NO996282L - Homogeneous oxidation catalysis using metal complexes - Google Patents
Homogeneous oxidation catalysis using metal complexesInfo
- Publication number
- NO996282L NO996282L NO996282A NO996282A NO996282L NO 996282 L NO996282 L NO 996282L NO 996282 A NO996282 A NO 996282A NO 996282 A NO996282 A NO 996282A NO 996282 L NO996282 L NO 996282L
- Authority
- NO
- Norway
- Prior art keywords
- point
- target compound
- lewis acid
- catalyst
- metal complexes
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/39—Actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Foreliggende oppfinnelse tilveiebringer en fremgangsmåte for å overføre oksygen til minst ett oksiderbart punkt på en målforbindelse. Fremgangsmåten inkluderer trinnene å selektivt oksidere et oksiderbart punkt på en målfor- bindelse ved reaksjon i løsning: målforbindelsen, en Kilde av oksygenatomer, en kilde av Lewis-syre, så som proton, alkali-, jordalkali-, sjeldne jordalkali-, overgangsmetall, eller hovedgruppemetallioner, og en katalysator. Kataly- satoren har den generelle strukturen (I) hvor Z fortrinns- vis er N, men kan inkludere O, og MO er en metall-okso type. Lewis-syren binder seg til et totakket punkt på Chj- substituenten for å gi et Lewis-syre katalysatorkompleks.The present invention provides a method for transferring oxygen to at least one oxidizable point on a target compound. The process includes the steps of selectively oxidizing an oxidizable point of a target compound by reaction in solution: the target compound, a source of oxygen atoms, a source of Lewis acid, such as proton, alkali, alkaline earth, rare earth alkaline, transition metal, or main group metal ions, and a catalyst. The catalyst has the general structure (I) where Z is preferably N but may include O and MO is a metal oxo type. The Lewis acid binds to a two-point point on the Chj substituent to give a Lewis acid catalyst complex.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US87975297A | 1997-06-20 | 1997-06-20 | |
PCT/US1998/012749 WO1998058735A1 (en) | 1997-06-20 | 1998-06-18 | Homogeneous oxidation catalysis using metal complexes |
Publications (2)
Publication Number | Publication Date |
---|---|
NO996282D0 NO996282D0 (en) | 1999-12-17 |
NO996282L true NO996282L (en) | 2000-02-21 |
Family
ID=25374825
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO996282A NO996282L (en) | 1997-06-20 | 1999-12-17 | Homogeneous oxidation catalysis using metal complexes |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP0991468A1 (en) |
JP (1) | JP2002505688A (en) |
KR (1) | KR20010013986A (en) |
CN (1) | CN1267238A (en) |
AP (1) | AP9901723A0 (en) |
AU (1) | AU8152998A (en) |
BR (1) | BR9810754A (en) |
CA (1) | CA2295006A1 (en) |
IL (1) | IL133484A0 (en) |
NO (1) | NO996282L (en) |
OA (1) | OA11237A (en) |
PL (1) | PL337523A1 (en) |
WO (1) | WO1998058735A1 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6797196B2 (en) | 2001-01-10 | 2004-09-28 | Kao Corporation | Bleaching formulation |
JP4104966B2 (en) * | 2002-03-06 | 2008-06-18 | 花王株式会社 | Bleaching catalyst |
KR100561058B1 (en) * | 2004-09-23 | 2006-03-17 | 삼성토탈 주식회사 | Catalyst for olefin polymerization including phenoxy ligand and method of (co)polymerization of olefin using the same |
JP5002761B2 (en) * | 2007-03-09 | 2012-08-15 | 国立大学法人大阪大学 | Oxoporphyrin-based electrode catalyst material |
CN104785296B (en) * | 2015-04-17 | 2017-03-08 | 中国石油大学(华东) | A kind of liquid cobalt sulfonated phthalocyanine catalyst for petroleum gas sweetening |
CN106082419B (en) * | 2016-05-10 | 2019-05-31 | 北京服装学院 | Method and application of the degradation of macrocyclic amide metal complex containing organic pollutant wastewater |
CN106111199B (en) * | 2016-06-21 | 2018-10-12 | 中南民族大学 | The nanocrystalline preparation and application of more sulfur-bearing aza porphyrin arrays |
CN112675908A (en) * | 2020-12-23 | 2021-04-20 | 清华大学 | Aerobic oxidation method of alcohols |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4758682A (en) * | 1983-03-17 | 1988-07-19 | California Institute Of Technology | Homogeneous coordination compounds as oxidation catalysts |
US5665890A (en) * | 1995-03-14 | 1997-09-09 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
US5847120A (en) * | 1996-07-22 | 1998-12-08 | Carnegie Mellon University | Long-lived homogenous oxidation catalysts |
-
1998
- 1998-06-18 JP JP50482899A patent/JP2002505688A/en active Pending
- 1998-06-18 WO PCT/US1998/012749 patent/WO1998058735A1/en not_active Application Discontinuation
- 1998-06-18 CN CN98808220A patent/CN1267238A/en active Pending
- 1998-06-18 BR BR9810754-2A patent/BR9810754A/en not_active Application Discontinuation
- 1998-06-18 EP EP98931384A patent/EP0991468A1/en not_active Withdrawn
- 1998-06-18 AU AU81529/98A patent/AU8152998A/en not_active Abandoned
- 1998-06-18 KR KR19997012013A patent/KR20010013986A/en not_active Application Discontinuation
- 1998-06-18 PL PL98337523A patent/PL337523A1/en unknown
- 1998-06-18 IL IL13348498A patent/IL133484A0/en unknown
- 1998-06-18 AP APAP/P/1999/001723A patent/AP9901723A0/en unknown
- 1998-06-18 CA CA002295006A patent/CA2295006A1/en not_active Abandoned
-
1999
- 1999-12-15 OA OA9900283A patent/OA11237A/en unknown
- 1999-12-17 NO NO996282A patent/NO996282L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
PL337523A1 (en) | 2000-08-28 |
IL133484A0 (en) | 2001-04-30 |
OA11237A (en) | 2003-05-27 |
NO996282D0 (en) | 1999-12-17 |
JP2002505688A (en) | 2002-02-19 |
CN1267238A (en) | 2000-09-20 |
AU8152998A (en) | 1999-01-04 |
AP9901723A0 (en) | 1999-12-31 |
BR9810754A (en) | 2000-08-15 |
EP0991468A1 (en) | 2000-04-12 |
CA2295006A1 (en) | 1998-12-30 |
KR20010013986A (en) | 2001-02-26 |
WO1998058735A1 (en) | 1998-12-30 |
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