NO871141L - Wood preservative. - Google Patents
Wood preservative.Info
- Publication number
- NO871141L NO871141L NO871141A NO871141A NO871141L NO 871141 L NO871141 L NO 871141L NO 871141 A NO871141 A NO 871141A NO 871141 A NO871141 A NO 871141A NO 871141 L NO871141 L NO 871141L
- Authority
- NO
- Norway
- Prior art keywords
- acid
- copper
- water
- wood
- application concentration
- Prior art date
Links
- 239000003171 wood protecting agent Substances 0.000 title claims abstract description 4
- 239000010949 copper Substances 0.000 claims abstract description 49
- 229910052802 copper Inorganic materials 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 150000002894 organic compounds Chemical class 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- 239000005749 Copper compound Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 150000001880 copper compounds Chemical class 0.000 claims description 5
- 230000000855 fungicidal effect Effects 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 230000003115 biocidal effect Effects 0.000 claims description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 2
- 239000004334 sorbic acid Substances 0.000 claims description 2
- 229940075582 sorbic acid Drugs 0.000 claims description 2
- 235000010199 sorbic acid Nutrition 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims 1
- 239000002917 insecticide Substances 0.000 claims 1
- 239000002023 wood Substances 0.000 abstract description 18
- 150000001879 copper Chemical class 0.000 abstract description 7
- 238000002386 leaching Methods 0.000 description 16
- 241000221198 Basidiomycota Species 0.000 description 15
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 14
- 241001600095 Coniophora puteana Species 0.000 description 12
- 241001504481 Monticola <Aves> Species 0.000 description 12
- 241001619461 Poria <basidiomycete fungus> Species 0.000 description 12
- 238000005470 impregnation Methods 0.000 description 9
- 239000003755 preservative agent Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 239000004327 boric acid Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Chemical class CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 2
- NBDAHKQJXVLAID-UHFFFAOYSA-N 5-nitroisophthalic acid Chemical class OC(=O)C1=CC(C(O)=O)=CC([N+]([O-])=O)=C1 NBDAHKQJXVLAID-UHFFFAOYSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 230000009918 complex formation Effects 0.000 description 2
- YEOCHZFPBYUXMC-UHFFFAOYSA-L copper benzoate Chemical compound [Cu+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 YEOCHZFPBYUXMC-UHFFFAOYSA-L 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- WKEDVNSFRWHDNR-UHFFFAOYSA-N salicylanilide Chemical class OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 description 2
- 229950000975 salicylanilide Drugs 0.000 description 2
- 229940075554 sorbate Drugs 0.000 description 2
- XXMBEHIWODXDTR-UHFFFAOYSA-N 1,2-diaminoethanol Chemical compound NCC(N)O XXMBEHIWODXDTR-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- ILRWUJFQWWUGBG-UHFFFAOYSA-N 2-(dodecylamino)butanoic acid Chemical compound CCCCCCCCCCCCNC(CC)C(O)=O ILRWUJFQWWUGBG-UHFFFAOYSA-N 0.000 description 1
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 1
- 239000005750 Copper hydroxide Substances 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 206010041662 Splinter Diseases 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- WBZLOKPDCSPGJZ-UHFFFAOYSA-L copper 2-methylbenzoate Chemical compound CC1=C(C(=O)[O-])C=CC=C1.[Cu+2].CC1=C(C(=O)[O-])C=CC=C1 WBZLOKPDCSPGJZ-UHFFFAOYSA-L 0.000 description 1
- 150000004699 copper complex Chemical class 0.000 description 1
- 229910001956 copper hydroxide Inorganic materials 0.000 description 1
- PWGQHOJABIQOOS-UHFFFAOYSA-N copper;dioxido(dioxo)chromium Chemical compound [Cu+2].[O-][Cr]([O-])(=O)=O PWGQHOJABIQOOS-UHFFFAOYSA-N 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K1/00—Damping wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/22—Compounds of zinc or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
Abstract
Trebeskyttelsesmiddel som inneholder kobber, et alkanolamin og en syre, hvis kobbersalt er vannuløselig, og fremgangsmåte for impregnering av tre.Wood preservative containing copper, an alkanolamine and an acid, the copper salt of which is water-insoluble, and the process for impregnating wood.
