NO20013696D0 - Tetrafluoroethylene / hexafluoropropylene copolymers with better ductility - Google Patents
Tetrafluoroethylene / hexafluoropropylene copolymers with better ductilityInfo
- Publication number
- NO20013696D0 NO20013696D0 NO20013696A NO20013696A NO20013696D0 NO 20013696 D0 NO20013696 D0 NO 20013696D0 NO 20013696 A NO20013696 A NO 20013696A NO 20013696 A NO20013696 A NO 20013696A NO 20013696 D0 NO20013696 D0 NO 20013696D0
- Authority
- NO
- Norway
- Prior art keywords
- tetrafluoroethylene
- terminal groups
- product
- copolymer
- hexafluoropropene
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title abstract 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 title abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- 230000004927 fusion Effects 0.000 abstract 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 238000005245 sintering Methods 0.000 abstract 2
- 239000004812 Fluorinated ethylene propylene Substances 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- 238000005469 granulation Methods 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920009441 perflouroethylene propylene Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/06—Rod-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
- B29K2027/18—PTFE, i.e. polytetrafluorethene, e.g. ePTFE, i.e. expanded polytetrafluorethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof
- B29L2031/3462—Cables
Abstract
The invention relates to a fluorinated ethylene propylene copolymer which is processed from the melt by fusion granulation and which consists essentially of monomer units of 78 to 95 wt. % tetrafluoroethylene, 5 to 22 wt. % hexafluoropropene and not more than 3 mol % fluorinated monomers that can be copolymerised with a mixture of tetrafluoroethylene and hexafluoropropene. Said copolymer has a molar ratio of weight average to number average of less than 2, has less than 80 unstable terminal groups per 1x10<6> carbon atoms and is produced by aqueous emulsion polymerisation. The copolymer is coagulated after polymerisation and then agglomerated. The agglomerate is isolated and dried to form a free flowing product, partial sintering being prevented. Said product is brought into contact with an effective amount of fluorine at a temperature between 60 DEG C and the preliminary sintering temperature, whereby unstable terminal groups are converted into stable terminal groups. The fusion granulate is advantageously treated with ammonia or a compound which liberates ammonia, in water. The product can be used for coating wires and cables.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11778099P | 1999-01-29 | 1999-01-29 | |
DE19903657A DE19903657A1 (en) | 1999-01-29 | 1999-01-29 | Tetrafluoroethylene/hexafluoropropylene copolymers useful in production of wires and cables and as structural materials for halls have increased drawability and avoid difficulty in controlling metal impurity levels |
PCT/EP2000/000528 WO2000044797A1 (en) | 1999-01-29 | 2000-01-24 | Tetrafluoro ethylene / hexafluoro propylene copolymers with better ductility |
Publications (2)
Publication Number | Publication Date |
---|---|
NO20013696D0 true NO20013696D0 (en) | 2001-07-27 |
NO20013696L NO20013696L (en) | 2001-09-28 |
Family
ID=26051581
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO20013696A NO20013696L (en) | 1999-01-29 | 2001-07-27 | Tetrafluoroethylene / hexafluoropropylene copolymers with better ductility |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP1165632B2 (en) |
KR (1) | KR20010089893A (en) |
CN (1) | CN1142948C (en) |
AT (1) | ATE253086T1 (en) |
AU (1) | AU2293200A (en) |
BR (1) | BR0007853A (en) |
CA (1) | CA2360025A1 (en) |
CZ (1) | CZ20012751A3 (en) |
HU (1) | HUP0105071A3 (en) |
IL (1) | IL144541A0 (en) |
NO (1) | NO20013696L (en) |
PL (1) | PL349004A1 (en) |
TR (1) | TR200102130T2 (en) |
WO (1) | WO2000044797A1 (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE60113249T2 (en) * | 2000-05-31 | 2006-06-29 | E.I. Dupont De Nemours And Co., Wilmington | METHOD FOR ROTATING FORMING MELTED EXTRUDED TFE / PAVE COPOLYMERS |
