NO742765L

NO742765L -

Info

Publication number: NO742765L
Application number: NO742765A
Authority: NO
Inventors: A Fischer
Original assignee: Basf Ag
Priority date: 1973-08-28
Filing date: 1974-07-31
Publication date: 1975-03-24
Also published as: JPS5063137A; FR2250477A1; FR2250475A1; IL45502A0; BE819261A; DD112340A5; BR7407004D0; FR2250476A1; LU70800A1; DK454974A; NL7410128A; SE7410736L; AU7248474A; DE2343293A1

Description

"Nye herbicider" "New Herbicides"

Den foreliggende oppfinnelse angår verdifulle nye herbicider som inneholder blandinger av forskjellige virksomme stoffer. The present invention relates to valuable new herbicides containing mixtures of different active substances.

Det er kjent at benzofuranylmetansulfonater, karbamater, tiolkarbamater, halogenfettsyrer, pyridazoner, ditiokarbamater og syreamider har en herbicid virkning. Deres herbicide virkning er imidlertid ikke alltid tilstrekkelig. It is known that benzofuranylmethanesulfonates, carbamates, thiolcarbamates, halogenated fatty acids, pyridazones, dithiocarbamates and acid amides have a herbicidal effect. However, their herbicidal effect is not always sufficient.

Det ble funnet at en blanding avIt was found that a mixture of

a) en forbindelse med formelena) a compound with the formula

hvor R og ^ betyr et lavere alkyl, og/eller where R and ^ mean a lower alkyl, and/or

b) en forbindelse med formelenb) a compound with the formula

hvor R betyr et lavere alkyl, alkenyl, alkinyl, en eventuelt where R means a lower alkyl, alkenyl, alkynyl, an optionally

med metyl substituert cykloalifatisk rest, en bi- eller tricykloalifatisk rest, R1betyr lavere alkyl, alkenyl, alkinyl, X betyr oksygen eller svovel, R2betyr en eventuelt med halogen substituert alkyl-, alkenyl-, alkinyl-, fenyl- eller benzylrest eller en med metyl substituert fenyl- eller benzylrest, og/eller with methyl substituted cycloaliphatic residue, a bi- or tricycloaliphatic residue, R1 means lower alkyl, alkenyl, alkynyl, X means oxygen or sulphur, R2 means an optionally halogen-substituted alkyl, alkenyl, alkynyl, phenyl or benzyl residue or one with methyl substituted phenyl or benzyl residue, and/or

c) en forbindelse med formelenc) a compound with the formula

hvor R betyr en eventuelt med halogen, alkyl substituert fenyl- eller benzylrest, alkyl, alkinyl, alkenyl, halogenalkyl, halogenalkinyl, halogenalkenyl, where R means a phenyl or benzyl radical optionally substituted by halogen, alkyl, alkyl, alkynyl, alkenyl, haloalkyl, haloalkynyl, haloalkenyl,

R betyr alkyl, fenyl, halogen- R means alkyl, phenyl, halogen-

fenyl, metylfenyl, nitro eller aminobenzensulfonyl, og/eller phenyl, methylphenyl, nitro or aminobenzenesulfonyl, and/or

d) en forbindelse med formelend) a compound with the formula

hvor R betyr naftyl, 5-klor-4-metyl-tiazolyl, en eventuelt where R means naphthyl, 5-chloro-4-methyl-thiazolyl, an optionally

med alkyl, halogen substituert fenyl- eller benzylrest, alkyl, alkenyl, alkinyl, metoksy, R^betyr hydrogen, alkoksyalkyl, alkoksykarboksymetyl, alkyl, alkenyl, alkinyl, hvor alkoksyalkyl, alkyl, alkenyl og alkinyl kan være substituert med halogen, R2betyr alkyl, halogenalkyl, alkenyl, halogenalkenyl, alkinyl, halogenalkinyl, en eventuelt med karboksy, halogen, metyl, halogenalkyl substituert fenyl- eller benzylrest, a-naftoksyetyl, difenylmetyl, 4-klor-2-metylfenoksy-metyl, X betyr oksygen eller svovel, med den ytterligere bestemmelse at ved blandingen d + f skal R^ikke bety. alkyl, with alkyl, halogen substituted phenyl or benzyl residue, alkyl, alkenyl, alkynyl, methoxy, R^ means hydrogen, alkoxyalkyl, alkoxycarboxymethyl, alkyl, alkenyl, alkynyl, where alkoxyalkyl, alkyl, alkenyl and alkynyl can be substituted with halogen, R2 means alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, a phenyl or benzyl residue optionally substituted with carboxy, halogen, methyl, haloalkyl, α-naphthoxyethyl, diphenylmethyl, 4-chloro-2-methylphenoxy-methyl, X means oxygen or sulphur, with the further provision that in the case of the mixture d + f, R^ shall not mean. alkyl,

alkenyl eller alkinyl, og/eller alkenyl or alkynyl, and/or

e) en forbindelse med formelen e) a compound with the formula

hvor R betyr alkyl, halogenalkyl, benzamidooksy, en eventuelt where R means alkyl, haloalkyl, benzamidooxy, an optionally

med halogen, alkyl, halogenalkyl substituert benzylrest, X with halogen, alkyl, haloalkyl substituted benzyl residue, X

betyr hydrogen, halogen, R^betyr alkyl, hydrogen og saltene, for eksempel natriumsaltet, en med halogen substituert alkyl-, alkenyl-, alkinyl- eller benzylrest, og/eller means hydrogen, halogen, R^ means alkyl, hydrogen and the salts, for example the sodium salt, a halogen-substituted alkyl, alkenyl, alkynyl or benzyl residue, and/or

f) en forbindelse med fprmelenf) a connection with the fprmel

hvor X betyr eventuelt med halogen substituert alkylamino, where X means optionally halogen-substituted alkylamino,

dialkylamino, alkoksyalkylamino, alkoksyamino, alkylalkoksy-amino, a-hydroksy-6,8,8-trikloretylamiho, acetylamino, halo-genacetylamino, acetoacetylamino, amino, dimetylformamidin, metylformamidin, aminotartronsyredietylester, adipinamidsyre, metoksy, -NH-CO-COOR, NH-COOR, hvor R betyr en eventuelt med halogen substituert fenylrest, Y betyr klor, brom, metoksy, Z betyr hydrogen, metyl-halogenalkyl, alkoksy, og/eller Dialkylamino, Alkoxyalkylamino, Alkoxyamino, Alkylalkylamino, α-Hydroxy-6,8,8-Trichloroethylamiho, Acetylamino, Halogenacetylamino, Acetoacetylamino, Amino, Dimethylformamidine, Methylformamidine, Aminotartronic acid diethyl ester, Adipinamic acid, Methoxy, -NH-CO-COOR, NH -COOR, where R means an optionally halogen-substituted phenyl radical, Y means chlorine, bromine, methoxy, Z means hydrogen, methyl-haloalkyl, alkoxy, and/or

g) forbindelseng) the compound

har en bedre herbicid virkning enn de virksomme enkeltstoffer. has a better herbicidal effect than the active individual substances.

Blandingene kan inneholde en eller flere forbindelser med formelen a og forbindelser med formlene b, c, d, e, f og g i blan-dingsforholdene 0,1 : 10 til 10 : 1 på vektsbasis eller 0,1 til 10 : 0,1 til 10 : 0,1 : 10 på vektsbasis. The mixtures may contain one or more compounds with the formula a and compounds with the formulas b, c, d, e, f and g in the mixing ratios 0.1:10 to 10:1 by weight or 0.1 to 10:0.1 to 10 : 0.1 : 10 by weight.

De mengder som anvendes av midlene ifølge oppfinnelsen, kan variere. Den anvendte mengde avhenger hovedsakelig av arten av den ønskede virkning. Mengden ligger i alminnelighet mellom 0,1 og 30 eller, mer, fortrinnsvis 0,2-6, kg virksomt stoff pr. hektar. Midlene ifølge oppfinnelsen kan blant annet anvendes før plantingen, etter plantingen, før såingen, før plantene kommer opp av jorden, etter at plantene er kommet opp av jorden eller mens kulturplantene eller de uønskede planter er i ferd med å komme opp av jorden,, . og midlene kan anvendes en eller flere ganger. The amounts used of the agents according to the invention may vary. The amount used depends mainly on the nature of the desired effect. The amount is generally between 0.1 and 30 or, more, preferably 0.2-6, kg of active substance per hectares. The agents according to the invention can be used, among other things, before planting, after planting, before sowing, before the plants emerge from the soil, after the plants have emerged from the soil or while the cultivated plants or the unwanted plants are in the process of emerging from the soil. and the funds can be used one or more times.

Blandingene er egnet til bekjempelse av uønskede planterThe mixtures are suitable for combating unwanted plants

i forbindelse med nytteplanter, for eksempel Beta spp., Arachis hypogaea, Asparagus officinalis, Brassica napus,Vitis vinifera,Daucus carota, Tragaria spp., Gossypium hirsutum, Hordeum spp., Malus spp., Medicago sativa, Nicotiana tabacum, Oryza sativa, Zea mays, Phaseolus vulgaris, Pisum sativum, Pyrus spp., Ribes spp., Tulipa, Saccharum officinarum, Scorzbnera hispanica, Secale cereale,Glycine max., Solanum lycopersicum, Solanum tuberosum, Ulmus spp., Sorghum, Spinacia oleracea, Tilia spp., Trifolium spp., Triticum spp., Thype spp. in connection with useful plants, for example Beta spp., Arachis hypogaea, Asparagus officinalis, Brassica napus, Vitis vinifera, Daucus carota, Tragaria spp., Gossypium hirsutum, Hordeum spp., Malus spp., Medicago sativa, Nicotiana tabacum, Oryza sativa, Zea mays, Phaseolus vulgaris, Pisum sativum, Pyrus spp., Ribes spp., Tulipa, Saccharum officinarum, Scorzbnera hispanica, Secale cereale, Glycine max., Solanum lycopersicum, Solanum tuberosum, Ulmus spp., Sorghum, Spinacia oleracea, Tilia spp. , Trifolium spp., Triticum spp., Thype spp.

Dessuten kan blandingene anvendes som totalmiddel ved graver, langs elver og bekker, langs jernbaneskinner, på øde flater etc. In addition, the mixtures can be used as a total solution at graves, along rivers and streams, along railway tracks, on deserted surfaces, etc.

Blandingene a+b+c, a+b+d, a+b+e, a+b+f, a+c+d, a+d+e, a+d+f, b+c+d, b+c+e, b+c+f, b+d+e, b+d + f, b + e + f, c+d + e, c+d + f, d + e + f, The combinations a+b+c, a+b+d, a+b+e, a+b+f, a+c+d, a+d+e, a+d+f, b+c+d, b +c+e, b+c+f, b+d+e, b+d + f, b + e + f, c+d + e, c+d + f, d + e + f,

a + b, a + d, b + c, b + d, b + e, b + f, c + d, d + e, d + f,a + b, a + d, b + c, b + d, b + e, b + f, c + d, d + e, d + f,

a + g, b + g, c + g, d + g, e+g, f + g, a+b + g, a+c+g, a+d+g, a+e+g, a+f+g, b+c+g, b+d+g, b+e+g, b+f+g, c+d+g, c+e+g, c+f+g, d+e+g, d+f+g og e + f + g foretrekkes. a + g, b + g, c + g, d + g, e+g, f + g, a+b + g, a+c+g, a+d+g, a+e+g, a+ f+g, b+c+g, b+d+g, b+e+g, b+f+g, c+d+g, c+e+g, c+f+g, d+e+ g, d+f+g and e + f + g are preferred.

Anvendelsen skjer eksempelvis i form av direkte sprøyt-bare løsninger, pulvere, suspensjoner, dispersjoner, emulsjoner, oljedispersjoner, pastaer, støvformige midler, strømidler og gra-nulater, ved utsprøyting, forstøvning, utstrøing eller uthelling. Anvendelsesformene retter seg helt etter anvendelsesformålet; man tar imidlertid alltid sikte på å oppnå en mest mulig fin fordeling av de virksomme stoffer ifølge oppfinnelsen. The application takes place, for example, in the form of directly sprayable solutions, powders, suspensions, dispersions, emulsions, oil dispersions, pastes, dusty agents, flow agents and granules, by spraying, atomizing, spreading or pouring. The forms of application depend entirely on the purpose of application; however, the aim is always to achieve as fine a distribution as possible of the active substances according to the invention.

