NO138720B - PRESSURE SENSITIVE, TOUR, TWO-LAYER TYPE REGISTRATION MATERIAL WITH ACID TRANSMISSION LAYER - Google Patents
PRESSURE SENSITIVE, TOUR, TWO-LAYER TYPE REGISTRATION MATERIAL WITH ACID TRANSMISSION LAYER Download PDFInfo
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- NO138720B NO138720B NO3708/73A NO370873A NO138720B NO 138720 B NO138720 B NO 138720B NO 3708/73 A NO3708/73 A NO 3708/73A NO 370873 A NO370873 A NO 370873A NO 138720 B NO138720 B NO 138720B
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- weight
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- mixture
- acid
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims description 17
- 239000002253 acid Substances 0.000 title 1
- 230000005540 biological transmission Effects 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000012876 carrier material Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 32
- 238000000576 coating method Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 13
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 12
- 239000002775 capsule Substances 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000011592 zinc chloride Substances 0.000 description 6
- 235000005074 zinc chloride Nutrition 0.000 description 6
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229960000892 attapulgite Drugs 0.000 description 4
- 229910052625 palygorskite Inorganic materials 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920001756 Polyvinyl chloride acetate Polymers 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 206010015719 Exsanguination Diseases 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 1
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- ZKURGBYDCVNWKH-UHFFFAOYSA-N [3,7-bis(dimethylamino)phenothiazin-10-yl]-phenylmethanone Chemical compound C12=CC=C(N(C)C)C=C2SC2=CC(N(C)C)=CC=C2N1C(=O)C1=CC=CC=C1 ZKURGBYDCVNWKH-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- GWOWVOYJLHSRJJ-UHFFFAOYSA-L cadmium stearate Chemical compound [Cd+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O GWOWVOYJLHSRJJ-UHFFFAOYSA-L 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- FRVCGRDGKAINSV-UHFFFAOYSA-L iron(2+);octadecanoate Chemical compound [Fe+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRVCGRDGKAINSV-UHFFFAOYSA-L 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
- 235000002867 manganese chloride Nutrition 0.000 description 1
- 229940099607 manganese chloride Drugs 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
Landscapes
- Color Printing (AREA)
- Medicinal Preparation (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Description
Det foreligger tallrike forslag når det gjelder registreringssystemer som er basert på kjemiske fargereaksjoner. Hos slike registreringssystemer er hvert av de to over hverandre liggende blad i et registreringssett forsynt med et sjikt på There are numerous proposals regarding registration systems based on chemical color reactions. In such registration systems, each of the two overlapping sheets in a registration set is provided with a layer of
de overflater som berører hverandre. Disse sjiktene som be- the surfaces that touch each other. These layers which be-
rører hverandre ved bruk, inneholder hver en fargereaksjons-komponent som under skrivetrykk forbinder seg med den til- touch each other during use, each contains a color reaction component which, during printing, connects with the
svarende komponent i det andre sjiktet, hvorved de to kom- corresponding component in the second layer, whereby the two com-
ponentene reagerer kjemisk under dannelse av en farget markering. the ponents react chemically to form a colored marking.
Slike registreringssystemer har forskjellige fordeler sammen- Such registration systems have various advantages over
lignet med de systemer som beror på overføring av allerde i sjiktet nærværende fargestoffer. De skriftfremkallende sjikt til papirene i et slikt registreringssett er fargeløse eller meget lyst fargede og søler ikke til hendene. Registrerings-effekten er ytterst selektiv, dvs. registrering fås bare når to blad fra samme system kommer til å ligge over hverandre. similar to the systems that depend on the transfer of already present dyes in the layer. The writing-developing layers of the papers in such a registration set are colorless or very brightly colored and do not spill to the hands. The registration effect is extremely selective, i.e. registration is only obtained when two sheets from the same system come to lie on top of each other.
Ved utvelging av reaksjonspartnerne som kommer til anvendelse, When selecting the reaction partners to be used,
kan forskjellige markeringer oppnås. Fargen til de således erholdte markeringer kan utnyttes til arkiveringsformål eller til andre organisatoriske formål. different markings can be achieved. The color of the thus obtained markings can be used for archiving purposes or for other organizational purposes.
