NZ265379A - High speed battery charging by monitoring battery voltage and temperature - Google Patents

Abstract

PCT No. PCT/JP94/00651 Sec. 371 Date May 24, 1995 Sec. 102(e) Date May 24, 1995 PCT Filed Apr. 20, 1994 PCT Pub. No. WO95/09471 PCT Pub. Date Apr. 6, 1995To provide a single universal charging apparatus, capable of charging at high speed and efficiency any type of secondary battery, and capable of charging secondary batteries any arbitrary charging rate. In selecting the arbitrary amount of current from low current to high current while charging a variety of secondary batteries, the voltage and temperature of the battery are monitored, so that either at the point at which the rate of rise of the temperature of the battery exhibits an increase over the immediately previous rate of rise that exceeds a given reference value, or at the point at which the difference in change of battery voltage is decreased continuously for a preestablished amount of time, the charging of the battery is stopped.

Description

New Zealand No. International No. 265379 Priority Date(s): Complete Specification Filed: ZQ.lbl3.ti Class: (§1 Bs.'X.Xl/j.S?. .....

Publication Date: 2.-8--MAY..199& P.O. Journal No: .L±^.!±..

NEW ZEALAND PATENTS ACT 1953 COMPLETE SPECIFICATION Title of Invention: , hatteries and apparatus therefor Method for high-speed charging of secondary batter.es and app Name, address and nationality of applicant(s) as in international D^ALINk'cORP. a japanese corporation of Akasaka Tokyu bldg., 14-3 Nagata-cho 2-chome, Chiyoda-ku. Tokyo 100, Jap WO 95/05471 PCT/JP94/00651 26531 <5, 26 5 3 7 9 Method for High-speed Charging of Secondary Batteries and Apparatus Therefor 5 TECHNICAL FIELD The present invention is related to the high-speed charging of secondary batteries and, more specifically, to a high-speed charging apparatus and high-speed charging method for such secondary batteries as 10 nickel-cadmium batteries, nickel-hydrogen batteries, and lithium ion batteries.

The present invention is configured so as to enable, with regard to nickel-cadmium, nickel-hydrogen (Ni/H2) and lithium ion secondary batteries, the monitoring of 15 the temperature and voltage of the battery during the recharging process, and so as to stop said charging process when these monitored parameters of either temperature or temperature and voltage reach a particular condition.

BACKGROUND ART Secondary batteries (secondary cells) such as Nickel-cadmium storage batteries, nickel-hydrogen batteries, or lithium ion batteries can be recharged any number of times during their useful lifetimes. It is 25 widely known by persons skilled in the art that this recharging process must be performed under careful control to minimize the damaging affects to the storage battery. (For example refer to "Charging Storage Batteries: Extending Useful Life", Bob Williams, 30 "Cellular Business" April, 1989, pp 44 to 49.) At the beginning of secondary battery recharging technology, the process of recharging required as much as a number of hours. As consumer products powered by secondary batteries became more and more common, there 35 arose a need for a system capable of charging times measured in minutes rather than hours.

While it is possible to fast charge a secondary WO 95/09471 PCT/JP94/00651 battery, to prevent irreversible damage to the storage battery, the storage battery recharging process must be performed with even more care. (For example refer to "Latest Information on Nickel-Cadmium Batteries" in the 5 report of the September 1990 Cadmium Society Brussels Seminar, published in November, 1990.) Prior art has shown that a variety of systems have been developed for the fast recharging of secondary batteries. In these systems it has been standard to 10 monitor the voltage and/or temperature of the storage battery being charged, and to interrupt or change the charging current applied to the storage battery when the temperature or voltage reaches a preestablished level. Typical prior art is described in US patent 4,006,397 15 (Catotti et al).

Japanese patent publications Sho 62-23528 and Sho 62-23529 disclose a method for use in recharging of secondary batteries such as nickel-cadmium batteries, wherein the voltage waveform of the battery is observed 20 during charging, a number of deflection points appearing in the voltage waveform being stored beforehand, and if the stored deflection points occurred in a given sequence, the charging process is interrupted. In this method, however, it is required for each type of battery 25 o store beforehand the variations occurring in the voltage waveform of that type of battery during the charging process, and to change the stored contents before charging to contents appropriate to the type of battery to be recharged, not only making operation 30 complex, but giving no assurance, by reasons of the charging environment and history of the battery, that the voltage output waveform of the battery would follow in sequence am amplitude the stored information, thereby making it impossible to perform accurate charging and 35 recharging, making it difficult to perform high-speed charging without causing loss of battery performance.

In addition to nickel-cadmium, nickel-hydrogen and WU 93/1)9471 PCT/JP94/00651 lithium ion batteries exist as secondary batteries.

Previously the recharging of the above-mentioned secondary batteries, it required from 6 hours to even as much as 16 hours in some instances, and even with what 5 was called fast charging at over a relatively short time, still required 1 to 2 hours.

In the past, although in recharging what were called rechargeable batteries or storage batteries for use in their intended purposes, it was known that it was 10 desirable to make the charging time as short as possible, the limitations imposed by the rise in internal battery temperature and internal pressure in the battery caused by a chemical reaction within the secondary battery not ' only lead to destruction of the cells, but also to a 15 deterioration of the electrical characteristics of the cells, that is, the output characteristics and charging characteristics, so that the method of charging by means of a large current over a short period of time was not ■ used.

However, today the demand for secondary batteries is increasing in a large of number of applications in various industries, and in particular, there is a strong demand for secondary batteries for use in applications such as in environments in which machine tools are used, 25 in medical and other equipment for hospitals, and in communications, such as in mobile telephones, applications which not only require that batteries do not run down during operation but also require fast or even instantaneous recharging.

If a graphical comparison is made of the above-mentioned voltage and temperature variations with respect to charge level during the charging of the various types of secondary batteries mentioned above, it can be seen that each type of battery exhibits unique 35 characteristics, as shown in FIG. 2 to FIG. 4.

That is, the voltage and temperature characteristics of a nickel-cadmium storage battery are as shown in FIG.

WO 95/09471 PCT/JP94/00651 265 3 / y 2, the voltage and temperature characteristics of a nickel-hydrogen battery cure as shown in FIG. 3, and the voltage and temperature characteristics of a lithivun ion battery are as shown in FIG. 4.

For this reason, in the past, not only did the charging of any type of secondary battery require a long period of time of at least one hour, but also it had the problem of requiring a change of the charging method or charging apparatus to suit the type of secondary battery, 10 making the only charging methods available troublesome, time-consuming, and costly.

The purpose of the present invention is to improve the above-described shortcomings of the prior art, and to facilitate the recharging of secondary batteries, and 15 in particular nickel-cadmium, nickel-hydrogen, and lithium ion secondary batteries, within an extremely short period of time of from several minutes to 20 minutes. Recharging at this extremely fast speed increases the significance of a number of parameters 20 which were not so significant in the relatively slow-speed prior art recharging systems. However, it was discovered that these parameters could be processed so as to produce a recharging system which performs safe, high-speed charging without damaging side-effects to the 25 storage battery being charged.

In the past, to charge secondary batteries which consist of mutually differing technical elements, and which have differing charging characteristics and behavior, it was necessary to make available separate 30 chargers and to select the charger appropriate for charging the type of secondary battery to be charged.

Therefore, the charger was something to be used only for the charging of a particular type of secondary battery, it being necessary to make available individual 35 chargers for individual secondary batteries, making the charging operation not only inconvenient, but troublesome and complex as well.

WO ys/iw/l PCT/JP94/00651 Even for the same type of secondary batteries, if an amount of charging current used in a charging operation, which is generally represented by a charge rate C, differ, the chargers would have to be provided 5 separately, causing the problem of the need to have a considerable number of charger types "fevailable.

However, with the demand for such secondary batteries increasing, and with a diversification in the fields and location in which secondary batteries are 10 used, there has arisen an increasing need for a charger capable of use anywhere in charging any type of secondary battery completely within a short period of time, for applications requiring quick charging and immediate use of secondary batteries, such as in mobile data 15 communications, mobile telephone communications, and at construction sites.

For this reason, the is a desire to have a single charger not only capable of charging a secondary battery of any type of construction, but also capable of charging 20 under any charging rate C conditions. However, until the present, there has been no such practically usable charger.

Thereifore, the object of the present invention is to improve on the defects described above, and provide a 25 single charger which is universally usable to charge any type of secondary battery in a short period of time under any arbitrary charging rate C.

DISCLOSURE OF INVENTION To solve the above-described problems, the present 30 invention has the following technical configuration. Specifically, the first aspect of the method of high-speed charging of secondary batteries of the present invention is a method for charging secondary batteries comprising, a step 1 which sets the basic data reading 35 time tb required to read data, a step 2 which sets the charging rate C, a step 3 which sets the corrected data reading time tc, according to the set charging rate C and WO 95/09471 PCT/JP94/00651 | said basic data reading time tb, said corrected data reading time tc being characteristic to said charging rate C, a step 4 which, during the charging operation, uses an appropriate sampling means to measure the 5 terminal voltage of said secondary battery at least one time during each said corrected data reading time tc, and which stores the voltage data at that time into an appropriate 1st memory means, a step 5 which repeats the operation of said step 4 a predetermined number of times 10 L, takes the summation of the plurality of voltage data obtained in each corrected data reading time tc, and stores the resulting amount of change Dvn over the amount of voltage data change reading sampling time ts (where ts=Lxtc) into an appropriate 2nd memory means, a step 6 15 which calculates the difference between the amount of change Dvl for the 1st sampling time (tsl) and the amount of change Dv2 for the next, 2nd, sampling time (ts2) obtained in step 5, and which stores the resulting difference in amount of change ADv in a 3rd memory means, 20 a step 7 which continuously repeats said step 6 a predetermined number of times M, and which takes the summation of each of the values of ADvl to ADvM (M values) obtained at each amount of change reading sampling time (ts), and determines the amount of voltage 25 data change ATDv for the overall said amount of change reading sampling time t (where t=tsxM), the results being stored in a 4th memory means, a step 8 which performs a calculation, based on the amount of voltage data change ATDv stored in said 4th memory means, to determine the 30 difference AHv between the voltage amount of change ATDvl measur "-om over the first overall amount of change reading sampling time tl established as running from said 1st sampling time (tsl) to the mth sampling time (tsM) for the predetermined M-th sampling, and the voltage 35 amount of change ATDv2 measured from over the second overall amount of change reading sampling time established as running from said 2nd sampling time (ts2) nusawH/* i'Cl/JF94/U0651 to the (m+l)th sampling time (tsM+1) for the predetermined M+l-th sampling, said calculated difference AHv (where AHv=ATDv2-ATDvl) being stored in a 5th memory means, a step 9 which repeats said step 8 while 5 calculating the difference value AHvn (where AHvn=ATDv(N+l)-ATDvn) between the amount of voltage changes ATDvn and ATDv(n+l) at each pair of adjacent overall amount of change sampling times tn and tn+1, and stores the calculated results in 5th memory means, a step 10 10 which judges whether each of the m amounts of differences in amount of voltage changes AHvl to AHvm obtained continuously in said step 9 are positive (zero or greater than zero) or negative (less than zero), and a step 11 which judges, in the sequence of occurrence of 15 said differences in amount of voltage changes AHvl to AHvm, whether or not said difference in amount of voltage change AHv is zero or negative for a predetermined number of S times continuously, and if said difference in amount of voltage change AHv is zero or negative S times 20 continuously, stops said charging.

Additionally, the second aspect of the method of high-speed charging of secondary batteries of the present invention is a method for charging secondary batteries comprising, a step 1 which sets the basic data reading 25 time tb required to read data, a step 2 which sets the charging rate C, a step 3 which sets the corrected data reading time tc, according to the set charging rate C and said basic data reading time tb, said corrected data reading time tc being characteristic to said charging 30 rate C, a step 4 which, during the charging operation, uses an appropriate sampling means to measure the temperature of said secondary battery at least one time during each said corrected data reading time tc, and which stores the temperature data at that time in an 35 appropriate 1st memory means, a step 5 which repeats the operation of said step 4 a predetermined number of times L, takes the summatiori of the plurality of data obtained WO 95/09471 PCT/JP94/00651 j ^ in each corrected data reading time tc, and stores the resulting amount of change Dtn over the amount of temperature data change reading sampling time ts (where ts=Lxtc) into an appropriate 2nd memory means, a step 6 5 which calculates the difference between the amount of change Dtl for the 1st sampling time (tsl) and the amount of change Dt2 for the next, 2nd, sampling time (ts2) obtained in step 5, and which stores the resulting difference in amount of change ADt in a 3rd memory means., 10 a step 7 which continuously repeats said step 6 a predetermined number of times M, and which takes the summation of each of the values of ADtl to ADtM (M values) obtained at each amount of change reading sampling time (ts), and determines the amount of 15 temperature data change ATDt for the overall said amount of temperature change reading sampling time t (where t=tsxM), the results being stored in a 4th memory means, a step 8 which performs a calculation, based on the values of amount of temperature data change ATDt stored 20 in said 4th memory means, to determine the ratio between the temperature amount of change ATDtl measured from over a first overall amount of change reading sampling time tl established as running from said 1st sampling time (tsl) to the sampling time (tsM) for the predetermined M-th 25 sampling, and the temperature amount of change ATDt2 measured from over a second overall amount of change \ reading sampling time t2 established as running from said 2nd sampling time (ts2) to the sampling time (tsM+1) for the predetermined M+l-th sampling, said calculated ratio 30 AHt (where AHt=ATDt2/ATDtl) being stored in a 5th memory means, a step 9 which repeats the operations of said step 8 while calculating the ratio value AHtn (where AHtn=ATDt(N+l)/ATDtn) between the amount of temperature changes ATDtn and ATDt(n+l) at each pair of adjacent 35 overall amount of change s.ampling times tn and tn+1, and stores the calculated results in 5th memory means, a step 10 which judges from the information stored in said 5th WUS5rtW71 PCT/JP94/00651 - 9 * 1 memory means whether the ratio AHm between two adjacent said temperature amounts of change is equal to or greater than or is less than a given value K, and a step 11 which, if the temperature amount of change ratio AHm 5 value is equal to or greater than the given value K, stops said charging. .