For fremstilling av direkte sprøytbare løsninger, emulsjoner, pastaer og oljedispersjoner kan man bruke mineraloljefrak-sjoner med midlere til høyt kokepunkt, så som kerosin eller diesel-olje, ennvidere kulltjæreoljer etc, samt oljer av vegetabilsk eller animalsk opprinnelse, alifatiske, cykliske og aromatiske hydrokarboner, for eksempel benzen, toluen, xylen, paraffin, tetra-hydronaftalin, alkylerte naftaliner eller derivater derav, for eksempel metanol, etanol, propanol, butanol, kloroform, karbontetra-klorid, cykloheksanol, cykloheksanon, klorbenzen, isoforon etc., For the production of directly sprayable solutions, emulsions, pastes and oil dispersions, you can use mineral oil fractions with high boiling points, such as kerosene or diesel oil, further coal tar oils etc., as well as oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons , for example benzene, toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or derivatives thereof, for example methanol, ethanol, propanol, butanol, chloroform, carbon tetrachloride, cyclohexanol, cyclohexanone, chlorobenzene, isophorone, etc.,

sterkt polare løsningsmidler, som for eksempel dimetylformamid, dimetylsulfoksyd, N-metylpyrrolidon, vann etc. strongly polar solvents, such as dimethylformamide, dimethylsulfoxide, N-methylpyrrolidone, water etc.

Vandige bruksformer kan fremstilles av emulsjonskonsentra-Aqueous forms of use can be prepared from emulsion concentrates

ter, pastaer eller fuktbare pulvere (sprøytepulvere) eller oljedispersjoner ved tilsetning av vann. Ved fremstilling av emulsjoner, pastaer eller oljedispersjoner kan stoffene som sådanne eller løst i olje eller løsningsmiddel homogeniseres i vann ved hjelp av fukte-, klebe-, dispergerings- eller emulgeringsmidler. Det kan imidlertid også fremstilles konsentrater bestående av virksomt stoff, fukte-, klebe-, dispergerings- eller emulgeringsmiddel og eventuelt løsnings-middel eller olje, hvilke konsentrater er egnet til å fortynnes med vann. ter, pastes or wettable powders (spray powders) or oil dispersions by adding water. When producing emulsions, pastes or oil dispersions, the substances as such or dissolved in oil or solvent can be homogenised in water using wetting, adhesive, dispersing or emulsifying agents. However, it is also possible to prepare concentrates consisting of active substance, wetting, adhesive, dispersing or emulsifying agent and any solvent or oil, which concentrates are suitable for diluting with water.

Blant overflateaktive stoffer kan nevnes:Surfactants include:

alkali-, jordalkali- og ammoniumsalter av ligninsulfonsyre, nafta-linsulfonsyre, fenolsulfonsyrer, alkylarylsulfonater, alkylsulfater, alkylsulfonater, alkali- og jordalkalisalter av dibutylnaftalinsul-fonsyre, lauryletersulfat, fettalkoholsulfater, fettsure alkali- og jordalkalisalter, salter av sulfaterte heksadekanoler, heptadekanoler, oktadekanoler, salter av sulfatert fettalkoholglykoleter, kondensa-sjons produkter av sulfonert naftalin og naftalinderivater med formaldehyd, kondensasjonsprodukter av naftalin eller naftalinsulfon- alkali, alkaline earth and ammonium salts of lignin sulfonic acid, naphthalene sulfonic acid, phenol sulfonic acids, alkylaryl sulfonates, alkyl sulfates, alkyl sulfonates, alkali and alkaline earth salts of dibutyl naphthalene sulfonic acid, lauryl ether sulfate, fatty alcohol sulfates, fatty acid alkali and alkaline earth salts, salts of sulfated hexadecanols, heptadecanols, octadecanols, salts of sulphated fatty alcohol glycol ether, condensation products of sulphonated naphthalene and naphthalene derivatives with formaldehyde, condensation products of naphthalene or naphthalene sulfone

syrer med fenol og formaldehyd, polyoksyetylen-oktylfenyleter, etoksylert isooktylfenol, -oktylfenol, -nonylfenol, alkylfenolpolyglykol-eter, tributylfenylpolyglykoleter, alkylårylpolyeteralkohol, isotri-decylalkohol, fettalkohol-etylenoksyd-kondensater, etoksylert rici-nusolje, polyoksyetylenalkyleter, etoksylert polyoksypropylen, lau-rylalkohol-polyglykoleteracetal, sorbitolester, lignin, sulfittav-luter og metylcellulose. acids with phenol and formaldehyde, polyoxyethylene-octylphenyl ether, ethoxylated isooctylphenol, -octylphenol, -nonylphenol, alkylphenol polyglycol ether, tributylphenylpolyglycol ether, alkylaryl polyether alcohol, isotridecyl alcohol, fatty alcohol-ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylated polyoxypropylene, lauryl alcohol -polyglycol ether acetal, sorbitol ester, lignin, sulphite solvent and methyl cellulose.

Pulver, strø- og støvformige midler kan fremstilles ved blanding eller sammaling av de virksomme stoffer med et fast bære-materiale. Powders, sprinkles and dust-like agents can be prepared by mixing or grinding together the active substances with a solid carrier material.

Granulater, for eksempel omhyllings-, impregnerings- og homogengranulater kan fremstilles ved binding av de virksomme stoffer på faste bærematerialer. Faste bærematerialer er eksempelvis mine- ralmaterialer så som silikagel, kiselsyrer, kiselgeler, silikater, talkum, kaolin, attaclay, kalkstein, kalk, kritt, bolus, løss, Granules, for example encasing, impregnation and homogenous granules, can be produced by binding the active substances to solid carrier materials. Solid carrier materials are, for example, mineral materials such as silica gel, silicic acids, silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bolus, loess,

leire, dolomitt, diatoméjord, kalsium og magnesiumsulfat, magne-siumoksyd, malte harpikser>gjødningsstoffer så som ammoniumsulfat, ammoniumfosfat, ammoniumnitrat, urinstoffer og vegetabilske pro-dukter så som mel av korn, bark, tre og nøtteskall, cellulosepulver og andre faste bærematerialer. clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground resins>fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea and vegetable products such as grain flour, bark, wood and nut shells, cellulose powder and other solid carrier materials.

Preparatene inneholder mellom 0,1 og 95 vekt% virksomtThe preparations contain between 0.1 and 95% by weight of active ingredients

stoff, fortrinnsvis mellom 0,5 og 90 vekt%.substance, preferably between 0.5 and 90% by weight.

Til blandingene eller de enkelte virksomme stoffer kan man, eventuelt først umiddelbart før anvendelsen (tankblanding), til- To the mixtures or the individual active substances, one can, possibly only immediately before use (tank mixture), add

sette oljer av forskjellige typer, herbicider, fungicider, nematocider,' insekticider, baktericider, sporelementer, gjødningstoffer, skumhindrende midler (eksempelvis silikoner), vekstregulatorer, motgiftmidler og andre herbicid virksomme forbindelser, som for eksempel put oils of various types, herbicides, fungicides, nematicides,' insecticides, bactericides, trace elements, fertilisers, anti-foaming agents (for example silicones), growth regulators, antidotes and other herbicidally active compounds, such as

substituerte anilinersubstituted anilines

substituerte aryloksykarboksylsyrer og deres salter, estere ogsubstituted aryloxycarboxylic acids and their salts, esters and

amideramides

substituerte eteresubstituted ethers

substituerte arsonsyrer og deres salter, estere og amider substituerte benzimidazoler substituted arsonic acids and their salts, esters and amides substituted benzimidazoles

substituerte benzisotiazolersubstituted benzisothiazoles

substituerte benztiadiazinondioksydersubstituted benzthiadiazine dioxides

substituerte benzoksazxnersubstituted benzoxanes

substituerte benzoksazinonersubstituted benzoxazinones

substituerte benztiadiazblersubstituted benzthiadiazbels

substituerte biureter substituerte kinoliner substituted biurets substituted quinolines

substituerte karbamater substituerte alifatiske karboksylsyrer og deres salter, estere og substituted carbamates substituted aliphatic carboxylic acids and their salts, esters and

amideramides

substituerte aromatiske karboksylsyrer og deres salter, esteresubstituted aromatic carboxylic acids and their salts, esters

og amiderand amides

substituerte karbamoylalkyl-tiol eller -ditiofosfatersubstituted carbamoylalkyl thiol or -dithiophosphates

substituerte kinazolinersubstituted quinazolines

substituerte, cykloalkylamidokarbontiolsyrer og deres salter,substituted, cycloalkylamidocarbonthiolic acids and their salts,

estere og amideresters and amides

substituerte cykloalkylkarbonamido-tiazolersubstituted cycloalkylcarbonamidothiazoles

substituerte dikarboksylsyrer og deres salter, estere og amider substituted dicarboxylic acids and their salts, esters and amides

substituerte dihydrobenzofuranylsulfonatersubstituted dihydrobenzofuranyl sulfonates

substituerte disulfidersubstituted disulfides

substituerte dipyridyliumsaltersubstituted dipyridylium salts

substituerte ditiokarbamatersubstituted dithiocarbamates

substituerte ditiofosforsyrer og deres salter, estere og amider substituerte'urinstoffer substituted dithiophosphoric acids and their salts, esters and amides substituted'ureas

substituerte heksahydro-lH-karboti|oatersubstituted hexahydro-1H-carbothioates

substituerte hydantSanersubstituted hydant Saner

substituerte hydrazidersubstituted hydrazides

substituerte hydrazoniumsaltersubstituted hydrazonium salts

substituerte isooksazolpyrimidonersubstituted isoxazolepyrimidones

substituerte imidazoler substituerte isotiazolpyrimidoner substituted imidazoles substituted isothiazolepyrimidones

substituerte ketoner substituerte naftSSinoner substituted ketones substituted naphthSSinones

substituerte alifatiske nitrilersubstituted aliphatic nitriles

substituerte aromatiske nitriler substituerte oksadiazoler. substituted aromatic nitriles substituted oxadiazoles.

substituerte oksadiazinonersubstituted oxadiazinones

substituerte oksadiazolidindioner substituerte oksadiazindioner substituted oxadiazolidinediones substituted oxadiazinediones

substituerte fenoler og deres salter og esteresubstituted phenols and their salts and esters

substituerte fosforsyrer og deres salter, estere og amider substituerte fosfoniumklorider substituerte fosfonaikylglyciner. substituerte fosfitter substituerte fosforsyrer og deres salter, estere og amider substituerte pyrazoler substituerte piperidiner substituted phosphoric acids and their salts, esters and amides substituted phosphonium chlorides substituted phosphonicylglycines. substituted phosphites substituted phosphoric acids and their salts, esters and amides substituted pyrazoles substituted piperidines

substituerte pyrazolalkylkarboksylsyrer og deres salter, estere og amider substituted pyrazolealkylcarboxylic acids and their salts, esters and amides

substituerte pyrazoliumsaltersubstituted pyrazolium salts

substituerte pyrazoliiumalkylsulfatersubstituted pyrazolium alkyl sulfates

substituerte pyridazinersubstituted pyridazines

substituerte pyridåzonersubstituted pyridozones

substituerte pyridinkarboksylsyrer og deres salter, estere og substituted pyridine carboxylic acids and their salts, esters and

amideramides

substituerte pyridinersubstituted pyridines

substituerte pyridinkarboksylatersubstituted pyridine carboxylates

substituerte pyridinonersubstituted pyridinones

substituerte pyrimidinersubstituted pyrimidines

substituerte pyrimidonersubstituted pyrimidones

substituert pyrrilidinkarboksylsyre og dennes salter, estere og substituted pyrrilidine carboxylic acid and its salts, esters and

amideramides

substituerte pyrrolidinersubstituted pyrrolidines

substituerte pyrrolidonersubstituted pyrrolidones

substituerte arylsulfonsyrer og deres salter, estere og amider substituerte styrener substituted arylsulfonic acids and their salts, esters and amides substituted styrenes

substituerte tetrahydro-oksadiazindioner substituted tetrahydro-oxadiazindiones

substituerte ~te~trån\ydro-oksadiazoldionersubstituted ~te~trån\hydro-oxadiazolediones

substituerte tetrahydrometanoindenersubstituted tetrahydromethanoindenes

substituerte tetrahydro-diazol-tionersubstituted tetrahydro-diazole ions

substituerte tetrahydro-tiadiazin-tionersubstituted tetrahydro-thiadiazine ions

substituerte tetrahydro-tiadiazoldionersubstituted tetrahydrothiadiazolediones

substituerte aromatiske tiokarboksylsyreamidersubstituted aromatic thiocarboxylic acid amides

substituerte tiokarboksylsyrer og deres salter, estere og amider substituerte tiolkarbamater substituted thiocarboxylic acids and their salts, esters and amides substituted thiol carbamates

substituerte tiourinstoffersubstituted thioureas

substituerte tiofosforsyrer og deres salter, estere og amider substituerte triaziner substituted thiophosphoric acids and their salts, esters and amides substituted triazines

substituerte triazolersubstituted triazoles

substituerte uracilersubstituted uracils

substituerte uretidindioner.substituted uretidine diones.

