DESCRIPTION
Method for closing wells
The invention relates to a method corresponding to the preamble of claim 1.
For reasons including economic considerations, the use of gas or oil wells is limited in time, abandoned wells having to be reliably sealed in order to prevent liquid or gaseous substances that are possibly environmentally harmful, in particular contain hydrocarbons, from escaping and spreading unchecked. A comparative task is also faced when, for whatever reasons, a sealed well is to be reopened and put to use.
A series of techniques are known for sealing wells, in particular for setting well seals, the implementation of which includes the use of a heat source, in many cases making use of the thermite reaction known per se, which forms the basis of aluminothermal welding and is used extensively in track construction for welding the ends of rails. The thermite reaction is a redox reaction, in which aluminium is used as a reducing agent for reducing iron(III) oxide to iron. The reaction products of this highly exothermic reaction are elemental iron and a slag of aluminium oxide, which are initially in a molten state, the slag floating on the iron because of its lower density. The starting product of the thermite reaction is a powdered substance mixture consisting of aluminium and iron oxide, known as the welding portion, the heat that is required for initiating the reaction being applied by means of a chemical or electrical detonating means.
WO 2013/135583 A2 discloses a method for permanently sealing a well and/or partially removing parts of a wall of the well, wherein surrounding materials and/or parts of the wall of the well at a chosen location of the well are melted by using an ignitable compound that is suitable for producing an exothermic reaction, and forming a seal of the well at this location once they have cooled down. The compound mentioned may be a thermite mixture, which releases the heat required in the course of the aluminothermic reaction. In order to spatially confine the region that is influenced by the heat released, extending from the location at which a seal is to be created, the thermite mixture, provided with an igniting head, lies directly against a heatresistant plate-shaped element consisting of ceramic or glass from above and below within the well, and the heatresistant element in turn lies against a likewise plateshaped sealing element from above and below. While the two heat-resistant elements spatially confine the thermal effect of the reaction in the longitudinal direction of the well, the two sealing elements are intended to produce a seal above and below the reaction site of the thermite reaction and are made of appropriate materials. The actual permanent seal of the well is formed by a substance mixture consisting of the reaction products of the thermite reaction and parts of the wall of the well and of the rock surrounding the well. In view of the density of the iron developed as a result of the reaction, which is high in comparison with the materials of the plate-shaped elements performing the function underneath of a support for the reaction mentioned, its mass and in particular its initial temperature, there are uncertainties as to whether the elements mentioned can perform sufficiently reliably the functions assigned to them in the context of this concept.
US 2015/0368542 A1 discloses a method for closing and opening gas or oil wells in which a thermite mix is used as a heat source in conjunction with a damping agent intended for lowering the temperature of the thermite reaction, such as for example sand. The thermite mix is used in the form of blocks, in order to ensure a homogeneous state of mixing, a number of blocks being put together and intended to influence the local reaction temperature occurring in the thermite reaction by means of the composition of the blocks, to be specific the proportion of the damping agent. According to this document, a permanent seal or plug of the well consists of an alloy of bismuth and germanium, which makes it possible to set suitable melting temperatures, the composition of the multiple blocks that are used simultaneously and have different compositions being based on the task to be achieved, to be specific whether such a seal is to be set or removed. Taking into consideration the fact that the characteristics of the rock along the well, in particular the local heat dissipating conditions, are often not sufficiently known, there are also uncertainties with regard to the temperatures occurring locally as a result of the thermite reaction.
It is characteristic of these known methods that a seal consisting of the reaction products of the thermite reaction is to be formed at a predetermined location of the well, possibly incorporating parts of the wall of the well, the region along the well in which there is an input of heat from the thermite reaction being confined from above and below by inserting structural elements with an insulating effect. This requires an at least temporarily effective seal of the well at the bottom, which is protected by the intermediate arrangement of a refractory layer that is not impaired by the temperatures of the thermite reaction. This seal forms the basis for the thermite reaction and it must be suitable for reliably withstanding all of the mechanical loads that are produced by the thermite reaction, caused by the density of the molten iron and thermal loads caused by the reaction temperature. It should be taken into consideration here that the properties of the rock adjacent to the wall of the well are not always known sufficiently for the question of heat input, and the associated spatial formation of a heat input zone. This in turn is of significance for the temperature zone produced by the reaction. In particular, it must be ensured that the thermite melt is prevented from running out into the well. It is not ensured in all cases that such a temporary seal can dependably withstand all of the mechanical and thermal loads.