In addition, it is possible to think of the coupling of the two above-described aspects of the present invention of a high-speed secondary battery charging 10 method as a third aspect of the present invention.

Because the high-speed charging method for secondary batteries of the present invention makes use of the above-described basic technical configuration, even for secondary batteries of differing types, in consideration 15 of the mutually differing charging characteristics exhibited by the secondary batteries, such as terminal voltage or temperature, it is possible to determine the common characteristics of secondary batteries having differing constituent elements, to accurate determine 20 point at which the charge level reaches nearly 100%, enabling not only one and the same apparatus to be used to reliably charge secondary batteries of differing construction, but also enabling the accurate determination of the charge level during the charging 25 process, the quick determination of the point at which the charge level reaches a level of nearly 100%, and the stopping of the charging process at that point, the result being not only a reliable avoidance of the problem encountered when the charging is continued even after the 30 charge level has exceeded 100%, thereby causing the temperature of the secondary battery to rise above its rated maximum temperature, leading to damage to said secondary battery, but also a determination of the characteristics of said secondary battery with respect to 35 the speed of charge, or charge rate, thereby enabling charging of secondary batteries which are of the same constituent elements at different charge rates, further 1 enabling in particular the precise high-speed charging of secondary batteries.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a block diagram which shows the 5 configuration of a specific example of the high-speed charging apparatus for secondary batteries of the present invention.

FIG. 2 is a graph which shows the charging characteristics of a nickel-cadmium battery. 10 FIG. 3 is a graph which shows the charging characteristics of a nickel-hydrogen battery.

FIG. 4 is a graph which shows the charging characteristics of a lithium ion battery.

FIG. 5 (A) is a drawing which shows a curve of 15 measurement data and the relationship of the sampling interval p to the amount of change, and FIG. 5 (B) is a drawing which shows the relationship of the measurement data sampling period t and the measurement data amount of change reading sampling time (ts) for the present 20 invention.

FIG. 6 (A) is a drawing which describes one example of analysis of the voltage measurement data and condition of change thereof in the present invention, and FIG. 6 (B) is a drawing which describes one example of analysis 25 of the temperature measurement data and condition of change thereof in the present invention FIG. 7 is a flowchart which shows one example of the procedure in the case of executing the secondary battery charging method of the present invention. 30 FIG. 8 is a flowchart which shows one example of the procedure in the case of executing the secondary battery charging method of the present invention..

FIG. 9 is a flowchart which shows one example of the procedure in the case of executing the secondary battery 35 charging method of the present invention.

FIG. 10 is a flowchart which shows another example of the procedure in the case of executing the secondary WO 95/09471 PCT/JP94/00651 \ ' battery charging method of the present invention.

FIG. 11 is a flowchart which shows one example of the procedure in the case of executing the secondary battery charging method of the present invention. 5 FIG. 12 is a graph showing one example of the voltage characteristics of a nickel-cadmium battery when charged at 0.25C.

FIG. 13 is a graph showing the a graph of the changes in the overall voltage amount of change ATDvn and 10 the counter value N when the charging of FIG. 12 is done.

FIG. 14 is a graph showing one example of the temperature characteristics of a nickel-cadmium battery when charged at 3C.

FIG. 15 is a graph showing one example of the 15 voltage characteristics of a nickel-cadmium battery when charged at 3C.

FIG. 16 is a graph showing the a graph of the changes in the overall voltage amount of change ATDvn and the counter value N when the charging of FIG. 15 is done. 20 FIG. 17 is a graph showing one example of the voltage characteristics of a nickel-hydrogen battery when charged at 0.25C.

FIG. 18 is a graph showing the a graph of the changes in the overall voltage amount of change ATDvn and 25 the counter value N when the charging of FIG. 17 is done.

FIG. 19 is a graph showing one example of the voltage characteristics of a nickel-hydrogen battery when charged at 1C.

FIG. 20 is a graph showing the a graph of the 30 changes in the overall voltage amount of change ATDvn and the counter value N when the charging of FIG. 19 is done.

Best Mode for Carrying Out the Invention The following is a detailed description, presented with reference to drawings, of concrete examples of the 35 method and apparatus high-speed charging of secondary batteries of the present invention.

The background of why the inventors of the present WO 95/09471 P CT/JP94/00651 invention employed the above-described technical configuration in the method for high-speed charging of secondary batteries of the present invention starts with the inventors of the present invention making a thorough 5 analysis and investigation of the charging characteristics of secondary batteries that have been commercially available in the past, and making efforts to determine, for the purposes of fulfilling the above-described object of the present invention, the 10 desired form of a single apparatus and method for performing high-speed charging of different types of secondary batteries, for performing precise charging even if the charging rate is varied with respect to said secondary batteries of differing types, and further for 15 performing high-speed charging of said secondary batteries of differing types.

The inventors, then, analyzed, the nickel-cadmium batteries, nickel-hydrogen batteries, and lithium ion batteries, which were thought to be the important types 20 of those types commercially available in the past, the result of this analysis being that in general for nickel-cadmium batteries, as shown in FIG. 2, the terminal voltage during charging continues a gradual increase up to the point at which 100% charge level is 25 reached, at which point a peak voltage is reached, with further charging causing a decrease in voltage.

When the temperature of a nickel-cadmium battery is observed, there is a slight increase in temperature from the start of charging to just before the 100% charge 30 level, and although the overall characteristics is virtually flait with no extremely temperature increase, except when the 100% charge level region is approached, when there is a sudden increase in temperature.

In the case of nickel-hydrogen batteries, which is 35 shown in FIG. 3, the battery terminal voltage continues its gradual increase from the start of the charge until the 100% charge level, and when the charge level reaches WO 95/09471 PCT/JP94/OOfi51 100% the voltage value exhibits the peak value, after which subsequent charging results in no further change the battery voltage, which maintains the peak value.

The temperature of a nickel-hydrogen battery, 5 similar to a nickel-cadmium battery, gradually increase from the start of charging to just before the 100% charge level, and although the overall characteristics is virtually flat with no extremely temperature increase, except when the 100% charge level region is approached, 10 when there is a sudden increase in temperature.

In the case of yet another type of secondary batteries, lithium ion batteries, as shown in FIG. 4, the battery terminal voltage increasing approximately in direct proportion to elapsed time, from the start of 15 charging to the 100% charge level, and when the 100% charge level is reached, the voltage value exhibits the peak value, after which subsequent charging results in no further change in the battery >voltage, which maintains the peak value.

The battery temperature in the case of a lithium ion secondary battery exhibits a gradual increase from the start of charging, which, during the charging process, changes to a gradual increase, until the 100% charge level is reached, at which point the battery temperature 25 increases sharply as the same configuration as that of the nickel-cadmium battery.

In an ideal secondary battery, the energy of the current caused to flow in the battery until the 100% charge level is reached is spent in the chemical reaction 30 required for charging, and is not converted to thermal energy.

However, after approaching the 100% charge level, the rate of said chemical reaction becomes slow, the remaining energy being spent in a chemical reaction not 35 related to charging, and converted to thermal energy.

Therefore, after the charge level reaches 100%, the reaction contributing to charging does not occur WO 95/09471 PCT/JP94/00651 immediately, gas is formed, and the temperature rises.

When the temperature rises, the speed of the chemical reaction increases, causing the temperature to rise, and this also causes a great deal of gas to be 5 generated.

These phenomena form a vicious circle/ and ultimately lead to the destruction of the battery.

If the charging operation is performed repeatedly, the matter inside the battery which contributes to the 10 occurrence of the chemical reaction deteriorates, so that it is not possible to store sufficient energy.

Therefore, as described above, if charging is continued even after the charge level reaches 100%, a problem arises in that the deterioration of internal 15 matter in the battery is accelerated, resulting in a lifetime for the battery considerable shorter than the intended life of the secondary battery.

For that reason, in the past, because of limitation imposed because of the makeup and characteristics of 20 secondary batteries, said charging operation was only possible by means of very limited methods, and it was not possible to solve the problems cited above.

Charging methods in the past have included, for example, the following. (1) Charging with a minute (trickle) current (for example, a current of 1/10 to 1/20 of the capacity of the battery), and performing no control at the point at which charging is completed.

In this charging method, there is absolutely 30 not control of the current, and the charging time generally ends in approximately 10 hours to 15 hours.

For this reason, in this charging method, the charging time becomes extremely long, and there is a danger or overcharging. (2) Charging with a small current (for example, a current of 1/3 to 1/10 of the capacity of the battery), with the end of controlled as being after a preestablished time, which was generally 5 hours to 10 hours.

In this charging method, the charging time becomes long, and there is a danger of temperature rise caused by 5 excessive current in the case in which the battery had some remaining capacity. (3) Charging with a relatively large current (for example, a current of 1/3 to 1/1 of the battery capacity), and stopping the charging when the voltage 10 value of the battery being charged falls below a given value (generally approximately 10 mV per cell) .

The time for completion of the charging is approximately 1 hourr and this is what is known as relatively fast charging.

In this charging method, while the charging time is relatively short, there is a great danger of excessive current, and a large rise in temperature.

Additionally, in this method, it is impossible to detect the completion of charging in batteries having 20 characteristics such as were described in FIG. 2 and FIG. 3.

For this reason, in the present invention, in consideration of the characteristics of a variety of previous secondary battery types, characteristics 25 heretofore unknown, which are common to secondary batteries are employed in achieving the above-stated object of the present invention.

Specifically, in the high-speed charging method for secondary batteries of the present invention, a method 30 and an apparatus for high-speed charging of secondary batteries is provided which makes possible the reliable stopping of charging of any type of secondary battery at a point in the charge level of 95% to 100%, charging at current levels ranging from small to large (for example, 35 equal to or greater than the capacity of the battery), and in particular, high-speed charging, for example at a charge rate of 2C in an extremely short period of time, for example 15 minutes or less.

What follows is a description of the high-speed charging method and apparatus of the present invention, with reference made to drawings.