De sistnevnte herbicide forbindelser kan etter ønske anvendes før eller etter de virksomme stoffer.eller blandinger ifølge oppfinnelsen. The latter herbicidal compounds can, if desired, be used before or after the active substances or mixtures according to the invention.

Tilblandingen av disse midler til herbicidene ifølge oppfinnelsen kan skje i vektforholdet 1 : 10 til 10 : 1. Det samme gjelder for oljer, fungicider, nematocider, insekticider, baktericider, motgiftmidler og vekstregulatorer. The addition of these agents to the herbicides according to the invention can take place in a weight ratio of 1:10 to 10:1. The same applies to oils, fungicides, nematocides, insecticides, bactericides, antidotes and growth regulators.

Midlene oppviser en sterk herbicid virkning bg kan derfor anvendes som ugrasdrepende midler eller til bekjempelse av uønsket plantevekst. Om midlene virker som totale eller selektive midler, avhenger hovedsakelig av den mengde virksomt stoff som anvendes pr. flateenhet. The agents exhibit a strong herbicidal effect and can therefore be used as weed killers or to combat unwanted plant growth. Whether the agents act as total or selective agents depends mainly on the amount of active substance used per surface unit.

Med ugras eller uønsket plantevekst menes her alle enfrø-bladede og tofrøbladede planter som vokser på steder hvor de ikke er ønsket. By weeds or unwanted plant growth is meant here all monocotyledonous and dicotyledonous plants which grow in places where they are not wanted.

§ji.ledes kan'man med midlene ifølge oppfinnelsen eksempelvis bekjempe §ji.led can be fought with the means according to the invention, for example

planter av grasfamilien, så som plants of the grass family, such as

I drivhus og på friland ble de følgende forbindelser i forskjellige blandinger utprøvet: 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranylmetan-sulfonat N-metyl-karbaminsyre-3,4-diklorbenzylester ' N-fenyl-karbaminsyre-isopropylester N-(4-nitrobenzo^sulfonyl)-karbaminsyre-metylester N-(4-aminobenzolsulfonyl)-karbarainsyre-metylester N-3,4-diklorfenyl-karbaminsyre-metylester In greenhouses and in the open field, the following compounds were tested in various mixtures: 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl methane-sulfonate N-methyl-carbamic acid-3,4-dichlorobenzyl ester ' N-phenyl -carbamic acid isopropyl ester N-(4-nitrobenzo^sulfonyl)-carbamic acid methyl ester N-(4-aminobenzenesulfonyl)-carbamic acid methyl ester N-3,4-dichlorophenyl-carbamic acid methyl ester

N-3-klorfenyl-karbaminsyre-isopropylester N-3-chlorophenyl-carbamic acid isopropyl ester

N-3-klorfenyl-karbaminsyre-4-klor-butin-2-yl-l-ester N-3-klorfenyl-karbaminsyre-butin-l-yl-3-ester N-3-Chlorophenyl-carbamic acid-4-chloro-butyn-2-yl-1-ester N-3-Chlorophenyl-carbamic acid-butyn-1-yl-3-ester

3-metoksy-karbonylaminofenyl-N-(3'-metylfenyl)-karbamat 0- (N-fenyl-karbamoyl)-propanonoksim 3-Methoxy-carbonylaminophenyl-N-(3'-methylphenyl)-carbamate O-(N-phenyl-carbamoyl)-propanone oxime

Trikloreddiksyre-natriumsaltTrichloroacetic acid sodium salt

a,a-diklorpropionsyre-natriumsalt α,α-Dichloropropionic acid sodium salt

a,a1, B,-triklorpropionsyre-natriumsalt a,a1,B,-trichloropropionic acid sodium salt

a,a-diklorpropionsyre-benzylester α,α-Dichloropropionic acid benzyl ester

a, a, B, B-tetraf luorpropionsyre-natriumsalt a, a, B, B-tetrafluoropropionic acid sodium salt

a,a-diklorsmørsyré-natriumsalt a,a-Dichlorobutyric acid sodium salt

a-klor-6-(4-klorfenyl)-propionsyre-raetylester α-Chloro-6-(4-chlorophenyl)-propionic acid raethyl ester

Benzoamido-oksyeddiksyreBenzoamido-oxyacetic acid

1- fenyl-4-kloracetyl-5-brompyridazon-(6) 1- phenyl-4-chloroacetyl-5-bromopyridazone-(6)

l-fenyl-4-amino-5-klorpyridazon-(6) l-fenyl-4-amino-5-brompyridazon-(6) 1-fenyl-4-amino-5-metoksypyridazon-(6) 1-m-trifluormetylfenyl-4-amino-5-klorpyridazon-(6) 1-m-trif lruprmetylfenyl-4-amino-5-bronipyridazon-(6) l-m-metylfenyl-4-amino-5-brompyridazon-(6) l-m-metylfenyl-4-amino-5-klorpyridazon-(6) l-fenyl-4-(a-hydroksy-B,6,B-trikloretyl)-amino-5-brom-pyridazon-(6) 1-m-trifluormetylfenyl-4-(a-hydroksy-6,B,3-trikloretyl)-amino-5- klorpyridazon-(6) 1-m-trifluormetylfenyl-4-(a-hydroksy-6,6,6-trikloretyl)-amino-5- brompyridazon-(6) l-fenyl-4-acetylamino-5-klorpyridazon-(6) l-fenyl-4-acetylamino-5-brompyridazon-(6) l-phenyl-4-amino-5-chloropyridazone-(6) l-phenyl-4-amino-5-bromopyridazone-(6) 1-phenyl-4-amino-5-methoxypyridazone-(6) 1-m-trifluoromethylphenyl -4-amino-5-chloropyridazone-(6) 1-m-trifluoromethylphenyl-4-amino-5-bronipyridazone-(6) 1-m-methylphenyl-4-amino-5-bromopyridazone-(6) 1-m-methylphenyl-4 -amino-5-chloropyridazone-(6) l-phenyl-4-(α-hydroxy-B,6,B-trichloroethyl)-amino-5-bromo-pyridazone-(6) 1-m-trifluoromethylphenyl-4-( α-hydroxy-6,B,3-trichloroethyl)-amino-5- chlorpyridazone-(6) 1-m-trifluoromethylphenyl-4-(α-hydroxy-6,6,6-trichloroethyl)-amino-5- bromopyridazone-(6) l-phenyl-4-acetylamino-5-chloropyridazone-(6) l-phenyl-4-acetylamino-5-bromopyridazone-(6)

1-m-trifluormetylfenyl-4-acetylamino-5-brompyridazon-(6) 1-m-trifluormetylfeny1-4-acetylamino-5-klorpyridazon-(6) 1-m-trifluormetylfenyl-4-kloracetylamino-5-klorpyridazon-(6) l-fenyl-4-bromacetylamino-5-brompyridazon-(6) 1-m-trifluoromethylphenyl-4-acetylamino-5-bromopyridazone-(6) 1-m-trifluoromethylphenyl-4-acetylamino-5-chloropyridazone-(6) 1-m-trifluoromethylphenyl-4-chloroacetylamino-5-chloropyridazone-(6 ) l-phenyl-4-bromoacetylamino-5-bromopyridazone-(6)

1-feny1-4-acetoacetylamino-5-brompyridazon-(6) 1-phenyl1-4-acetoacetylamino-5-bromopyridazone-(6)

1-m-trifluormetylfenyl-4-kloracetylamino-5-brompyridazon-(6) 1-m-trifluormetylfenyl-4-dietylamino-5-klorpyridazon-(6) N-[m-metylfenyl-5-brompyridazon-(6)-yl-(4)]-oksamidsyre-tert.butylester 1-m-trifluoromethylphenyl-4-chloroacetylamino-5-bromopyridazone-(6) 1-m-trifluoromethylphenyl-4-diethylamino-5-chloropyridazone-(6) N-[m-methylphenyl-5-bromopyridazon-(6)-yl -(4)]-oxamic acid tert-butyl ester

N-[fenyl-5-brompyridazon-(6)-yl-(4)]-karbaminsyre-tert.butyl-ester N-[phenyl-5-bromopyridazon-(6)-yl-(4)]-carbamic acid tert-butyl ester

l-fenyl-4-metoksy-5-klor-pyridazon-(6) l-phenyl-4-methoxy-5-chloro-pyridazone-(6)

N-[l-fenyl-5-brompyridazon-(6)-yl-(4)]-oksamidsyre-metylester N-[1-phenyl-5-bromopyridazon-(6)-yl-(4)]-oxamic acid methyl ester

N-[l-fenyl-5-brompyridazon-(6)-yl-(4)]-oksamidsyre-etylester N-[1-feny1-5-brompyridazon-(6)-y1-(4)]-oksamidsyre-fenylester N-[1-m-trifluormetylfeny1-5-brompyridazon-(6)-y1-(4J-oksamid-syreetylester N-[1-phenyl-5-bromopyridazon-(6)-yl-(4)]-oxamic acid ethyl ester N-[1-phenyl-5-bromopyridazon-(6)-yl-(4)]-oxamic acid phenyl ester N-[1-m-trifluoromethylphenyl-5-bromopyridazone-(6)-y1-(4H-oxamide-acid ethyl ester

N-[1-m-trifluormetylfenyl-5-brompyridazon-(6)-yl-(4)]-oksamid-N-[1-m-trifluoromethylphenyl-5-bromopyridazon-(6)-yl-(4)]-oxamide-

syre acid

N-[1-m-trifluormetylfenyl-5-klorpyridazon-(6)-yl-(4)]-oksamid-N-[1-m-trifluoromethylphenyl-5-chloropyridazon-(6)-yl-(4)]-oxamide-

syre acid

N-[l-m-trifluormetylfeny1-5-brompyridazon-(6)-yl-(4)]-oksamidsyre-tert.butylester N-[1-m-trifluoromethylphenyl-5-bromopyridazon-(6)-yl-(4)]-oxamic acid tert-butyl ester

N-[1-m-trifluormetylfeny1-5-brompyridazon-(6)-yl-(4)]-oksamidsyre -natriumsalt N-[1-m-trifluoromethylphenyl-5-bromopyridazon-(6)-yl-(4)]-oxamic acid sodium salt

N-[1-m-trifluormetylfenyl-4-dikloracetylamino-5-brom-pyrida-N-[1-m-trifluoromethylphenyl-4-dichloroacetylamino-5-bromo-pyrida-

zon-(6) zone-(6)

N-[l-fenyl-5-brompyridazon-(6)-yl-(4) ]-oksamidsyre-na triumsalt N-[1-feny1-5-brompyridazon-(6)-yl-(4)]-oksamidsyre-dimetyl-etanolaminsalt N-[1-phenyl-5-bromopyridazon-(6)-yl-(4)]-oxamic acid sodium salt N-[1-phenyl-5-bromopyridazon-(6)-yl-(4)]-oxamic acid- dimethyl ethanolamine salt

N-[l-fenyl-5-brompyridazon-(6)-yl-(4)]-oksamidsyre-isopfopyl-N-[1-phenyl-5-bromopyridazon-(6)-yl-(4)]-oxamic acid-isophopyl-

esterester

1-feny1-4-dikloracetylamino-5-brompyridazon-(6) 1-phenyl1-4-dichloroacetylamino-5-bromopyridazone-(6)

N-[l-fenyl-5-brompyridazon-(6)-yl-(4)-adipinamidsyre-metyl-N-[1-phenyl-5-bromopyridazon-(6)-yl-(4)-adipinamidic acid-methyl-

ester ester

N-[1-m-trifluormetylfeny1-5-brompyridazon-(6)-yl-(4)]-dimetylformamidin N-[1-m-trifluoromethylphenyl1-5-bromopyridazon-(6)-yl-(4)]-dimethylformamidine

1-m-trifluormetylfenyl-4-metylamino-5-klorpyridazon-(6) 1-m-trifluoromethylphenyl-4-methylamino-5-chloropyridazone-(6)

1-m-trifluormetylfenyl-4-dimetylamino-5-klorpyridazon-(6) 1-m-trifluormetylfeny1-4-dimetylamino-5-brompyridazon-(6) N-[4-(1-feny1-5-brompyridazon)-yl-Taminotarttronsyre-dietyl-ester 1-m-trifluoromethylphenyl-4-dimethylamino-5-chloropyridazon-(6) 1-m-trifluoromethylphenyl-4-dimethylamino-5-bromopyridazon-(6) N-[4-(1-phenyl1-5-bromopyridazon)-yl -Taminotartric acid diethyl ester

1-m-trifluormetylfenyl-4-metoksy-5-klorpyridazon-(6) 1-m-trifluoromethylphenyl-4-methoxy-5-chloropyridazone-(6)

