NO801364L - PROCEDURE FOR MANUFACTURING FLAMMABLE GAS AND FERTILIZERS FROM LIQUID ANIMAL FERTILIZERS - Google Patents

PROCEDURE FOR MANUFACTURING FLAMMABLE GAS AND FERTILIZERS FROM LIQUID ANIMAL FERTILIZERS

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Publication number
NO801364L
NO801364L NO801364A NO801364A NO801364L NO 801364 L NO801364 L NO 801364L NO 801364 A NO801364 A NO 801364A NO 801364 A NO801364 A NO 801364A NO 801364 L NO801364 L NO 801364L
Authority
NO
Norway
Prior art keywords
fertilizers
liquid
sludge
vessel
container
Prior art date
Application number
NO801364A
Other languages
Norwegian (no)
Inventor
Vladimiro Pozzi
Original Assignee
Giza Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Giza Spa filed Critical Giza Spa
Publication of NO801364L publication Critical patent/NO801364L/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M27/00Means for mixing, agitating or circulating fluids in the vessel
    • C12M27/02Stirrer or mobile mixing elements
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M41/00Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/12Means for regulation, monitoring, measurement or control, e.g. flow regulation of temperature
    • C12M41/18Heat exchange systems, e.g. heat jackets or outer envelopes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Wood Science & Technology (AREA)
  • Genetics & Genomics (AREA)
  • General Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Biomedical Technology (AREA)
  • Sustainable Development (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Fertilizers (AREA)
  • Treatment Of Sludge (AREA)
  • Fire-Extinguishing Compositions (AREA)

Description

Foreliggende oppfinnelse vedrører en fremgangsmåte ved frem- |. The present invention relates to a method by developing |.

stilling av brennbar gass og gjødsel fra flytende animalsk gjødsel. position of flammable gas and fertilizer from liquid animal manure.

I store husdyrbruk, særlig ved oppdrett av kveg og svin,In large livestock farms, especially when breeding cattle and pigs,

vil det oppstå store mengder flytende materiale og det kan være problematisk å kvitte seg med dette som følge av for-urensningsproblemer som kan oppstå. Det er riktig nok at there will be large amounts of liquid material and it can be problematic to get rid of this as a result of contamination problems that may arise. It is true enough that

i visse tilfeller kan slike flytende gjødselmaterialer anvendes for gjødsling men også i dette tilfellet oppstår det store ulemper ved behovet for meget store oppsamlingstanker for. at. et slikt flytende materiale kan være tilgjengelig på et egnet tidspunkt og ytterligere er det nødvendig med spe-sielle transportkjøretøyer. fra lagringsstedet til anvend-elsesstedet. Man har prøvet å behandle slikt avfallsmat-eriale ved spaltning av dette til gass og ikke forurensende - restvæsker, men så vidt vites med dårlige og i alle fall util-fredsstillende resultater, hvilket fremgår av det faktum at problemet ennå ikke er løst. in certain cases, such liquid fertilizer materials can be used for fertilising, but even in this case there are major disadvantages due to the need for very large collection tanks for. that. such a liquid material may be available at a suitable time and furthermore special transport vehicles are required. from the place of storage to the place of use. Attempts have been made to treat such waste material by splitting it into gas and non-polluting residual liquids, but as far as is known with poor and in any case unsatisfactory results, which is evident from the fact that the problem has not yet been solved.

Det er en hovedhensikt ved foreliggende oppfinnelse å til-veiebringe en fremgangsmåte ved hvilken flytende gjødsel-materiale kan behandles og derved oppnå brennbare gasser som direkte kan utnyttes som sådanne, samt behandlede slam som kan anvendes som gjødningsstoff av høy kvalitet. It is a main purpose of the present invention to provide a method by which liquid fertilizer material can be treated and thereby obtain flammable gases that can be directly used as such, as well as treated sludge that can be used as a high-quality fertilizer.

Det er en ytterligere hensikt med oppfinnelsen å tilveie-bringe en fremgangsmåte av den ovenfor nevnte typen som It is a further purpose of the invention to provide a method of the above-mentioned type which

lett og enkelt lar seg utføre og som bare krever meget enkelt og billig utstyr. easily and simply can be carried out and which only requires very simple and cheap equipment.