DE60226655D1 (en) * | 2001-04-26 | 2008-06-26 | Daikin Ind Ltd | Powdered fluorine-containing polymer and method of preparation thereof and coated article |
KR100726318B1 (en) | 2001-12-04 | 2007-06-11 | 다이킨 고교 가부시키가이샤 | Molding Material for Ozone-Resistant Articles and Ozone-Resistant Injection-Molded Articles |
US6703464B2 (en) | 2002-01-17 | 2004-03-09 | Daikin America, Inc. | Flourine-containing copolymer |
US6743508B2 (en) | 2002-01-17 | 2004-06-01 | Daikin America, Inc. | Fep pellet |
DE60314663T2 (en) * | 2002-11-08 | 2008-02-28 | E.I. Du Pont De Nemours And Co., Wilmington | IMPLEMENTATION OF FLUORO POLYMER MELTS |
US6838545B2 (en) | 2002-11-08 | 2005-01-04 | E. I. Du Pont De Nemours And Company | Reaction of fluoropolymer melts |
US7122609B2 (en) | 2003-05-14 | 2006-10-17 | E. I. Du Pont De Nemours And Company | High melt flow fluoropolymer |
DE602004027068D1 (en) | 2003-11-20 | 2010-06-17 | Daikin Ind Ltd | PROCESS FOR PREPARING FLUOROUS POLYMERS AND FLUOROUS POLYMERS |
JP5298853B2 (en) | 2006-10-20 | 2013-09-25 | ダイキン工業株式会社 | Fluorine-containing copolymer and molded product |
US20080161435A1 (en) * | 2006-12-21 | 2008-07-03 | E. I. Du Pont De Nemours And Company | Extrusion of a Foamable Fluoropolymer |
US20080149899A1 (en) | 2006-12-21 | 2008-06-26 | E. I. Du Pont De Nemours And Company | Foamable Fluoropolymer Composition |
US20080153936A1 (en) | 2006-12-21 | 2008-06-26 | E. I. Du Pont De Nemours And Company | Foamed Fluoropolymer Article |
CN101998968B (en) * | 2008-04-14 | 2012-08-29 | 旭硝子株式会社 | Production method of polytetrafluoroethylene fine powder |
CN102070740B (en) * | 2010-11-16 | 2012-10-03 | 巨化集团公司 | Preparation method of fluorine-containing microemulsion |
KR101591615B1 (en) * | 2011-09-22 | 2016-02-03 | 다이킨 고교 가부시키가이샤 | Laminate body and method for producing laminate body |
CN109320646B (en) * | 2017-07-31 | 2020-08-11 | 中昊晨光化工研究院有限公司 | Preparation method of fluorinated ethylene propylene resin with excellent melting uniformity in extrusion processing process |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0222945B1 (en) * | 1985-11-08 | 1992-01-02 | E.I. Du Pont De Nemours And Company | Melt-processible tetrafluoroethylene/perfluoroolefin copolymers and processes for preparing them |
CA2140869C (en) * | 1992-08-28 | 2005-03-29 | George Richard Chapman, Jr. | Low-melting tetrafluoroethylene copolymer and its uses |
-
2000
- 2000-01-24 KR KR1020017009470A patent/KR20010089893A/en not_active Application Discontinuation
- 2000-01-24 BR BR0007853-0A patent/BR0007853A/en not_active IP Right Cessation
- 2000-01-24 AU AU22932/00A patent/AU2293200A/en not_active Abandoned
- 2000-01-24 CN CNB008031819A patent/CN1142948C/en not_active Expired - Lifetime
- 2000-01-24 TR TR2001/02130T patent/TR200102130T2/en unknown
- 2000-01-24 CA CA002360025A patent/CA2360025A1/en not_active Abandoned
- 2000-01-24 EP EP00901592.6A patent/EP1165632B2/en not_active Expired - Lifetime
- 2000-01-24 PL PL00349004A patent/PL349004A1/en unknown
- 2000-01-24 IL IL14454100A patent/IL144541A0/en unknown
- 2000-01-24 CZ CZ20012751A patent/CZ20012751A3/en unknown
- 2000-01-24 WO PCT/EP2000/000528 patent/WO2000044797A1/en not_active Application Discontinuation
- 2000-01-24 HU HU0105071A patent/HUP0105071A3/en unknown
- 2000-01-24 AT AT00901592T patent/ATE253086T1/en not_active IP Right Cessation
-
2001
- 2001-07-27 NO NO20013696A patent/NO20013696L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
ATE253086T1 (en) | 2003-11-15 |
CZ20012751A3 (en) | 2002-02-13 |
CN1337970A (en) | 2002-02-27 |
EP1165632B2 (en) | 2019-10-02 |
IL144541A0 (en) | 2002-05-23 |
PL349004A1 (en) | 2002-06-17 |
HUP0105071A3 (en) | 2003-07-28 |
HUP0105071A2 (en) | 2002-04-29 |
EP1165632B1 (en) | 2003-10-29 |
BR0007853A (en) | 2001-10-23 |
TR200102130T2 (en) | 2001-12-21 |
KR20010089893A (en) | 2001-10-12 |
CA2360025A1 (en) | 2000-08-03 |
CN1142948C (en) | 2004-03-24 |
AU2293200A (en) | 2000-08-18 |
EP1165632A1 (en) | 2002-01-02 |
WO2000044797A1 (en) | 2000-08-03 |
NO20013696L (en) | 2001-09-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FC2A | Withdrawal, rejection or dismissal of laid open patent application |