1-m-trif luormetylf eny l-4-met'6ksy-5-brompyr idazon - (6) 1-m-trifluoromethylphenyl-4-methoxy-5-bromopyridazone - (6)

1-m-trifluormetylfenyl-4,5-dimetoksypyridazon-(6) 1-m-trifluoromethylphenyl-4,5-dimethoxypyridazone-(6)

1-m-metylfenyl-4-metoksy-5-brompyridazon-(6) 1-m-methylphenyl-4-methoxy-5-bromopyridazone-(6)

l-m-metylfenyl-4-metoksy-5-klorpyridazon-(6) 1-m-methylphenyl-4-methoxy-5-chloropyridazone-(6)

i-m-metylfenyl-4-metoksy-5-metoksypyridazon-(6) i-m-methylphenyl-4-methoxy-5-methoxypyridazone-(6)

1-feny1-4,5-dimetoksy-pyridazon-(6) 1-phenyl1-4,5-dimethoxy-pyridazone-(6)

1-fenyl-4-metoksy-5-brompyridazon-(6) 1-phenyl-4-methoxy-5-bromopyridazone-(6)

1-m-trifluormetylfeny1-4-metoksyamino-5-klorpyridazon-(6) 1-m-trifluormetylfeny1-4-metyl-metoksyamino-5-klor- 1-m-trifluoromethylphenyl1-4-methoxyamino-5-chloropyridazone-(6) 1-m-trifluoromethylphenyl1-4-methyl-methoxyamino-5-chloro-

pyridazon-(6)pyridazone-(6)

2,2-diklorpropionsyre-B-kloretylester 2,2-Dichloropropionic acid B-chloroethyl ester

1- m-trifluormetylfenyl-4-metylamino-5-brompyridazon-(6) N,N-diailyl-2-klor-acetam|id| 2- (2-metyl-4-klor-fenoksy)-N-metoksy-acetamid 2-(a-naftoksy)-N,N-dietyl-propionamid 1-m-trifluoromethylphenyl-4-methylamino-5-bromopyridazone-(6)N,N-diallyl-2-chloro-acetamide| 2-(2-methyl-4-chloro-phenoxy)-N-methoxy-acetamide 2-(a-naphthoxy)-N,N-diethyl-propionamide

N,N-dimetyl-2,2-difenyl-acetamid N,N-dimethyl-2,2-diphenyl-acetamide

N-(l,1-dimetyl-propionyl)-3,5-diklor-banzamid a,a-dimetyl-valeriansyre-p-klor-anilid N-(1,1-dimethyl-propionyl)-3,5-dichloro-banzamide α,α-dimethyl-valeric acid-p-chloro-anilide

Propionsyre-3 >^Rdiklor-anilid Propionic acid-3 >^Rdichloroanilide

Metylakrylsyre-3,4-diklor-anilid Methylacrylic acid-3,4-dichloroanilide

2-metyl-pentansyre-3,4-diklor-anilid 2-methyl-pentanoic acid-3,4-dichloro-anilide

2-metyl-pentansyre-3-klor-4-metyl-anilid 2-methyl-pentanoic acid-3-chloro-4-methyl-anilide

N-bicyklo-(2,2,1)-heptyl-N-etyl-tiolkarbaminsyre-propylester N-cykloheksy1-N-propargyl-tiolkarbaminsyre-etylester N-isopropyl-os-kloracetanilid N-bicyclo-(2,2,1)-heptyl-N-ethyl-thiocarbamic acid propyl ester N-cyclohexy1-N-propargyl-thiocarbamic acid ethyl ester N-isopropyl-os-chloroacetanilide

N-butin-(l)-yl-(3)-a-kloracetanilid N-butyn-(1)-yl-(3)-α-chloroacetanilide

a-kloracet-2-metyl-6-tert.butyl-anilid α-chloroacet-2-methyl-6-tert-butyl-anilide

a-bromacet-2-metyl-6-tert.butyl-anilid α-bromoacet-2-methyl-6-tert.butyl-anilide

N-metoksymetyl- a-bromacet-2-metyl-6-tert.butyl-anilid N-metoksymetyl-a-kloracet-2,6-dietyl-anilid N-Methoxymethyl-α-bromoacet-2-methyl-6-tert.butyl-anilide N-Methoxymethyl-α-chloroacet-2,6-diethyl-anilide

N-isobutoksymetyl-a-kloracet-2,6-dimetyl-anilid N-isopropoksymetyl-a-kloracet-2,6-dimetyl-anilid 5-klor-4-metyl-2-propionamid-tiazol N-isobutoxymethyl-a-chloroacet-2,6-dimethyl-anilide N-isopropoxymethyl-a-chloroacet-2,6-dimethyl-anilide 5-chloro-4-methyl-2-propionamide-thiazole

N-l-naftyl-ftalamidsyre N-1-Naphthyl-phthalamic acid

N,N-diisopropyl-tiolkarbaminsyre-2,3-diklorallylester N,N-diisopropyl-tiolkarbaminsyre-2,3,3-triklorallylester N,N-di-n-propyl-tiolkarbaminsyre-etylester N,N-diisopropyl-thiocarbamic acid-2,3-dichloroallyl ester N,N-diisopropyl-thiocarbamic acid-2,3,3-trichloroallyl ester N,N-di-n-propyl-thiocarbamic acid ethyl ester

N,N-di-n-butyl-tiolkarbaminsyre-etylester N,N-diisobutyl-tiolkarbaminsyre-etylester N,N-di-n-butyl thiolcarbamic acid ethyl ester N,N-diisobutyl thiolcarbamic acid ethyl ester

N-etyl-N-n-butyl-tiolkarbaminsyre-n-propylester N,N-di-n-propyl-tiolkarbaminsyre-n-propylester N,N-di-n-propyl-tiolkarbaminsyre-tert.butylester N-etyl-N-cykloheksyl-tiolkarbaminsyre-etylester N-metyl-karbaminsyre-2,6-di-tert.butyl-p-tolyl-ester N-ethyl-N-n-butyl-thiocarbamic acid-n-propyl ester N,N-di-n-propyl-thiocarbamic acid-n-propyl ester N,N-di-n-propyl-thiocarbamic acid-tert-butyl ester N-ethyl-N-cyclohexyl -thiocarbamic acid ethyl ester N-methyl-carbamic acid 2,6-di-tert-butyl p-tolyl ester

N-[l eller 2-(3a,4,5,6,7,7a-heksahydro-4,7-metanoindanyl)]-N-etyltiolkarbaminsyre-etylester N-[1 or 2-(3a,4,5,6,7,7a-hexahydro-4,7-methanoindanyl)]-N-ethylthiocarbamic acid ethyl ester

N-bicyklo-(3,3,0)-oktyl-N-etyl-tiolkarbaminsyre-etylester N-bicyklo-(3,3,0)-okty1-N-ety1-tiolkarbaminsyre-metylester N-bicyklo-(3,3,0)-oktyl-N-etyl-tiolkarbaminsyre-isopropylester N-bicyclo-(3,3,0)-octyl-N-ethyl-thiocarbamic acid ethyl ester N-bicyclo-(3,3,0)-octyl-N-ethyl-1-thiocarbamic acid methyl ester N-bicyclo-(3,3 ,O)-octyl-N-ethyl-thiocarbamic acid isopropyl ester

N,N-dietyl-ditiokarbaminsyre-2~klorallylester N-bicyklo-(2,2,1)-heptyl-N-etyl-tiolkarbaminsyre-etylester N-bicyklo-(2,2,1)-heptyl-N-etyl-ditiokarbaminsyre-etylester N-ety1-N-o-metylcykloheksyl-tiolkarbaminsyre-etylester N-etoksy~karboksymetyl-a-kloracet-2,6-dietylanilid Tiopropionsyre-3,4-dikloranilid N,N-dietyl-tiolkarbaminsyre-p-klorbenzylester N-butoKsymetyl-a-kloreddiksyre-2,6-dietylanilid Ety1-N-benzoyl-N-(3,4-diklorfenyl)-2-aminopropionat. N,N-diethyl-dithiocarbamic acid-2~chloroallyl ester N-bicyclo-(2,2,1)-heptyl-N-ethyl-thiocarbamic acid-ethyl ester N-bicyclo-(2,2,1)-heptyl-N-ethyl- dithiocarbamic acid ethyl ester N-ethyl-N-o-methylcyclohexyl-thiocarbamic acid ethyl ester N-ethoxy~carboxymethyl-a-chloroacet-2,6-diethylanilide Thiopropionic acid-3,4-dichloroanilide N,N-diethyl-thiocarbamic acid p-chlorobenzyl ester N-butoXymethyl -α-chloroacetic acid-2,6-diethylanilide Ethyl-N-benzoyl-N-(3,4-dichlorophenyl)-2-aminopropionate.

Det ble slått fast at den biologiske virkning var som for de i eksemplene anførte blandHnger. It was established that the biological effect was the same as for the mixtures listed in the examples.

Eksempel 1Example 1

I et drivhus ble forsøkskasser fyllt med leirholdig sand-, jorS^l og forskjellige frø ble sådd. Deretter ble jorden behandlet In a greenhouse, experimental boxes were filled with loamy sand, jorS^l and different seeds were sown. The soil was then treated

med de følgende virksomme enkeltstoffer og deres blandinger som with the following active single substances and their mixtures which

.granulat:.granules:

I 2~etoksy-2,3-dihydro~3,3-dimetyl-5-behzofuranyl-metan- sulfonat In 2~ethoxy-2,3-dihydro~3,3-dimethyl-5-bezofuranyl-methane- sulfonate

II l-fenyl-4-amino-5-klorpyridazon-(6)II 1-phenyl-4-amino-5-chloropyridazone-(6)

III N,N-diisopropyl-tiolkarbaminsyre-2,3-diklorallylesterIII N,N-Diisopropyl-thiolcarbamic acid-2,3-dichloroallyl ester

IV N,N-diisopropyl-tiolkarbaminsyre-2,3,3-triklorallyl-ester IV N,N-diisopropyl-thiocarbamic acid-2,3,3-trichloroallyl ester

V N-ety1-N-n-butyl-tiolkarbaminsyre-n-propylesterV N-Ethy1-N-n-butyl thiolcarbamic acid n-propyl ester

VI N,N-di-(n-propyl)-tiolkarbaminsyre-etylesterVI N,N-di-(n-propyl)-thiocarbamic acid ethyl ester

VII N-etyl-N-cykloheksyl-tiolkarbaminsyre-etylesterVII N-ethyl-N-cyclohexyl-thiocarbamic acid ethyl ester

VIII N-bicyklo-(3,3,0)-oktyl-N-etyl-tiolkarbaminsyreetyl-ester VIII N-bicyclo-(3,3,0)-octyl-N-ethyl-thiocarbamic acid ethyl ester

IX N-bicyklo-(2,2,1)-heptyl-N-etyl-tiolkarbaminsyreetyl-ester IX N-bicyclo-(2,2,1)-heptyl-N-ethyl-thiocarbamic acid ethyl ester

X N,N-diisobutyl-tiolkarbaminsyre-etylesterX N,N-diisobutyl thiolcarbamic acid ethyl ester

XI N,N-dietyl-tiolkarbaminsyre-p-klorbenzylesterXI N,N-diethyl-thiocarbamic acid p-chlorobenzyl ester

i hvert tilfelle 0,15, 1,5 og kg/ha aktivt stoff. in each case 0.15, 1.5 and kg/ha of active substance.

I+II+III, I+II+V, I+II+IV, I+II+VI, I+II+VII, I+II+VIII, I+II+IX,'I+II+X, I+II+XIvI+II+III, I+II+V, I+II+IV, I+II+VI, I+II+VII, I+II+VIII, I+II+IX,'I+II+X, I +II+XIv

i hvert tilfelle 0,15+0,15+1,5; 0,15+1,5+0,15 og 1,5+0,15+0,15 kg/ha aktivt stoff. in each case 0.15+0.15+1.5; 0.15+1.5+0.15 and 1.5+0.15+0.15 kg/ha active substance.

Etter 3-4 uker ble det slått fast at blandingene viste en - bedre herbicid virkning ved samme forenlighet med kulturplantene enn de virksomme enkeltstoffer. After 3-4 weeks, it was established that the mixtures showed a - better herbicidal effect at the same compatibility with the cultivated plants than the active single substances.

Forsøksresultatet vil fremgå av den følgende tabell. The test result will appear in the following table.