Disse og andre hensikter oppnås ved en fremgangsmåte i henhold til hvilken flytende husdyrgjødselmateriale innføres i et lufttett, forseglet fermenteringskar eller beholder og i denne holdes det flytende materiale under omrøring.ved en temperatur på 30 - 40°C for et tidsrom på 10 - 20 døgn, under denne prosess dannes det forbrennbare gasser og et høykvalitetsgjødningsslam. These and other purposes are achieved by a method according to which liquid manure material is introduced into an airtight, sealed fermentation vessel or container and in which the liquid material is kept under stirring at a temperature of 30 - 40°C for a period of 10 - 20 days , during this process combustible gases and a high-quality fertilizer sludge are formed.

j For lettere å forstå foreliggende fremgangsmåte skal i det j To make it easier to understand the present method, it should

etterfølgende beskrives under henvisning til den vedlagte tegning, et system for behandling av et slikt husdyrgjødsel-avfallsmateriale,•i henhold til foreliggende fremgangsmåte. subsequently, with reference to the attached drawing, a system for treating such manure-waste material is described, • according to the present method.

Det flytende materiale fra røret 1 tilføres en tank 2 og . føres gjennom en sikt 3. Ved hjelp av en neddykket elek-tropumpe 4 og rørledningen 5 føres det flytende materiale til en homogeniseringstank 6 forsynt med mekanisk rører. The liquid material from the pipe 1 is supplied to a tank 2 and . is passed through a sieve 3. By means of a submerged electric pump 4 and the pipeline 5, the liquid material is passed to a homogenization tank 6 equipped with a mechanical stirrer.

Fra denne tank 6 tilføres det flytende materiale via rørled- . ningen 8 og pumpen 7 til toppen av et fermenteringsapparat eller reaktor 9, også forsynt med en mekanisk rører som in-:dikert i tegningen. From this tank 6, the liquid material is supplied via pipeline. the pipe 8 and the pump 7 to the top of a fermenter or reactor 9, also provided with a mechanical stirrer as indicated in the drawing.

I lokket eller toppen av fermenteringskaret eller reaktorenIn the lid or top of the fermentation vessel or reactor

9 er det anordnet en rørledning 10 for utføring av dé i 9, a pipeline 10 is arranged for carrying out the i

reaktoren dannede brennbare gasser som etter å ha vært ført gjennom en kondensatseparator og rensetårn (ikke vist), kan anvendes direkte eksempelvis for oppvarming eller for f rem-stilling av elektrisk energi. Fra bunnen av fermenteringskaret eller reaktoren 9 kan det fermenterende, flytende materiale uttrekkes via rørledningen 11 og ved hjelp av pumpen 12 sirkuleres gjennom varmeveksleren 13 og deretter tilbake til reaktoren via returrørledningen 14. the reactor formed combustible gases which, after being passed through a condensate separator and purification tower (not shown), can be used directly, for example, for heating or for the production of electrical energy. From the bottom of the fermentation vessel or reactor 9, the fermenting, liquid material can be extracted via the pipeline 11 and, with the help of the pump 12, circulated through the heat exchanger 13 and then back to the reactor via the return pipeline 14.

Varmeveksleren 13 virker til å bibeholde konstant temperatur i væsken inne i fermenteringskaret eller reaktoren 9. The heat exchanger 13 works to maintain a constant temperature in the liquid inside the fermentation vessel or reactor 9.

Skal fermenteringsprosessen fortsettes kan behandlet (digested) slam, d.v.s. slam som er ferdiggjæret eller fullstendig utarmet, utføres kontinuerlig gjennom utløpet 15 anordnet i toppdelen av fermenteringskaret eller reaktoren 9. Når det dreier seg om en satsvis prosess kan slam-et utføres fra reaktorens bunn. Det flytende husdyrgjødsel-materiale, som når det dreier seg om gjødsel fra kveg underkastes først en omrøringsoperasjon for å slå opp tilstede-værende stråmateriale og deretter for en grovsikteopera-sjon, mens for ét flytende avfall fra gris så underkastes i materialet kun en grovsileoperasjon og holdes deretter i f ermenteringskaret eller reaktoren 9 (som er lufttett lukket )j i et tidsrom på 10 - 20 døgn ved en temperatur i området 30 40°C, fortrinnsvis 35°C. Det er funnet for tilfellet av kvegavfall at den optimale oppholdstid i reaktoren ved 35°C for fullstendig å opparbeide materiale er 20 døgn, mens kun 10 - 15 døgn er tilstrekkelig for et flytende avfall fra svin. Det er også funnet at for gode driftsbeting-elser for fremgangsmåten bør tørrstoffinnholdet i fermenteringskaret eller reaktoren 9 ligge i området 5 - 10% av totalen for et flytende materiale fra kveg. If the fermentation process is to be continued, treated (digested) sludge can be used, i.e. sludge that is fully fermented or completely depleted is carried out continuously through the outlet 15 arranged in the top part of the fermentation vessel or reactor 9. When it is a batch process, the sludge can be carried out from the bottom of the reactor. The liquid animal manure material, which when it comes to manure from cattle, is first subjected to a stirring operation to break up the straw material present and then to a coarse sieving operation, while for one liquid waste from pigs, the material is only subjected to a coarse sieving operation and is then kept in the fermentation vessel or reactor 9 (which is hermetically sealed)j for a period of 10 - 20 days at a temperature in the range 30 40°C, preferably 35°C. It has been found for the case of cattle waste that the optimal residence time in the reactor at 35°C to fully process material is 20 days, while only 10 - 15 days are sufficient for a liquid waste from pigs. It has also been found that for good operating conditions for the method, the dry matter content in the fermentation vessel or reactor 9 should be in the range of 5 - 10% of the total for a liquid material from cattle.