Hos et i praksis kjent registreringssystem av denne type er undersiden til hvert øvre blad forsynt med et sjikt som inne- With a registration system of this type known in practice, the underside of each upper leaf is provided with a layer which contains
holder et organisk kromogent materiale som f.eks. "krystallfiolettlakton", oppløst i en olje, mens skriftmottakings- holds an organic chromogenic material such as "crystal violet lactone", dissolved in an oil, while letter-receiving
sjiktet består av et adsorpsjonsdyktig leire-mineral. Oljen er innleiret i det øvre bladets sjikt i form av fine dråper. the layer consists of an adsorbable clay mineral. The oil is embedded in the upper layer of the leaf in the form of fine droplets.
Denne olje presses under skrivetrykket ut av sjiktet og over- This oil is pressed under the printing pressure out of the layer and over-
føres til skriftmottakingsbladet, hvor det der nærværende "krystallfiolettlakton" reagerer med leiremineralet under dan- is taken to the letter receiving blade, where the "crystal violet lactone" present there reacts with the clay mineral during the
neise av den fargede markeringen. Ifølge en eldre utførelses-form av et slikt reaksjonsregistreringsmateriale var oljedråpene gjennomgående innesluttet i et sjikt av et filmdannende bindemiddel. Det viser seg imidlertid at slike papir har en tendens til "utbløing" ("Ausbluten"), dvs. at oljen kan gå ut av sjiktet sammen med fargestoffproduktet uten skrivetrykk og enten fremkalle en fargeendring i fargemottakingssjiktet eller diffundere gjennom bærematerialet og farge dette når den andre siden av bladet oppviser et skriftmottakingssjikt. noise of the colored marking. According to an older embodiment of such a reaction recording material, the oil droplets were completely enclosed in a layer of a film-forming binder. However, it turns out that such paper has a tendency to "bleed out" ("Ausbluten"), i.e. the oil can leave the layer together with the dye product without printing and either cause a color change in the color receiving layer or diffuse through the carrier material and color this when it the other side of the blade exhibits a writing-receiving layer.
P.g.a. dette har man i en ny utførelsesform først innelukket oljedråpene hver for seg i en kapsel i en første arbeidsgang, hvilke kapsler består av en vegg av et filmdannende bindemiddel. I en andre arbeidsgang har man deretter anvendt en dispersjon av slike kapsler for fremstilling av overføringssjik-tet. Da diameteren til slike kapsler bare er noen hundredels millimeter, og da veggtykkelsen til disse kapslene er enda mindre, blir kapselveggene dannet av bare noen molekyl-sjikt. For å redusere diffusjonen, og da fremfor alt mindre molekyler, gjennom slike tynne kapselvegger, ble det foreslått å tette kapselveggene ved innleiring av andre stoffer eller ved påføring av ytterligere overtrekk. Because of. in a new embodiment, the oil droplets are first enclosed individually in a capsule in a first work step, which capsules consist of a wall of a film-forming binder. In a second work step, a dispersion of such capsules was then used to produce the transfer layer. As the diameter of such capsules is only a few hundredths of a millimetre, and as the wall thickness of these capsules is even smaller, the capsule walls are formed from only a few molecular layers. In order to reduce the diffusion, and above all smaller molecules, through such thin capsule walls, it was proposed to seal the capsule walls by embedding other substances or by applying additional coatings.
Et registreringsmateriale som beskrives i US-patent nr. 3.491.111 inneholder det kromogene utgangsmaterialet i oppløst for inn-kapslet i mikrokapsler. Ved anvendelse av trykk under skri-vingen destrueres kapselveggene, slik at en adsorpsjon av løs-ningen på mottakingsmassen finner sted. Derved oppstår farge-reaksjonen hvorunder det forflyttede fargestoffet foreligger i flytende form på mottakingsmassen. Heri angis et motsatt prinsipp av foreliggende oppfinnelse, hvor Lewis-syre over-føres til sjiktmassen som inneholder det kromogene utgangsmaterialet. Reaksjonskomponentene foreligger i fast form. A recording material described in US Patent No. 3,491,111 contains the chromogenic starting material in solution for encapsulation in microcapsules. When pressure is applied during writing, the capsule walls are destroyed, so that adsorption of the solution onto the receiving mass takes place. Thereby the color reaction occurs during which the displaced dye is present in liquid form on the receiving mass. Herein, an opposite principle of the present invention is stated, where Lewis acid is transferred to the bed mass containing the chromogenic starting material. The reaction components are available in solid form.