Eksempel 2 Example 2

En jordbruksflate ble tilsådd med forskjellige frø. Umiddelbart deretter ble jorden behandlet med de følgende virksomme enkeltstoffer og deres blandinger som dispersjon eller emulsjon: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl-metan- sulfonat An agricultural area was sown with different seeds. Immediately thereafter, the soil was treated with the following active single substances and their mixtures as a dispersion or emulsion: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl-methane- sulfonate

IV N,N-diisopropyl-tiolkarbaminsyre-2,3,3-triklorallyl-IV N,N-diisopropyl-thiolcarbamic acid-2,3,3-trichloroallyl-

esterester

V ■ N-etyl-N-n-butyl-tiolkarbaminsyre-n-propylester VI N,N-di-(n-propyl)-tiolkarbaminsyre-etylester VII N-ety1-N-cykloheksyl—tiolkarbaminsyre-etylester V ■ N-ethyl-N-n-butyl-thiocarbamic acid n-propyl ester VI N,N-di-(n-propyl)-thiocarbamic acid ethyl ester VII N-ethyl-N-cyclohexyl-thiocarbamic acid ethyl ester

VIII N-l- eller -2-bicyklo-(3,3,0)-oktyl-N-etyl-tiolkarbamin-syreetylester VIII N-1- or -2-bicyclo-(3,3,0)-octyl-N-ethyl-thiocarbamic acid ethyl ester

X N,N-di-(isobutyl)-tiolkarbaminsyre-etylesterX N,N-di-(isobutyl)-thiocarbamic acid ethyl ester

i hyert tilfelle 1, 2 og 3 kg/ha aktivt stoff.in high cases 1, 2 and 3 kg/ha of active substance.

I+II+III, I+II+IV, I+II+V, I+II+VI, I+II+VII, I+II+VIII, I+II+IX, I+II+X, I+II+XI, I+II+III, I+II+IV, I+II+V, I+II+VI, I+II+VII, I+II+VIII, I+II+IX, I+II+X, I+ II+XI,

i hvert tilfelle 1+1+2, 2+1+1 og 1+2+1 kg/ha aktivt stoff. in each case 1+1+2, 2+1+1 and 1+2+1 kg/ha of active substance.

Etter 3-4 uker ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkelts^tpffene. After 3-4 weeks, it was established that the mixtures showed a better herbicidal effect at the same compatibility with the cultivated plants than the individual strains.

Eksempel 3 Example 3

I et drivhus ble forsøkskasser fyllt med leirholdig sand-jord, og forskjellige frø ble sådd. Deretter ble jorden behandlet med de følgende virksomme enkeltstoffer og deres blandinger som pasta: I 2-etoksy-2,3-dihydro-3,3-dimety1-5-benzofuranyl-metan- sulfonat In a greenhouse, experimental boxes were filled with loamy sandy soil, and different seeds were sown. The soil was then treated with the following active single substances and their mixtures as a paste: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl-methane- sulfonate

III N,N-diisopropyi-tiolkarbaminsyre-2,3-diklorallylesterIII N,N-Diisopropylthiolcarbamic acid 2,3-dichloroallyl ester

VIII N-bicyklo-(3,3,0)-oktyl-N-etyltiolkarbaminsyre-etylester VIII N-bicyclo-(3,3,0)-octyl-N-ethylthiocarbamic acid ethyl ester

IX N-bicyklo-(3,3,0)-heptyl-N-etyl-tiolkarbaminsyre-etylester X N,N-diisobutyl-tiolkarbaminsyre-rety lester XI N,N-dietyl-tiolkarbaminsyre-p-klorbenzylester IX N-bicyclo-(3,3,0)-heptyl-N-ethyl-thiocarbamic acid ethyl ester X N,N-diisobutyl-thiocarbamic acid rethy ester XI N,N-diethyl-thiocarbamic acid p-chlorobenzyl ester

XXI [a[a.4diklorpropionsyre-natriumsaltXXI [a[a.4dichloropropionic acid sodium salt

XXII Trikloreddiksyre-natriumsaltXXII Trichloroacetic acid sodium salt

XXIII a, a, 8, B-tetrafluorpropionsyre-natriumsaltXXIII a, a, 8, B-tetrafluoropropionic acid sodium salt

XXIV Fenylkarbaminsyre-isopropylesterXXIV Phenylcarbamic acid isopropyl ester

XXVm-klorfenylkarbaminsyre-isopropylesterXXVm-chlorophenylcarbamic acid isopropyl ester

XXVIm-klorfenylkarbaminsyre-butin-l-yi-3-esterXXVIm-chlorophenylcarbamic acid butyn-1-yi-3-ester

XXVII 0-(N-fenyl-karbambyl)-propanonoksimXXVII O-(N-phenylcarbamyl)-propanone oxime

i hvert tilfelle 0,25, 0,5 og 1 kg/ha aktivt stoff. in each case 0.25, 0.5 and 1 kg/ha of active substance.

I+XI+XXI, I+XI+XXII, I+XI+XXIII, I+XXIV+XI, I+XI+XXV, I+XI+XXVI, I+XI+XXVil, I+X+XXI, I+X+XXII, I+X+XXIII, I+XI+XXIV, I+X+XXV, I+X+XXVI, I+X+XXVII, I+IX+XXI, I+IX+XXII, I+IX+XXIII, I+IX+XXIV, I+IX+XXV, I+IX+XXVI, I+IX+XXVII, I+VIII+XXIvJl+VIII+XXII, I+VIII+XXIII, I+VIII+XXIV, I+VIII+XXV, I+VIII+XXVI, I+VIII+XXVII, I+VII+XXI, I+VI+XXII, I+VII+XXIII, I+VII+XXIV, I+VII+XXV, I+VII+XXVI, I+VII+XXVII, I+VI+XXI til XXVII, I+V+XXI til XXVII, I+XI+XXI, I+XI+XXII, I+XI+XXIII, I+XXIV+XI, I+XI+XXV, I+XI+XXVI, I+XI+XXVil, I+X+XXI, I+ X+XXII, I+X+XXIII, I+XI+XXIV, I+X+XXV, I+X+XXVI, I+X+XXVII, I+IX+XXI, I+IX+XXII, I+IX+ XXIII, I+IX+XXIV, I+IX+XXV, I+IX+XXVI, I+IX+XXVII, I+VIII+XXIvJl+VIII+XXII, I+VIII+XXIII, I+VIII+XXIV, I+ VIII+XXV, I+VIII+XXVI, I+VIII+XXVII, I+VII+XXI, I+VI+XXII, I+VII+XXIII, I+VII+XXIV, I+VII+XXV, I+VII+ XXVI, I+VII+XXVII, I+VI+XXI to XXVII, I+V+XXI to XXVII,

I+IV+XXI til XXVII og I+III+XXI til XXVIII+IV+XXI to XXVII and I+III+XXI to XXVII

i hvert tilfelle 0,25+0,25+0,5; 0,25+0,5+0,25 og 0,5+0,25+0,25 kg/ha aktivt stoff. in each case 0.25+0.25+0.5; 0.25+0.5+0.25 and 0.5+0.25+0.25 kg/ha active substance.

Etter 3-4 uker ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. After 3-4 weeks, it was established that the mixtures showed a better herbicidal effect at the same compatibility with the cultivated plants than the individual substances.

Eksempel 4 Example 4

I et drivhus ble forsøkskasser fyllt med leirholdig sand-jord, og forskjellige frø ble sådd. Deretter ble jorden behandlet med de følgende virksomme enkeltstoffer og deres blandinger som granulat: I 2-etoksy-2,3-dihydro-3,3-dimety1-5-benzofuranylmetan- sulfonat In a greenhouse, experimental boxes were filled with loamy sandy soil, and different seeds were sown. The soil was then treated with the following active single substances and their mixtures as granules: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranylmethane- sulfonate

III N,N-diisopropylr-tiolkarbaminsyre-2,3-diklorally lesterIII N,N-diisopropyl-r-thiocarbamic acid-2,3-dichloroally ester

V N-etyl-N-n-butyl-tiolkarbaminsyre-n-propylesterV N-ethyl-N-n-butyl thiolcarbamic acid n-propyl ester

VI N,N-di-n-propyl-tiolkarbaminsyre-etylesterVI N,N-di-n-propyl thiolcarbamic acid ethyl ester

VII N-ety l-N-cykloheksyl\-t iolkarbaminsyre-ety lesterVII N-Ethy l-N-cyclohexyl\-t iolcarbamic acid ethyl ester

VIII N-bicyklo-(3,3,0)-oktyl-N-etyl-tiolkarbaminsyre-etylester VIII N-bicyclo-(3,3,0)-octyl-N-ethyl-thiocarbamic acid ethyl ester

XII N,N-diallyl-2-kloracetamidXII N,N-diallyl-2-chloroacetamide

XIII N-(l, 1-dimetylpropinyT)~^3, 5-diklor-benzamidXIII N-(1,1-dimethylpropynyl)~^3,5-dichlorobenzamide

XIV N-isopropyl-a-kloracetanilidXIV N-isopropyl-α-chloroacetanilide

XV N-butyn-l-yl-3-a-kloracetanilidXV N-butyn-1-yl-3-a-chloroacetanilide

XVI a-bromacet-2-metyl-6-tert.butyl-anilidXVI a-bromoacet-2-methyl-6-tert-butyl-anilide

XVII N-metoksymetyl-a-bromacet-2-metyl-6-tert.butyl-anilid XVIII N-metoksymety1- a-kloracet-2,6-dietylanilid XVII N-Methoxymethyl-α-bromoacet-2-methyl-6-tert.butyl-anilide XVIII N-Methoxymethyl-α-chloroacet-2,6-diethylanilide

XIX N-isobutoksymetyl-a-kloracet-2,6-dimetylanilidXIX N-isobutoxymethyl-α-chloroacet-2,6-dimethylanilide

XX N-butoksymetyl-a-kloracet-2,6-dietylanilid.XX N-butoxymethyl-α-chloroacet-2,6-diethylanilide.

XXI a,a-diklorpropionsyre-natriumsaltXXI a,a-Dichloropropionic acid sodium salt

XXII Trikloreddiksyre-natriumsaltXXII Trichloroacetic acid sodium salt

XXIII a, a, '6,16-tetraf luorpropionsyre-natriumsaltXXIII a, a, '6,16-tetrafluoropropionic acid sodium salt

XXIV N-fenylkarbaminsyre-isopiopylesterXXIV N-phenylcarbamic acid isopioyl ester

XXV N-m-klorfenylkarbaminsyre-isopropylesterXXV N-m-chlorophenylcarbamic acid isopropyl ester

XXVI N-m-klorfenylkarbaminsyre-butin-(l)-yl-(3)-esterXXVI N-m-Chlorophenylcarbamic acid butyn-(1)-yl-(3)-ester

XXVII O-(N-fenyl-karbamoyl)-propanonoksimXXVII O-(N-phenyl-carbamoyl)-propanone oxime

i hvert tilfelle 0,5 - 0,75 - 1 - 1,5 kg/ha aktivt stoff VII+XXIV henholdsvis XII, XV, XVII, XVIII, XX, XXI, XXII, XXIII, VIII+XXIV henholdsvis XXVII, XXI, XXII, XV, in each case 0.5 - 0.75 - 1 - 1.5 kg/ha active substance VII+XXIV respectively XII, XV, XVII, XVIII, XX, XXI, XXII, XXIII, VIII+XXIV respectively XXVII, XXI, XXII , XV,

X+XXIV henholdsvis XII, XIII, XV, XVII, XVIII, XX,X+XXIV respectively XII, XIII, XV, XVII, XVIII, XX,

XI+XXIV henholdsvis XXI, XV, XVII, XVIII, XX, III,XI+XXIV respectively XXI, XV, XVII, XVIII, XX, III,

XII+XXI henholdsvis XXIV,XII+XXI respectively XXIV,

XIII+XXI henholdsvis XXIV, XXII,XIII+XXI respectively XXIV, XXII,

I+III henholdsvis IV, V, VI, VII, VIII, X, XI, XII, XIII, XV, XVI, I+III respectively IV, V, VI, VII, VIII, X, XI, XII, XIII, XV, XVI,

XIV, XVII, XVIII, XIX, XX,XIV, XVII, XVIII, XIX, XX,

II+III henholdsvis IV, V, VI, VII, VIII, X, XI, XII, XVI, XVII, II+III respectively IV, V, VI, VII, VIII, X, XI, XII, XVI, XVII,

XVIII, XIX, XXXVIII, XIX, XX

III+XXI henholdsvis XV, XXIV,III+XXI respectively XV, XXIV,

IV+XXII henholdsvis XVIIr, XXIV, XXV, XXVI, XXVII,IV+XXII respectively XVIIr, XXIV, XXV, XXVI, XXVII,

VI+XXI henholdsvis XXIV,VI+XXI respectively XXIV,

XIV+XXI, XV+XXI, XVII+XXI, XVII+XII, XVIII+XXI, XVIII+XXII, XX+XXI, XIV+XXIV, XV+XXIV, XV+XXVII, XVII+XXIV, V+XXIV, XVIII+XXIV, XX+XXIV XIV+XXI, XV+XXI, XVII+XXI, XVII+XII, XVIII+XXI, XVIII+XXII, XX+XXI, XIV+XXIV, XV+XXIV, XV+XXVII, XVII+XXIV, V+XXIV, XVIII+ XXIV, XX+XXIV

i hvert tilfelle 0,5+1; 1+0,5; 0,75+0,75 kg/ha aktivt stoff. in each case 0.5+1; 1+0.5; 0.75+0.75 kg/ha active substance.