FIG. 1 shows a block diagram of one concrete example of the configuration of the high-speed charging apparatus for secondary batteries of the present invention, which basically shows an apparatus for high-speed charging of secondary batteries 1, comprising, a current-supplying 10 means 3 which supplies electrical current to the cells of a secondary battery 2 requiring charging, a switch means 5 provided between said current-supplying means 3 and terminal 4 of said secondary battery being charged, a temperature measurement means 6 which measures the 15 temperature of said cells of said secondary battery 2, a voltage measurement means 7 which measures the terminal voltage of said secondary battery, a sampling means 8 which operates said temperature-measurement means 6 and/or said voltage measurement means 7 to measure the 20 temperature and/or the voltage of said cells of said secondary battery 2 with the desired sampling interval, a storage device 30 which stores each of the data sampled by said sampling means 8, and which executes the required calculations on said stored data, storing the results in 25 a separate memory means, a charging-control means 9 which is connected to said sampling means and controls said switch means 5, a charging rate setting means 10 which sees the charging rate C, a basic data reading timing generator means 11 which, based on the charging rate C 30 set by said charging rate setting means 10, generates the predetermined basic data reading time tb, a corrected data reading time setting means 12 which,, set the corrected data reading time tc, the value of which is characteristic to said charging rate C, an amount of data 35 change reading sampling time setting means 13 which multiplies the corrected data reading time tc by a preestablished value L to set the temperature data amount WO 95/09471 PCT/JP94/00651 > change reading sampling time ts, an overall sampling time setting means 14 which multiplies said data amount of change reading sampling time ts by a preestablished value M to set the overall sampling time t, a 1st memory 5 means 15 which stores the values of temperature data dtn measured each said corrected data reading time tc, a 2nd memory means 16 which stores the data Dtn which is the summation of the L values of temperature data dtn stored in said 1st memory means 15, a 3rd memory means 17 which, 10 from the data Dtn stored in said 2nd memory means, stores the difference ADt between data Dt(n-l) measured at the previous amount of change reading sampling time ts and data Dtn measured at the current amount of change reading sampling time ts+1, this difference value being ADt 15 (where ADt=Dtn-Dt(n-l)), a 4th memory means 18 which stores the amount of temperature data change ATDt obtained by taking the summation of each of the M amounts of temperature data obtained at each amount of change reading sampling time (ts) in the overall amount of 20 change reading sampling time t (where t=tsxM) obtained by repeating said amount of change reading sampling time (ts) M the required number of M times, a 5th memory means 19(A) which, with regard to the temperature data amount of change ATDt stored in said 4th memory means 18, stores 25 the change ratio AHt calculated between the amount of temperature data change ATDtn at the 1st overall amount of change reading sampling time tn and the amount of temperature data change ATDt(n+l) at the 2nd overall amount of change reading sampling time tn+1, which is 30 formed by shifting the time by one amount of change reading sampling time (ts), said change ratio being AHt (where AHt=ATDt(n+1)/ATDtn), a 1st judgment means 22 which compares said temperature change ratio AHt which are stored in said 5th memory means 19(A) between said 35 amounts of temperature change with a preestablished reference value K, and if said change ratio AHtm between said amounts of temperature change exceeds said reference WO 95/09471 PCT/JP94/00651 value K, outputs a signal which stops said charging, a 6th memory means 19(B) which, with regard to the terminal voltage data amount of change ATDv stored in said 4th memory means, stores the difference calculated between 5 the amount of temperature data change ATDvn at the 1st overall amount of change reading sampling time tn and the amount of temperature data change ATDv(n+l) at the 2nd overall amount of change reading sampling time tn+1, which is formed by shifting the time by one amount of 10 change reading sampling time (ts), said difference being AHvm (where AHvm=Hv(m+l)-Hvm), a 2nd judgment means 23 which, with regard to each the m values of voltage data amounts of change differences AHvl to AHvm stored continuously in said 6th memory means 19(B), makes a 15 judgment as to whether the values are positive (zero or larger) or negative (less than zero), and which performs said judgment processing in the sequence of occurrence of said voltage data amount of change differences AHvl to AHvm, and if said voltage data amount of change 20 difference AHv is a negative value a preestablished number of times S or more continuously, output s signal which stops said charging operation, and a processing means 24 which processes each of the individual data stored by each of said means, and a central processing 25 means 25 which controls the operation of each said means.

In the present invention, one and the same high-speed secondary battery charging apparatus is capable of performing high-speed charging of, as described above, nickel-cadmium batteries, a 30 nickel-hydrogen batteries, or a lithium ion batteries.

One of the characteristics of the present invention is that, for the purpose of performing precise, high-speed charging of any secondary battery, a comprehensive study of the characteristics of said 35 secondary batteries was made, and the configuration was made so as to enable accurate and quick detection of changes in characteristics values of said secondary WO 95/09471 PCT/JP94/00651 batteries, enabling not only reliable detection of the point at which said secondary batteries reach a condition in which they are as close as can be to the 100% charge level, but also stopping of the charging process at that 5 point, and to enable this performance, the present invention is configured to perform measurement of voltage data and/or voltage data of said secondary batteries at an extremely short interval, the results- of these measurements being used to effectively determine the 10 charging condition of said secondary batteries.

More specifically, in the charging operation performed by the present invention, in order to make a judgment of whether or not the charge level of 100% or the 100% region has been reached, regardless of which 15 type of secondary battery is being charged, as shown in FIG. 2 through FIG. 4, it is appropriate to detect the point of the occurrence of a peak value in the voltage data, or, in the temperature data, to detect the point at which the temperature rises at a sudden high rate. 20 For example, in measuring voltage data, as shown in FIG. 5 (A), with previous methods, to make the amount of data change Aa large, it is necessary to make the sampling interval p a somewhat long interval.

However, in charging, if the sampling interval p is 25 long, as shown in FIG. 5 (A), there is the problem of losing the opportunity of detecting the peak in the voltage data, thus making it impossible to detect the proper time to stop charging.

On the other hand, if the sampling interval p is 30 made short, the cost of reading the amounts of data change Aa becomes very high, making it impossible to implement an economic system.

For this reason, in the present invention, the basic data reading time tb required to read data is set, a 35 corrected data reading time tc, which is characteristic to the charging rate C is set based on that time and the charging rate, the terminal voltage of said battery WO 95/09471 PCT/JP94/00651 and/or surface temperature of said battery is measured one time each within said corrected data reading time tc, these operations being repeated a preestablished number of times L, the voltage data and/or temperature data from 5 which operations are summed separately, the summed data being taken as the variable Dn with respect to the amount of data change reading sampling time ts (where ts=Lxtc). Refer to the graph of FIG. 5 (B) .

By virtue of these operations, the apparent accuracy 10 of the measured voltage data and/or temperature data is thus multiplied by L.

A 3rd memory means 17 which, from the data Dtn stored in said 2nd memory means, stores the difference between data Dt(n-l) measured at the previous amount of 15 change reading sampling time ts and data Dtn measured at the current amount of change reading sampling time ts+1, this difference value being AD (where AD=Dtn-D(n-l)); Next, in the present invention, the difference between the variable Dn at said amount of data change 20 reading sampling time ts (where ts=Lxtc) and the variable D(n-l) at said previous amount of data change reading sampling time ts is determined as AD (where AD=Dtn-D(n-l)), the results being sequentially stored in 3rd memory means 17.

Subsequently, these operations are repeated a preestablished number of times M, the total, as shown in FIG. 5 (B), being taken as the amount of voltage data and/or temperature data change ATD for the overall said amount of change reading sampling time t (where t=tsxM). 30 After that, as shown in FIG. 5 (B), the overall said amount of change reading sampling time t and said data amount of change reading sampling time ts are each shifted by one at a time, as the amount of temperature data and/or voltage data change ATD1 to ATDm for 35 respective overall amount of change reading sampling times tl to tm is determined.

Therefore, ultimately in the present invention, the WU 931119471 PCT/JP94/0D651 \ time of measuring the voltage data and/or temperature data amount of change ATD is expressed as t=MxLxtbxA/C.

Therefore, in the present invention, by properly selecting the values of the above-stated constants M and 5 L, it is possible, with a low-cost reading apparatus, not only to read measurement data with high accuracy, but also, because the range obtained by shifting said overall amount of change reading sampling time (ts) is shifted one at a time is set, so that said voltage data and/or 10 temperature data amount of change ATD is obtained at an interval which is said amount of change reading Sampling time (ts), it is possible to obtain the large amount of change data ATD which is sampled at the relatively long interval of the overall amount of change reading sampling 15 time t, within the relative short time which is the amount of data change sampling time (ts), it is possible to determine at a short sampling interval whether or not to stop charging, resulting in a detailed and precise charging operation.

In addition, in the present invention, for the purpose of performing high-speed charging, and in consideration of the fact that said secondary batteries of differing types are used, the measurement conditions are changed, the configuration is made such that, 25 according to the the speed of charging, or what is normally called the charging rate, so that high or low charging speeds can be employed to obtain the optimum charging operation.

The apparatus for high-speed charging of secondary 30 batteries 1 of the present invention, is provided with a switch means 5 which is connected between the terminal 4 of the secondary battery being charged and the current-supplying means 3 for the purpose of supplying charging current to a secondary battery 2 requiring 35 charging, said switch means 5 being controlled by said charging-control means 9, so that the current from said current-supplying means 3 is on and off controlled.

WO 95/09471 PCT/JP94/00651 In performing charging of said secondary battery 2, said switch means 5 is turned on, so that current flows from said current-supplying means 3 to said secondary battery 2 of said secondary battery, and when the charge 5 level of said secondary battery reaches 100% or when, as described later, a condition is detected which indicates that said secondary battery is approaching the 100% charge level, said switch means 5 is switched off, and the current from said current-supplying means 3 to said 10 secondary battery 2 is cut off.

In the present invention, as described later, when measuring voltage and/or temperature at each sampling time, it is desirable to make the measurement with said charging current cut off, and in this case, when 15 measuring the above-stated data, intermittent drive is used, so that said switch means 5 is cut off in synchronization with the sampling signal of said sampling times.

In addition^ from the measurement results of each of 20 said data, when a measured data is detected which is outside the range of normally allowed values, it is also possible to turn said switch means 5 off, so that the charging operation is stopped.

The reason for this is that, in the present 25 invention, in measuring the above-stated voltage and/or temperature, if a measurement is made with the charging current flowing from said current-supplying means 3 to said secondary battery 2, because there will not be a uniform reaction occurring within the battery, the 30 voltage value will include an error, making the acquisition of accurate measurement data impossible.

As described above, when a measurement is performed while charging current is flowing, it is impossible to avoid contact resistance between said secondary battery 35 and the charging apparatus, so that, for example, a voltage drop will develop across the contact resistance due to the charging current, this also making it WO 95/09471 PCT/JP94/00651 \ • difficult to obtain accurate measurement data.

Next, in the present invention, a microcomputer is used to measure a large amount of terminal voltage and battery surface temperature voltage for the secondary 5 battery in an extremely short period of time, and to analyze the results of these measurements, making judgments as to whether or not the secondary battery has reached a charge level of 100% or the region near 100% as it tracks the minute variations of secondary battery 10 characteristic values.

Furthermore, in the present invention, the configuration is such that even if the charging rate C, which is a charging condition, is varied, it is possible to complete precise charging in a short period of time. 15 For this reason, in the apparatus for high-speed charging of secondary batteries 1 of the present invention, there is provided a charging rate setting means 10, for the purpose of adjusting the speed of charging, that is the charging rate c, to the 20 characteristics charging rate of the secondary battery to be charged.

By virtue of the above, it is possible to set the sampling period for measurement during the charging operation to a value that is optimized with respect to 25 the charging rate C for said secondary battery.

In the apparatus for high-speed charging of secondary batteries 1 of the present invention, there is provided as part of the circuit configuration a basic data reading timing generator means 11 which sets the 30 basic data reading time tb, the basic data reading time tb generated by said basic data reading timing generator means 11 being adjusted by corrected data, reading time setting means 12, based on the charging rate C set by said charging rate setting means 10, so that the 35 corrected data reading time tc is characteristic to the charge rate C of said secondary battery.

In this case, the corrected data reading time tc, WO 95/09471 PCT/JP94/00651 which is set in accordance with said charging rate C and said basic data reading time tb, can also be expressed as tc=tbxA/C (where A is a constant).

The above constant A can be set as appropriate, for 5 example, as a positive integer such as 16.

In the present invention, during the charging of the battery, the battery terminal voltage or battery temperature is measured by means of said sampling means 8 at least one time during said corrected reading time tc, 10 the voltage data or temperature data d at that point being separately stored in an appropriate 1st memory means 15, said measurement operations being repeated continuously a preestablished number of times L, with the plurality of voltage data obtained at each of the 15 corrected reading times tc being summed, the amount of change Dn in the resulting voltage data or temperature data at the amount of change sampling time ts (where ts=Lxtc), for example Dvn and Dtn, being stored in an appropriate 2nd memory means 16.

Next, in the present invention the difference between the amount of change D1 at the 1st sampling time (tsl), which was stored in the 2nd memory means 16 and the amount of change D2 at the next, 2nd, sampling time (ts2), which was stored in said 2nd memory means 16 is 25 determined by calculation, the results being the differences in amount of change AD, which are stored in 3rd memory means 17.

In the present invention, during a preestablished period, which is the overall amount of data change 30 reading sampling time t, these operations are repeated continuously a preestablished M number of times, with the overall amount of data change reading sampling time t expressed as t-txxH.

In the present invention, the measured values of 35 data AD1 to ADM obtained by performing repeated continuous measurements during said amount of data change reading sampling time are summed, the amount of voltage WO 95/09471 PCT/JP94/00651 I data change ATD at said overall amount of change reading sampling time t (t=txxM) being determined, and result for voltage data and temperature data being' stored separately in 4 th memory means 18.

Because subsequent operation differs slightly between voltage data and temperature data, the operation for voltage data will be described first.

First, using the amount of voltage data change ATDv which was stored in said 4th memory means 18, the 10 difference between the voltage amount of change ATDvl measured from over the said overall amount of change reading sampling time established as running from said 1st sampling time (tsl) to the sampling time (tsM) for the M-th sampling, and the voltage amount of change ATDv2 15 measured from over the overall amount of change reading sampling time established as running from said 2nd sampling time (ts2) to the sampling time (tsM+1) for the M+l-th sampling is determined by calculation, said calculated difference AHv being stored in a 5th memory 20 means.