Fremstillingen av slike kapsler foretas bare i noen få spe-sialiserte fabrikker, og man innser lett at dette, samt de nødvendige mange arbeidsprosessene betydelig fordyrer fremstillingen av et slikt registreringspapir. The production of such capsules is only carried out in a few specialized factories, and it is easy to realize that this, as well as the necessary many work processes, significantly increase the production of such a registration paper.
Oppfinnelsen har til formål å fremskaffe et registreringsmateriale som oppviser fordelene med de kjente reaksjons-registreringssystemene uten derved å få med andre ulemper på kjøpet. The purpose of the invention is to provide a registration material which exhibits the advantages of the known reaction registration systems without thereby adding other disadvantages to the purchase.
Oppfinnelsen tar således sikte på å fremskaffe et registreringsmateriale som består av minst to over hverandre liggende blad, hvorved hvert blad på sidene som berører hverandre, The invention thus aims to provide a registration material consisting of at least two overlapping sheets, whereby each sheet on the sides that touch each other,
er forsynt med et sjikt som hvert inneholder en reaksjonskom-ponent som uten medvirkning av løsningsmiddel ved berøring med hverandre gir en kjemisk fargereaksjon, og hvorved reaksjons-komponenten til det overliggende blad under skrivetrykket is provided with a layer which each contains a reaction component which, without the involvement of solvent, when in contact with each other produces a chemical color reaction, whereby the reaction component of the overlying leaf under the printing pressure
overføres til det derunder liggende blad. Oppfinnelsen består i at skriftmottakingssjiktet på oversiden til det undre bladet inneholder et organisk kromogent materiale som danner et fargestoff på i og for seg kjent måte ved berøring med surt reagerende stoffer under molekylomleiring, hvorved fargestoffproduktet bindes fast til bærematerialet til det underste bladet, og at det under skrivetrykk i alt vesentlig fullstendig overførbare sjiktet inneholder det surt reagerende stoffet på undersiden til det øvre bladet. transferred to the underlying leaf. The invention consists in that the writing-receiving layer on the upper side of the lower leaf contains an organic chromogenic material which forms a dye in a manner known per se by contact with acid-reactive substances during molecular rearrangement, whereby the dye product is firmly bound to the carrier material of the lower leaf, and that the under letterpress the essentially completely transferable layer contains the acid-reactive substance on the underside of the upper leaf.
Overfor den kjente teknikkens stand har foreliggende oppfinnelse den fordel at det kromogene utgangsmateiralet er bundet fast til bærematerialet i uoppløst tilstand og ikke overføres på mottakingssjiktet. Derved økes fargeintensi-teten fordi fargekonsentrasjonen på skriftsstedet utnyttes fullt. Dertil har kopiene som oppnås ved hjelp av regi-streringsmaterialet ifølge oppfinnelsen en høy lysstabili-tet siden det ikke anvendes et oppløsningsmiddel for det kromogene materialet, idet en organisk forbindelse er vesentlig mer stabil i uoppløst enn i oppløst tilstand. Compared to the state of the art, the present invention has the advantage that the chromogenic starting material is firmly bound to the carrier material in an undissolved state and is not transferred onto the receiving layer. Thereby, the color intensity is increased because the color concentration at the writing location is fully utilized. In addition, the copies obtained using the recording material according to the invention have a high light stability since no solvent is used for the chromogenic material, an organic compound being significantly more stable in undissolved than in dissolved state.
Oppfinnelsen skal ytterligere anskueliggjøres ved hjelp av følgende eksempler. The invention shall be further illustrated by means of the following examples.
Eksempel 1 Example 1
A. Et maskinglatt bærepapir med en beleggvekt på ca. 40 g/m o blir på en side forsynt med et sjikt som er fremstilt ifblge nedenstående appliseringsblanding: A. A machine-smooth carrier paper with a coating weight of approx. 40 g/m o is provided on one side with a layer produced according to the application mixture below:
5 vektsdeler bis-(p-hydroksy-fenyl)-propan 5 parts by weight of bis-(p-hydroxy-phenyl)-propane
2o vektsdeler sinkstearat 20 parts by weight zinc stearate
lo vektsdeler jernklorid lo parts by weight ferric chloride
lo vektsdeler polyvinylklorid/acetat-kopolymerisat lo parts by weight polyvinyl chloride/acetate copolymer
(f.eks. "vinylite VYHH") (eg "vinylite VYHH")
15o vektsdeler aceton 150 parts by weight of acetone
Bindemidlet oppioses i aceton, og de bvrige bestanddeler tilsettes i den angitte rekkefolge og males omhyggelig sammen. Den erholdte blandingen blir påfbrt således at man etter tbrking får en The binder is dissolved in acetone, and the remaining ingredients are added in the order indicated and carefully ground together. The resulting mixture is applied in such a way that after use you get a
22
beleggvekt på 4 g/m . coating weight of 4 g/m .