Etter 3-4 uker ble det slått fast at blandingene viste en bedre herbicid virkning enn enkeltstoffene. After 3-4 weeks, it was established that the mixtures showed a better herbicidal effect than the individual substances.

Eksempel 5 Example 5

I et drivhus ble forskjellige planter ved en veksthøyde på 2-12 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl-metan- sulfonat In a greenhouse, different plants at a growth height of 2-12 cm were treated with the following active single substances and their mixtures as an emulsion: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl-methane- sulfonate

XV N-butin-l-yl-3-a-kloracetanilidXV N-butyn-1-yl-3-a-chloroacetanilide

XVII N-metoksymetyl-a-bromacet-2-metyl-6-tert.butylanilidXVII N-Methoxymethyl-a-bromoacet-2-methyl-6-tert.butylanilide

XVIII N-metoksymetyl-a-kloracet-2,6-dietylanilidXVIII N-Methoxymethyl-α-chloroacet-2,6-diethylanilide

XX N-butoksymetyl-a-kloracet-2,6-rdietylanilidXX N-butoxymethyl-α-chloroacet-2,6-diethylanilide

XXXI N-etoksykarboksymetyl-a-kloracet-2,6-diétylanilidXXXI N-ethoxycarboxymethyl-a-chloroacet-2,6-diethylanilide

i hvert tilfelle 0,25, 1,5 og 2 kg/ha aktivt stoff. in each case 0.25, 1.5 and 2 kg/ha of active substance.

I+VII+XVII, I+VII+XV, I+VII+XXXI, I+VII+XVIII, I+VII+XXI+VII+XVII, I+VII+XV, I+VII+XXXI, I+VII+XVIII, I+VII+XX

i hvert tilfelle 0,25+0,25+1,5; 0,25+1,5+0,25 og 1,5+0,25+0,25 kg/ha aktivt stoff. in each case 0.25+0.25+1.5; 0.25+1.5+0.25 and 1.5+0.25+0.25 kg/ha active substance.

Etter 12-15 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. After 12-15 days, it was established that the mixtures showed a better herbicidal effect at the same compatibility with the cultivated plants than the individual substances.

Forsøksresultatet vil fremgå' av den følgende tabell. The test result will appear in the following table.

Eksempel 6 Example 6

I et drivhus ble forskjellige planter ved en veksthøyde på 2-15 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon-dispersjon: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl-metan- sulfonat In a greenhouse, different plants at a growth height of 2-15 cm were treated with the following active single substances and their mixtures as emulsion-dispersion: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl-methane - sulfonate

XV N-butin-l-yl-3-a-kloracetanilidXV N-butyn-1-yl-3-a-chloroacetanilide

XVIIN-metoksymetyl-a-bromacet-2-metyl-6-tert.butyl-anilidXVIIN-Methoxymethyl-α-bromoacet-2-methyl-6-tert.butyl-anilide

XX N-butoksymetyl-a-kloracet-2,6-dietylaniiidXX N-butoxymethyl-α-chloroacet-2,6-diethylaniide

XXIX N-3-klorfenyl-karbaminsyre-4-klor-butin-2-y1-1-esterXXIX N-3-chlorophenyl-carbamic acid 4-chloro-butyn-2-y1-1-ester

XXXI N-etoksy-karboksymetyl-o£-kloracet.-2,6-dietylanilidXXXI N-ethoxy-carboxymethyl-o£-chloroacet.-2,6-diethylanilide

I+XXIX+XVII henholdsvis XVIII, XV, XX og XXXII+XXIX+XVII respectively XVIII, XV, XX and XXXI

i hvert tilfelle 0,25+0,25+1,5; 0,25+1,5+0,25 og 1,5+ 0,25+0,25 kg/ha aktivt stoff. in each case 0.25+0.25+1.5; 0.25+1.5+0.25 and 1.5+ 0.25+0.25 kg/ha active substance.

Eksempel 7 Example 7

I et drivhus ble forskjellige planter ved en veksthøyde på 2-10 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon-dispersjon-tankblanding: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl- metansulfonat In a greenhouse, different plants at a growth height of 2-10 cm were treated with the following active single substances and their mixtures as an emulsion-dispersion-tank mixture: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl - methanesulfonate

XXIV N-fenylkarbaminsyre-isopropyles'térXXIV N-phenylcarbamic acid isopropyl esters

XXXI N-etoksy-karboksymetyl-a-kloracet-2,6-dietylanilidXXXI N-ethoxy-carboxymethyl-a-chloroacet-2,6-diethylanilide

I+XXIV+XVII, I+XXIV+XXXII+XXIV+XVII, I+XXIV+XXXI

Etter 12-16 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. After 12-16 days, it was established that the mixtures showed a better herbicidal effect at the same compatibility with the cultivated plants than the individual substances.

Eksempel 8 Example 8

I et drivhus ble forkjellige planter ved en veksthøyde på 2-10 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon, dispersjon-tankblanding: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl-metan- sulfonat In a greenhouse, different plants at a growth height of 2-10 cm were treated with the following active single substances and their mixtures as emulsion, dispersion-tank mixture: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl -methane- sulfonate

VI N,N-di-n-propyltiolkarbaminsyre-etylesterVI N,N-di-n-propylthiocarbamic acid ethyl ester

\VII N-etyl-N-cykloheksyl-tiolkarbaminsyre-etylester\VII N-ethyl-N-cyclohexyl-thiocarbamic acid ethyl ester

IX N-etyl-N-bicyklo-(2,2,1)-heptyltiolkarbaminsyre-ety le ster IX N-ethyl-N-bicyclo-(2,2,1)-heptylthiocarbamic acid ethyl ester

XV N-butin-(l)-yl-(3)-a-kloracetanilidXV N-butyn-(1)-yl-(3)-α-chloroacetanilide

XVII N-metoksymetyl-a-bromacet-2-metyl-6-tert.butyl-anilid XVIII N-metoksymetyl-a-kloracet-2,6-dietyl-anilid XVII N-methoxymethyl-a-bromoacet-2-methyl-6-tert.butyl-anilide XVIII N-methoxymethyl-a-chloroacet-2,6-diethyl-anilide

XX N-butoksymetyl-a-kloracet-2,6-dietylanilidXX N-butoxymethyl-α-chloroacet-2,6-diethylanilide

XXI 2,2-diklor-propionsurt natriumXXI 2,2-dichloro-propionic acid sodium

XXIII 2,2,3,3-tetrafluor-propionsyre-natriumsaltXXIII 2,2,3,3-tetrafluoropropionic acid sodium salt

XXIV N-fenyl-karbaminsyre-isopropylesterXXIV N-phenyl-carbamic acid isopropyl ester

XXVI N-3-klorfenyl-karbaminsyre-butin-l-yl-3-esterXXVI N-3-Chlorophenyl-carbamic acid butyn-1-yl-3-ester

XXVIII 3-metoksykarbonylaminofenyl-N-(3'-metyl-fenyl)-karbamat XXIX N-3-klorfenyl-karbaminsyre-4-klor-butin-2-yl-l-ester XXVIII 3-methoxycarbonylaminophenyl-N-(3'-methyl-phenyl)-carbamate XXIX N-3-chlorophenyl-carbamic acid 4-chloro-butyn-2-yl-1-ester

XXX N-etoksy-karboksymetyl-a-kloracet-2,6-dietylanilidXXX N-ethoxy-carboxymethyl-α-chloroacet-2,6-diethylanilide

i hvert tilfelle 0,5ft 1 - 1,5.og 2 kg/ha aktivt stoff. in each case 0.5 ft 1 - 1.5 and 2 kg/ha of active substance.

I+VI, I-fVII, I+IX, VII+XV, VII+XVII, VII+VIII, VII+XX, VII+XXVIII, VII+XXIX, VII+XXXI, XVII+XXI, XVIII+XXX, XX+XXIII, XXIV+XVII, I+VI, I-fVII, I+IX, VII+XV, VII+XVII, VII+VIII, VII+XX, VII+XXVIII, VII+XXIX, VII+XXXI, XVII+XXI, XVIII+XXX, XX+ XXIII, XXIV+XVII,

XXVIII+XV, xxviii.ixviii,XXVIII+XXXI,XXXI+XXXXXVIII+XV, xxviii.ixviii,XXVIII+XXXI,XXXI+XXX

I hvert tilfelle 0,5+1,5; 1+1 og 1,5+0,5 kg/ha aktivt stoff. In each case 0.5+1.5; 1+1 and 1.5+0.5 kg/ha active substance.

Eksempel 9 Example 9

I et drivhus ble forskjellige planter ved en veksthøyde på 2-16 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som dispersjon-emulsjon-tankblanding: I 2-etoksy-2,3-dihydro-3,3-dimetyl-benzofuranyl-metan- sulfonat In a greenhouse, different plants at a growth height of 2-16 cm were treated with the following active single substances and their mixtures as dispersion-emulsion-tank mixture: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-benzofuranyl-methane - sulfonate

II l-fenyl-4-amino-5-klor-pyridazon-(6)II 1-phenyl-4-amino-5-chloro-pyridazone-(6)

VII N-ety1-N-cykloheksyl-tiolkarbaminsyre-etylesterVII N-Ethyl-N-Cyclohexyl Thiolcarbamic Acid Ethyl Ester

XXI 2,2-diklor-propionsurt natriumXXI 2,2-dichloro-propionic acid sodium

XXVIII 3-metoksykarbonylaminofenyl-N-((3 '-métyT-rfenyl)-XXVIII 3-Methoxycarbonylaminophenyl-N-((3 '-méthyT-rphenyl)-

karbamatcarbamate

XXIX N-3-klorfenyl-karbaminsyre-4-klor-butin-2-yl-l-ésterXXIX N-3-Chlorophenyl-carbamic acid-4-chloro-butyn-2-yl-1-ester

XXX a-klor-B-(4-klorfenyl)-propionsyre-metylesterXXX α-Chloro-B-(4-chlorophenyl)-propionic acid methyl ester

I+VII+XXIII, I+VII+XXIV, I+VII+XXVIII, I+VII+XXIX, I+VII+XXX, I+VII+XXI, VII+XXIV, VII+XXIX+XXX, VII+XXVIII+XXIII, I+VII+XXIII, I+VII+XXIV, I+VII+XXVIII, I+VII+XXIX, I+VII+XXX, I+VII+XXI, VII+XXIV, VII+XXIX+XXX, VII+XXVIII+ XXIII,

VII+XXI+II, VII+XXIII+II, VII+XXX+II, VII+XXIV+XXX, VII+XXIV+XXIII, VII+XXIV+XXIX, VII+XXVIII+XXI, og VII+XXVIII+XXX, VII+XXI+II, VII+XXIII+II, VII+XXX+II, VII+XXIV+XXX, VII+XXIV+XXIII, VII+XXIV+XXIX, VII+XXVIII+XXI, and VII+XXVIII+XXX,

Etter 12-15 dager ble det slått fast at blandingene viste en bedre herbicid virkning, vé|d samme forenlighet med kulturplantene enn enkeltstoffene. After 12-15 days, it was established that the mixtures showed a better herbicidal effect, with the same compatibility with the cultivated plants than the individual substances.

Eksempel 10 Example 10

I et drivhus ble forskjellige planter ved enyveksthøyde på 2-25. cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon, disipersjon: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl- metansulfonat In a greenhouse, different plants were grown at a single growth height of 2-25. cm treated with the following active single substances and their mixtures as emulsion, dispersion: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl- methanesulfonate

XXI 2, 2-diklor-propionsi'urt natriumXXI 2, 2-dichloro-propionic acid sodium

XXIII Natriumsaltet av 5712,3, 3-tetraf luor-propionsyreXXIII The sodium salt of 5712,3, 3-tetrafluoro-propionic acid

i hvert tilfelle 0,25,1,5 og 2 kg/ha aktivt stoffpj in each case 0.25, 1.5 and 2 kg/ha active substance pj

I+XVII+XXI, I+XXXI+XXIII, I+XVIII+XXX og I+XV+XXXI+XVII+XXI, I+XXXI+XXIII, I+XVIII+XXX and I+XV+XXX

Etter 12-15 dager ble det slått fast at blandingene viste en bedre herbicid virkning.ved samme forenlighet med kulturplantene enn enkeltstoffene. After 12-15 days, it was established that the mixtures showed a better herbicidal effect with the same compatibility with the cultivated plants than the individual substances.

