of about 12 mm, and the tubes 29 and 30 are wound helically around the tank 21 from a position closest to the cold water inlet the tank to a position as close as possible to the hot water outlet at the top side wall of the tank. The tank 21 is preferably fabricated from a material having a similar co-efficient of thermal expansion as the tubes 29 and 30, such as mild steel. 20 Where materials having slightly different co-efficients of thermal expansion are used, the different rates of expansion and contraction of the materials may be compensated for by increasing the winding tension of the tube 8. In any event, the winding of the tube under tension ensures that the thermal bond is maintained Printed from Mimosa WO 99/24764 PCT/AU98/00922 " _ notwithstanding the flexing of the materials caused by expansion and contraction in use.
The upper ends of the heat exchange tubes 29 and 30 are connected directly to the inlet manifold 27, whereas the lower ends of the heat exchange tubes 29 and 30 are 5 connected to the outlet manifold 28 by respective riser tubes 39 and 40 The riser tubes 39,40 may be conveniently formed from a 3/8 inch (9.5 mm) diameter copper tube. The inlet and outlet manifolds 27 and 28 are preferably also formed from copper, the inlet manifold 27 having an upper tube section 41 connected to the compressor 22 of about 1/2 inch (12.5 mm) diameter and the outlet manifold 28 10 having an upper tube section 42 connected to the receiver/filter/drier 23 of about 3/8 inch (9.5 mm) diameter. It will, however, be appreciated that the sizes of the heat exchange tubes 29, 30, the riser tubes 39, 40 and the upper tube sections 41,42 of the manifolds 27, 28 and the materials from which they are made may vary from different applications The "U" tube formation 43 is created to trap, accumulate and help rising of compressor oil returning to the compressor via the rest of the closed circuit.
In a particularly preferred embodiment, for a 340 litre water tank, the total length of each of the heat exchange tubes 29,30 is about 32 metres, and each of the tubes 29, 30 is wound helically around the water tank 21 for about 18 turns with the 20 pitch of each winding being about 54 mm.
It has been found that a heat exchanger arrangement with at least two heat exchange tubes connected in parallel between the inlet and outlet manifolds provides more rapid and efficient heating of water in a water tank as compared with the single Printed from Mimosa WO 99/24764 PCT/AU98/00922 " - tube arrangement of Figure 1 Two parallel heat exchange tubes positioned very close to each other effectively increase the tank surface temperature and maintain an evenly constant temperature across the nearest tubes. This leads to increased heat transfer between the tank and the water. For instance, for a 340 litre water tank, the 5 arrangement of Figure 2 with a pair of tubes 29, 30 as described above can heat up water from ambient temperature to about 60°C in approximately two hours compared with approximately four hours for a single tube arrangement such as that of Figure 1.
There is a limit to the size of the compressor which can be installed with the heat transfer arrangement of Figure 1, and thus a limit to the hot water recovery rate 10 achievable. A design for a higher recovery capacity is often required for larger domestic or commercial applications. For R22 refrigerant, the limit using the previous arrangement of Figure 1 is about 1300W nominal compressor size for a single 12 mm tube wrapped around the tank. Having plural coils wrapped around the tank allows a larger gas flow rate enabling a larger compressor to be mstalled to achieve the high 15 recovery rate required for larger domestic or commercial installations.
It will be appreciated that various modifications and/or alterations may be made to the embodiment of the invention described above without departing from the scope and spirit of the present invention. For instance, it is envisaged that more than two heat exchange tubes could be connected in parallel between the inlet and outlet 20 manifolds and wound around the water tank.
Printed from Mimosa WO 99/24764 PCT/AU98/00922 - II -

Claims (1)