These operations are performed continuously, and a general description of the above operations is that, with respect to the measured amount of voltage change ATDvn at a given overall amount of voltage data change reading 25 sampling time tn, said amount of change reading sampling time (ts) is shifted one at a time, while continuous repeated calculation is performed of the amount of voltage changes ATDvn to ATDv(n+x) at said overall amount of change sampling reading times t(n+l) to t(n+x), which 30 are derived constantly by summing M of said amount of change reading sampling times (ts), and, similar to as described previously, these are stored in said 4th memory means 18, while the amount of voltage changes ATDvn and ATDv(n+l) occurring at adjacent overall amount of change 35 reading sampling times tn and t(n+l) are used to calculate the difference value AHvn (where AHvn=ATDv(n+l)-ATDvn), this being stored in 6th memory WO 95/09471 PCT/JP94/00651 j I means 19(B).

With respect to the m continuously obtained values of amount of voltage change differences AHvl to AHvm, a judgment is made by 2nd judgment means 23 as to whether a 5 value is positive (zero or greater) or negative (less than zero), and said 2nd judgment means 23 further executes a judgment processing in the sequence of occurrence of said amount of voltage change differences AHvl to AHvm, to make a judgment as to whether or not at 10 least a preestablished number of continuous values of said amount of voltage change difference AHv is or is not negative, and if S continuous values of said amount of voltage change difference AHv are negative, a judgment is made that said secondary battery has reached the 100% 15 charge level or is in the 100% charge level region, and a signal is output for the purpose of stopping said charging operation, which causes said charging-control means 9 to operate to turn switch means 5 off, and stop the charging operation with respect to said secondary 20 battery.

Essentially, as shown in FIG. 6A, when an approach is made to the fully charged condition, the rising curve of said voltage data becomes gradual, and the above-mentioned difference becomes either zero or 25 negative.

Then, in the case in which said difference value is either zero or negative, an appropriate counter value is advanced by 1, and when said counter value reaches a given value of, for example, 3, said charging operation 30 is stopped.

What this means is that with the method of stopping the charging as described above in the present invention, if the difference between the previous value of voltage of the secondary battery and the current value of voltage 35 of the secondary battery is either zero or negative for 3 times in a row, it will be assumed that the secondary battery has reached a 100% charge level, and the charging ni/ Tannrt /1 rui/jjV4/UU65l ') operation will be stopped.

In the case of measuring the surface temperature of the secondary battery, of the temperature data amount of change values ATDt stored in said 4th memory means 18, a 5 calculation is performed to determine the change ratio between the temperature data amount of change ATDtn at the 1st overall amount of change reading sampling time tn and the 2nd overall amount of change reading sampling time t(n+l), which is formed by shifting by said amount. 10 of change reading sampling time (ts) at a time, this change ratio of AHt (where AHt=ATDt(n+l)/ATDtn) being stored in 5th memory means 19 (A).

Subsequently, said change ratio AHt between amounts of temperature change is compared by 1st judgment means 15 22 with a preestablished reference value K, and if said change ratio AHt between amounts of temperature change exceeds said reference value K, a signal is output from 1st judgment means 22 for the purpose of stopping said charging operation.

Thus, as shown in FIG. 6B, in the region of full charge, since in the rising curve of measured temperatures of the secondary battery suddenly increases, the ratios of ATDt(n+l) and ATDtn for each amount of change reading sampling time (ts) is taken, and if said 25 ratio is greater than a preestablished reference value K, it is assumed that said secondary battery has reached 100% charge level, and the charging operation is stopped.

In said 1st judgment means 22, if said change ratio AHt between amounts of temperature change differences 30 exceeds a preestablished reference value K, the judgment will be made that said secondary battery has reached 100% charge level or the 100% charge level region, and a signal will be output for the purpose of stopping said charging operation, the result being that said 35 charging-control means 9 is operated to turn said switch means 5 off, thereby stopping the charging operation of said secondary battery.

WO 95/09471 PCT/JP94/00651 With regard to the present invention, although the method of measuring the terminal voltage of said secondary battery during charging and stopping the charging operation if the judgment is made that the 5 charge level has reached 100% or the 100% region, and the method of measuring the temperature of said secondary battery during charging and stopping the charging operation if the judgment is made that the charge level has reached 100% or the 100% region were described 10 separately, in the present invention it is possible to combine these two methods, thereby enabling a more accurate determination of the charge level.

Additionally, in the present invention, although the basic method is when measuring voltage data, to measure 15 the voltage data measured at each amount of change reading sampling time (ts), repeating this M times, thereby accumulating the overall data value during the overall sampling period t (tsxM), using the results to observe the change of said voltage data, in the charging 20 of a secondary battery, when the charge level of said secondary battery is 100% or is in the 100% region, the change in temperature becomes very gradual, so that if the sampling period is made long, it is possible to, for example, detect the peak value on the temperature 25 variation graph, or to accurately and quickly detect such conditions as a dropoff from the peak value, or in addition, the condition in which there is no change from the peak value over a given period of time.

For this reason, in the high-speed charging method 30 for secondary batteries of the present invention, another possible form is that in which, every time a voltage data amount of change ATDvn is measured each said amount of change reading sampling time (ts), a difference between that value and the previously determined voltage data 35 amount of change ATDv(n-1) is determined, a determination is made as to whether that value is either zero or positive or zero, and if the value is positive, a counter WO 95/09471 PCT/JP94/00651 AS having a preestablished upper limit value W is reset to zero, but if the value is negative, the current said counter value AS is incremented by 1, or a value corresponding to said negative value is added to the AS, 5 and if the resulting sum exceeds the preestablished upper limit value W, the charging operation with regard to said secondary battery is stopped.

In the case in which said difference amount is zero, it is possible, for example, to forcibly add a 10 preestablished negative constant Z (for example -2) to said counter value AS, so that if the difference value is zero, indicating that the voltage data curve is not changing, it is treated as if it were a negative value for the purposes of processing.

Next, one concrete example of the operating procedure for the high-speed charging method for secondary battery of the present invention will be described, with references made to the flowcharts of FIG. 7 through FIG. 9.

FIG. 7 through FIG. 9 are flowcharts that explain the operation of one specific example of the high-speed charging method for secondary batteries of the present invention. First, at step (1), the basic data reading time tb required to read data is set, operation 25 proceeding to step (2), at which the charging rate C which is a rated value suitable for executing charging with respect to said secondary battery.

In the present invention, in addition to being able to charge secondary batteries having individually 30 differing constructions, there being secondary batteries of the same type but having differing charging rates, it is possible to also, in accordance with the charging rate that is indicated as a specification, by executing sampling of the ideal measurement values, to collect 35 precise data, enabling accurate and high-speed charging.

Next, operation proceeds to step (3), at which the corrected data reading time tc, which is characteristic 1 to the set charging rate c is set in accordance with the set charging rate C and said basic data reading time tb.

Then, at step (4), since in the case in which the measured voltage value amount of change is either zero or 5 negative a preestablished number of times, for example P, in a row, the judgment is made that said secondary battery being charged has reached the 100% charge level or the region of 100% charge level, and said charging operation is stopped, if this occnrs, at this step the 10 preestablished value of P is set into the counter I, which counts down.

At step (5), in order to repeat the sampling operation every corrected data reading time tc, which value is characteristics to the charging rate C, for 15 example L times, said preestablished number of times L is set into counter II, which controls said number of repetitions.

Next, operation proceeds to step (6), at which the time data corresponding to the corrected data reading 20 time, which is characteristics to the charging rate and which is set at step (3), is set into counter II.

After this, at step (7), when measuring the voltage and temperature data of the secondary battery being charged, for the reason described previously, the supply 25 of current to charging said secondary battery is cut off at the instant of the data measurement.

As described previously, the charging current at the time of these data measurements is cut off by turning the switch means 5 which comprises the transistor in FIG. 1 30 to off.

After that, at step (8), the terminal voltage (dv) of said secondary battery being charged is measured, and at step (9), the results are stored into 1st memory means 15, that is, in memory I.

In the same manner, at step (10), the surface temperature (dt) of said secondary battery being charged is measured, and at step (13), the results are stored — — r v. i/jjryi/uut)3i into the same 1st memory means 15, that is, into memory I.

Next, operation proceeds to step (12), at which the supply of charging current is starting once again to restart the charging operation, after which at step (13) a judgment is made as to vhether or not either the voltage value or the temperature value just measured exceeds the preestablished data limit value, and if said measured data does exceed said limit value, the judgment is made that an abnormal condition has occurred in the secondary battery being charged, and said charging operation is stopped.

If, however, both the voltage value and the temperature value just measured are judged normal at step (13), operation proceeds to step (14), at which the set value of counter-III is decremented by 1, and operation proceeds to step (15), at which a judgment is made as to whether or not the value of said counter III is zero, and if it is not zero, a wait is made until the value of counter III is zero, that is, until the corrected data reading time tc has elapsed, and after a verification is made that the value of said counter III is- zero, operation proceeds to step (16), at which the values of voltage data dv and temperature data dt obtained from the measurement just mad are added to the respective values of voltage data dv and temperature data dt obtained at the immediately previous measurement, the results being cumulatively stored separately into said 1st memory means 15.

Next, operation proceeds to step (17), at which 1 is subtracted from the setting value L of counter II, and operation proceeds to step (18), where a judgment is made as to whether or not the setting value L of said counter II is zero.

Thus, in the present invention, while voltage data and temperature data are measured at least one time during said corrected data reading time tc, the WO 95/09471 PCT/JP94/00651 associated operations are repeated during a preestablished time, that is during the measurement data amount of change reading sampling time (ts), a preestablished number of times, that is, L, which causes 5 repetition of said measurements, said value of L being arbitrarily settable.

Therefore, at step (18), if the setting value L of said counter II is not zero, it means that the required number of measurements has not yet been reached, so that 10 return is made to step (6), at which the above-mentioned steps are repeated.

If, however, at step (18), the setting value L of said counter II is zero, this means that the required number of measurements has been reached, so that 15 operation proceeds to step (19), at which a calculation is performed to determine the sums, Dvn and Dtn, of the voltage and temperature data values that had been stored into 1st memory means 15 L times each corrected data reading time tc, these results being stored separately 20 into 2nd memory means 16 (memory II).

Next, at step (20), using the data that had been stored into said 2nd memory means 16, the differences between the values Dv(n-l) and Dt(n-l) stored into memory II the immediately previous measurement and the values 25 Dvn and Dtn of the current measurement, that is, the amounts of change between the data measured at the current measurement data amount of change reading sampling time (ts) and the data measured at the immediately previous measurement data amount of change 30 reading sampling time (ts-1) are calculated, at the step (21) the resulting ADv and ATt are stored separately into said 3rd memory means 17 (memory III).

After this, at step (22), using the data ADv and ADt which had been individually cumulatively stored into 3rd 35 memory means 17, said amount of change data ADv and ADt obtained at the current measurement data amount of change reading time (tsl) are added respectively to the amounts wu ya/iwi/i Jrtrr/JF94/0U65] of change data obtained at the immediately previous measurement data amount of change reading time (tsO), the results of ATDv and ATDt being stored separately into 4th memory means 18 (memory IV).

At this step (22), said measurement data amount of change reading sampling time (ts) is set a number of times, for example M times, and the accumulated sum of the amount of change data values obtained at each of the sampling times (tsn) is calculated.

For this reason, at step (23), a judgment is made as to whether or not the total number of data stored in said 4th memory means 18 (memory IV) is a preestablished number, for example M, and if the result of this judgment is NO, the judgment is made that the measurement data 15 amount of change reading sampling time (ts) has not been repeated the preestablished number of times M, and return is made to step (5), after which step the above steps are repeated.

If, however, the result of step (23) is YES, 20 operation proceeds to step (24), at which a calculation is made, with regard to the measured voltage data, from the overall amount of change data which had been stored into said 4th memory means 18, to determine the difference value AHv (where AHv-ATDv(n-l)-ATDvn) between 25 the amount of change from the immediately previous measurement data, that is, the overall amount of data change ATDvn, which is based on the M data measurements at said measurement data amount of change reading sampling times (tsl) to (tsra), and the amount of change 30 from the current measurement data, that is, the overall amount of change ATDv(n-l), which is based on the M data measurements of said measurement data amount of change reading sampling times (tsO) to (tsM-1), and at which also a calculation is made, with regard to the measured 35 temperature data, from the overall amount of change data which had been stored into said 4th memory means 18, to determine the change ratio value AHt (where WO 95/09471 PCT/JP94/00651 ) AHt=ATDt(n-l)/ATDtn) between the amount of change from the immediately previous measurement data, that is the overall amount of data change ATDtn, which is based on the M data measurements at said measurement data amount 5 of change reading sampling times (tsl) to (tsm) and the amount of change from the current measurement data, that is the overall amount of data change ATDtn-1, which is based on the M data measurements of said measurement data amount of change reading sampling times (tsO) to (tsM-1), 10 the results, AHv and AHt, of said calculations being stored, respectively, in 6th memory means 19(B) (memory VI) and 5th memory means 19(A) (memory V).

After that, at step (25), a judgment is made as to whether or not measurement data is voltage data, and if 15 the result is NO, operation proceeds to step (27), at which, as shown in FIG. 6B, a judgment is made as to whether or not said overall amount of change, AHt, of said measurement data is larger than a preestablished value, for example the value K, and if the result is YES, 20 operation proceeds to step (28).