Eksempel 11 Example 11

I et drivhus ble forskjellige planter ved en veksthøyde på 2-25 cm behandlet med de følgend'e\virksomme enkeltstoffer og deres blandinger som emulsjon, oljedispersjon: I 2-etoksy-2 , 3-dihydro-3 , 3-dimetyl-=5-benzof uranyl-metan- sulfonat In a greenhouse, different plants at a growth height of 2-25 cm were treated with the following single active substances and their mixtures as emulsion, oil dispersion: I 2-ethoxy-2 , 3-dihydro-3 , 3-dimethyl-=5 -benzofuranyl-methane- sulfonate

XVIII N-metoksymetometyl-a-kloracet-2,6-dietyl-anilid XXI 2,2-diklor-propionsurt natrium XVIII N-Methoxymethomethyl-a-chloroacetate-2,6-diethyl-anilide XXI 2,2-Dichloro-propionic acid sodium

XXIII Natriumsaltet av 2, 2, 3,3-tetrafluorpropionsyreXXIII The sodium salt of 2, 2, 3,3-tetrafluoropropionic acid

XXXII 2-(2-metyl-4-klorfeno'ks'y) -N-metoksy-acetamidXXXII 2-(2-Methyl-4-chlorophenoxy)-N-methoxy-acetamide

I+XXI+XXXII og I+XXIII+XVIII,I+XXI+XXXII and I+XXIII+XVIII,

Etter 10-14 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. After 10-14 days, it was established that the mixtures showed a better herbicidal effect at the same compatibility with the cultivated plants than the individual substances.

Forsøksresultatet vil fremgå av den følgende, tabell. The test result will appear in the following table.

Eksempel 12 Example 12

I et drivhus ble forskjellige planter ved en veksthøydeIn a greenhouse, different plants were grown at a growing height

på 2-18 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon, oljedispersjon: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl-metansulfonat of 2-18 cm treated with the following active single substances and their mixtures as emulsion, oil dispersion: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl-methanesulfonate

VI'N,N-di-n-propyl-tiolkarbaminsyre-etylesterVI'N,N-di-n-propyl thiolcarbamic acid ethyl ester

XIII N-(l,1-dimetyl-propionyl)-3,5-diklor-benzamidXIII N-(1,1-dimethyl-propionyl)-3,5-dichloro-benzamide

XXXVII Propionsyre-3,4-diklor-anilidXXXVII Propionic acid-3,4-dichloroanilide

XXXVIII 5-klor-4-metyl-2-propionamid-tiazolXXXVIII 5-chloro-4-methyl-2-propionamide-thiazole

i hvert tilfelle 0,25, 1,5 og 2 kg/ha aktivt stoff in each case 0.25, 1.5 and 2 kg/ha of active substance

I+VI+XXXVII, I+VI+XXXVIII, I+VI+XX, I+VI+XIII,I+VI+XXXVII, I+VI+XXXVIII, I+VI+XX, I+VI+XIII,

Etter 12-15 dag~e,r ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. After 12-15 days, it was established that the mixtures showed a better herbicidal effect at the same compatibility with the cultivated plants than the individual substances.

Eksempel 13 Example 13

I et drivhus ble forskjellige planter ved en veksthøyde på 2-17 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som oljedispersjon: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl-metan- sulfonat In a greenhouse, different plants at a growth height of 2-17 cm were treated with the following active single substances and their mixtures as an oil dispersion: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl-methane- sulfonate

XIII N-(l, 1-dimetyl-propihyjl)-3, 5-diklor-benzamid XV N-butin-(l)-yl-(3)-a-kloracetanilid XIII N-(1,1-dimethylpropyl)-3,5-dichlorobenzamide XV N-butyn-(1)-yl-(3)-a-chloroacetanilide

XVII N-metoksymetyl-a-bromacet-2-metyl-6-tert.butyl-anilid XVIII N-metbksymetyl- a-kloracet-2,6-dietylanilid XVII N-Methoxymethyl-α-bromoacet-2-methyl-6-tert.butyl-anilide XVIII N-Methoxymethyl-α-chloroacet-2,6-diethylanilide

XX N-butoksymetyvl-a-kloracet-2,6-dietylanilid XXXI N-etoksy-karboksymetyl-a-kloracet-2,6-dietylanilid XX N-butoxymethyl-a-chloroacet-2,6-diethylanilide XXXI N-ethoxy-carboxymethyl-a-chloroacet-2,6-diethylanilide

XXXII. 2-(2-metyl-4-klorfenoksy)-N-metoksy-acetamidXXXII. 2-(2-methyl-4-chlorophenoxy)-N-methoxyacetamide

XXXIV Metakrylsyre-3,4-diklor-anilidXXXIV Methacrylic acid-3,4-dichloroanilide

-i hvert, tilfelle 0,5, 1,5 og 2 kg/ha aktivt stoff. -in each case, 0.5, 1.5 and 2 kg/ha of active substance.

I+XIHpll+XV, I+XVII, I+XVIII, I+XX, I+XXXI, I+XXXII og I+XXXIVI+XIHpll+XV, I+XVII, I+XVIII, I+XX, I+XXXI, I+XXXII and I+XXXIV

i hvert tilfelle 0,5+1,5 og 1,5+0,5 kg/ha aktivt stoff. in each case 0.5+1.5 and 1.5+0.5 kg/ha of active substance.

Etter 12-15.dager ble det slått fast at blandingene viste en bedre, herbicid virkning ved samme forenlighet med kulturplantene enn [enkeltstoffene. After 12-15 days, it was established that the mixtures showed a better herbicidal effect at the same compatibility with the cultivated plants than the individual substances.

Eksempel 14 Example 14

I et drivhus ble forskjellige planter ved en veksthøyde på 2-10 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som dispersjon-emulsjon-tankblanding: I 2-etoksy-2,3-dihydro-3,3-dimety1-5-benzofurany1- metansulfonat In a greenhouse, different plants at a growth height of 2-10 cm were treated with the following active single substances and their mixtures as dispersion-emulsion-tank mixture: I 2-ethoxy-2,3-dihydro-3,3-dimethyl1-5-benzofurany1 - methanesulfonate

XXV N-3-klorfenyl-karbaminsyre-isopropylesterXXV N-3-chlorophenyl-carbamic acid isopropyl ester

XXVI N-3-klorfeny1-karbaminsyre-butin-l-y1-3-esterXXVI N-3-chlorophenyl-carbamic acid butyn-1-y1-3-ester

XXXIII a,a-dimetyl-valeriansyre-p-klor-anilidXXXIII a,a-dimethyl-valeric acid-p-chloro-anilide

XXXIV Metakrylsyre-3,4-diklor-anilidXXXIV Methacrylic acid-3,4-dichloroanilide

XXXV 2-metyl-pentansyre-3,4-diklor-anilidXXXV 2-methyl-pentanoic acid-3,4-dichloro-anilide

XXXVI 2-metyl-pentansyre-3-klor-4-metyl-anilidXXXVI 2-Methyl-pentanoic acid-3-chloro-4-methyl-anilide

I+XXXIII+XXIV, I+XXXIV+XXVI, I+XXXV+XXV og I+XXXVI+XXV,I+XXXIII+XXIV, I+XXXIV+XXVI, I+XXXV+XXV and I+XXXVI+XXV,

Eksempel 15 Example 15

I et drivhus ble forskjellige planter ved en veksthøyde på 1-18 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som pasta: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl- metansulfonat In a greenhouse, different plants at a growth height of 1-18 cm were treated with the following active single substances and their mixtures as pastes: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl- methanesulfonate

XXI 2, 2-diklor-propions(ur1?! natriumXXI 2, 2-dichloro-propions(ur1?! sodium

XXIII Natriumsaltet av 2,2,3,3-tetrafluorpropionsyre XXX a-klor-B-(4-klorfenyl)-propionsyre-metylester XXIII The sodium salt of 2,2,3,3-tetrafluoropropionic acid XXX α-chloro-B-(4-chlorophenyl)-propionic acid methyl ester

XXXII 2-(2-metyl-4-klor-fenoksy)-N-metoksy-acetamidXXXII 2-(2-methyl-4-chloro-phenoxy)-N-methoxy-acetamide

I+XXXII+XXI, I+XXXII+XXIII og I+XXXII+XX,I+XXXII+XXI, I+XXXII+XXIII and I+XXXII+XX,

Etter 12-15 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forénlighet med kulturplantene enn enkeltstoffene. After 12-15 days, it was established that the mixtures showed a better herbicidal effect at the same compatibility with the cultivated plants than the individual substances.

Eksempel 16 Example 16

på 2-12 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon-dispersjon-tankblanding: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl-metansulfonat of 2-12 cm treated with the following active single substances and their mixtures as emulsion-dispersion-tank mixture: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl-methanesulfonate

XVII N-metoksymetyl-a-bromacet-2-metyl-6-tert.butyl-anilidXVII N-Methoxymethyl-a-bromoacet-2-methyl-6-tert-butyl-anilide

XVIII N-metoksymetyl-a-kloracet-2,6-dietyl-anilidXVIII N-Methoxymethyl-a-chloroacet-2,6-diethyl-anilide

XXI 2,2-diklor-propionsurt natriumXXI 2,2-dichloro-propionic acid sodium

XXIII Natriumsaltet av 2,2,3,3-tetrafluor-propionsyreXXIII The sodium salt of 2,2,3,3-tetrafluoropropionic acid

XXIV N-feny1-karbaminsyre-isopropylesterXXIV N-phenyl-carbamic acid isopropyl ester

XXVIII 3-metoksykarbonylaminofenyl-N-(3'-mety1-feny1)-karbamatXXVIII 3-Methoxycarbonylaminophenyl-N-(3'-methyl-phenyl)-carbamate

XXIX N-3-klorfenyl-kafbaminsyre-4-klor-butin-2-yl-l-ester.XXIX N-3-Chlorophenyl-caffeic acid 4-chloro-butyn-2-yl-1-ester.

XXXI N-etoksy-karboksymety l- a-kloracet-2,6-dietylanilidXXXI N-ethoxy-carboxymethyl-a-chloroacet-2,6-diethylanilide

i hvert.tilfelle 0,25, 1,5 og 2 kg/ha aktivt stoff.in each case 0.25, 1.5 and 2 kg/ha of active substance.

I+VII+II, I+XXVIII+XVII, I+XXVIII+XXXI, I+XXVIII+XVIII,I+VII+II, I+XXVIII+XVII, I+XXVIII+XXXI, I+XXVIII+XVIII,

I+XXVIII+XX, I+XXVIII+XV, I+XVII+II, I+XXXI+II, I+XVIII+II,I+XXVIII+XX, I+XXVIII+XV, I+XVII+II, I+XXXI+II, I+XVIII+II,

I+XX+II, I+XV+II, VII+XXXIX+XXXI, VII+XXIV+XVII, VII+XXVIII+I+XX+II, I+XV+II, VII+XXXIX+XXXI, VII+XXIV+XVII, VII+XXVIII+

XVIII, VII+XXIV+II, VII+XXIX+II, VII+XXVIII+II, VII+XVII+XXI, VII+XXXI+XXX, VII+XVIII+XXIII, VII+XX+II, VII+XXVIII+XX, VII+XXVIII+XV, XVII+XXI+II, XXXI+XXIII+II, XVIII+XXX+II, XVIII, VII+XXIV+II, VII+XXIX+II, VII+XXVIII+II, VII+XVII+XXI, VII+XXXI+XXX, VII+XVIII+XXIII, VII+XX+II, VII+XXVIII+XX, VII+XXVIII+XV, XVII+XXI+II, XXXI+XXIII+II, XVIII+XXX+II,

XX+XXX+II, XV+XXX+II, VII+XV+II, XXIV+XVII+XXI, XXIX+XXXI+XXIII, XX+XXX+II, XV+XXX+II, VII+XV+II, XXIV+XVII+XXI, XXIX+XXXI+XXIII,

xxviii+xviii+xxx, xxviii+xx+ii, xxviii+xv+n, xxix+xxxiZ+ii, xxviii+xviii+xxx, xxviii+xx+ii, xxviii+xv+n, xxix+xxxiZ+ii,

XXVIII+XXXI+II, VII+XXVIII+XXXI,XXVIII+XXXI+II, VII+XXVIII+XXXI,

i hvert tilfelle 0,25+0,25+1,5; 0,25+1,5+0,25 og 1,5+0,25+0,25 kg/ha akt|vt stoff. in each case 0.25+0.25+1.5; 0.25+1.5+0.25 and 1.5+0.25+0.25 kg/ha active substance.

Etter 12-15 da'ger ble det slått fast at blandingene visteAfter 12-15 days it was determined that the mixtures showed

en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. a better herbicidal effect with the same compatibility with the cultivated plants than the individual substances.

