NO941739L - Copolymers of ethylene and their preparation - Google Patents
Copolymers of ethylene and their preparationInfo
- Publication number
- NO941739L NO941739L NO941739A NO941739A NO941739L NO 941739 L NO941739 L NO 941739L NO 941739 A NO941739 A NO 941739A NO 941739 A NO941739 A NO 941739A NO 941739 L NO941739 L NO 941739L
- Authority
- NO
- Norway
- Prior art keywords
- olefin
- copolymer
- ethylene
- mol
- derived units
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title abstract 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 4
- 239000005977 Ethylene Substances 0.000 title abstract 4
- 239000004711 α-olefin Substances 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000004291 polyenes Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Medicinal Preparation (AREA)
Abstract
Amorf kopolymer av etylen og minst ett a-olefin, innholdende mellom 35 og 85 mol% etylenavledede enheter, og mellom 10 og 60 mol% a-olefin-avledede enheter. Kopolymeren har følgende kjennetegnende egenskaper: (A) innholdet i mol% av a-olefin i ko- polymeren (%a) og forholdet mellom den molare mengde a-olefin-diader og det molare innhold av a-olefin i kopolymeren (aa/a) tilfredsstiller følgende ligning: (%a) - 250 (aa/a) > 10 (B) mindre enn 2% av CH2-gruppene i polymerkjeden er i sekvenser (CH2)n, hvor n er et helt tall. Det beskrives også en fremgangsmåte for fremstilling av kopolymeren, omfattende polymerisering av etylen og ett eller flere a-olefiner, eventuelt også ett eller flere polyener, i nærvær av en spesiell katalysator omfattende omset- ningsproduktet av en metallocenforbin- delse og et alumoksan. Katalysatoren har to fluorenyl-grupper forbundet gjennom en brodannende gruppe.Amorphous copolymer of ethylene and at least one α-olefin, containing between 35 and 85 mol% ethylene-derived units, and between 10 and 60 mol% α-olefin-derived units. The copolymer has the following characteristic properties: (A) the content in mole% of α-olefin in the copolymer (% a) and the ratio of the molar amount of α-olefin dyads to the molar content of α-olefin in the copolymer (aa / a ) satisfies the following equation: (% a) - 250 (aa / a)> 10 (B) less than 2% of the CH 2 groups in the polymer chain are in sequences (CH 2) n, where n is an integer. Also disclosed is a process for preparing the copolymer comprising polymerization of ethylene and one or more α-olefins, optionally also one or more polyenes, in the presence of a special catalyst comprising the reaction product of a metallocene compound and an alumoxane. The catalyst has two fluorenyl groups connected through a bridging group.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT93MI000943A IT1264406B1 (en) | 1993-05-11 | 1993-05-11 | AMORPHOUS COPOLYMERS OF ETHYLENE WITH ALPHA-OLEFINS AND PROCEDURE FOR THEIR PREPARATION |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO941739D0 NO941739D0 (en) | 1994-05-10 |
| NO941739L true NO941739L (en) | 1994-11-14 |
Family
ID=11366098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO941739A NO941739L (en) | 1993-05-11 | 1994-05-10 | Copolymers of ethylene and their preparation |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US6160071A (en) |
| EP (1) | EP0624604B1 (en) |
| JP (1) | JP3672338B2 (en) |
| CN (1) | CN1048734C (en) |
| AT (1) | ATE181932T1 (en) |
| AU (1) | AU680654B2 (en) |
| BR (1) | BR9401056A (en) |
| CA (1) | CA2123335A1 (en) |
| DE (1) | DE69419363T2 (en) |
| ES (1) | ES2134288T3 (en) |
| FI (1) | FI942155A (en) |
| IL (1) | IL109433A (en) |
| IT (1) | IT1264406B1 (en) |
| MY (1) | MY131765A (en) |
| NO (1) | NO941739L (en) |
| RU (1) | RU2140932C1 (en) |
| TW (1) | TW397843B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1264483B1 (en) * | 1993-06-30 | 1996-09-23 | Spherilene Srl | ELASTOMERIC COPOLYMERS OF ETHYLENE WITH PROPYLENE |
| IT1264482B1 (en) * | 1993-06-30 | 1996-09-23 | Spherilene Srl | AMORPHOUS COPOLYMERS OF ETHYLENE WITH PROPYLENE AND PROCEDURE FOR THEIR PREPARATION |
| IT1273660B (en) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | PROCEDURE FOR THE PREPARATION OF AMORPHOUS PROPYLENE POLYMERS |
| IT1270125B (en) * | 1994-10-05 | 1997-04-28 | Spherilene Srl | PROCESS FOR THE (CO) POLYMERIZATION OF OLEFINE |
| US6977283B1 (en) | 1998-04-07 | 2005-12-20 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| ES2241278T3 (en) * | 1998-04-07 | 2005-10-16 | Exxonmobil Chemical Patents Inc. | POLYMERIZATION PROCEDURE |