Under de ovenfor nevnte fermenteringsbetingelser vil det i fermenteringskaret eller reaktoren 9 spontant utvikle seg anaerobe mikroorganismer (i visse tilfeller kan mikroorganismer av den aktuelle type tilsettes fermenteringskaret eller reaktoren utenifra), som vil nedbryte det flytende materialet under dannelse av brennbare gasser, i det vesentlige bestående av ca. 70% metan og 30% karbondioksyd som utføres gjennom rørledningen 10 uten at det er nødvendig å anvende en pumpe eller lignende fordi det eksisterer det vist overtrykk på ca. 200 mm F^O i fermenteringskaret eller reaktoren. Under the above-mentioned fermentation conditions, anaerobic microorganisms will spontaneously develop in the fermentation vessel or reactor 9 (in certain cases, microorganisms of the relevant type can be added to the fermentation vessel or reactor from the outside), which will break down the liquid material with the formation of flammable gases, essentially consisting of approx. 70% methane and 30% carbon dioxide which is carried out through the pipeline 10 without it being necessary to use a pump or the like because there exists the shown overpressure of approx. 200 mm F^O in the fermentation vessel or reactor.

Slammet som dannes i fermenteringskaret eller reaktoren 9The sludge that forms in the fermentation vessel or reactor 9

og som kontinuerlig eller diskontinuerlig utføres fra denne har en meget høy gjødningsverdi, den samme som det ube-handlede flytende utgangsmaterialet. Det erholdte gj-ød-ningsslam har også egenskapen at det er "ballansert" d.v.s. at det utviser et nitrogen-, fosfor- og kaliuminnhold innen de riktige områder for direkte anvendelse som gjød-sel. and which is carried out continuously or discontinuously from this has a very high fertilizing value, the same as the untreated liquid starting material. The obtained fertilizer sludge also has the property that it is "balanced", i.e. that it exhibits a nitrogen, phosphorus and potassium content within the correct ranges for direct application as fertiliser.

I tillegg så tilveiebringes slammet meget viktige egenskap-er ved den ovenfor beskrevne fremgangsmåte ved at det meget lett kan tørkes, hvilket muliggjør fylling i sekker, lagring i reduserte volumer og er lett-transporterbart og ytterligere at det er vannpermeabelt hvilket gjør at vann In addition, the sludge is provided with very important properties by the method described above in that it can be dried very easily, which enables filling in bags, storage in reduced volumes and is easily transportable and furthermore that it is water permeable, which means that water

lett trekker gjennom slikt slam når dette spres på marken for gjødningsformål. easily pulls through such sludge when it is spread on the field for fertilization purposes.

Ytterligere kan slammet lett pumpes, hvilket letter dets Furthermore, the sludge can be easily pumped, which facilitates its

anvendelse for gjødslingsformål, som følge av den lille partikkelstørrelse av suspendert faststoff og nedsatt inn-hold av flyktige bestanddeler. application for fertilizing purposes, due to the small particle size of suspended solids and reduced content of volatile components.

Claims (5)