Description
Foreliggende oppfinnelse gjelder et trebeskyttelsesmiddel som inneholder en vandig løsning av et kobberkompleks med et alkanolamin og en monomer, organisk forbindelse (syre), hvis kobbersalt er vannuløselig. Trebeskyttelsesmidler på basis av uorganiske kobberforbindelser med alkanolamin som kompleks-danner er kjent (EP-89 958). De har den ulempe at etter fiksering av kobberet i treet på den ene siden, kan opptre en kobberutvasking med vann på ca. 10 %, og på den annen side at midlets virksomhet overfor treødeleggende basidiomyceter på tross av det høye kobberinnholdet i sammenligning med kobber-og kromatholdige salter (CK-, CKB-typer) er mindre. Kobber-fikseringen hos de kjente trebeskyttelsesmidlene med en pH-verdi i løsningene over 8 skjer i treet fra pH ca. 7,5-8,0. The present invention relates to a wood preservative which contains an aqueous solution of a copper complex with an alkanolamine and a monomeric, organic compound (acid), the copper salt of which is water insoluble. Wood preservatives based on inorganic copper compounds with alkanolamine as a complex-former are known (EP-89 958). They have the disadvantage that after fixing the copper in the wood on one side, a copper leaching with water of approx. 10%, and on the other hand, that despite the high copper content, the agent's activity against wood-destroying basidiomycetes is less in comparison with copper- and chromate-containing salts (CK, CKB types). The copper fixation in the known wood preservatives with a pH value in the solutions above 8 takes place in the wood from a pH of approx. 7.5-8.0.
Det danner seg herved basiske kobberforbindelser, for eksempel kobberhydroksyd. Disse kobberforbindelsene er stabile til en pH-verdi på ca. 5,0, men kan så igjen oppløses av fortynnede syrer, slike som foreligger i sur jord eller surt regn, slik at det under disse betingelsene foregår en forhøyet utvasking fra treet. This forms basic copper compounds, for example copper hydroxide. These copper compounds are stable at a pH value of approx. 5.0, but can then be dissolved again by diluted acids, such as are present in acid soil or acid rain, so that under these conditions there is an increased leaching from the wood.
Det ble nå funnet at de ovennevnte ulempene bortfaller når det anvendes vann-løselige trebeskyttelsesmidler på basis av en blanding av kobberforbindelser som er kompleksdannet med alkanolaminer og en monomer organisk forbindelse (syrer) eller deres salter som danner vannuløselige salter med kobber. Et alkanolamin er eksempelvis et mono-Ci- Ca-alkanolamin, for eksempel etanolamin. En forbindelse, spesielt en syre, som danner et vannuløselig kobbersalt, er eksempelvis sorbinsyre, benzosyre, substituert benzosyre, dehydracetsyre, 5-nitroisoftalsyre, oksalsyre, salicylanilid, amfotensider eller deres blanding. En substituert benzosyre er for eksempel benzosyre som er substituert en gang eller to ganger, eksempelvis med halogen (Cl, Br, J), NO2, OH eller Ci- Ca-alkyl (for eksempel mestyl), fortrinnsvis i orto-stilling. Amfotensider er eksempelvis fungicide amfotensider, for eksempel en Cs-C20-alkylaminokarboksylsyre, eksempelvis Ci 0-Ci 4-alkylamino-C2-Ca - karboksylsyre, et alkylaminoalkylglycin, for eksempel Ca-C20 - alkylaminoalkylglycin, eksempelvis Ci 0-Ci 4-alkylamino-C2-C3-alkyl-glycin eller Ci 0-Ci 4-alkylamino-C2-C3-alkylamino-C2- Ca - alkyl-glycin. Syren kan også foreligge i form av sitt vann-løselige salt, for eksempel alkalisalt, alkanolaminsalt. It was now found that the above-mentioned disadvantages disappear when water-soluble wood preservatives are used based on a mixture of copper compounds which are complexed with alkanolamines and a monomeric organic compound (acids) or their salts which form water-insoluble salts with copper. An alkanolamine is, for example, a mono-Ci-Ca-alkanolamine, for example ethanolamine. A compound, especially an acid, which forms a water-insoluble copper salt is, for example, sorbic acid, benzoic acid, substituted benzoic acid, dehydracetic acid, 5-nitroisophthalic acid, oxalic acid, salicylanilide, amphotensides or their mixture. A substituted benzoic acid is, for example, benzoic acid which is substituted once or twice, for example with halogen (Cl, Br, J), NO2, OH or Ci-Ca-alkyl (for example mestyl), preferably in the ortho position. Amphotensides are, for example, fungicidal amphotensides, for example a Cs-C20-alkylaminocarboxylic acid, for example Ci 0-Ci 4-alkylamino-C2-Ca - carboxylic acid, an alkylaminoalkylglycine, for example Ca-C20 - alkylaminoalkylglycine, for example Ci 0-Ci 4-alkylamino- C2-C3-alkyl-glycine or C10-C14-alkylamino-C2-C3-alkylamino-C2-C6-alkyl-glycine. The acid can also exist in the form of its water-soluble salt, for example alkali salt, alkanolamine salt.