WO 2011/151271 A1 discloses a method and a device for setting a seal or for removing a seal of gas or oil wells, wherein a cylindrical plug consisting of steel bears a eutectic bismuth alloy on the outside and is designed on the inside for detachable connection to a heat source. The heat source may be an electrical heat source or alternatively the heat required may also be provided by means of a chemical reaction. For setting a seal, the plug bearing the alloy mentioned is lowered into the well to the location at which a seal is to be set, wherein the alloy is subsequently melted by supplying heat, the annular space between the wall of the well and the plug is filled under the effect of gravitational force and a seal of the annular space forms as a result of volume expansion after cooling down has occurred. The heat source can subsequently be removed. For removing such a seal, such a heat source is introduced into the seal, the alloy that fills the annular space being melted by an input of heat, so that it comes away from the wall of the well and the seal can subsequently be removed from the well.
The object of the invention is to devise a method of the type referred to at the beginning with a view to producing reproducible process conditions for an underlying aluminothermic reaction as a heat source and the production of a reliable seal of a well that is stable over time, wherein in particular thermite melt is reliably prevented from running out into the well. This object is achieved in the case of such a method by the features of the characterizing part of claim 1.
It is accordingly essential to the invention that, for setting a seal, two reactions are used one after the other in time, to be specific, as preparation in a first step, a thermochemical, in particular exothermic reaction, which is aimed at the formation of a refractory shaped body, which forms a tight seal of the well on a supporting structure created within the well. This shaped body also forms at the respective location the basis on which, in a second step, the subsequent aluminothermic main reaction is carried out, the reaction products of which form the permanent seal of the well. It is of essential importance that the reactants of the thermochemical reaction are selected on the basis of producing a shaped body which is not melted at the temperatures of the main reaction and with which in particular undercutting by molten steel is prevented. The supporting structure must have such characteristics that any loads resulting from the thermochemical reaction are withstood and a shaped body that is suitable for plugging the well in a sealing manner can be formed. The shaped body forms a basis for the main reaction which, in the course of the aluminothermic reaction thereof, makes it possible on the basis of the local heat dissipating conditions for the wall of the well and/or parts of a tubular of the well to be melted, though spreading of the thermite melt in the longitudinal direction of the well is reliably prevented by the shaped body just as excessive thermal influencing of the supporting structure is reliably prevented.
According to the features of claim 2, the supporting structure is formed by a temporary sealing element which is overlaid by a refractory layer. The sealing element must be fixed here in a suitable way within the well.
According to the features of claim 3, the reactants of the thermochemical reaction are chosen on the basis of achieving the effect that the shaped body lies against the wall of the well in a sealing manner, and that there is a solid connection therewith which can withstand loads, but on the other hand, unlike in the case of the main reaction, melting of the same is avoided.
According to the features of claim 4, the reactants of the thermochemical reaction are chosen on the basis of achieving the effect that the shaped body lies against the wall of the well in a sealing manner, and that there is a solid connection therewith which can withstand loads, but on the other hand, unlike in the case of the plugging reaction, melting of the same is avoided.
According to the features of claim 5, the thermochemical reaction is an aluminothermic reaction, the reactants of which additionally contain a damping agent that lowers the reaction temperature. The reactants of the aluminothermic reaction are used in the form of granules or powder, it being possible for the reaction sequence, in particular including the reaction temperature, to be influenced by means of the quantitative composition and also the grain size distribution. The aim here is to obtain a moulded body with a material structure in the manner of a metal/metal-oxide matrix which binds in the reaction products, which in any event can no longer be melted by the subsequent main reaction. The temperature that develops thereby can also be estimated, as can its influence on the supporting structure mentioned, by the amount of the reactants underlying this aluminothermic reaction and their composition.
According to the features of claim 6, the characteristics of the reactants in the course of the aluminothermic reaction that forms the thermochemical reaction are set so as to suppress, at least substantially, a segregation of slag, iron and other reaction products. Under given heat dissipating conditions of the wall of the well or of the tubular of the well, this can be achieved by providing rapid cooling, the slag solidifying first because of its high melting point, with the effect that a sponge-like material skeleton is created before segregation of the various components can occur. A shaped body formed in this way is in any event unable to be completely melted once again by the subsequent aluminothermic plugging reaction.
The uncertainties concerning the function of the supporting structure that exist because of the unknown local heat dissipating conditions of the well are consequently countered by the formation of a shaped body which, on the basis of its material-related characteristics, withstands the thermal and mechanical loads of the plugging reaction.