B. På et blad av samme bærepapir påfbras og tbrkes en blanding med etterfølgende sammensetning, hvorved man får en beleggvekt på B. On a sheet of the same carrier paper, a mixture with the following composition is applied and used, resulting in a coating weight of
6 g/m<2>: 6 g/m<2>:
3 vektsdeler rodamin "B-lakton" 3 parts by weight rhodamine "B-lactone"
5 vektsdeler akrylharpiks 5 parts by weight acrylic resin
15 vektsdeler kaolin 15 parts by weight kaolin
15o vektsdeler bensin 15o parts by weight petrol
De angitte bestanddelene blandes med hverandre som angitt for blanding A. Man legger de to bladene slik over hverandre at sidene som er påfbrt et sjikt, berbrer-hverandre, og hvorved det under B beskrevne bladet befinner seg underst. Ved skriving på den frie siden til det 'ovre bladet A får man på sjiktsiden av det underste bladet en rød registrering.. The specified components are mixed with each other as specified for mixture A. The two sheets are placed one above the other so that the sides that have been coated with a layer are touching each other, and whereby the sheet described under B is at the bottom. When writing on the free side of the upper leaf A, you get a red registration on the layer side of the lower leaf.
Eksempel 2 Example 2
A. På samme måte som beskrevet i eksempel 1 fremstilles en blanding med nedenstående sammensetning: lo vektsdeler "attapulgit" A. In the same way as described in example 1, a mixture with the following composition is prepared: lo parts by weight "attapulgite"
2o vektsdeler jernstearat 20 parts by weight of iron stearate
lo vektsdeler sinkklorid lo parts by weight zinc chloride
4 vektsdeler etylcellulose 4 parts by weight of ethyl cellulose
15o vektsdeler etylalkohol 15o parts by weight of ethyl alcohol
Blandingen påfbres slik at man får en beleggvekt på 2 g/m 2. The mixture is applied so that a coating weight of 2 g/m 2 is obtained.
B. For fremstilling av et skriftmottakings-sjikt tjener nedenstående appli seringsblanding: 3 vektsdeler "krystallfiolettlakton"B. For the production of a letter-receiving layer, the following application mixture serves: 3 parts by weight "crystal violet lactone"
5 vektsdeler etylcellulose 5 parts by weight of ethyl cellulose
2o vektsdeler kalsiumkarbonat 20 parts by weight calcium carbonate
loo vektsdeler aceton loo parts by weight acetone
Beleggvekten er 4 g/m 2. Ved registrering som beskrevet under eksempel 1 får man en blå skrift. The coating weight is 4 g/m 2. When registering as described under example 1, you get a blue font.
Eksempel 3 Example 3
A. På samme måte som beskrevet i eksempel 1 fremstilles en blanding med nedenstående sammensetning: A. In the same way as described in example 1, a mixture with the following composition is prepared:
5 vektsdeler bis-(p-hydroksy-fenyl)-propan 5 parts by weight of bis-(p-hydroxy-phenyl)-propane
2o vektsdeler blystearat 20 parts by weight of lead stearate
lo vektsdeler sinkklorid lo parts by weight zinc chloride
15 vektsdeler titandioksyd 15 parts by weight titanium dioxide
5 vektsdeler polyvinylklorid-acetat 5 parts by weight polyvinyl chloride acetate
2o vektsdeler aceton 20 parts by weight of acetone
Blandingen påfores bærepapiret slik at man får en beleggvekt The mixture is applied to the carrier paper so that a coating weight is obtained
2 2
på 4 g/m . of 4 g/m .
