NO320124B1 - Magnetiske materialer - Google Patents

Magnetiske materialer Download PDF

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Publication number
NO320124B1
NO320124B1 NO19982865A NO982865A NO320124B1 NO 320124 B1 NO320124 B1 NO 320124B1 NO 19982865 A NO19982865 A NO 19982865A NO 982865 A NO982865 A NO 982865A NO 320124 B1 NO320124 B1 NO 320124B1
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NO
Norway
Prior art keywords
magnetic
materials
magnetic materials
rare earth
iron
Prior art date
Application number
NO19982865A
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English (en)
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NO982865L (no
NO982865D0 (no
Inventor
Alan Gordon Ian Jenner
Kamlesh Prajapati
Original Assignee
Univ Hull
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Filing date
Publication date
Application filed by Univ Hull filed Critical Univ Hull
Publication of NO982865D0 publication Critical patent/NO982865D0/no
Publication of NO982865L publication Critical patent/NO982865L/no
Publication of NO320124B1 publication Critical patent/NO320124B1/no

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C28/00Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/0302Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity characterised by unspecified or heterogeneous hardness or specially adapted for magnetic hardness transitions
    • H01F1/0306Metals or alloys, e.g. LAVES phase alloys of the MgCu2-type
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N35/00Magnetostrictive devices
    • H10N35/80Constructional details
    • H10N35/85Magnetostrictive active materials

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Hard Magnetic Materials (AREA)
  • Soft Magnetic Materials (AREA)
  • Valve Device For Special Equipments (AREA)

Description

Foreliggende oppfinnelse vedrører generelt magnetiske materialer og spesielt magnetiske materialer som utviser magnetostriktive egenskaper.
En kjent form for et slikt magnetisk materiale er et magnetisk jem-basert materiale som i tillegg til jern i kombinasjon innbefatter sjeldne jordarts-elementer i forskjellige meng-der. Jerninnholdet til materialet er ansvarlig for den høyere Curie-temperaturen til materialet. Magnetostriksjon kommer fra de sjeldne jordatrsmetallene. Sjeldne jordartsmetaller er ferromagnetiske ved meget lave temperaturer, d.v.s. 4K.
Et eksempel på slike materialer er materialer av Terfenol-typen som for eksempel er kjent fra: S.C. Busbridge, A.R. Piercy, "Domain configurations in the giant magneto-strictive TbxHolxFel.9 system in different easy axis regimes", Journal of Applied Physics, 1993, vol 73, nr. 10 Pt2A, side 5354-5356.
S.C. Busbridge, A.R. Piercy, "Magnetostriction and magnetization processes in TbxHolxFel.9", Journal of Magnetism and Magnetic materials, 1995, vol. 144, nr, Pt2, side 817-818.
S.C. Busbridge, A.R.Piercy, "Magnetomechanical properties and anisotropy compensa-tion in quaternary rare earth-iron materials of the type TbxDyyHozFe2", IEEE transac-tions on Magnetics, 1995, vol. 31, nr. 6Pt2, side 4044-4046.
EP 0 509 628 beskriver en magnetostriktiv legering av formelen TbxRyDyi.x.y(Fei. zMnz)w hvor x + y er mindre enn 1, 0,005<y<0,9,0,005<z<0,5, l,5^w^2,5 og R er minst en av Y, Ln, Ce, Pr, Nd og Sm.
Al-Jiboory M. et al., J. Appl. Phys., bind 73, nr. 10,1993, s. 6168-6170 omhandler Terfenol-D som har formelen Tbo,3Dyo,7Fe2.
I henhold til oppfinnelsen er det tilveiebragt et magnetisk materiale med formelen:
hvor 0<x<0.05,
Med henvisning til figuren, er det vist magnetisk induserte påkjenninger i materialene av den ovenfor beskrevne type, over et temperaturområde fra ca. 20°C til ca. 270°C. Den magnetiske påkjenningen er indusert av et forspenningsfelt på 120 A/m påført over materialet. Påkjenningen måles med påkjenningsmålere i enheter på ppm (parts per million). X\ i og Xi angir påkjenningen målt parallelt og loddrett på den magnetiske felt-retningen. Det ble undersøkt seks materialer, alle med generell formel:
Med x = 0.025, 0.050, 0.075, 0.100, 0.125 og 0.150.
For sammenligning ble det også undersøkt to materialer som ikke inneholdt serium
Det vil sees at når x = 0.025 og 0.050 hadde materialene en økt magnetisk indusert på-kjenning over det meste av det undersøkte temperaturområdet. Dette var spesielt tilfelle for materialet x = 0.025.
Den langtrekkende magnetiske ordenen i et materiale blir brutt ned ved Curie-temperaturen ved termisk energi. Desto sterkere utbytningsinteraksjonen er mellom de magnetiske momentene, jo mer termisk energi er nødvendig for å bryte opp den magnetiske ordenen. I det vesentlige betyr dette at det er nødvendig med en høyere temperatur. Over sin Curi-temperatur blir materialene paramagnetiske, det vil si ikke-magnetiske. Magnetostriktive egenskaper oppstår fra avhengigheten av endringshastig-heten til de magnetiske egenskapene som er tilstede i materialet. Dersom det ikke er noen magnetisering, er det heller ingen magnetostriksjon.
Tilsettingen av små menger serium opprettholder den magnetisk induserte påkjenningen i materialet, i det vesentlige over verdiene for den opprinnelige Terfenolforbindelsen for temperaturer opptil 250°C. Dette er overraskende siden konvensjonell teori forutsier at erstatning av jern med ioner av sjeldne jordartsmetaller kan medføre et fall i Curie-temperaturen og derved en ødeleggelse av de magnetostriktive egenskaper ved høyere temperaturer.