De fortynnede, vandige løsningene (impregneringsløsningene) av disse midlene har en pH-verdi på 8 til 11, fortrinnsvis 9-10. De vannuløselige kobbersaltene av de ovennevnte syrene er også bestandige ved pH-verdier under 5. De virker godt mot basidiomycet-sopper og de forminsker utvaskingen av kobber. The diluted aqueous solutions (impregnation solutions) of these agents have a pH value of 8 to 11, preferably 9-10. The water-insoluble copper salts of the above-mentioned acids are also stable at pH values below 5. They work well against basidiomycete fungi and they reduce the leaching of copper.
Som kompleksdannere egner seg av økonomiske grunner spesielt monoetanolamin. Fremstillingen av de nye trebeskyttelsesmidlene er også mulig med andre alkanolaminer, for eksempel isopropanolamin, 1,1-, 1,2-di-aminoetanol, amino-etyletanolamin, dietanolamin, dimetyletanolamin. Herved tilmåles mengden av det tilsatte alkanolaminet fordelaktig slik at den er tilstrekkelig for kompleksdannelse av kobberet (1 gram-atom kobber behøver ialt 4 ekvivalenter amin) og det dessuten eventuelt dannes alkanolamin-salter av de organiske syrene, slik at det innstiller seg en pH-verdi på 8 eller mer, fortrinnsvis 9 til 10 i den vandige impregneringsløsningen. Monoethanolamine is particularly suitable as a complexing agent for economic reasons. The production of the new wood preservatives is also possible with other alkanolamines, for example isopropanolamine, 1,1-, 1,2-di-aminoethanol, amino-ethylethanolamine, diethanolamine, dimethylethanolamine. In this way, the amount of the added alkanolamine is advantageously measured so that it is sufficient for complex formation of the copper (1 gram-atom of copper requires a total of 4 equivalents of amine) and alkanolamine salts are also possibly formed from the organic acids, so that a pH value of 8 or more, preferably 9 to 10 in the aqueous impregnation solution.
pH-verdien i trebeskyttelsesmidlene og den fortynnede, vandige impregneringsløsningen kan eventuelt innstilles uavhengig av kompleksdannelsen også ved tilsetning av alkalier, ammoniakk eller andre vannløselige aminer. The pH value in the wood preservatives and the diluted, aqueous impregnation solution can optionally be adjusted independently of the complex formation also by adding alkalis, ammonia or other water-soluble amines.
De nye trebeskyttelsesmidlene kan eventuelt inneholde vanlige, ytterligere bestanddeler som korrosjonsinhibitorer, The new wood preservatives may possibly contain common, additional components such as corrosion inhibitors,
for eksempel isonansyre henholdsvis deres salter.for example isonanoic acid or their salts.
Det anbefales å tilsette borsyre og/eller borater til trebeskyttelsesmidlene, for ved hjelp av disse diffusjonsdyktige bestanddelene også å oppnå en impregnering av ikke tilgjengelige treområder (kjerneved). It is recommended to add boric acid and/or borates to the wood preservatives, in order to achieve an impregnation of inaccessible wood areas (heartwood) with the help of these diffusible components.
De nye trebeskyttelsesmidlene kan også foreligge som mer eller mindre viskøs væske, som pasta eller i fast form. The new wood preservatives can also be available as a more or less viscous liquid, as a paste or in solid form.