B. For fremstilling av et skriftmottakings-sjikt tjener nedenstående appliseringsblanding: 3 vektsdeler "krystallfiolettlakton" B. For the production of a letter-receiving layer, the following application mixture serves: 3 parts by weight "crystal violet lactone"
5 vektsdeler polyvinylklorid-acetat 5 parts by weight polyvinyl chloride acetate
2o vektsdeler titandioksyd 20 parts by weight of titanium dioxide
15o vektsdeler trikloretylen 150 parts by weight trichlorethylene
Beleggvekten er 4 g/m2. Ved registrering som beskrevet i eksempel 1 får man en blå skrift. The coating weight is 4 g/m2. When registering as described in example 1, you get a blue font.
Eksempel 4 Example 4
A. På samme måte som beskrevet i eksempel 1 fremstilles en blanding med nedenstående sammensetning: A. In the same way as described in example 1, a mixture with the following composition is prepared:
lo vektsdeler sinkklorid lo parts by weight zinc chloride
2o vektsdeler kadmiumstearat 20 parts by weight of cadmium stearate
3o vektsdeler kalsiumkarbonat 30 parts by weight calcium carbonate
6 vektsdeler polyvinylacetat 6 parts by weight polyvinyl acetate
5 vektsdeler fosforsyre 5 parts by weight phosphoric acid
2oo vektsdeler trikloretylen 2oo parts by weight trichlorethylene
B. For fremstilling av et skriftmottakings-sjikt tjener nedenstående appliseringsblanding: 5 vektsdeler "malakittgrbnnlakton" B. For the production of a letter-receiving layer, the following application mixture serves: 5 parts by weight "malachite grbnnlactone"
lo vektsdeler karboksy-metylcellulose lo parts by weight carboxy-methylcellulose
2o vektsdeler kalsiumkarbonat 20 parts by weight calcium carbonate
2oo vektsdeler vann 2oo parts by weight of water
Beleggvekten er 4 g/m 2. Ved registrering som beskrevet i eksempel 1 får man en grbnn skrift. The coating weight is 4 g/m 2. When registering as described in example 1, you get a gray font.
Eksempel 5 Example 5
A. På samme måte som beskrevet i eksempel 1 fremstilles en blandii med nedenstående sammensetning: 5 vektsdeler "attapulgit" A. In the same way as described in example 1, a mixture is prepared with the following composition: 5 parts by weight "attapulgite"
lo vektsdeler aluminiumstearat lo parts by weight aluminum stearate
-lo-vektsdeler sinkklorid -lo parts by weight zinc chloride
3o vektsdeler kaolin 30 parts by weight of kaolin
5 vektsdeler gummi-arabikum 5 parts by weight of gum arabic
2oo vektsdeler vann 2oo parts by weight of water
Blandingen påfbres bærepapiret slik at man får en beleggvekt The mixture is applied to the carrier paper so that a coating weight is obtained
på 3 g/m . of 3 g/m .
B. For fremstilling av et skriftmottakings-sjikt tjener nedenstående appliseringsblanding: 3 vektsdeler "krystallfiolettlakton" B. For the production of a letter-receiving layer, the following application mixture serves: 3 parts by weight "crystal violet lactone"
1 vektsdel benzoyl leukometylenblå 1 part by weight of benzoyl leucomethylene blue
5 vektsdeler polyvinylalkohol 5 parts by weight polyvinyl alcohol
2o vektsdeler titandioksyd 19o vektsdeler vann 2o parts by weight titanium dioxide 19o parts by weight water
Beleggvekten er 7 g/m 2. Ved registrering som beskrevet i eksempel 1 får man en blå skrift. The coating weight is 7 g/m 2. When registering as described in example 1, you get a blue print.
Eksempel 6 Example 6
A. På samme måte som beskrevet i eksempel 1 fremstilles en blandin med nedenstående sammensetning: A. In the same way as described in example 1, a mixture is prepared with the following composition:
lo vektsdeler bis-(p-hydroksy-fenyl)-propan lo parts by weight of bis-(p-hydroxy-phenyl)-propane
2o vektsdeler sinkstearat 20 parts by weight zinc stearate
lo vektsdeler bariumklorid lo parts by weight barium chloride
2o vektsdeler kaolin 20 parts by weight of kaolin
lo vektsdeler akrylharpiks (4o%'ig lbsning i alifatiske estere og som er vanlig forekommende i handelen) 2oo vektsdeler xylen 10 parts by weight acrylic resin (40% solution in aliphatic esters and which is commonly found in the trade) 200 parts by weight xylene
Blandingen påfbres bærepapiret slik at man får en beleggvekt på 3 g/m 2. The mixture is applied to the carrier paper so that a coating weight of 3 g/m 2 is obtained.