Thus, the overall sum of said temperature data amounts of change ATDtn over the M times of measurement data amount of change reading sampling time (tsl) to (tsM) is shift one said measurement data amount of change 25 reading sampling time (ts) at a time, and if the change ratio with respect to the overall sum said temperature data amounts of change ATDt (n+1) over the M times of measurement data amount of change reading sampling time (ts2) to (tsM+1) is large, indicating that the rate of 30 rise of said temperature measurement data has increased over a short period of time, the judgment is made that said secondary battery being charged has reached the 100% charge level or the region of the 100% charge level, and the charging operation is stopped at this point. 35 The preestablished value K can be set as desired, and in the present invention, it is set as a value of, for example, 2 or greater.

PCT/JP94/006S1 That is, in the present invention, as shown in FIG. 2 through FIG. 4, for a secondary battery of any configuration, in the case in which the charge level either reaches 100% or the region of 100%, or exceeds the 100% level, since the measured temperature data rate of rise changes suddenly from its previous gradual increase to a rapid rate of rise, this condition is detected, enabling detection the reaching of the 100% level or the region of 100% charge leval, or the exceeding of the 100% charge level.

If at step (27) the judgments result is NO, operation proceeds to step (29), at which, for the purpose of determining the overall amount temperature measurement data amount of change, ATDt(n+2) for the M temperature data over the measurement data amount of change reading sampling time (ts3) to (tsM+2) by shifting said measurement data amount of change reading sampling time (ts) one at a time, after first deleting the first of the M temperature measurement data currently stored in memory V, return is made to step (23), after which the above operations are repeated.

At step (28), if the result was YES, the operation proceeds to step (30), at which a judgment is made as to whether the change in said overall voltage data amount of change, that is AHv, is zero or negative less than zero, and if the result was YES, operation proceeds to step (31), at which the setting value P of counter I is decremented by 1, and then to step (32), at which a judgment is made as to whether the setting value P of said counter is P, and if the result is YES, operation proceeds to step (28), at which the charging operation is stopped. When the result was NO at step (32), return is made to step (7), after which the above operations are repeated.

Thus, in the present invention, as shown in FIG. 2 through FIG. 4, for a secondary battery of any configuration, if the charge level reaches 100% or the WO 95/09471 PCT/JP94/00651 region of 100% or exceeds 100%, the measured voltage data which had previously been rising is seen to start to fall or remain unchanged.

Therefore, in tiie present invention, for any 5 secondary battery, to detect the condition in which the charge level has reached 100% or the 100% region, a judgment is made as to whether the overall change in the amount of change, that is, the difference amount AHv is zero or negative, and further a determination of whether 10 the difference value AHv has been zero or negative for P times in a row, and if so, the judgment is made that said secondary battery has reached the charge level of 100% or the region of charge level 100%, and the charging operation is then stopped.

In the present invention, the setting value P of said counter I can be established arbitrarily as desired, for example it can be set to a P value of 3.

Therefore, in this case, although if said difference amount AHv is zero or negative for 3 times in a row, the 20 judgment is made that the charge level of said secondary battery has reached 100% or has reached the 100% region, and the charging operation will be stopped, if in any 3 consecutive measurements the difference value AHv is positive even one time, the setting value of said counter 25 I is reset to the original setting value P and the above-stated judgment is repeated.

On the other hand, at step (30), if the result was NO, in step (33) the setting value of counter I is reset to P, and operation returns to step (4), and thereafter 30 each of the above-stated steps is repeated.

While in the above-described specific example of the present invention, said count I is set to an initial value of P, and counts down sequentially, in accordance with the result of measurements, so that when the setting 35 value P is 0 the judgment is made that the charge level of the secondary battery is 100%, it is also possible to reverse this, by setting said counter I to an initial rwi/«7r?«i.'uuodi value of 0 and having said counter count up sequentially according to the results of measurements, and when the setting value of said counter I reached a preestablished value of P, to make the judgment that the charge level of the secondary battery is 100%.

However, in either of the above-described mechods, during charging, there is a danger that the charging operation will be stopped if for some reason the variation in the difference values of said data is zero or negative three times consecutively, even at a point at which the charge level is not that high, so that to solve this problem, in the present invention, since the output voltage of the various secondary batteries in the region of 100% is known beforehand, it is desirable to make the configuration such that the output voltage of said secondary battery is constantly measured and the results monitored, so that the above-described calculation method is only valid in the case in which said output voltage is above 70% to 80% of the secondary battery's nominal output.

In the high-speed charging method for secondary batteries of the present invention, as described above, it is sufficient to at least measure the terminal voltage data of said secondary battery, so that the amount of change in the terminal voltage data are detected, and it is also possible to measure the surface temperature data of said secondary battery, so that the change ratio in the surface temperature is detected.

In addition, in the present invention, it is also possible to make use of both temperature data and voltage data to estimate the charge level.

In the present invention, for example, the basic data reading time tb required for reading data is set to 0.75 second, counter II value L is set to 4, the charge rate C at which said secondary battery is to be charged is set to 4, and constant A is set to 16.

In addition, at step (23) if the number of VTVT / X rci/jr^/uuooi repetitions M is set to 8, said measurement data amount of cbnnge reading sampling time (ts) will be 12 seconds, ana the time required for 8 repetitions of the measurement data amount of change reading sampling time 5 (ts) will be 96 seconds.

In the present invention, therefore, in the actual example given above, the measurement of either voltage or temperature will require a considerable amount time, and in such cases it is also possible, instead of repeating 10 the above-stated measurement data amount of change reading sampling time (ts) M times, to use individual values of the amount of change ADv and ADt to judge the charge level.

That is, in the charging method of the present 15 invention, in the case in which said secondary battery has a considerable residual capacity, there is a possibility that 100% charge level will be reached in a short period of time, and since if the charging is continued without noticing this, the temperature will 20 rise, leading to a danger of deterioration of the secondary battery, to prevent this danger, it is desirable to provide safety measures in addition to the basic charging method of the present invention.

Another specific example of the present invention 25 will be described, with references made to the flowcharts of FIG. 10 and FIG. 11.

While the flowcharts of FIG. 10 and FIG. 11 are basically the same as the flowcharts of FIG. 7 through FIG. 9 which show a high-speed charging method for 30 secondary batteries of the present invention, there are slight differences in the method of calculation and judging performed at individual steps.

That is, in the specific example shown in FIG. 7 through FIG. 9, in performing voltage measurements, for 35 example, said voltage data is totaled within the measurement data amount of change reading sampling tdLme (ts), so that in the case of the charge level of said A V* AiUX7*t/UUU«71 secondary battery approaching 100%, because the voltage exhibits particularly small changes in a short period of time, it is desirable to constantly track the changes to detect such a condition, and in the present invention the configuration is made such that, for each measurement data amount of change reading sampling time (ts), detection is performed of how said voltage data is varying, so that if said voltage data variation exhibits a particular condition, as shown in steps (24) through (32) in said FIGs. 8 and 9 after repeating the voltage measurement data at least 8 times at the measurement data amount of change reading sampling time (ts), the charging operation can be stopped before judging the charging condition.

FIG. 10 and FIG. 11 show the flowcharts of the operations performed in practicing the other specific example of the present invention, wherein because step (7) through step (20) are the same as in the flowchart of FIGs. 7 and 8, these steps are omitted from FIG. 10, with the flowchart beginning with the step corresponding to step (20) of FIG. 8.

Note that in the following steps 120 and 121, the same calculation as indicated in step 20 in FIG. 8, are carried out.

Essentially, in FIG. 10 and FIG. 11, based on the data Dn that is calculated and stored into the 2nd storage means before step (120), a calculation is performed to determine the difference ADv (where ADv=ADvn-ADv-l) between the voltage data Dvn-1 at the immediately previous amount of change reading sampling time ts—1 and the voltage data ADvn at the current amount of change reading sampling time ts, and in addition in step 121, a calculation is performed in the saute manner to determine the difference ADt (where ADt=ADtn-ADtn-l) between the temperature data Dtn-1 at the previous amount of change reading sampling time ts-1 and the temperature data Dtn at the current amount of change reading sampling WO 95/09471 PCT/JP94/00651 ') time ts.

After the above is done, at step (122), said difference ADv (where ADv=ADvn-ADv-l), which is the amount of change in said voltage data, is stored into 5 memory IV (VBora), and at step (123), said difference (ADt=ADtn-ADtn-l), which is the amount of change in said temperature data is stored into memory IV (TBUFF).

Next, in said specific example of the present invention, in particular with regard to voltage data, it 10 is desirable to detect the width of variation occurring over a short period of time, and for that reason, at step (124), said difference ADv is judged as being either a non-zero positive value or not, and if the result is YES, operation proceeds to step (126) at which AS is reset to 15 zero.

Essentially, what occurs is that, if the difference in the amount of change in said voltage data between the 1st measurement data amount of change reading sampling time (tsl) and the 2nd measurement data amount of change 20 reading sampling time (ts2) is positive, this indicates that said voltage measurement data is increasing, and in this case, the judgment is made that the charge level of the secondary battery has not reached 100%, so that constant AS which indicates a change in said voltage 25 measurement means is reset to zero and operation proceeds to step (127).

On the other hand, a NO result occurs at step (124), that is, if the voltage data is either decreasing or constant, operation proceeds instead to step (125), at 30 which the current said difference value ADv is added to immediately previous value of constant AS and the value preestablished constant value X is subtracted from this, the result being taken as the new value of constant AS.

In this example, since the value of ADv is negative, 35 the result is that both the difference ADv and the preestablished constant Z are subtracted from the WO 95/09471 PCT/JP94/00651 i / immediately previous value of constant AS.

In addition, the above-stated constant Z is a counting constant value such that, when there is no change in the difference value ADv, it makes it appear,as 5 though there is change, and is set to, for example, Z=2. Therefore, in this specific example, when the voltage data is at a peak value, and said peak value is being maintained, said constant AS is actually subtracted from.

Next, at step (127), a judgment is made as to whether said constant AS is equal to or less than a preestablished value of w, and if the result is YES, since it is possible to assume that the charge level of the secondary battery is at 100% or in the region of 15 100%, operation proceeds to step (135), at which the charging operation is stopped.

That is, in this specific example, said value w is set to, for example, 6, and if said constant Z is 2 and said difference value ADv is zero 3 times consecutively, 20 that is, if there is no change, the following sequence will occur.

After 1 ts: AS=AS-ADv-Z=0-0-2=-2 After 2 ts: AS=AS-ADv-Z=-2-0-2=-4 After 3 ts: AS=,AS-ADv-Z=-4-0-2=-6 25 Thus, the charging operation will be stopped at the point at which the third repetition of the measurement data amount of cheuige reading sampling time (ts) is made.

By way of providing an explanation with more specific data if, for example, the case in which the 30 basic data reading time tb required for reading data is set as 0.75 second, the value L of counter II is set as 4, the charging rate C at which the secondary battery is to be charged is set to 4, and said constant A is set to 16.

In addition, in the case in which the number of repetitions M of the measurement at the measurement data amount of change reading sampling time (ts) is set to 8, WO 95/09471 PCT/JP94/00651 and said constant w is set to -6, and the constant Z is set to 2, if the erroneous recharging of a nickel-cadmium battery is done after the completion of charging is hypothesized, the measurement data amount of change 5 reading sampling time (ts) for measuring the charging voltage characteristics would be (0.75xl6/3)x4=16 seconds, and the battery voltage, ADv, and AS with respect to each measurement data amount of change reading sampling time (ts) would be as follows. ts Battery voltage ADv AS Its 632 632 0 2ts 631 -1 -3 3TS 629 -2 -7 From the above results, the charging operation with 15 respect to the secondary battery would be stopped at the measurement at the third measurement data amount of change reading sampling time (ts), the time required for this to occur being merely 48 milliseconds.

At step (128) in the flowchart of FIG. 10, from the 20 amount of change data for voltage of each of the data stored in said memory IV (VBOTF) after the M repetitions of the operations of step (22) through step (23) of FIG. 8, a calculation performed to determine the difference value AHv between the current amount measurement data 25 change, that is, the total amount of change, ATDvn, based on the 14 measurement data at said measurement value amount of change reading sampling time (tsl) to (tsM) and the total value of the immediately previous amount of measurement data change, that is, the overall amount of 30 change based on the M measurement data at said measurement data amount of change reading sampling time (tsO) to (tsM-1), and at step (129) a judgment is made as to whether AHv is positive or negative or zero, and if it is positive, operation proceeds to step (131), at which 35 the value N of an appropriate counter is reset to zero, after which operation proceeds to step (132) rv.i;jry The effect of this is that in this specific example, a judgment is made of what condition, if any, said difference value AHv is maintaining continuously, and in the same maimer as in the previously described specific example, in the case in which the value of said difference AHv is negative N times consecutively, said secondary battery is judged to have reached a charge level of 100% or the region of 100% charge level, and said charging operation is stopped.

The value N of said counter can be set appropriately as desired, and in an actual example, can be set to, for example N=3.