Eksempel 17 Example 17

I et drivhus ble forskjellige planter ved en veksthøyde på 2-14 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon-dispersjon-tankblanding: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl- metansulfonat In a greenhouse, different plants at a growth height of 2-14 cm were treated with the following active single substances and their mixtures as an emulsion-dispersion-tank mixture: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl - methanesulfonate

XXI 2,2-diklor-propionsurt natriumXXI 2,2-dichloro-propionic acid sodium

XXVIII 3-metoksykarbonylaminofenyl-N-(3'-metyl-fenyl)-karbamat XXVIII 3-Methoxycarbonylaminophenyl-N-(3'-methyl-phenyl)-carbamate

XXIX N-3-klorfenyl-karbaminsyre-4-klor-butin-2-yl-l-ester XXX a-klor-B-(4-klorfenyl) -propionsyre-!metylester XXXIX Etyl-N-benzoyl-N-(3,4-diklorfenyl)-2-aminopropionat XXIX N-3-Chlorophenyl-carbamic acid 4-chloro-butyn-2-yl-1-ester XXX a-Chloro-B-(4-chlorophenyl)-propionic acid !methyl ester XXXIX Ethyl-N-benzoyl-N-(3 ,4-dichlorophenyl)-2-aminopropionate

i hvert tilfelle 0,5 - 1 - 1,5 og 2 kg/ha aktivt stoff. in each case 0.5 - 1 - 1.5 and 2 kg/ha of active substance.

I+XXXIX, II+XXXIX, VII+XXXIX, XXI+XXXIX, XXVIII+XXXIX, XXIX+XXXIX, XXX+XXXIX, I+XXXIX, II+XXXIX, VII+XXXIX, XXI+XXXIX, XXVIII+XXXIX, XXIX+XXXIX, XXX+XXXIX,

i hvert tilfelle 0,5+1,5; 1+1 og 1,(5+0,5 kg/ha aktivt stoff. in each case 0.5+1.5; 1+1 and 1,(5+0.5 kg/ha active substance.

Forsøksresultajtet vil fremgå av den følgende tabell. The test results will appear in the following table.

Eksempel 18 Example 18

I et drivhus ble forsøkskasser fyllt med leirholdig sand-jord., dg]forskjellige frø ble sådd. Deretter ble jorden behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon-dispersjon-tankblanding: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl- metansulfonat In a greenhouse, test boxes were filled with clayey sandy soil, and different seeds were sown. The soil was then treated with the following active single substances and their mixtures as an emulsion-dispersion-tank mixture: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl- methanesulfonate

III N,N-diisopropyl-tiolkarbaminsyre-2,3-diklorallylester IV N,N-diisopropyl-tiolkarbaminsyre-2,3,3-triklorallyl-ester III N,N-diisopropyl-thiocarbamic acid-2,3-dichloroallyl ester IV N,N-diisopropyl-thiocarbamic acid-2,3,3-trichloroallyl ester

VI N,N-di-n-propyl-tiolkarbamins'yre-etylesterVI N,N-di-n-propyl thiolcarbamic acid ethyl ester

IX N-bicyklo-(2 , 2 ,1) -heptyl4l-etyl-tiolkarbaminsyre-etylester IX N-bicyclo-(2,2,1)-heptyl-4-ethyl-thiocarbamic acid ethyl ester

XI N,N-dietyl-tiolkarbaminsyre-para-klor-benzylesterXI N,N-diethyl-thiocarbamic acid para-chloro-benzyl ester

XII N,N-diallyl-2-klor-acetamidXII N,N-diallyl-2-chloroacetamide

XIII N-(l,1-dimetyl-propyl)-3,5-diklor-benzamidXIII N-(1,1-dimethyl-propyl)-3,5-dichloro-benzamide

XVI o!-bromacet-2-metyl-6-tert .butyl-anilidXVI o!-bromoacet-2-methyl-6-tert.butyl-anilide

XVII N-metoksymety1- a-bromacet-2-metyl-6-tert.buty1-anilid XVIII N-metoksymetyl-a-kloracet-2,6-dietyl-anilid XVII N-methoxymethyl-α-bromoacet-2-methyl-6-tert.buty1-anilide XVIII N-methoxymethyl-α-chloroacet-2,6-diethylanilide

XIX N-isobutoksymetyl-a-kloracet-2,6-dimetyl-anilidXIX N-isobutoxymethyl-α-chloroacet-2,6-dimethylanilide

XX N-butoksymetyl-2-kloracet-2,6-dietylanilidXX N-butoxymethyl-2-chloroacet-2,6-diethylanilide

XXI 2,2-diklor-propionsurt natriumXXI 2,2-dichloro-propionic acid sodium

XXII Trikloreddiksjulqt natriumXXII Trichloroacetic julqt sodium

XXIV N-feny1-karbaminsyre-isbpropylesterXXIV N-phenyl-carbamic acid isbpropyl ester

i hvert tilfelle 0,25, 1,5 og 2 kg/ha aktivt stoff,in each case 0.25, 1.5 and 2 kg/ha of active substance,

og blandingene:and the mixtures:

I+III+XXXI, I+IV+XXXI, I+VII+XXXI, I+VIII+XXXI, I+X+XXXI, I+XI+XXXI, I+XXXI+XXI, I+XXXI+XXII, I+XXXI+II, I+XIII+XXI, I+XIII+II, I+XV+XXI, I+XV+XXII, I+XVII+XXII, I+XVII+II' III+XXIV+XV, III+XXI+II, IV+XXI+II, IV+XXII+II, III+XIII+XXI, III+XIII+II, IV+XVII+XXI, IV+XVII+II, IV+XXXI+XXII, I+III+XXXI, I+IV+XXXI, I+VII+XXXI, I+VIII+XXXI, I+X+XXXI, I+XI+XXXI, I+XXXI+XXI, I+XXXI+XXII, I+ XXXI+II, I+XIII+XXI, I+XIII+II, I+XV+XXI, I+XV+XXII, I+XVII+XXII, I+XVII+II' III+XXIV+XV, III+XXI+ II, IV+XXI+II, IV+XXII+II, III+XIII+XXI, III+XIII+II, IV+XVII+XXI, IV+XVII+II, IV+XXXI+XXII,

iv+xxiv+xiii, iv+xxiv+n, iv+xxiv+xxxi, vii+xxiv+xxxi, iv+xxiv+xiii, iv+xxiv+n, iv+xxiv+xxxi, vii+xxiv+xxxi,

VII+XXIV+XVII, VII+XXXI+XXI, VII+XXXI+II, VII+XXI+II, VII+XXII+II, X+XXIV+II, XI+XXIV+II, XIII+XXI+II, VII+XXIV+XVII, VII+XXXI+XXI, VII+XXXI+II, VII+XXI+II, VII+XXII+II, X+XXIV+II, XI+XXIV+II, XIII+XXI+II,

XV+XXI+II, XVII+XXII+II, XXIV+XII+XXIII, XXIV+XII+II, XXIV+XIII+XXI, XXIV+XIII+II, XXIV+XIII+XXIV, XXIV+XVII+II, XXIV+XXXI+XXI/, XXIV+XXXI+II og XXXI+XXI+II, XV+XXI+II, XVII+XXII+II, XXIV+XII+XXIII, XXIV+XII+II, XXIV+XIII+XXI, XXIV+XIII+II, XXIV+XIII+XXIV, XXIV+XVII+II, XXIV+ XXXI+XXI/, XXIV+XXXI+II and XXXI+XXI+II,

Eksempel 19 Example 19

I et drivhus ble forskjellige planter ved en veksthøyde pa7l2-12 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som oljedispersjon-emulsjon: I 2-etoksy-2,3-dihydro-3,3-dimetyl-5-benzofuranyl- metansulfonat In a greenhouse, different plants at a growth height of 712-12 cm were treated with the following single active substances and their mixtures as oil dispersion-emulsion: I 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl- methanesulfonate

II 1-fenyl-4-amino-5-klor-pyr ida zonII 1-phenyl-4-amino-5-chloro-pyr ida zone

XXI 2, 2-diklor-propionsurt nat>riumXXI 2, 2-Dichloro-propionic acid sodium

XXVIII 3-metoksykarbohylaminofenyl-N-(3'-metyl-fenyl)-XXVIII 3-methoxycarbylaminophenyl-N-(3'-methyl-phenyl)-

karbamatcarbamate

XXIXN-3-klorfenyl-karbaminsyre-4-klor-butin-2-yl-l^-esterXXIXN-3-Chlorophenyl-carbamic acid-4-chloro-butyn-2-yl-1^-ester

XXXIX Etyl-N-benzoyl-N-(3,4-diklorfenyl)-2-aminopropionat .XXXIX Ethyl-N-benzoyl-N-(3,4-dichlorophenyl)-2-aminopropionate .

I+II+XXXIX, I+VII+XXXIX, I+XXI+XXXIX, I+XXVIII+XiXXIX, I+XXIX+XXXIX, I+XXX+XXXIX, II+VII+XXXIX, II+XXI+XXXIX, II+XXIX+XXXIX, II+XXX+XXXIX, VII+XXIII+XXXIX, I+II+XXXIX, I+VII+XXXIX, I+XXI+XXXIX, I+XXVIII+XiXXIX, I+XXIX+XXXIX, I+XXX+XXXIX, II+VII+XXXIX, II+XXI+XXXIX, II+ XXIX+XXXIX, II+XXX+XXXIX, VII+XXIII+XXXIX,

VII+XXIX+XXXIX, VII+XXX+XXXIX, XXVIII+XXIX+XXXIX,VII+XXIX+XXXIX, VII+XXX+XXXIX, XXVIII+XXIX+XXXIX,

XXVIII+XXX+XXXIX^øg XXIX+XXX+XXXIX,XXVIII+XXX+XXXIX^and XXIX+XXX+XXXIX,

Etter 12-15 dager ble det slått fast at blandingene viste en bedre<r>nerbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. After 12-15 days, it was established that the mixtures showed a better<r>nerbicidal effect at the same compatibility with the cultivated plants than the individual substances.

Forsøksresultatet v'|il fremgå av den følgende tabell. The test result will appear in the following table.

Claims

Herbicide, characterized in that it contains a mixture ava) a compound with the formula

where R and R 1 mean lower alkyl, and/or b) a compound of the formula

where R means a lower alkyl, alkenyl, alkynyl, an optionally methyl-substituted cycloaliphatic residue, a bis- or tricycloaliphatic residue, R^ means a lower alkyl, alkenyl, alkynyl, X means oxygen or sulphur, R^ means an optionally with halogen substituted alkyl, alkenyl, alkynyl, phenyl or benzyl radical or a methyl-substituted phenyl or benzyl radical, and/orc) a compound of the formula

where R means a phenyl or benzyl radical optionally substituted by halogen, alkyl, alkyl, alkynyl, alkenyl, haloalkyl, haloalkynyl, haloalkenyl,

R^ means alkyl, phenyl, halophenyl, methylphenyl, nitro or aminobenzenesulfonyl, and/or d) a compound of the formula

where R means naphthyl, 5-chloro-4-methyl-thiazolyl, an optionally with .alpha.alkyl,. halogen-substituted phenyl or benzyl radical, alkyl, alkenyl, alkynyl, methoxy, R^ means hydrogen, alkyloxyalkyl, carboxycarboxymethyl, alkyl, alkenyl, alkynyl, where alkyloxy- . alkyl, alkyl, alkenyl, alkynyl may be substituted with halogen, R2 means alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, an optionally substituted phenyl or benzyl radical with carboxy, halogen, methyl, haloalkyl, α-naphthoxyethyl, diphenylmethyl, 4-chloro-2-methyl-phenoxymethyl, X = 0 or S, with the additional stipulation that R^ i the mixture d + f does not mean an alkyl, alkenyl, alkynyl residue, and/or) a compound with the formula

where R means alkyl, haloalkyl, benzSrhidoxy, a benzyl radical optionally substituted with halogen, alkyl, haloalkyl, X means hydrogen, halogen, R^ means alkyl, hydrogen bg the salts, a halogen-substituted alkyl, alkenyl, alkynyl and benzyl radical , and/or f) a compound with the formula

where X means an optionally substituted with hal <j> p <gen> alkylamino, dialkylamino, lkoxyalkylamino, lkoxyamino, alkylalkoxy-amino, α-hydroxy-6,6,6-trichloroethylamino, acetylamino, halo-acetylamino, acetoacetylamino, amino, dimethylformamidine , methylformamidine, aminotartronic acid diethyl ester, adipinamic acid, methoxy, -NH-CO-COOR, NH-COOR, where R means an optionally halogen-substituted alkyl or phenyl residue, Y means chlorine, bromine, methoxy, Z means hydrogen, methylhaloalkyl, alkoxy, and/or g) the compound