NO312553B1 - Fremgangsmåte ved fremstilling av lagringsstabil asfaltholdig blanding og derved erholdte blanding, bituminös emulsjon,asfaltholdig materiale samt en veibeleggsblanding - Google Patents
Fremgangsmåte ved fremstilling av lagringsstabil asfaltholdig blanding og derved erholdte blanding, bituminös emulsjon,asfaltholdig materiale samt en veibeleggsblanding Download PDFInfo
- Publication number
- NO312553B1 NO312553B1 NO19981025A NO981025A NO312553B1 NO 312553 B1 NO312553 B1 NO 312553B1 NO 19981025 A NO19981025 A NO 19981025A NO 981025 A NO981025 A NO 981025A NO 312553 B1 NO312553 B1 NO 312553B1
- Authority
- NO
- Norway
- Prior art keywords
- mixture
- asphalt
- polymer
- weight
- temperature
- Prior art date
Links
- 239000010426 asphalt Substances 0.000 title claims abstract description 169
- 239000000203 mixture Substances 0.000 title claims abstract description 147
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 title claims description 13
- 239000000839 emulsion Substances 0.000 title claims description 6
- 229920000642 polymer Polymers 0.000 claims abstract description 90
- 239000011230 binding agent Substances 0.000 claims abstract description 44
- 229920002959 polymer blend Polymers 0.000 claims abstract description 43
- 238000000034 method Methods 0.000 claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- 238000002156 mixing Methods 0.000 claims abstract description 21
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 38
- 230000035515 penetration Effects 0.000 claims description 14
- -1 acyl sulfates Chemical class 0.000 claims description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- 235000011149 sulphuric acid Nutrition 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 3
- 229920000359 diblock copolymer Polymers 0.000 claims description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 2
- 229920000428 triblock copolymer Polymers 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 abstract description 7
- 239000000178 monomer Substances 0.000 abstract description 7
- 239000012530 fluid Substances 0.000 abstract description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 54
- 239000012071 phase Substances 0.000 description 43
- 239000007789 gas Substances 0.000 description 29
- 238000003860 storage Methods 0.000 description 27
- 229910052757 nitrogen Inorganic materials 0.000 description 25
- 239000002253 acid Substances 0.000 description 22
- 239000000047 product Substances 0.000 description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 239000007788 liquid Substances 0.000 description 19
- 230000003472 neutralizing effect Effects 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000006277 sulfonation reaction Methods 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000010306 acid treatment Methods 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 150000007530 organic bases Chemical class 0.000 description 2
- 125000001477 organic nitrogen group Chemical group 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000002925 chemical effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000000879 optical micrograph Methods 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 238000000954 titration curve Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
- E01C7/26—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
- E01C7/267—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre with sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
- E01C7/26—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
- E01C7/265—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre with rubber or synthetic resin, e.g. with rubber aggregate, with synthetic resin binder
Landscapes
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Road Paving Structures (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Working-Up Tar And Pitch (AREA)
- Inorganic Insulating Materials (AREA)
- Control Of Motors That Do Not Use Commutators (AREA)
- Photoreceptors In Electrophotography (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Body Structure For Vehicles (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/525,898 US5549744A (en) | 1995-09-08 | 1995-09-08 | Pavement Binder |
US08/664,610 US5637141A (en) | 1995-09-08 | 1996-06-18 | Pavement binder and method of making same (LAW441) |
