NO996282L - Homogeneous oxidation catalysis using metal complexes - Google Patents

Homogeneous oxidation catalysis using metal complexes

Info

Publication number
NO996282L
NO996282L NO996282A NO996282A NO996282L NO 996282 L NO996282 L NO 996282L NO 996282 A NO996282 A NO 996282A NO 996282 A NO996282 A NO 996282A NO 996282 L NO996282 L NO 996282L
Authority
NO
Norway
Prior art keywords
point
target compound
lewis acid
catalyst
metal complexes
Prior art date
Application number
NO996282A
Other languages
Norwegian (no)
Other versions
NO996282D0 (en
Inventor
Terrence J Collins
Scott W Gordon-Wylie
Christine G Woomer
Colin P Horwitz
Erich S Uffelman
Original Assignee
Univ Carnegie Mellon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Carnegie Mellon filed Critical Univ Carnegie Mellon
Publication of NO996282D0 publication Critical patent/NO996282D0/en
Publication of NO996282L publication Critical patent/NO996282L/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/39—Actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Foreliggende oppfinnelse tilveiebringer en fremgangsmåte for å overføre oksygen til minst ett oksiderbart punkt på en målforbindelse. Fremgangsmåten inkluderer trinnene å selektivt oksidere et oksiderbart punkt på en målfor- bindelse ved reaksjon i løsning: målforbindelsen, en Kilde av oksygenatomer, en kilde av Lewis-syre, så som proton, alkali-, jordalkali-, sjeldne jordalkali-, overgangsmetall, eller hovedgruppemetallioner, og en katalysator. Kataly- satoren har den generelle strukturen (I) hvor Z fortrinns- vis er N, men kan inkludere O, og MO er en metall-okso type. Lewis-syren binder seg til et totakket punkt på Chj- substituenten for å gi et Lewis-syre katalysatorkompleks.The present invention provides a method for transferring oxygen to at least one oxidizable point on a target compound. The process includes the steps of selectively oxidizing an oxidizable point of a target compound by reaction in solution: the target compound, a source of oxygen atoms, a source of Lewis acid, such as proton, alkali, alkaline earth, rare earth alkaline, transition metal, or main group metal ions, and a catalyst. The catalyst has the general structure (I) where Z is preferably N but may include O and MO is a metal oxo type. The Lewis acid binds to a two-point point on the Chj substituent to give a Lewis acid catalyst complex.

NO996282A 1997-06-20 1999-12-17 Homogeneous oxidation catalysis using metal complexes NO996282L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87975297A 1997-06-20 1997-06-20
PCT/US1998/012749 WO1998058735A1 (en) 1997-06-20 1998-06-18 Homogeneous oxidation catalysis using metal complexes

Publications (2)

Publication Number Publication Date
NO996282D0 NO996282D0 (en) 1999-12-17
NO996282L true NO996282L (en) 2000-02-21

Family

ID=25374825

Family Applications (1)

Application Number Title Priority Date Filing Date
NO996282A NO996282L (en) 1997-06-20 1999-12-17 Homogeneous oxidation catalysis using metal complexes

Country Status (13)

Country Link
EP (1) EP0991468A1 (en)
JP (1) JP2002505688A (en)
KR (1) KR20010013986A (en)
CN (1) CN1267238A (en)
AP (1) AP9901723A0 (en)
AU (1) AU8152998A (en)
BR (1) BR9810754A (en)
CA (1) CA2295006A1 (en)
IL (1) IL133484A0 (en)
NO (1) NO996282L (en)
OA (1) OA11237A (en)
PL (1) PL337523A1 (en)
WO (1) WO1998058735A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6797196B2 (en) 2001-01-10 2004-09-28 Kao Corporation Bleaching formulation
JP4104966B2 (en) * 2002-03-06 2008-06-18 花王株式会社 Bleaching catalyst
KR100561058B1 (en) * 2004-09-23 2006-03-17 삼성토탈 주식회사 Catalyst for olefin polymerization including phenoxy ligand and method of (co)polymerization of olefin using the same
JP5002761B2 (en) * 2007-03-09 2012-08-15 国立大学法人大阪大学 Oxoporphyrin-based electrode catalyst material
CN104785296B (en) * 2015-04-17 2017-03-08 中国石油大学(华东) A kind of liquid cobalt sulfonated phthalocyanine catalyst for petroleum gas sweetening
CN106082419B (en) * 2016-05-10 2019-05-31 北京服装学院 Method and application of the degradation of macrocyclic amide metal complex containing organic pollutant wastewater
CN106111199B (en) * 2016-06-21 2018-10-12 中南民族大学 The nanocrystalline preparation and application of more sulfur-bearing aza porphyrin arrays
CN112675908A (en) * 2020-12-23 2021-04-20 清华大学 Aerobic oxidation method of alcohols

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4758682A (en) * 1983-03-17 1988-07-19 California Institute Of Technology Homogeneous coordination compounds as oxidation catalysts
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts

Also Published As

Publication number Publication date
EP0991468A1 (en) 2000-04-12
CN1267238A (en) 2000-09-20
BR9810754A (en) 2000-08-15
NO996282D0 (en) 1999-12-17
AU8152998A (en) 1999-01-04
CA2295006A1 (en) 1998-12-30
IL133484A0 (en) 2001-04-30
AP9901723A0 (en) 1999-12-31
KR20010013986A (en) 2001-02-26
JP2002505688A (en) 2002-02-19
WO1998058735A1 (en) 1998-12-30
OA11237A (en) 2003-05-27
PL337523A1 (en) 2000-08-28

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