NZ209310A

NZ209310A - Rendering fly ash deposits more friable

Info

Publication number: NZ209310A
Application number: NZ209310A
Authority: NZ
Inventors: G G Engstrom; D I Bain
Original assignee: Dearborn Chemicals Co
Priority date: 1981-11-03
Filing date: 1984-02-28
Publication date: 1986-09-10

Description

<div class="application article clearfix" id="description"> New Zealand Paient Spedficaiion for Paient Number £09310 209310 Priority Oate(s): Complete Specification Filed: Class: . E.HSljloQ Publication Date: .... f! ^ J?.?? P.O. Journal, No: ... fXn<?«r the provisions of Regulation 23 (I) the Specification has been ante-<tate# tO 19 J? ^ ^ Jai J tfals POST+DATED UNDER SECT. 12(1) to 2$ .ffkwry.Jffl/t.v! NEW ZEALAND PATENTS ACT, 1953 No.: Divided from NZ Patent Application No. 198,850, filed 3 November 1981 Date: Patent of Additlion to NZ Patent Application Ifo. 198,850, " filed 3 November 1981 COMPLETE SPECIFICATION "VER1VHCULITE AS. A DEPOSIT MODIFIER IN FURNACES" jff VVe, DEARBORN CHEMICAL CCMPANY, a corporation of Delaware, United States of America, of 300 Genesee Street, Lake Zurich, Illinois 60047/ United States of America hereby declare the invention for which I / we pray that a patent be granted to pae/us, and the method by which it is to be performed, to be particularly described in and by the following statement:- _,-;A ... 209310 In our NZ patent specification No. 198,85 0 there is disclosed and claimed a method of rendering fly ash deposits in a .solid carbonaceous fuel tfired furnace more friable, thereby facilitating their removal by steam or air probe, comprising injecting vermiculite into the flue gas stream of the furnace at 3000-1200 ° F and in an amount effective to render the deposits more friable. j \ Such. a method relates, to coal-fired furnaces. The present invention relates to a discovery that the method is applicable to the rendering of fly ash deposits more friable even where other solid carbonaceous fuels are .used to fire the furnace. Use of the present invention facilitates removal of deposits that form on the walls and heat-exchange surfaces in an industrial furnace or utility boiler burning a solid carbonaceous fuel. This is accomplished by injecting uncalcined vermiculite into the flue gas stream where the stream has a temperature of about 3000° F. to 1200° F. at a rate of ' 0.05 to io.o pounds of vermiculite (most preferably 1-3 lbs.) per short ton of fuel burned. The vermiculite increases the friability of the deposits, making them easier to remove by conventional soot blowers (i.e., probes located within the boiler blowing in air or steam at about 200 psig.) The mineral matter (ash) in coal leads to deposits in the heat absorbing regions of the boiler, particularly the super heater and convection passes. These sintered fly ash deposits can be stronger than the potential of conventional cleaning equipment. We have discovered that the injection of vermiculite will reduce the strength of deposits in order to maintain clean heat exchange surfaces and prevent the eventual blockage of these passages. Vermiculite, a natural occurring mineral, expands 15-20 times its original volume when exposed to temperatures in excess of approximately 1200° F. This greatly reduces the strength of sintered (bonded) deposits in which vermiculite is present. In the past Ithe chemical and physical properties of materials such as magnesium oxide, alumina, etc., have been employed to interfere with sintered deposits. Vermiculite is superior to these additives. 2 2093 1 0 m Vermiculite, a hydrated magnesium-aluminum-iron silicate, consists of 14 closely related micaceous minerals. When unexfoliated vermiculite is applied in such a manner as to be incorporated in the ash deposit and subjected to temperatures in the range encountered in superheater and convection regions, a dramatic reduction in the strength of the bonded deposit is evident. The unique properties which account for this activity includes thermally induced exfoliation (expansion) and the presence of a naturally occurring platelet structure (silica sheets) which acts as a cleave plane. Deposits can be removed with greater ease as a result of this treatment. Example 1 The boiler had■a 34 7 megawatt design capacity. It was cyclone fired and burned Eastern bituminous c coal. It was equipped with soot blowers. Unexpanded vermiculite was blown into the furnace at 2600° F at the rate of 0.6-0.8 lbs./ton of fuel. The additive caused the in-line deposits to be relatively friable and readily removed by the soot blowers at 200 psig. In contrast, in a comparable run by omitting the vermiculite, the deposits were hard, sintered, and bonded, making them difficult to loosen and dislodge with the steam probes. We prefer that the vermiculite be relatively finely divided, e.g., mostly 3 to 325 mesh (Tyler screen), and even more preferably, mostly 28 to 200 mesh. The product in the above example and in the Tables was mostly about 80-150 mesh. u -3- 2093 Solids Addition Apparatus In the above example a water-cooled probe was used to inject the vermiculite into the furnace. The probe was about 5 feet long and consisted of 3 concentric tubes made of 3/16" stainless steel. The outer tube was 2.5 inches outer diameter, the middle tube 2 inches, the center tube 1 inch. Water flows down the annulus formed by the outer and middle tubes and returns via the annulus formed by the middle and center tubes. There is about 0.277 inches clearance between the terminus of the outer tube and the terminus of the middle tube to permit water return. Water is introduced in the front end of the outer tube, outside the boiler. The incoming flow is lateral, so that the water spins tangentially on its way down the tube. The vermiculite is taken off a hopper with a screw feeder which meters the vermiculite into an air conveying system, which delivers the vermiculite to the center tube of the probe. The air flow helps cool the center tube and may also contribute to cooling the water jacketed areas of the pr obe. The Sintering Test developed by Babcock and Wilcox has been employed to determine the fouling tendency (formation of bonded deposits) of various ashes and the effect of additives. See "The Sintering Test, An Index to Ash-Fouling Tendency" by D. H. Barnhart and P. C. Williams, Transactions of the ASME, August, 1956, p. 1229. Briefly, the test consists of forming the ash into pellets, heating to various elevated temperatures for 15 hours, and measuring the force required to crush the resulting sintered samples. Table 1 summarizes the - 4 results obtained without additive, with various levels of vermiculite, and with magnesium oxide. Magnesium oxide was found to have the greatest effect in work done by Babcock and Wilcox and is included for comparison. Table 2 lists the corresponding percent reduction in sinter strength for the samples tested. The results show the dramatic effect that vermiculite has in deposit modifications. (" ) •'r" 2 093 f 0 TABLE 1 Sinter Strength of Pellets, psi 1800*F 2000 *F B1 ank 10,800 15.200 13,400 25,600 (no creatment) 13,000 14.500 7,756 22,400, 11,200 15.300 24,900 19,300 Average Blank 13 .333 18 .893 Vermiculite, 0.52 6,570 9.810 12.800 14,100 9.980 10.300 12.200 14,300 7.650 8,660 AveraRe 0.52 8.862 12 .412 Vermiculite, 1.02 6,490 7.190 6,140 6,130 5-. 190 5. 300 6.090 6,810 6,560 10.000 5.850 6.930 Average 1.02 6. 788 6 325 Vermiculite, 1.52 A, 960 4.530 4,880 4.48C A.990 3.950 4,950 3.89C 5,540 3.770 4,190 4,27C Average 1.52 4. 620 4 443 Magnesium Oxide, 1.52 8,300 8,100 12,900 13,500 6,720 6,470 10,300 10.50C 8.500 5.170 14,500 Average 1.52 MgO 7. 210 12, 340 ■o - 6 </div>