De vannfortynnbare midlene inneholder, i konsentrert form, kobberet, beregnet som element, ialt i en mengde fra 1 til 15 vekt%. The water-dilutable agents contain, in concentrated form, the copper, calculated as an element, in a total amount of from 1 to 15% by weight.
Egnede konsentrater inneholder eksempelvis (i vekt%)Suitable concentrates contain, for example (in weight%)
2,5 til 50 % Cu-forbindelse2.5 to 50% Cu compound
10 til 50 % alkanolamin10 to 50% alkanolamine
10 til 30 % organisk forbindelse (syre)10 to 30% organic compound (acid)
opptil 30 % av forbindelse med et fungicid virkende anion up to 30% of compound with a fungicidal active anion
(borsyre),(boric acid),
hvorved summen blir 100 (vekt%), såvel som eventuelt under-ordnede mengder av andre bestanddeler som aminer, ammoniakk, korrosjonsinhibitorer og om nødvendig vann, hvis andel imidlertid kan holdes liten og i det vesentlige tjener håndteringen. Oppfinnelsen strekker seg imidlertid i samme grad til de impregneringsløsningene med tilsvarende liten enkelt-konsentrasjon som kan fremstilles ved fortynning med vann. whereby the sum becomes 100 (weight%), as well as possibly subordinate amounts of other components such as amines, ammonia, corrosion inhibitors and, if necessary, water, the proportion of which can however be kept small and essentially serves the handling. However, the invention extends to the same extent to the impregnation solutions with a correspondingly low individual concentration which can be prepared by diluting with water.
Innholdet av den organiske forbindelse (syre) oppgår eksempelvis til 8 til 35 %, for eksempel 10 til 30 %, spesielt 10 til 25 %. Forbindelsen kan også foreligge i form av dens kobbersalt. The content of the organic compound (acid) is, for example, 8 to 35%, for example 10 to 30%, especially 10 to 25%. The compound may also exist in the form of its copper salt.
Oppfinnelsen forklares ved hjelp av følgende eksempler. The invention is explained by means of the following examples.
Klasser av furusplintvedklosser ved ble impregnert med impregneringsløsninger som var fremstilt av trebeskyttelsesmidlene ved fortynning med vann. Etter impregneringen ble treklassene utvasket med vann, mengden av utvasket kobber bestemt og grenseverdiene for den konsentrasjon av impregnerings-løsning fastslått, ved hvilke treklassene etter impregneringen og etter utvaskingen av basidiomycet-sopper ikke lenger ble angrepet. Classes of pine splinter wood blocks were impregnated with impregnation solutions which were prepared from the wood preservatives by diluting them with water. After the impregnation, the wood classes were washed out with water, the amount of leached copper determined and the limit values for the concentration of impregnation solution determined, at which the wood classes after the impregnation and after the washing out were no longer attacked by basidiomycete fungi.
Sammenligningseksempel (ikke ifølge oppfinnelsen)Comparative example (not according to the invention)
20 % Cu(OH)2CuC0320% Cu(OH) 2 CuCO 3
45 % monoetanolamin45% monoethanolamine
10 % borsyre10% boric acid
25 % vann25% water
Cu-innhold: 11,60 %. 40 g av løsningen ble oppfylt med vann Cu content: 11.60%. 40 g of the solution was filled with water
til 1 liter (anvendelseskonsentrasjon 4 %). Cu-utvasking (4 % anvendelseskonsentrasjon): 9,5 % to 1 liter (use concentration 4%). Cu leaching (4% application concentration): 9.5%
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mer enn 5 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) more than 5% application concentration.
Eksempel 1:Example 1:
37,00 % Cu-sorbat37.00% Cu sorbate
30,00 % monoetanolamin30.00% monoethanolamine
10,00 % borsyre10.00% boric acid
23,00 % vann23.00% water
Cu-innhold: 8,20 %Cu content: 8.20%
Cu-utvasking (4 % anvendelseskonsentrasjon): 4,5 %. Cu leaching (4% application concentration): 4.5%.
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 4 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 4% application concentration.
