NO307698B1 - Process for desulfurizing a gas mixture containing H2S and SO2 with recovery of these compounds in the form of sulfur - Google Patents

Process for desulfurizing a gas mixture containing H2S and SO2 with recovery of these compounds in the form of sulfur

Info

Publication number
NO307698B1
NO307698B1 NO913957A NO913957A NO307698B1 NO 307698 B1 NO307698 B1 NO 307698B1 NO 913957 A NO913957 A NO 913957A NO 913957 A NO913957 A NO 913957A NO 307698 B1 NO307698 B1 NO 307698B1
Authority
NO
Norway
Prior art keywords
sulphur
catalyst
compounds
gaseous mixture
desulfurizing
Prior art date
Application number
NO913957A
Other languages
Norwegian (no)
Other versions
NO913957L (en
NO913957D0 (en
Inventor
Andre Philippe
Robert Voirin
Original Assignee
Elf Exploration Prod
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Elf Exploration Prod filed Critical Elf Exploration Prod
Publication of NO913957L publication Critical patent/NO913957L/en
Publication of NO913957D0 publication Critical patent/NO913957D0/en
Publication of NO307698B1 publication Critical patent/NO307698B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • B01D53/8615—Mixtures of hydrogen sulfide and sulfur oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0426—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
    • C01B17/0434—Catalyst compositions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0426—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
    • C01B17/0439—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion at least one catalyst bed operating below the dew-point of sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
  • Treating Waste Gases (AREA)
  • Industrial Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

A method for desulphurising a gaseous mixture which contains a low overall concentration of H2?S and SO2? in a mol ratio of H2?S:SO2? of about 2:1, and recovering said compounds in the form of sulphur, wherein said gaseous mixture is contracted with a catalyst which is a promoter of the sulphur-forming CLAUS reaction between H2?S and SO2? and comprises at least one end portion consisting of a composite catalytic mass obtained by combining alumina with at least one compound of a metal selected from titanium, yttrium, lanthanum and rare earth metals having an atomic number between 58 and 71. The gaseous mixture to be desulphurised is brought into contact with the catalyst at a temperature which is lower than the dew point of the sulphur thereby produced, preferably at between 120 C and 170 C, so that the sulphur is deposited on the catalyst.
NO913957A 1990-02-13 1991-10-09 Process for desulfurizing a gas mixture containing H2S and SO2 with recovery of these compounds in the form of sulfur NO307698B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9001649A FR2658091B1 (en) 1990-02-13 1990-02-13 PROCESS FOR DESULFURIZING A GAS MIXTURE CONTAINING H2S AND SO2 WITH RECOVERY OF SUCH COMPOUNDS IN THE SULFUR FORM.
PCT/FR1991/000101 WO1991012201A1 (en) 1990-02-13 1991-02-11 Method for desulphurising a gaseous mixture containing h2s and so2 and recovering said compounds in the form of sulphur

Publications (3)

Publication Number Publication Date
NO913957L NO913957L (en) 1991-10-09
NO913957D0 NO913957D0 (en) 1991-10-09
NO307698B1 true NO307698B1 (en) 2000-05-15

Family

ID=9393631

Family Applications (1)

Application Number Title Priority Date Filing Date
NO913957A NO307698B1 (en) 1990-02-13 1991-10-09 Process for desulfurizing a gas mixture containing H2S and SO2 with recovery of these compounds in the form of sulfur

Country Status (12)

Country Link
EP (1) EP0466900B1 (en)
JP (1) JP3287843B2 (en)
AT (1) ATE133396T1 (en)
CA (1) CA2050497C (en)
DE (1) DE69116615T2 (en)
DK (1) DK0466900T3 (en)
ES (1) ES2085470T3 (en)
FR (1) FR2658091B1 (en)
NO (1) NO307698B1 (en)
PL (1) PL165925B1 (en)
RU (1) RU2062638C1 (en)
WO (1) WO1991012201A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2702673B1 (en) * 1993-03-16 1995-04-28 Elf Aquitaine Process for removing the H2S contained in a gas in a concentration of less than 5% by volume with recovery of this H2S in the form of sulfur.
FR2734809B1 (en) * 1995-05-30 1997-07-18 Elf Aquitaine CATALYTIC DESULFURATION PROCESS OF A GAS CONTAINING THE H2S AND SO2 COMPOUNDS AND POSSIBLY COS AND / OR CS2, WITH RECOVERY OF THE SAID COMPOUNDS IN THE FORM OF SULFUR AND A CATALYST FOR THE IMPLEMENTATION OF THE SAID PROCESS
DE60226580D1 (en) * 2002-06-25 2008-06-26 Ford Global Tech Llc SOX trap for diesel and lean-burn vehicles
CN113600171B (en) * 2021-07-30 2022-06-21 南京工业大学 CO catalytic reduction industrial flue gas SO2Catalyst for preparing sulfur, preparation method and application

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4054642A (en) * 1973-08-30 1977-10-18 Rhone-Poulenc Industries Process for the treatment of gases containing various derivatives of sulphur
DE3526706A1 (en) * 1985-07-25 1987-01-29 Linde Ag Process and reactor for the catalytic conversion of hydrogen sulphide to elemental sulphur
FR2589082B1 (en) * 1985-10-25 1989-12-01 Elf Aquitaine PROCESS FOR REMOVAL OF SULFUR COMPOUNDS CONTAINED IN A WASTE GAS, PARTICULARLY FROM A CLAUS SULFUR FACTORY, WITH RECOVERY OF SUCH SULFUR COMPOUNDS

Also Published As

Publication number Publication date
DE69116615D1 (en) 1996-03-07
DE69116615T2 (en) 1996-09-19
PL165925B1 (en) 1995-03-31
FR2658091B1 (en) 1992-05-07
FR2658091A1 (en) 1991-08-16
CA2050497C (en) 1999-12-07
EP0466900A1 (en) 1992-01-22
CA2050497A1 (en) 1991-08-14
NO913957L (en) 1991-10-09
RU2062638C1 (en) 1996-06-27
JPH04505446A (en) 1992-09-24
PL289053A1 (en) 1991-08-26
WO1991012201A1 (en) 1991-08-22
JP3287843B2 (en) 2002-06-04
DK0466900T3 (en) 1996-06-10
ES2085470T3 (en) 1996-06-01
ATE133396T1 (en) 1996-02-15
EP0466900B1 (en) 1996-01-24
NO913957D0 (en) 1991-10-09

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