1. Fremgangsmåte ved omdannelse av et flytende husdyr-gjødselavfall til brennbare gasser og et gjødningsslam, karakterisert ved at det flytende hus-dyrg jødselavf all holdes under omrøring i et lufttett kar eller beholder i et tidsrom på 10 - 20 døgn ved en temperatur i området 30 - 40°C hvorved dannes brennbare gasser og et slam med høy gjødningsverdi.1. Procedure for converting a liquid livestock manure waste into flammable gases and a fertilizer sludge, characterized in that the liquid livestock manure waste is all kept under stirring in an airtight vessel or container for a period of 10 - 20 days at a temperature in the area 30 - 40°C, whereby flammable gases and a sludge with a high fertilizing value are formed. 2. Fremgangsmåte ifølge krav 1, karakterisert ved at temperaturen holdes i det vesentlige konstant ved ca. 35°C.2. Method according to claim 1, characterized in that the temperature is kept essentially constant at approx. 35°C. 3. Fremgangsmåte ifølge krav 1 eller 2, karakterisert ved at det flytende materiale holdes i karet eller beholderen i 15 - 20 døgn.3. Method according to claim 1 or 2, characterized in that the liquid material is kept in the vessel or container for 15 - 20 days. 4. Fremgangsmåte ifølge kravene 1-3, karakterisert ved at tørrstoffinnholdet i beholderen eller, karet holdes i området 5 - 10%, regnet på total-mengden av materiale i karet eller beholderen.4. Method according to claims 1-3, characterized in that the dry matter content in the container or vessel is kept in the range of 5 - 10%, calculated on the total amount of material in the vessel or container. 5. Gjødningsslam erholdt ved fremgangsmåten ifølge kravene 1-4, karakterisert ved at det lett kan dehydreres å pumpes og er vannpermeabelt og utviser en høy gjødningsgrad.5. Fertilizer sludge obtained by the method according to claims 1-4, characterized in that it can be easily dehydrated and pumped and is water permeable and exhibits a high degree of fertilization.
NO801364A 1979-05-09 1980-05-08 PROCEDURE FOR MANUFACTURING FLAMMABLE GAS AND FERTILIZERS FROM LIQUID ANIMAL FERTILIZERS NO801364L (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2248879A IT1113392B (en) 1979-05-09 1979-05-09 PROCEDURE FOR THE TRANSFORMATION OF ZOOTECHNICAL LIQUAMS IN COMBUSTIBLE GASES AND IN FERTILIZING MUD

Publications (1)

Publication Number Publication Date
NO801364L true NO801364L (en) 1980-11-10

Family

ID=11196938

Family Applications (1)

Application Number Title Priority Date Filing Date
NO801364A NO801364L (en) 1979-05-09 1980-05-08 PROCEDURE FOR MANUFACTURING FLAMMABLE GAS AND FERTILIZERS FROM LIQUID ANIMAL FERTILIZERS

Country Status (22)

Country Link
JP (1) JPS5665699A (en)
AR (1) AR224402A1 (en)
AU (1) AU5802380A (en)
BE (1) BE883184A (en)
BR (1) BR8002824A (en)
CH (1) CH641746A5 (en)
DD (1) DD150592A5 (en)
DE (1) DE3017642A1 (en)
DK (1) DK170880A (en)
ES (1) ES491270A0 (en)
FI (1) FI801349A (en)
FR (1) FR2455848A1 (en)
GB (1) GB2050339A (en)
GR (1) GR67603B (en)
IN (1) IN152493B (en)
IT (1) IT1113392B (en)
MA (1) MA18835A1 (en)
NO (1) NO801364L (en)
PL (1) PL224112A1 (en)
PT (1) PT71193A (en)
SE (1) SE8003431L (en)
YU (1) YU123080A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8602652A (en) * 1986-10-23 1988-05-16 Promest Bv METHOD FOR PROCESSING SLURRY.
AUPM452094A0 (en) * 1994-03-17 1994-04-14 University Of Queensland, The Waste treatment plant and process
EP1280738B1 (en) 2000-05-12 2011-09-14 United Utilities Plc Sludge treatment at a mesophilic temperature
IT1400936B1 (en) * 2010-07-08 2013-07-02 Loppoli IMPROVED PLANT FOR BIOGAS PRODUCTION.

Also Published As

Publication number Publication date
DE3017642A1 (en) 1980-11-20
PL224112A1 (en) 1981-02-13
SE8003431L (en) 1980-11-10
CH641746A5 (en) 1984-03-15
FR2455848A1 (en) 1980-12-05
ES8102071A1 (en) 1981-01-16
YU123080A (en) 1983-01-21
AU5802380A (en) 1980-11-13
JPS5665699A (en) 1981-06-03
GB2050339A (en) 1981-01-07
GR67603B (en) 1981-08-31
BE883184A (en) 1980-09-01
IN152493B (en) 1984-01-28
PT71193A (en) 1980-06-01
AR224402A1 (en) 1981-11-30
MA18835A1 (en) 1980-12-31
DK170880A (en) 1980-11-10
IT1113392B (en) 1986-01-20
BR8002824A (en) 1980-12-16
DD150592A5 (en) 1981-09-09
IT7922488A0 (en) 1979-05-09
FI801349A (en) 1980-11-10
ES491270A0 (en) 1981-01-16

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