| US6582762B2 (en) | 1999-12-22 | 2003-06-24 | Exxonmobil Chemical Patents Inc. | Sprayable hot melt adhesives |
| AU2003223188A1 (en) * | 2002-03-22 | 2003-10-13 | Exxonmobil Chemical Patents Inc. | Adhesives |
| AU2003286667A1 (en) * | 2002-10-28 | 2004-05-25 | Exxonmobil Chemical Patents, Inc. | Low density ethylene copolymer, a process for making same and blends comprising such copolymer |
| US7180311B2 (en) | 2004-05-31 | 2007-02-20 | Yamaha Hatsudoki Kabushiki Kaisha | Physical quantity sensing device with bridge circuit and zero point adjusting method |
| US7126355B2 (en) | 2004-05-31 | 2006-10-24 | Yamaha Hatsudoki Kabushiki Kaisha | Physical quantity sensing device with bridge circuit and temperature compensating method |
| US7482409B2 (en) * | 2007-01-31 | 2009-01-27 | Sumitomo Chemical Company, Limited | Process for producing ethylene-α-olefin-polyene copolymer |
| KR100994252B1 (en) * | 2007-05-09 | 2010-11-12 | 주식회사 엘지화학 | Ethylene alpha-olefin copolymer |
| US9056939B2 (en) * | 2011-01-27 | 2015-06-16 | Lg Chem, Ltd. | Olefin block copolymer |
| KR101391692B1 (en) | 2012-11-14 | 2014-05-07 | 주식회사 엘지화학 | Elastic terpolymer and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4540753A (en) * | 1983-06-15 | 1985-09-10 | Exxon Research & Engineering Co. | Narrow MWD alpha-olefin copolymers |
| US5001205A (en) * | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| KR920006464B1 (en) * | 1988-09-14 | 1992-08-07 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | Olefin polymerization catalyst component olefin polymerization catalyst and process for the polymerization of olefins |
| US5436305A (en) * | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
| CA2068939C (en) * | 1991-05-20 | 1996-04-09 | Takashi Ueda | Olefin polymerization catalyst and olefin polymerization |
| US5292845A (en) * | 1992-01-23 | 1994-03-08 | Mitsui Petrochemical Industries, Ltd. | Ethylene/alpha-olefin/7-methyl-1,6-octadiene copolymer rubber and composition of the same |
-
1993
- 1993-05-11 IT IT93MI000943A patent/IT1264406B1/en active IP Right Grant
-
1994
- 1994-04-26 TW TW083103726A patent/TW397843B/en not_active IP Right Cessation
- 1994-04-26 IL IL10943394A patent/IL109433A/en not_active IP Right Cessation
- 1994-05-03 AU AU61847/94A patent/AU680654B2/en not_active Ceased
- 1994-05-04 AT AT94106976T patent/ATE181932T1/en not_active IP Right Cessation
- 1994-05-04 DE DE69419363T patent/DE69419363T2/en not_active Expired - Fee Related
- 1994-05-04 ES ES94106976T patent/ES2134288T3/en not_active Expired - Lifetime
- 1994-05-04 EP EP94106976A patent/EP0624604B1/en not_active Expired - Lifetime
- 1994-05-05 RU RU94015593A patent/RU2140932C1/en active
- 1994-05-06 MY MYPI94001132A patent/MY131765A/en unknown
- 1994-05-09 JP JP09521594A patent/JP3672338B2/en not_active Expired - Fee Related
- 1994-05-10 NO NO941739A patent/NO941739L/en unknown
- 1994-05-10 BR BR9401056A patent/BR9401056A/en not_active Application Discontinuation
- 1994-05-10 FI FI942155A patent/FI942155A/en unknown
- 1994-05-11 CA CA002123335A patent/CA2123335A1/en not_active Abandoned
- 1994-05-11 CN CN94106003A patent/CN1048734C/en not_active Expired - Fee Related
-
1997
- 1997-06-16 US US08/876,864 patent/US6160071A/en not_active Expired - Fee Related
-
2000
- 2000-10-24 US US09/694,160 patent/US6403737B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| IL109433A (en) | 1998-12-27 |
| DE69419363D1 (en) | 1999-08-12 |
| US6403737B1 (en) | 2002-06-11 |
| NO941739D0 (en) | 1994-05-10 |
| JP3672338B2 (en) | 2005-07-20 |
| US6160071A (en) | 2000-12-12 |
| ITMI930943A1 (en) | 1994-11-11 |
| EP0624604B1 (en) | 1999-07-07 |
| ATE181932T1 (en) | 1999-07-15 |
| AU680654B2 (en) | 1997-08-07 |
| CA2123335A1 (en) | 1994-11-12 |
| MY131765A (en) | 2007-08-30 |
| IL109433A0 (en) | 1994-07-31 |
| RU94015593A (en) | 1996-05-27 |
| CN1048734C (en) | 2000-01-26 |
| JPH072943A (en) | 1995-01-06 |
| AU6184794A (en) | 1994-11-17 |
| TW397843B (en) | 2000-07-11 |
| FI942155A0 (en) | 1994-05-10 |
| EP0624604A1 (en) | 1994-11-17 |
| ITMI930943A0 (en) | 1993-05-11 |
| RU2140932C1 (en) | 1999-11-10 |
| FI942155A (en) | 1994-11-12 |
| IT1264406B1 (en) | 1996-09-23 |
| ES2134288T3 (en) | 1999-10-01 |
| BR9401056A (en) | 1994-12-27 |
| DE69419363T2 (en) | 1999-11-25 |
| CN1096305A (en) | 1994-12-14 |
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