  1. CLAIMS 1 A water heater including: a water tank having a tank wall formed from a material having heat transfer properties; and 5 a heat pump system including a heat exchanger for transferring heat to the water tank, an evaporator, and a compressor for circulating refrigerant fluid to the evaporator via the heat exchanger, wherein the heat exchanger includes an inlet manifold connected to the compressor, an outlet manifold and a plurality of heat exchange tubes connected in 10 parallel between the inlet and outlet manifolds, said plurality of heat exchange tubes being wrapped around the water tank and secured to the tank wall in heat-conductive relation with the tank wall to transfer heat from the refrigerant due to de-superheating and condensing of the refrigerant within the tubes through the tank wall to water contained in the tank 15 2 A water heater according to claim 1 wherein the heat exchange tubes are secured to the tank wall by a heat-conductive bonding material. 3 A water heater according to claim 1 or 2 wherein the heat exchange tubes are wound helically around the water tank. 4. A water heater according to any one of claims 1 to 3 wherein the upper ends of 20 the heat exchange tubes are connected to the inlet manifold and the lower ends of the heat exchange tubes are connected to the outlet manifold 5. A water heater according to claim 4 wherein the lower ends of the heat exchange tubes are connected to the outlet manifold by one or more riser tubes. Printed from Mimosa WO 99/24764 PCT/AU98/00922 - - - 12- 6 A water heater according to claim 5 wherein said riser tubes include a substantially "U" shaped bend. 7 A water heater according to any one of claims 1 to 6 wherein the water tank and the heat exchange tubes are made from materials with substantially the same co- 5 efficient of expansion 8 A water heater according to any one of claims 1 to 7 wherein the lengths of the parallel tubes are substantially the same. 9 A water heater according to any one of claims 1 to 8 wherein an expansion valve is connected between the outlet manifold and the evaporator. 10 10 A water heater according to any one of claims 1 to 9 wherein the evaporator includes at least one solar collector panel having passages through which the refrigerant fluid is circulated in heat-conductive relationship with the panel. 11. A water heater according to any one of claims 1 to 10 wherein the diameter of the heat exchange tube is about 12 millimetres. 15 12. A water heater according to any one of claims 1 to 11 wherein the pitch of the winding for each of the heat exchange tubes is about 55 millimetres. Printed from Mimosa
NZ504369A 1997-11-05 1998-11-05 Spiral wound, externally mounted parallel heat exchanger tubes for water heater using heat pump NZ504369A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AUPP0211A AUPP021197A0 (en) 1997-11-05 1997-11-05 An improved water heater
PCT/AU1998/000922 WO1999024764A1 (en) 1997-11-05 1998-11-05 Heat exchanger for water heater using heat pump

Publications (1)

Publication Number Publication Date
NZ504369A true NZ504369A (en) 2001-10-26

Family

ID=3804490

Family Applications (1)

Application Number Title Priority Date Filing Date
NZ504369A NZ504369A (en) 1997-11-05 1998-11-05 Spiral wound, externally mounted parallel heat exchanger tubes for water heater using heat pump

Country Status (7)

Country Link
EP (1) EP1029205A1 (en)
KR (1) KR20010031811A (en)
CN (1) CN1186206A (en)
AU (1) AUPP021197A0 (en)
IT (1) IT1298167B1 (en)
NZ (1) NZ504369A (en)
WO (2) WO1999024765A1 (en)

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US8821599B2 (en) * 2009-06-09 2014-09-02 Sundrop Fuels, Inc. Systems and methods for biomass gasifier reactor and receiver configuration
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CN102012104B (en) * 2010-12-14 2013-10-09 广东美的电器股份有限公司 Water tank of heat pump water heater
CN102778033B (en) * 2011-05-09 2014-11-05 珠海格力电器股份有限公司 Air energy water heater
CN102230680A (en) * 2011-06-08 2011-11-02 东南大学 Solar hot water tank
CN102322687B (en) * 2011-09-23 2014-03-12 舒方硕 Heat-exchanging heat-preserving device of heat pump water heater
CN102538195A (en) * 2012-01-20 2012-07-04 沈雁茜 Solar special condensed state utilizing system and working method thereof
CN103117321A (en) * 2013-02-01 2013-05-22 唐玉敏 Cooling system for photovoltaic power generation module
CN104729085B (en) * 2013-12-24 2017-06-06 珠海格力电器股份有限公司 Heat pump water heater water tank, heat pump water heater water tank design method and heat pump water heater
CN105066445A (en) * 2015-08-10 2015-11-18 广东美的暖通设备有限公司 Light wave heating type air energy water heater
CN108375213A (en) * 2016-10-28 2018-08-07 青岛海尔新能源电器有限公司 A kind of integral type solar energy heat pump water heater
CN106979617B (en) * 2017-05-15 2023-10-31 珠海格力电器股份有限公司 Heat pump water heating device and control method thereof
GB201709759D0 (en) * 2017-06-19 2017-08-02 Magic Thermodynamic Box Ltd Water heating apparatus
CN107228586A (en) * 2017-07-31 2017-10-03 广东工业大学 One kind collection Water Heat Pipes
CN108088075A (en) * 2018-01-29 2018-05-29 浙江中广电器股份有限公司 A kind of heat pump system of air-source water heater
CN108413621A (en) * 2018-03-05 2018-08-17 中国科学院电工研究所 A kind of monophasic fluid toroidal helical rising heat dump
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Also Published As

Publication number Publication date
WO1999024765A1 (en) 1999-05-20
WO1999024764A1 (en) 1999-05-20
CN1186206A (en) 1998-07-01
EP1029205A1 (en) 2000-08-23
ITMI980096A1 (en) 1999-07-21
AUPP021197A0 (en) 1997-11-27
IT1298167B1 (en) 1999-12-20
KR20010031811A (en) 2001-04-16

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