Claims (1)

  1. Magnetisk materiale, karakterisert ved at materialet har en kjemisk formel:
    hvor 0<x<0.05.
NO19982865A 1995-12-21 1998-06-19 Magnetiske materialer NO320124B1 (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9526177A GB2308384B (en) 1995-12-21 1995-12-21 Magnetic materials
PCT/GB1996/003118 WO1997023913A1 (en) 1995-12-21 1996-12-17 Magnetic materials

Publications (3)

Publication Number Publication Date
NO982865D0 NO982865D0 (no) 1998-06-19
NO982865L NO982865L (no) 1998-08-19
NO320124B1 true NO320124B1 (no) 2005-10-31

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Family Applications (1)

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NO19982865A NO320124B1 (no) 1995-12-21 1998-06-19 Magnetiske materialer

Country Status (9)

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US (1) US5997660A (no)
EP (1) EP0868754B1 (no)
AU (1) AU712526B2 (no)
CA (1) CA2240958C (no)
DE (1) DE69604422T2 (no)
GB (1) GB2308384B (no)
NO (1) NO320124B1 (no)
WO (1) WO1997023913A1 (no)
ZA (1) ZA9610779B (no)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1322599C (zh) * 2003-09-28 2007-06-20 北京航空航天大学 新型宽温域巨磁致伸缩材料及其制备方法
GB0519843D0 (en) * 2005-09-29 2005-11-09 Univ Cambridge Tech Magnetocaloric refrigerant

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1513298A (en) * 1975-09-05 1978-06-07 Furukawa Electric Co Ltd Wear-resisting high permeability alloy
US4152178A (en) * 1978-01-24 1979-05-01 The United States Of America As Represented By The United States Department Of Energy Sintered rare earth-iron Laves phase magnetostrictive alloy product and preparation thereof
US4308474A (en) * 1979-11-14 1981-12-29 The United States Of America As Represented By The Secretary Of The Navy Rare earth-iron magnetostrictive materials and devices using these materials
GB2093480B (en) * 1981-02-25 1984-10-17 Nippon Steel Corp Non-oriented silicon steel sheet
EP0144112B1 (en) * 1983-10-26 1989-09-27 General Motors Corporation High energy product rare earth-transition metal magnet alloys containing boron
EP0338597B1 (en) * 1984-02-28 1995-01-11 Sumitomo Special Metals Co., Ltd. Permanent magnets
US5125988A (en) * 1987-03-02 1992-06-30 Seiko Epson Corporation Rare earth-iron system permanent magnet and process for producing the same
DE3883038T2 (de) * 1987-03-23 1994-01-05 Tokin Corp Verfahren zur Herstellung eines anisotropen seltene Erden-Eisen-Bor-Verbundmagneten mit Hilfe von bandähnlichen Spänen aus einer seltene Erden-Eisen-Bor-Legierung.
US5336337A (en) * 1991-02-05 1994-08-09 Kabushiki Kaisha Toshiba Magnetrostrictive materials and methods of making such materials

Also Published As

Publication number Publication date
NO982865L (no) 1998-08-19
WO1997023913A1 (en) 1997-07-03
DE69604422D1 (de) 1999-10-28
EP0868754A1 (en) 1998-10-07
CA2240958C (en) 2003-09-30
AU1185397A (en) 1997-07-17
AU712526B2 (en) 1999-11-11
GB2308384B (en) 1999-09-15
EP0868754B1 (en) 1999-09-22
GB9526177D0 (en) 1996-02-21
CA2240958A1 (en) 1997-07-03
GB2308384A (en) 1997-06-25
ZA9610779B (en) 1998-06-22
NO982865D0 (no) 1998-06-19
US5997660A (en) 1999-12-07
DE69604422T2 (de) 2000-05-11

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