Claims

<div class="application article clearfix printTableText" id="claims"> 2093 10 TABLE 2 Average Reduction in Sinter Strength, 2 lSOO'F 2000°F Blank Vermiculite, 0.5Z 33.5 34.3 Vermiculite, 1.02 49.1 66.5 Vermiculite, 1.52 65.4 76.5 Magnesium Oxide, 1.5% 45.9 34.7 - 7 - WHAT WE CLAIM IS: - 8 - 509310 o 1. A method of rendering fly ash deposits in a solid carbonaceous fuel-fired furnace more friable, thereby facilitating their removal by steam or air probe, comprising injecting vermiculite into the flue gas stream of the furnace at 3000-1200°F at the rate of 0.05 to lOlbs/short ton of fuel to thereby render the deposits more friable, but with the proviso that the fuel is not coal. I 2. A method according to Claim lj in which the vermiculite is injected at the rate of 1 - 3 Ibs./short ton of fuel. i 3. A method according to any one of the preceding claims in which the vermiculite is 80 to 150 mesh (Tyler screen). 4. A method according to any one of the preceding claims in which the temperature of injection is about 2600°F. 5. A method according to Claims 1, 2 or 3 in which the furnace is a boiler having a super heater and convection passes and the vermiculite is injected into the boiler so that vermiculite is incorporated in the deposits on the super heater and convection passes. I gj A method according to Claim 1 in which the fuel is selected from the group consisting of peat, sunflower seed hulls, wood, wood waste, paper, paper by-products, garbage, refuse derived fuels, sewage sludge, bagasse, and plant by-products. o < - 9 - 209310 '7.1 A method according to Claim 6 hul Is. in which the fuel is sunflower seed 8.| A method according to any one of the preceding claims in which the vermiculite is unexpanded. J 9. \A method according to any one of Claims 1 to b|in which the vermiculite is expanded. 10.! A method as claimed in any one of the preceding claims substantially as hereinbefore described. DATED DAY OF A. J. PARK & SON agents^FOR THE APPLICANTS </div>