Eksempel 2:Example 2:
20,00 % Cu-sorbat20.00% Cu sorbate
10,00 % Cu(OH)2CuC0310.00% Cu(OH)2CuC03
40,00 % monoetanolamin40.00% monoethanolamine
12,50 % oksalsyre (C2H204 •2H2O)12.50% oxalic acid (C2H204 •2H2O)
17,50 % vann17.50% water
Cu-innhold: 10,20 %Cu content: 10.20%
Cu-utvasking (4 % anvendelseskonsentrasjon): 3,9 %. Cu leaching (4% application concentration): 3.9%.
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 4 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 4% application concentration.
Eksempel 3:Example 3:
45,00 % kobber-2-metylbenzoat45.00% copper 2-methylbenzoate
40,00 % monoetanolamin40.00% monoethanolamine
15,00 % vann15.00% water
Cu-innhold: 8,6 %Cu content: 8.6%
Cu-utvasking (4 % anvendelseskonsentrasjon): 4,5 %. Cu leaching (4% application concentration): 4.5%.
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 4 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 4% application concentration.
Eksempel 4:Example 4:
15,00 % Cu(OH)2CuC0315.00% Cu(OH)2CuC03
28,00 % 5-nitroisoftalsyre28.00% 5-nitroisophthalic acid
42,00 % monoetanolamin42.00% monoethanolamine
15,00 % vann15.00% water
Cu-innhold: 8,7 %Cu content: 8.7%
Cu-utvasking (4 % anvendelseskonsentrasjon): 5 % Cu leaching (4% application concentration): 5%
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 4 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 4% application concentration.
Eksempel 5:Example 5:
30,00 % kobbersalt av dehydracetsyre 30,00 % monoetanolamin 30.00% copper salt of dehydracetic acid 30.00% monoethanolamine
15,00 % borsyre15.00% boric acid
25,00 % vann25.00% water
Cu-innhold: 4,8 %Cu content: 4.8%
Cu-utvasking (5 % anvendelseskonsentrasjon): 4,7 %. Cu leaching (5% application concentration): 4.7%.
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 5 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 5% application concentration.
Eksempel 6 :Example 6:
35,00 % Cu-2,5-diklorbenzoat35.00% Cu-2,5-dichlorobenzoate
30,00 % monoetanolamin30.00% monoethanolamine
10,00 % H3BO310.00% H3BO3
25,00 % vann25.00% water
Cu-innhold: 5,0 %Cu content: 5.0%
Cu-utvasking (5 % anvendelseskonsentrasjon): 4,0 % Cu leaching (5% application concentration): 4.0%
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 5 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 5% application concentration.
Eksempel 7:Example 7:
35,00 % kobbersalt av salicylanilid 30,00 % monoetanolamin 35.00% copper salt of salicylanilide 30.00% monoethanolamine
10 , 00 % Ha BG-3 10.00% Ha BG-3
25,00 % vann25.00% water
Cu-innhold: 4,7 %Cu content: 4.7%
Cu-utvasking (5 % anvendelseskonsentrasjon): 4,9 %. Cu leaching (5% application concentration): 4.9%.
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 5 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 5% application concentration.
Eksempel 8:Example 8:
40,00 kobberbenzoat40.00 copper benzoate
35,00 % monoetanolamin35.00% monoethanolamine
10,00 % H3 B03 10.00% H3 B03
15,00 % vann15.00% water
Cu-innhold: 8,4 %Cu content: 8.4%
Cu-utvasking (5 % anvendelseskonsentrasjon): 4,8 %. Cu leaching (5% application concentration): 4.8%.
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 4 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 4% application concentration.
Eksempel 9:Example 9:
15,00 % Cu(OH)2CuC0315.00% Cu(OH)2CuC03
30,00 % monoetanolamin30.00% monoethanolamine
15,00 % oksalsyre15.00% oxalic acid
12,50 % blanding av alkylaminoalkylglyciner<*>) 28,00 % vann 12.50% mixture of alkylaminoalkylglycines<*>) 28.00% water
Cu-innhold: 8,7 %Cu content: 8.7%
Cu-utvasking (5 % anvendelseskonsentrasjon): 2,9 %Cu leaching (5% application concentration): 2.9%
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 4 % anvendelseskonsentrasjon. Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 4% application concentration.