In the present invention, because, as shown in step (124) through step (127), if ADv is zero, it is assumed that the negative condition exists, even at said step (129), even if said voltage measurement data is maintaining a peak value, the condition in which the difference value AHv is zero will not occur, so that this will be counted as a negative value.

Then, operation proceeds to step (132), at which a judgment is made as to whether the value of N of said counter is 3, and if the result was YES, the charging operation with respect to said secondary battery is stopped, but if the results was NO, operation proceeds to step (133), at which, after said difference value ADt (ADt=Dtn-Dt(n-l)), which is the temperature data amount of change stored into memory IV (TBuyy) at step (123) is used and M repetitions are made, a determination is made of the current amount of measurement data change, that is, the overall amount of change, the total value ATDtn, WO 95/09471 PCT/JP94/00651 I based on the M measurement data at the measurement data amount of change reading sampling time (tsl) to (tsM), and a determination is made of the immediately previous total amount of change, which is the overall amount of 5 change ATDt(n-l), which is based on the M measurement data at said measurement value amount of change reading sampling time (tsO) to (tsM-1), and a judgment is made as to whether or not both these values are a preestablished value a.

In these operations, in performing the charging of said secondary battery, because if some sort of error or misoperation causes a sudden rise in temperature in spite of the fact that the charge level has not even reached the 100% region, an erroneous stoppage of said charging 15 operation would occur, to avoid this condition, since the temperature rise of said secondary battery during charging is known beforehand, data related to the normal amount of temperature change occurring when the charge level reaches the 100% region is set as the required 20 data, for example by setting an appropriate value of a is set into an appropriate memory, in which case a return would be made to step (7) of FIG. 7, whereupon the above-described steps would be repeated.

In said step (133), in the case in which both the 25 above-noted amounts of total temperature change are equal to or greater than the preestablished value a, operation proceeds to step (134), at which a judgment is made as to whether the rate of change AHt between the current amount of measurement data change, that is, the overall amount 30 of change ATDn, which is based on the M measurement data at said measurement data amount of change reading sampling time (tsl) to (tsM), and the immediately previous amount of measurement data change, that is, the overall amount of change ATDtn-1, which is based on the M 35 measurement data at said measurement data amount of change reading sampling tin. (tsO) to (tsM-1), is or is not greater than a preestablished value, for example K, "WO 95/09471 PCT/JP94/00651 ) and if the result of this judgment is YES, the charging operation is stopped.

If, however, the result was NO, return is made to step (5) of FIG. 7, whereupon the above-described steps 5 . would be repeated, What follows is an explanation of the results of using the secondary battery charging method of the present invention to charge secondary batteries of differing constituent elements and under different 10 charging conditions, with reference made to Table I through Table V and FIG. 12 through FIG. 20.

Table I shows the case of using the secondary battery charging method of the present invention suitable for nickel-cadmium batteries having a charging rate of 15 0.25C, and wherein the settings: the basic data reading time required to read data, tb=0.75 second; counter II value L=4; charging rate C=0.25; Setting constant A=16; and Nuinber of repetitions of the measurement operation to be performed at each measurement data amount of change reading sampling time (ts) M=8 were made for the execution of the charging operation.

In this specific example, the amount of change reading sampling time, ts, would be ts=(0.75x16/0.25)x4=192 seconds.

Table I shows the voltage measurement data at each measurement data amount of change reading sampling time 30 (ts), the total amount of voltage change ATDv at step (122) of FIG. 10, and the counter value N at step (130) and step (131) of FIG. 10.

Essentially in Table I the battery voltage data is the raw data obtained at each said measurement data 35 amount of change reading sampling time (ts), and the overall total amount of change ATDv indicates the difference value between the total of the shift values summed over 8 times at each of the measurement data amount of change reading sampling times (tsl) to (ts8) and total of the shift values summed over 8 times at each of the measurement data amount of change reading sampling 5 times (ts2) to (ts9).

The count value N, in accordance with above-stated step (129) through step (131) in FIG. 10, is added to or subtracted from, depending upon whether said difference value AHv is positive, negative, or zero.

That is, during the period from tsl to ts8, since there is no previous data, the output of said difference AHv is zero, so that the count value N remains zero, but at ts9, said total amount of change ATDv becomes 32, so that the AHv value of -521 is negative, resulting in said 15 count value N being incremented by 1.

Next, at tslO, in the same manner, since said \-otal amount of cheuige ATDv becomes 24, said difference amount AHv takes the negative value of -8, so that said count value N is incremented by 1, making said count value 2. 20 In the same manner, because up to tsl5 said difference value AHv is continuously negative, sound count value N is incremented by 1 each time, so that the count value is 7 at tsl5.

However, in this specific example, in general, said 25 count value is set to 3, so that the charging operation is stopped when said count value exceeds 3, so that although in this specific example the charging operation is stopped at ts11, since the battery voltage of said secondary battery which has reached 100% charge level is 30 known beforehand, it is possible to perform processing so that, as long as that voltage is not exceeded, the data value of said counter is not valid.

For this reason, in this specific example, if the battery voltage of said secondary battery is set to, for 35 example, tb 580 V, and if the above-stated count value N is made invalid when the battery voltage exceeds said 580 V, there will be no problem of the charging operation WO 95/09471 PCT/JP94/00651 ') y stopping at t.sll. ^ Furthermore, at tsl6, since the difference value AHv becomes -1, the counter value is reset from 7 to 0.

The same type of operation is.repeated, and at ts80 5 because the battery voltage is 600 V and said counter value is 3, said charging operation is stopped.

FIG. 12 shows a graph of the measurement data of Table I, with ts plotted along the horizontal axis, and in FIG. 13, plotted from the raw data of FIG. 12, the 10 solid line shows the plot of said total amount of change ATDv for each ts, and the dotted line shows said counter value N plotted for each ts.

Table II shows the case of using the secondary battery charging method of the present invention suitable 15 for nickel-cadmium batteries having a charging rate of 3C, and wherein the settings: the basic data reading time required to read data, tb=0.75 second; counter II value L=4; charging rate C=3; Setting constant A=16; Number of repetitions of the measurement operation to be performed at each measurement data amount of change reading sampling time (ts) M=8; and 25 constant K=2 were made for the execution of the charging operation..

In this specific example, the amount of change reading sampling time, ts, would be ts=(0.75xl6/3)x4=16 seconds.

Table II shows the battery temperature measurement data at each measurement data amount of change reading sampling time (ts), the total amount of temperature change ATDt at step (123) of FIG. 10, and the change ratio AHt of the amount of temperature change at step 35 (134) of FIG. 10.

Essentially in Table II the temperature data is the raw data obtained at each said measurement data amount of WO 95/09471 PCT/JP94/00651 ) change reading sampling time (ts), the overall total amount of temperature change ATDt indicates the difference value between the total of the shift values summed over 8 times at each of the measurement data 5 amount of cheuige reading sampling times (tsl) to (ts8) and total of the shift values summed over 8 times at each of the measurement data amount of change reading sampling times (ts2) to (ts9), and AHt indicates the rate of change between adjacent values of ATDt, that is 10 AHt=ATDtn/ATDtn-l.

In accordance with the operation of above-stated step (34) of FIG. 10, the change ratio of temperature change AHt is compared with above-described preestablished constant value K=2, and if AHt is equal to 15 or greater than 2 (i.e., AHt>K), because it can be predicted that the charge level has reached 100% or the 100% region, said charging operation is stopped.

In the data of Table II, if the denominator of the expression for AHt=ATDtn/ATDtn-l is zero, an error is 20 indicated.

In this specific example, at ts57, the data for said rate of change of temperature change AHt=ATDtn/ATDtn-l exceeds the constant K=2, so that at this point said charging operation is stopped.

Fig. 14 is a graph of with regard to battery temperature measurement data shown in Table II, with ts plotted along the horizontal axis.

Table III shows the case of using the secondary battery charging method of the present invention suitable 30 for nickel-cadmium batteries having a charging rate of 3C, and wherein the settings: the basic data reading time required to read data, tb=0.75 second; counter II value L=4; charging rate C=3; Setting constant A=16; and the number of repetitions of the measurement operation to WO 93/05471 PCT/JP94/006S1 1 be performed at each measurement data amount of change reading sampling time (ts) M=8 were made for the execution of the charging operation.

In this specific example, the amount of change 5 reading sampling time, ts, would be ts=(0.75xl6/3)x4=16 seconds.

Table III shows the battery voltage data at each measurement data amount of change reading sampling time (ts), the total amount of voltage change ATDv at step 10 (122) of FIG. 10, and the counter value N at step (130) and step (131) of FIG. 10.

Essentially, the battery voltage data and other data of Table III, are the same type of data as in above Table I, and therefore no particular separate explanation will 15 be provided, although it can be said that this indicates that the same type of operations as in the case of Table I enable charging in a short period of time with a large current, and in particular that, at 3C, at the point of ts61, because charging is completed, the charge is seen 20 to have been completed at a time approximately 16 minutes from the start of charging operation.

FIG. 15 and FIG. 16 are graphs that correspond to above-discussed FIG. 12 and FIG. 13.

Table IV shows the case of using the secondary 25 battery charging method of the present invention suitable for nickel-hydrogen batteries having a charging rate of 0.25C, and wherein the settings: the basic data reading time required to read data, tb=0.75 second; counter II value L=4; charging rate C=0.25; Setting constant A=16; and the number of repetitions of the measurement operation to be performed at each measurement data amount of change 35 reading sampling time (ts) M=8 were made for the execution of the charging operation.

In this specific example, the amount of change WO 95/09471 PCT/JP94/00651 ) reading sampling time, ts, would be ts=(0.75x16/0.25)x4=192 seconds.

Table IV shows the battery voltage data at each measurement data amount of change reading sampling time 5 (ts), the total amount of voltage change ATDv at step (122) of FIG. 10, and the counter value N at step (130) and step (131) of FIG. 10.

Essentially, the battery voltage data and other data of Table IV, are the same type of data as in above Table 10 I, and therefore no particular separate explanation will be provided, although it can be said that this indicates that the same type of operations as in the case of Table I enable complete charging of a new type of secondary battery, the nickel-hydrogen battery, at t.s79, which is 15 in a period of time of 252 minutes.

FIG. 17 and FIG. 18 are the graphs that correspond to above-discussed FIG. 12 and FIG. 13.

Table V shows the case of using the secondary battery charging method of the present invention suitable 20 for nickel-hydrogen batteries having a charging rate of 1C, and wherein the settings: the basic data reading time required to read data, tb=0.75 second; counter II value I«=4; charging rate C=l; Setting constant A=16; and the number of repetitions of the measurement operation to be performed at each measurement data amount of change reading sampling time (ts) M=8 were made for the 30 execution of the charging operation.

In this specific example, the amount of change reading sampling time, ts, would be ts=(0.75x16/1)x4=48 seconds.

Table V shows the battery voltage data at each 35 measurement data amount of change reading sampling time (ts), the total amount of voltage change ATDv at step (122) of FIG. 10, and the counter value N at step (130) WO 95/09471 PCT/JP94/00651 ^ and step (131) of FIG. 10.

Essentially, the battery voltage data and other data of Table V, are the same type of data as in above Table I, and therefore no particular separate explanation 5 will be provided, although it can be said that this indicates that the same type of operations as in the case of Table I enable complete charging of a new type of secondary battery, the nickel-hydrogen battery, at ts78, which is in a period of time of 62 minutes, 24 seconds. 10 FIG. 19 and FIG. 20 are the graphs that correspond to above-discussed FIG. 12 and FIG. 13.

Because the high-speed charging method for secondary batteries of the present invention makes use of the above-described technical configuration, even for 15 secondary batteries of differing types, in consideration of the mutually differing charging characteristics exhibited by the secondary batteries, such as terminal voltage or temperature, it is possible to determine the common characteristics of secondary batteries having 20 differing constituent elements, to accurate determine point at which the charge level reaches nearly 100%, enabling not only one and the same apparatus to be used to reliably charge secondary batteries of differing construction, but also enabling the accurate 25 determination of the charge level during the charging process, the quick determination of the point at which the charge level reaches a level of nearly 100%, and the stopping of the charging process at that point, the result being not only a reliable avoidance of the problem 30 encountered when the charging is continued even after the charge level has exceeded 100%, thereby causing the temperature of the secondary battery to rise above its rated maximum temperature, leading to damage to said secondary battery, but also a determination of the 35 characteristics of said secondary battery with respect to the speed of charge, or charge rate, thereby enabling charging of secondary batteries which are of the same constituent elements at different charge rates, further enabling in particular the precise high-speed charging of secondary batteries.

That is, in the present invention, in addition to 5 being able to charge secondary batteries having individually differing constructions, there being secondary batteries of the same type but having differing charging rates, it is possible to also, in accordance with the charging rate that is indicated as a 10 specification, by executing sampling of the ideal measurement values, to collect precise data, enabling accurate and high-speed charging.