PCT/US1996/014072 WO1997009390A1 (en) | 1995-09-08 | 1996-09-04 | Pavement binder and method of making same |
Publications (3)
Publication Number | Publication Date |
---|---|
NO981025D0 NO981025D0 (no) | 1998-03-09 |
NO981025L NO981025L (no) | 1998-05-08 |
NO312553B1 true NO312553B1 (no) | 2002-05-27 |
Family
ID=27061943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19981025A NO312553B1 (no) | 1995-09-08 | 1998-03-09 | Fremgangsmåte ved fremstilling av lagringsstabil asfaltholdig blanding og derved erholdte blanding, bituminös emulsjon,asfaltholdig materiale samt en veibeleggsblanding |
Country Status (13)
Country | Link |
---|---|
US (1) | US5637141A (es) |
EP (1) | EP0848738B1 (es) |
JP (1) | JP2000516969A (es) |
AT (1) | ATE211499T1 (es) |
AU (1) | AU703209B2 (es) |
CA (1) | CA2228592A1 (es) |
DE (1) | DE69618648T2 (es) |
DK (1) | DK0848738T3 (es) |
ES (1) | ES2170868T3 (es) |
MY (1) | MY112338A (es) |
NO (1) | NO312553B1 (es) |
PT (1) | PT848738E (es) |
WO (1) | WO1997009390A1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6031029A (en) * | 1997-03-31 | 2000-02-29 | Ergon, Incorporated | Asphalt compositions and methods of preparation thereof |
CA2235727C (en) * | 1997-06-17 | 2008-12-23 | Imperial Oil | Low temperature pavement binders and methods of their preparation |
US6362257B1 (en) | 1999-08-27 | 2002-03-26 | Crafco, Incorporated | Pavement patch material |
KR100478126B1 (ko) * | 2001-12-04 | 2005-03-21 | 주식회사 엘지화학 | 선형 이중 블록 공중합체를 포함하는 아스팔트 조성물 |
US20060089429A1 (en) * | 2004-10-22 | 2006-04-27 | Fina Technology, Inc. | Use of inorganic acids with crosslinking agents in polymer modified asphalts |
US8921490B2 (en) * | 2009-06-30 | 2014-12-30 | Henkel US IP LLC | Ultrafast heat/room temperature adhesive composition for bonding applications |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4514308A (en) * | 1983-07-29 | 1985-04-30 | Clampitt Richard L | Sulfonated asphalt |
US4591611A (en) * | 1984-09-20 | 1986-05-27 | W. R. Grace & Co. | Ionomeric polymer compositions |
US4741868A (en) * | 1985-03-04 | 1988-05-03 | Phillips Petroleum Company | Production of sulfonated asphalt |
US5348994A (en) * | 1992-03-05 | 1994-09-20 | Exxon Research & Engineering Co. | Polymer-modified functionalized asphalt compositions and methods of preparation (C-2747) |
US5288773A (en) * | 1992-03-05 | 1994-02-22 | Exxon Research And Engineering Company | Sulfonated unhydrogenated copolymers of styrene and butadiene |
US5248407A (en) * | 1992-07-16 | 1993-09-28 | Exxon Research And Engineering Company | Storage stable polymer modified asphalt paving binder |
US5549744A (en) * | 1995-09-08 | 1996-08-27 | Exxon Research And Engineering Company | Pavement Binder |
-
1996
- 1996-06-18 US US08/664,610 patent/US5637141A/en not_active Expired - Lifetime
- 1996-09-04 PT PT96931449T patent/PT848738E/pt unknown
- 1996-09-04 WO PCT/US1996/014072 patent/WO1997009390A1/en active IP Right Grant
- 1996-09-04 AU AU70127/96A patent/AU703209B2/en not_active Ceased
- 1996-09-04 DE DE69618648T patent/DE69618648T2/de not_active Expired - Fee Related
- 1996-09-04 ES ES96931449T patent/ES2170868T3/es not_active Expired - Lifetime
- 1996-09-04 AT AT96931449T patent/ATE211499T1/de not_active IP Right Cessation
- 1996-09-04 CA CA002228592A patent/CA2228592A1/en not_active Abandoned
- 1996-09-04 DK DK96931449T patent/DK0848738T3/da active
- 1996-09-04 JP JP09511315A patent/JP2000516969A/ja not_active Ceased
- 1996-09-04 EP EP96931449A patent/EP0848738B1/en not_active Expired - Lifetime
- 1996-09-07 MY MYPI96003706A patent/MY112338A/en unknown
-
1998
- 1998-03-09 NO NO19981025A patent/NO312553B1/no unknown
Also Published As
Publication number | Publication date |
---|---|
NO981025D0 (no) | 1998-03-09 |
EP0848738A1 (en) | 1998-06-24 |
AU7012796A (en) | 1997-03-27 |
DE69618648T2 (de) | 2002-09-12 |
EP0848738B1 (en) | 2002-01-02 |
JP2000516969A (ja) | 2000-12-19 |
CA2228592A1 (en) | 1997-03-13 |
MY112338A (en) | 2001-05-31 |
ES2170868T3 (es) | 2002-08-16 |
AU703209B2 (en) | 1999-03-18 |
US5637141A (en) | 1997-06-10 |
DK0848738T3 (da) | 2002-03-25 |
NO981025L (no) | 1998-05-08 |
WO1997009390A1 (en) | 1997-03-13 |
EP0848738A4 (en) | 1998-12-16 |
DE69618648D1 (de) | 2002-02-28 |
PT848738E (pt) | 2002-06-28 |
ATE211499T1 (de) | 2002-01-15 |
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