Eksempel 10:Example 10:
10,00 % Cu(OH)2CuC0310.00% Cu(OH)2CuC03
20,00 % monoetanolamin20.00% monoethanolamine
10,00 % oksalsyre10.00% oxalic acid
10,00 % 1-dodecyl-l,4,7-triazol-oktan-8-karboksylsyrehydroklorid 50,00 % vann 10.00% 1-dodecyl-1,4,7-triazole-octane-8-carboxylic acid hydrochloride 50.00% water
Cu-innhold: 5,8 %Cu content: 5.8%
Cu-utvasking (5 % anvendelseskonsentrasjon): 3,2 %Cu leaching (5% application concentration): 3.2%
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 5 % anvendelseskonsentrasjon. Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 5% application concentration.
Eksempel 11:Example 11:
15,00 % Cu(OH)2CuC0315.00% Cu(OH)2CuC03
15,00 % oksalsyre15.00% oxalic acid
12,50 % dodecylaminosmørsyre12.50% dodecylaminobutyric acid
5,00 % H3B035.00% H3B03
23,00 % vann23.00% water
Cu-innhold: 8,7 %Cu content: 8.7%
Cu-utvasking (5 % anvendelseskonsentrasjon): 2,5 %Cu leaching (5% application concentration): 2.5%
Grenseverdi overfor treødeleggende basidiomyceter (Coniophora puteana, Poria monticola) mindre enn 5 % anvendelses-konsentras jon . Limit value against wood-destroying basidiomycetes (Coniophora puteana, Poria monticola) less than 5% application concentration.
De nevnte syrene kan også anvendes i blandinger med hverandre. Således anbefales det å anvende biocide amfotensider og fungicide eller insekticide syrer i blandinger. The mentioned acids can also be used in mixtures with each other. Thus, it is recommended to use biocidal amphotensides and fungicidal or insecticidal acids in mixtures.
Fikseringen av kobberet fra midlet ifølge oppfinnelsen i treet er avsluttet i løpet av 2 til 4 uker under normal-betingelser, avhengig av temperatur. Ved tilførsel av energi, spesielt varm damp, kan fikseringen akselereres. The fixation of the copper from the agent according to the invention in the wood is completed within 2 to 4 weeks under normal conditions, depending on the temperature. By supplying energy, especially hot steam, the fixation can be accelerated.
Furuklosser ble impregnert med en anvendelseskonsentrasjon på 4 % av midlet ifølge eksempel 1 og behandlet 2 timer senere med varm damp på 100°C, til klossene hadde en temperatur på minst 90°C (2 timer). Klossene ble deretter utvasket med vann og den utvaskede Cu-mengden bestemt i forhold til Cu-innholdet i klossene. Den totale utvasking av Cu oppgikk til 2,5 %. Pine blocks were impregnated with a use concentration of 4% of the agent according to example 1 and treated 2 hours later with hot steam at 100°C, until the blocks had a temperature of at least 90°C (2 hours). The bricks were then washed out with water and the leached Cu amount determined in relation to the Cu content in the bricks. The total leaching of Cu amounted to 2.5%.
Claims (7)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863609317 DE3609317A1 (en) | 1986-03-20 | 1986-03-20 | WOOD PRESERVATIVES |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO871141D0 NO871141D0 (en) | 1987-03-19 |
| NO871141L true NO871141L (en) | 1987-09-21 |
Family
ID=6296797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO871141A NO871141L (en) | 1986-03-20 | 1987-03-19 | Wood preservative. |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0238051A1 (en) |
| AU (1) | AU7042887A (en) |
| DE (1) | DE3609317A1 (en) |
| DK (1) | DK141287A (en) |
| FI (1) | FI871254A (en) |
| NO (1) | NO871141L (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3839848A1 (en) * | 1988-11-25 | 1990-05-31 | Ruetgerswerke Ag | WOOD PRESERVATIVES |