Table I - (1) ts Battery Voltage (V) ATDvn 1 524 524 2 532 532 3 539 539 4 542 542 547 547 6 549 549 7 552 552 8 553 553 9 556 32 556 24 11 558 19 12 559 17 13 560 13 14 560 11 560 8 16 562 9 17 563 7 18 564 8 19 564 6 564 21 564 4 22 564 4 23 566 6 24 568 6 568 26 568 4 27 568 ; -4" 28 568 4 29 568 4 568 4 31 568 2 32 568 0 33 569 1 34 571 3 571 3 36 571 3 37 571 3 38 572 4 39 572 4 40 572 4 41 572 3 42 572 1 43 572 1 44 572 1 45 572 1 N 0 0 0 0 0 0 0 0 1 2 3 4 6 7 0 1 0 1 2 3 3 0 0 1 2 2 2 2 2 3 4 0 0 0 0 0 0 0 0 1 2 2 2 2 WO 951)9471 PCT/JP94/006S1 Table I - (2) ts Battery Voltage (V) ATDvn N 46 572 0 3 47 574 2 0 48 576 4 0 49 576 4 0 50 576 4 0 51 577 0 52 576 4 1 53 576 4 1 54 577 0 55 576 2 1 56 576 0 2 57 576 0 2 58 577 1 0 59 577 0 1 60 576 0 1 61 579 3 0 62 580 3 0 63 580 4 0 64 580 4 0 65 580 4 0 66 580 3 1 67 581 4 0 68 584 8 0 69 584 1 70 586 6 0 71 588 8 0 72 590 0 73 592 12 0 74 594 14 0 75 596 0 76 596 12 1 77 599 0 78 600 14 1 79 600 12 2 80 600 3 W09MW471 Table II - (l) tS Battery Temperature (°C) ATDtn ATDtn/ATDtn-1(K=2) 1 29.54 29.54 Error 2 29.32 29.32 0.99 3 28.65 28.65 0.98 4 28.65 28.65 1.00 28.65 28.65 1.00 6 28.65 28.65 1.00 7 28.65 28.65 1.00 8 28.65 28.65 1.00 9 27.99 -1.55 -0.05 27.76 -1.55 1.00 11 27.76 -0.89 0.57 12 27.76 -0.89 1.00 13 27.76 -0.89 1.00 14 27.76 -0.89 1.00 27.76 -0.89 1.00 16 27.76 -0.89 1.00 17 27.76 -0.22 0.25 18 27.76 0.00 0.00 19 27.76 0.00 Error 27.76 0.00 Error 21 27.76 0.00 Error 22 27.76 0.00 Error 23 27.76 0.00 Error 24 27.76 0.00 Error 27.10 -0.67 Error 26 26.88 -0.89 1.33 27 26.88 -0.89 1.00 28 26.88 -0.89 1.00 29 26.88 -0.89 1.00 26.88 -0.89 1.00 31 26.88 -0.89 1.00 32 26.88 -0.89 1.00 33 26.88 -0.22 0.25 34 26.88 0.00 0.00 26.88 o.oo Error 36 26.88 o.oo Error 37 26.88 o.oo Error 38 26.88 o.oo Error 39 26.88 . 0.00 Error 40 26.88 0.00 Error 41 26.88 ' o.oo Error 42 26.88 o.oo Error 43 26.88 o.oo Error 44 26.88 0.00 Error 45 26.88 0.00 Error PCT/JP94/O0651 Table II - (2) ts Battery Temperature (°C) ATDtn ATDtn/ATDtn-1 46 26.88 0.00 Error 47 26.88 0.00 Error 48 26.88 0.00 Error 49 26.88 0.00 Error 50 26.88 0.00 Error 51 26.88 0.00 Error 52 26.88 0.00 Error 53 26.88 0.00 Error 54 26.88 0.00 Error 55 26.88 0.00 Error 56 27.10 0.22 Error 57 27.54 0.67 3.00>K 58 27.76 0.89 1.33" 59 27.99 1.11 1.25 60 28.21 1.33 1.20 61 28.43 1.55 1.17 62 28.87 2.00 1.29 63 31.09 4.22 2.11 B OOOOOOOOHNOir^inintDOHniNOHHHNOOOHMOOOHNOOOHNOOOOO CT>CNr»ocsvovooi-4or^"^'^i,tNtsoonoooooa>oooooo'!t,t~-ooooin'!i*w>ooooin*i,^oooooiort cnNSoNU)icocr>iu)u>u>o\ooooN^,<4i^|<(i|u)oaoooo(D(S(>iri^|U) (N<4|^intointriu>U)U)Uivou)vou3tcr,>hhhhhr«roHCNrr>*i <*f .*}• «s»« 0 a PCT/JP94/0065I Table III - (2) tS Battery Voltage (V) ATDvn 46 597 9 47 600 12 48 601 13 49 604 12 50 606 14 51 609 17 52 612 18 53 616 20 54 620 23 55 624 24 56 627 26 57 630 26 58 632 26 59 632 23 60 632 20 61 632 16 N 0 0 0 1 0 0 0 0 0 0 0 0 0 1 2 3 PCT/JP94/0O651 Table XV - (1) ts Battery Voltage (V) ATDvn N 1 513 513 0 2 525 525 0 3 534 534 0 4 541 541 0 545 545 0 6 549 549 0 7 552 552 0 8 554 554 0 9 556 43 1 556 31 2 11 558 24 3 12 560 19 4 13 560 14 560 11 6 560 8 7 16 564 0 17 564 8 1 18 564 8 1 19 564 6 2 564 4 3 21 564 4 3 22 565 0 23 568 8 0 24 568 4 1 568 4 1 26 568 4 27 568 4 28 568 4 1 29 568 4 1 568 3 2 31 568 0 3 32 568 0 3 33 568 0 3 34 568 0 3 569 1 0 36 570 2 0 37 570 2 0 38 570 2 1 39 571 3 0 40 571 3 0 41 571 3 0 42 571 3 0 43 572 3. 1 44 572 2 2 45 572 2 3 Table IV - (2) tS Battery Voltage (V) ATDvn N 46 572 2 0 47 572 l l 48 572 1 l 49 572 1 l 50 572 1 1 51 574 2 0 52 576 4 1 53 576 4 1 54 576 4 1 55 576 4 1 56 576 4 1 57 576 4 1 58 576 4 1 59 576 2 2 60 578 2 2 61 580 4 0 62 580 4 0 63 580 4 0 64 580 4 0 65 580 4 0 66 583 7 0 67 584 8 0 68 584 6 1 69 587 7 2 70 588 8 0 71 591 11 0 72 592 12 0 73 595 15 0 74 596 13 1 75 597 13 1 76 600 16 0 77 600 13 1 78 600 12 2 79 600 9 3 Table V - (1) tS Battery Voltage (V) ATDvn N 1 543 543 0 2 560 560 0 3 564 564 0 4 565 565 0 568 568 0 6 568 568 0 7 568 568 0 8 568 568 0 9 568 25 1 572 12 2 11 572 8 3 12 572 7 4 13 572 4 5 14 572 4 5 572 4 5 16 572 4 5 17 572 4 5 18 573 1 6 19 575 3 0 576 4 0 21 576 4 0 22 576 4 0 23 576 4 0 24 576 4 0 576 4 0 26 576 3 1 27 576 1 2 28 576 0 3 29 576 0 3 576 0 3 31 576 0 3 32 576 0 3 33 576 0 3 34 576 0 3 578 2 0 36 579 3 0 37 580 4 0 38 580 4 0 39 580 4 0 40 580 4 0 41 580 4 0 42 580 4 0 43 580 2 1 44 580 1 2 45 580 0 3 o o -j-j-j-j^j^j-j-jvjcncnCTio^o^iTicnCTicncTiLnLnuiLniJiLnLnLnuiui^^^^ Q>>)oiU)itkU)NHOu)a>>i(nuii^u)iv)i-io(o oo -J oiui.^wnji-'ovooo-jct* rt cn a 0» Ctrl-(D otcnotcnatcnOkOiototintsiinLni/iuiiAlnuiuiOiuiUilfiUitnutintJit-nlnlnUi HHHHOOOOOOlOtOVDVOUJVOCOOOCOCOOOCOCOCOCOCOOOCOCOOOCOCOCD WtOtJM«3(DO*it»(00(»OMJtMWMlOOO(DOOOOm>|J>ip.i^i^i(»^iMAJOOO s- rt pi >Q (D P> tr H < I cn to I | * f*m$ jmj J * ^ | f 1^1 o to ^ cn ^ a\ iMoutoooo^mosaaui^itk^fru^itkiiixtii^^itkUiooo t-Hi a to WNJt-'OI-'OOl-'OOOOOI-'OOOOOOOI-'OOOOOOOOOJOJLO

Claims (10)

wu mwn /1 PCT/JP94/00651 - 63 - O CIAIMS

1. A method of charging a secondary battery, comprising: a step 1 which sets the basic data reading 5 time tb required to read data; a step 2 which sets the charging rate C; a step 3 which sets the corrected data reading time tc, according to the set charging rate C and said basic data reading time tb, said corrected data 10 reading time tc being characteristic to said charging rate C; a step 4 which, during the charging operation, uses an appropriate sampling means to measure the terminal voltage of said secondary battery at least 15 one time during each said corrected data reading time tc, and which stores the voltage data at that time into an appropriate 1st memory means; a step 5 which repeats the operation of said step 4 a predetermined number of times L, takes the 20 summation of the plurality of voltage data obtained in each corrected data reading time tc, and stores the resulting amount of change Dvn over the amount of voltage data change reading sampling time ts (where ts=Lxtc) into an appropriate 2nd memory means; 25 a step 6 which calculates the difference between the amount of change Dvl for the 1st sampling time (tsl) and the amount of change Dv2 for the next, 2nd, sampling time (ts2) obtained in step 5, and which stores the resulting difference in amount of change ADv 30 in a 3rd memory means; a step 7 which continuously repeats said step 6 a predetermined number of times M, and which takes the summation of each of the values of ADvl to ADvM (M values) obtained at each amount of change reading 35 sampling time (ts), and determines the amount of voltage data change ATDv for the overall said amount of change reading sampling time t (where t=tsxM), the results being WO 95/09471 PCT/JP94/00651 - 64 - stored in a 4th memory means; a step 8 which performs a calculation, based on the amount of voltage data change ATDv stored in said 4th memory means, to determine the difference AHv 5 between the voltage amount of change ATDvl measured from over the first overall amount of change reading sampling time (tl) established as running from said 1st sampling time (tsl) to the mth sampling time (tsM) for the predetermined M-th sampling, and the voltage amount of . 10 change ATDv2 measured from over the second overall amount of change reading sampling time established as running from said 2nd sampling time (ts2) to the (m+l)th sampling time (tsM+1) for the predetermined M+l-th sampling, said calculated difference AHv (where AHv=ATDv2-ATDvl) being 15 stored in a 5th memory means; a step 9 which repeats said step 8 while calculating the difference value AHvn (where AHvn=ATDv(N+l)-ATDvn) between the amount of voltage changes ATDvn and ATDv(n+l) at each pair of adjacent 20 overall amount of change sampling times tn and tn+1, and stores the calculated results in 5th memory means; a step 10 which judges whether each of the m amounts of differences in amount of voltage changes AHvl to AHvm are positive (zero or greater than zero) or 25 negative (less than zero); and a step 11 which judges, in the sequence of occurrence of said differences in amount of voltage changes AHvl to AHvm, whether or not said difference in amount of voltage change AHv is zero or negative for S 30 times continuously, and if said difference in amount of voltage change AHv is zero or negative S times continuously, stops said charging.

2. A method of charging a secondary battery, comprising: 35 a step 1 which sets the basic data reading time tb required to read data; a step 2 which sets the charging rate C; WO 95/09471 - 65 - PCT/JP94/00651 a step 3 which sets the corrected data reading time tc, according to the set charging rate C and said basic data reading time tb, said corrected data reading time tc being characteristic to said charging rate C; a step 4 which, during the charging operation, usee an appropriate sampling means to measure the temperature of said secondary battery at least one time during each said corrected data reading time tc, and which stores the temperature data at that time in an appropriate 1st memory means; a step 5 which repeats the operation of said step 4 a predetermined number of times L, takes the summation of the plurality of data obtained in each corrected data reading time tc, and stores the resulting amount of change Dtn over the amount of temperature data change reading sampling time ts (where ts=Lxtc) into an appropriate 2nd memory means; a step 6 which calculates the difference between the amount of change Dtl for the 1st sampling time (tsl) and the amount of change Dt2 for the next, 2nd, sampling time (ts2) obtained in step 5, and which stores the resulting difference in amount of change ADt in a 3rd memory means; a step 7 which continuously repeats said step 6 a predetermined nuinber of times M, and which takes the summation of each of the values.of ADtl to ADtM (M values) obtained at each amount of change reading sampling time (ts), and determines the amount of temperature data change ATDt for the overall said amount of temperature change reading sampling time t (where t=ts)dl), the results being stored in a 4th memory means; a step 8 which performs a calculation, based on the values of amount of temperature data change ATDt stored in said 4th memory means, to determine the ratio between the temperature amount of change ATDtl measured from over a first overall amount of change n WO 95/09471 PCT/JP94/00651 - 66 - reading sampling time tl established as running from said 1st sampling time (tsl) to the sampling time (tsM) for the predetermined M-th sampling, and the temperature amount of change ATDt2 measured from over a second 5 overall amount of change reading sampling time t2 established as running from said 2nd sampling time (ts2) to the sampling time (tsM+1) for the predetermined M+l-th sampling, said calculated ratio AHt (where AHt=ATDt2/ATDtl) being stored in a 5th memory means; 10 a step 9 which repeats the operations of said step 8 while calculating the ratio value AHtn (where AHtn=ATDt(N+l)/ATDtn) between the amount of temperature changes ATDtn and ATDt(n+l) at each pair of adjacent overall amount of change sampling times tn and tn+1, and 15 stores the calculated results in 5th memory means; a step 10 which judges from the information stored in said 5th memory means whether the ratio AHm between two adjacent said temperature amounts of change is equal to or greater than or is less than a 20 given value K; and a step 11 which, if the temperature amount of change ratio AHm value is equal to or greater than the given value K, stops said charging.