| BR8900666A (en) * | 1989-02-15 | 1990-10-02 | Johnson & Johnson Sa | DISPOSABLE CATAMENIAL ABOSERVENT |
| DE3937658A1 (en) * | 1989-11-11 | 1991-05-16 | Wolman Gmbh Dr | WOOD PRESERVATIVES |
| AT396897B (en) * | 1990-12-21 | 1993-12-27 | Haltmeier Georg | Agent for impregnating wood |
| DE4112652A1 (en) * | 1991-04-18 | 1992-10-22 | Wolman Gmbh Dr | WOOD PRESERVATIVES |
| JP3391449B2 (en) * | 1991-08-01 | 2003-03-31 | ヒクソン・インターナショナル・ピー・エル・シー | Preservatives for wood and other cellulosic materials |
| GB9116672D0 (en) * | 1991-08-01 | 1991-09-18 | Hickson Int Plc | Preservatives for wood and other cellulosic materials |
| DE4137621A1 (en) * | 1991-11-15 | 1993-05-19 | Wolman Gmbh Dr | WOOD PRESERVATIVES |
| DE4225528C2 (en) * | 1992-08-01 | 1994-09-15 | Kurt Obermeier Gmbh & Co Kg | Copper-containing wood preservative |
| ES2185155T3 (en) * | 1997-03-06 | 2003-04-16 | Wolman Gmbh Dr | WOOD PRESERVING AGENTS FOR SUBSEQUENT PROTECTION. |
| DE19727284A1 (en) * | 1997-06-27 | 1999-01-07 | Remmers Bauchemie Gmbh | Aqueous or water-dilutable wood preservative with fungicidal activity |
| US6172117B1 (en) | 1998-02-27 | 2001-01-09 | Akzo Nobel N.V. | Biocidal preservatives |
| ID26136A (en) * | 1998-03-20 | 2000-11-23 | John Bernard Watkins | COMPOSITION FOR FILLING PORTED PROCESSING MATERIALS AND THE USE OF IT |
| DE10062984A1 (en) * | 2000-12-16 | 2002-06-20 | Nutrinova Gmbh | Wood with fixed sorbic acid or sorbic acid salts |
| US7476371B2 (en) | 2002-02-14 | 2009-01-13 | Phibro-Tech, Inc. | Dissolution of copper metal in aqueous alkanolamine to form copper containing aqueous solution |
| FI118002B (en) | 2005-01-04 | 2007-05-31 | Granula Ab Ltd Oy | A method of impregnating a substance with wood |
| US8361210B2 (en) | 2005-01-04 | 2013-01-29 | Oy Granula Ab Ltd. | Method for treating wood |
| US20080026152A1 (en) * | 2006-07-28 | 2008-01-31 | Brient James A | Process for post-treatment of amine-based preservative-treated wood |
| US9796899B2 (en) | 2010-01-25 | 2017-10-24 | Oy Granula Ab Ltd | Method for preparing freezing point depressant composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3930834A (en) * | 1974-01-14 | 1976-01-06 | Applied Biochemists, Inc. | Algaecidal composition |
| NO810830L (en) * | 1980-03-22 | 1981-09-23 | Bp Chem Int Ltd | METALAMINE CARBOXYLATES AND THEIR USE AS PRESERVATIVES |
| SE459164B (en) * | 1981-05-08 | 1989-06-12 | Kenogard Ab | WOOD PROTECTIVE BASED ON CONSERVATIVE METALS AND ORGANIC NITROGEN CONTAINING COMPOUNDS AND USE OF THE MEDICINE |
| ZA852282B (en) * | 1984-04-04 | 1985-11-27 | Osmose Wood Preserv Co America | Preservative composition for wood |
| DE3520394A1 (en) * | 1985-06-07 | 1986-12-11 | Dr. Wolman Gmbh, 7573 Sinzheim | WOOD PRESERVATIVES |
-
1986
- 1986-03-20 DE DE19863609317 patent/DE3609317A1/en not_active Withdrawn
-
1987
- 1987-03-17 EP EP87103896A patent/EP0238051A1/en not_active Withdrawn
- 1987-03-19 NO NO871141A patent/NO871141L/en unknown
- 1987-03-19 DK DK141287A patent/DK141287A/en not_active Application Discontinuation
- 1987-03-20 FI FI871254A patent/FI871254A/en not_active Application Discontinuation
- 1987-03-20 AU AU70428/87A patent/AU7042887A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| DE3609317A1 (en) | 1987-09-24 |
| DK141287D0 (en) | 1987-03-19 |
| FI871254A0 (en) | 1987-03-20 |
| NO871141D0 (en) | 1987-03-19 |
| FI871254A (en) | 1987-09-21 |
| EP0238051A1 (en) | 1987-09-23 |
| AU7042887A (en) | 1987-09-24 |
| DK141287A (en) | 1987-09-21 |
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