3. A method of charging a secondary battery, 25 comprising: a step 1 which sets the basic data reading time tb required to read data; a step 2 which sets the charging rate C; a step 3 which sets the corrected data 30 reading time tc, according to the set charging rate C and said basic data reading time tb, said corrected data reading time tc being characteristic to said charging rate C; a step 4 which, during the charging 35 operation, uses an appropriate sampling means to measure the temperature and the terminal voltage of said secondary battery, respectively, at least one time during WO 95/09471 FCT/JP94/00651 - 67 - each said corrected data reading time tc, and which stores the temperature data and the terminal voltage data at that time into an appropriate 1st memory means, respectively; 5 a step 5 which repeats the operation of said step 4 a predetermined number of times L, takes the individual summation of the plurality of battery temperature data and voltage data obtained at each corrected data reading time tc, and stores the resulting 10 respective amounts of changes Dtn and Dvn over the temperature data and terminal voltage data reading sampling time ts (where ts=Lxtc) into an appropriate 2nd memory means; a step 6 which calculates the difference 15 between the amounts of change Dvl and Dtl for the 1st sampling time (tsl) and the respective amounts of change Dv2 and Dt2 for the next, 2nd, sampling time (ts2) obtained in step 5, and which stores the resulting difference amounts AD for temperature data and terminal 20 voltage data (ADv and ADt) in a 3rd memory means; a step 7 which continuously repeats step 6 a predetermined number of times M, and which takes the summation of each of the values of ADvl to ADvM (M values) and ADtl to ADtM (M values) obtained at each 25 amount of change reading sampling time (ts), and determines the amount of temperature data change and the amount of terminal voltage data change, ATDt and ATDv, for the overall said amount of change reading sampling time t (where t-tsxM), the results being stored in a 4th 30 memory means; ' a step 8 which performs a calculation, based on the values of amount of voltage data change ATDv stored in said 4th memory means, to determine the difference between the amount of voltage change ATDtl 35 measured from over a first overall amount of voltage change reading sampling time tl established as running from said 1st sampling time (tsl) to the sampling time WO 95/09471 PCT/JP94/00651 o - 68 - (tsM) for the predetermined M-th sampling, and the amount of voltage change ATDt2 measured from over a second overall amount of voltage change reading sampling time t2 established as running from said 2nd sampling time (ts2) 5 to the sampling time (tsM+1) for the predetermined M+l-th sampling, said calculated difference AHt (where AHv=ATDv2-ATDvl) being stored in a 6th memory means; a step 9 which repeats step 8 while calculating the difference value AHvn (where 10 AHvn=ATDv(N+l)-ATDvn) between the amount of voltage changes ATDvn and ATDv(n+l) at each pair of adjacent overall amount of change sampling times tn and tn+1, and stores the calculated results in 6th memory means. a step 10 which judges whether the m 15 amounts of voltage changes AHvl to AHvm are positive (zero or greater than zero) or negative (less than zero); a step 11 which performs a calculation, based on the values of amount of temperature data change ATDt stored in said 4th memory means, to determine the 20 ratio AHt between the amount of temperature change ATDtl measured from over a first overall amount of temperature change reading sampling time tl established as running from said 1st sampling time (tsl) to the sampling time . (tsM) for the predetermined M-th sampling, and the amount 25 of temperature change ATDt.2 measured from over a second overall amount of temperature change reading sampling time t2 established as running from said 2nd sampling time (ts2) to the sampling time (tsM+1) for the predetermined M+l-th sampling, said calculated difference 30 AHt (where AHt=ATDt2/ATDtl) being stored in a 5th memory means; a step 12 which repeats the operations of step 11 while calculating the change ratio value AHtn (where AHtn=ATDt(N+l)/ATDtn) between the amount of 35 temperature changes ATDtn and ATDt(n+l) at each pair of adjacent overall amount of temperature change sampling times tn and tn+1 respectively, and stores the calculated WO 95/09471 PCT/JP94/00651 - 69 - ) results in 5th memory means. a step 13 which judges from the information stored in said 5th memory means whether the ratio AHtm between two adjacent said amounts of 5 temperature change is equal to or greater than or is less than a given value K; and a step 14 which judges, for said temperature change ratios AHtm equal to or greater than the predetermined value of K and in the sequence of 10 occurrence of said differences in amount of voltage changes AHvl to AHvm, whether or not said difference in amount of voltage change AHv is zero or negative for S times continuously, and if said difference in amount of voltage change is zero or negative S times continuously, 15 stops said charging.

4. A method of charging a secondary battery according to claim 1, 2, or 3, wherein when said sampling means is used during charging to measure the terminal voltage or to measure the temperature of said secondary 20 battery at each corrected data reading time tc, the supply of charging current to said secondary battery is cutoff when making the measurement.

5. A method of charging a secondary battery according to claim 1, 2, 3, or 4, wherein when said 25 sampling means is used during charging to measure the terminal voltage or to measure the temperature of said secondary battery at each corrected data reading time tc, if measurement of even one of these values indicates a level exceeding a predetermined abnormal value level, 30 said charging operation is interrupted.

6. A method of charging a secondary battery according to claim 1,2,3, 4, or 5, wherein said corrected data reading time tc is calculated from said charging rate C and said basic data reading time tb by 35 the expression tc=tbxA/C, in which A is a constant.

7. . A method of charging a secondary battery according to claim 1, 2, 3,4, 5, or 6, wherein in a step WO 95/09471 PCT/JP94/00651 - 70 - ) which repeats measurement of voltage data M times continuously each said data change reading sampling time ts, at each time said voltage data is measured each said data change reading sampling time ts, the amount of 5 change ATDv in voltage data is calculated, a judgment is made as to whether said amount of voltage data change ATDv is positive, negative, or zero, and if it is positive, an appropriate counter value AS which judges a condition of a change in amount of the voltage data 10 change ATDv, is reset to zero, but if said amount of voltage data change ADTv is negative or zero, said counter value AS has added to it said ATDv value, said counter value AS being updated to the added value, after which said counter value AS is compared with a 15 preestablished reference value W, and if said counter value AS is smaller than said reference value W, said charging operation is stopped.

8. A method for charging a secondary battery according to claim 7, wherein when the value of said 20 voltage data amount of change ATDv is zero, a preestablished value Z is subtracted from said counter value AS.

9. An apparatus for charging a secondary battery comprising: 25 a current-supplying means for supplying electrical current to the cells of a secondary battery requiring charging; a switch means provided between said current-supplying means and said secondary battery being 30 charged; a temperature measurement means for measuring the temperature of said cells; . a sampling means for operating said temperature-measurement means to measure the temperature 35 of said cells with the desired sampling interval; a charging-control means which is connected to said sampling means and controls said switch WO 95/09471 - 11 - PCT/JP94/00651 means; a charging rate setting means which sets the charging rate C; a corrected data reading time setting means which, based on the charging rate C set at said charging rate setting means, calculates from a preestablished basic data reading time tb the corrected data reading time tc, the value of which is characteristic to said charging rate C; an amount of data change reading sampling time setting means which multiplies the corrected data reading time tc by a preestablished value L to set the temperature data amount of change reading sampling time ts; em overall sampling time setting means which multiplies said data amount of change reading sampling time ts by a preestablished value M to set the overall sampling time t; a 1st memory means which stores the values of temperature data dtn measured at each said corrected data reading time tc; a 2nd memory means which stores the data Dtn which is the summation of a predetermined member L values of temperature data dtn stored in said 1st memory meeuis; a 3rd memory means which, from the data Dtn stored in said 2nd memory means, stores the difference between data Dt(n-l) measured at the previous amount of change reading sampling time ts and data Dtn measured at the current amount of change reading sampling time ts+1, this difference value being ADt (where ADt=Dtn-Dt(n-1)); a 4th memory means which stores the amount of temperature data cheuige ATDt obtained by taking the summation of each of the M amounts of temperature data obtained at each amount of change reading sampling time (ts) in the overall amount of change reading sampling o WO 95/09471 PCT/JP94/00651 - 72 - time t (where t=tsxM) obtained by repeating said amount of change reading sampling time (ts) M the required number of M times; a 5th memory means which, with regard to 5 the temperature data amount of change ATDt stored in said 4th memory means, stores the change ratio AHt calculated between the amount of temperature data change ATDtn at the 1st overall amount of change reading sampling time tn and the amount of temperature data change ATDt(n+l) at 10 the 2nd overall amount of change reading sampling time tn+1, which is formed by shifting the time by one amount of change reading sampling time (ts), said change ratio being AHt (where AHt=ATDt(n+1)/ATDtn); a 1st judgment means which compares said 15 temperature change ratio AHtm between said amounts of temperature change with a preestablished reference value K, and if said change ratio AHtm between said amounts of temperature change exceeds said reference value K, outputs a signal which stops said charging; 20 a processing means which processes each of the individual data stored by each of said means; and a central processing means which controls the operation of each said means.

10. An apparatus for charging a secondary battery 25 comprising: a current-supplying means for supplying electrical current to the cells of a secondary battery requiring charging; a switch means provided between said 30 current-supplying means and said secondary battery being charged; a terminal voltage measurement means for measuring the terminal voltage of said cells; a sampling means for operating said 35 terminal voltage measurement means to measure the terminal voltage of said cells with the desired sampling interval; o WO 95/09471 PCT/JP94/00651 - 73 - a charging-control means which is connected to said sampling means and controls said switch means; a charging rate setting means which sets 5 the charging rate C; a corrected data reading time setting means which, based on the charging rate C set at said charging rate setting means, calculates from a preestablished basic data reading time tb the corrected 10 data reading time tc, the value of which is characteristic to said charging rate C; an amount of data change reading sampling time setting means which multiplies the corrected data reading time tc by a preestablished value L to set the 15 temperature data amount of change reading sampling time ts; a overall sampling time setting means which multiplies said data amount of change reading sampling time ts by a preestablished value M to set the 20 overall sampling time t; a 1st memory means which stores the values of terminal voltage data dvn measured each said corrected data reading time tc; a 2nd memory means which stores the data 25 Dvn which is the summation of the L values of temperature data dvn stored in said 1st memory means; a 3rd memory means which, from the data Dvn stored in said 2nd memory means, stores the difference between data Dv(n-l) measured at the previous 30 amount of change reading sampling time ts and data Dvn measured at the current amount of change reading sampling time ts+1, this difference value being ADv (where ADv=Dvn-Dv(n-1)); a 4th memory means which stores the amount 35 of terminal voltage data change ATDv obtained by taking the summation each of the M amounts of voltage change data obtained at each amount of change reading sampling WO 95/09471 PCT/JP94/00651 - 74 - ) time in the overall amount of change reading sampling time t (where t=tsxM) obtained by repeating said amount of change reading sampling time (ts) M the required number of M times; 5 a 6th memory means which, with regard to the terminal voltage data amount of change ATDv stored in said 4th memory means, stores the difference AHvm calculated between the amount of voltage data change ATDvn measured in the 1st overall amount of data change. 10 reading sampling time tn and the amount of voltage data change ATDv(n+l) measured in the 2nd overall amount of data change reading sampling time tn+1, which is formed by shifting the time by one amount of change reading sampling time (ts), said difference being AHvm (where 15 AHvm=AHvm=Hv (m+1) -Hvm); a judgment means which, with regard to each the m values of voltage data amounts of change differences AHvl to AHvm serially stored in said 6th memory means, makes a judgment as to whether each one of 20 said differences AHvl to AHvm is positive (zero or larger) or negative (less than zero), and which performs said judgment processing in the sequence of occurrence of said voltage data amount of change differences AHvl to AHvm, and if each one of the successively measured 25 voltage data amount of change difference AHv show a negative value, at least a preestablished number of times S, continuously, stops said charging operation; a processing means which processes each of the individual data stored by each of said means; and 30 a central processing means which controls the operation of each said means.