B. Som skriftmottakings-blad tjener et ifblge eksempel 2 fremstilt blad B. Som i dette eksempel får man en blå registrering. B. As a document receiving sheet, a sheet B produced according to example 2 serves. As in this example, you get a blue registration.
Eksempel 7 Example 7
A. På samme måte som beskrevet i eksempel 1 fremstilles en blanding med nedenstående sammensetning: 5 vektsdeler "attapulgit" A. In the same way as described in example 1, a mixture with the following composition is prepared: 5 parts by weight "attapulgite"
2o vektsdeler sinkstearat 20 parts by weight zinc stearate
lo vektsdeler manganklorid lo parts by weight manganese chloride
2o vektsdeler titandioksyd 20 parts by weight of titanium dioxide
lo vektsdeler akrylharpiks-dispersjon (5o%'ig i vann) 1 parts by weight acrylic resin dispersion (50% in water)
13o vektsdeler vann 13o parts by weight water
Blandingen påfbres bærepapiret slik at man får en beleggvekt The mixture is applied to the carrier paper so that a coating weight is obtained
på 5 g/m 2. of 5 g/m2.
B. Som skriftmottakings-blad tjener et ifblge eksempel 5 fremstilt blad B. Som i dette eksempel får man en blå registrering. B. As a document receiving sheet, a sheet B produced according to example 5 serves. As in this example, a blue registration is obtained.
Eksempel 8 Example 8
A. Man fremstiller en appliseringsblanding med fblgende sammensetning: A. An application mixture with the following composition is prepared:
6o vektsdeler ozokerit 6o parts by weight ozokerite
2o vektsdeler stearinsyre 20 parts by weight of stearic acid
5 vektsdeler silisiumdioksyd 5 parts by weight silicon dioxide
6 vektsdeler "attapulgit" 6 parts by weight "attapulgite"
2o vektsdeler sinkklorid 2o parts by weight zinc chloride
Forst blir de vokslignende bestanddelene ozokerit og stearinsyre smeltet med hverandre, hvoretter de bvrige bestanddelene innrbres i den angitte rekkefolge. Blandingen males varm, hvoretter man på-fbrer smeiten på et egnet bæremateriale med en styrke på 4o - 7o g/m 2 . Beleggvekten. skal være ca. 4-7 g/m 2. Det således erholdte bladet A kan kombineres med hvert av de i eksemplene 1-5 beskrevne blad B. Skriftfargen tilsvarer i alt vesentlig den i de aktuelle eksemplene angitte fargen. First, the wax-like components ozokerite and stearic acid are melted together, after which the remaining components are incorporated in the specified order. The mixture is milled hot, after which the melt is applied to a suitable carrier material with a strength of 4o - 7o g/m 2 . The coating weight. should be approx. 4-7 g/m 2. The sheet A thus obtained can be combined with each of the sheets B described in examples 1-5. The font color essentially corresponds to the color specified in the relevant examples.
Eksempel 9 Example 9
A. På samme måte som beskrevet i eksempel 8 fremstiller man en appliseringsblanding av: A. In the same way as described in example 8, an application mixture is prepared from:
5o vektsdeler ceresin 50 parts by weight ceresin
4o vektsdeler stearinsyre 40 parts by weight of stearic acid
5 vektsdeler silisiumdioksyd 5 parts by weight silicon dioxide
lo vektsdeler "bisfenol A" (bis-(p-hydroksy-fenyl)-iso-propan) lo parts by weight "bisphenol A" (bis-(p-hydroxy-phenyl)-iso-propane)
lo vektsdeler sinkklorid lo parts by weight zinc chloride
Som beskrevet i eksempel 8 males den erholdte blandingen og påfbre på bærepapiret. As described in example 8, the resulting mixture is ground and applied to the carrier paper.
Som allerede vist i eksemplene 6-9 innskrenker anvendelsen av skriftmottakings-blad B seg ikke til kombinasjonen med et skrift-overforings-blad A fra samme eksempel, men underbladene fra et eksempel kan også kombineres med overbladene fra de bvrige eksempler. Fargen til den oppnådde registrering tilsvarer derved i alt vesentlig den som er nevnt i forbindelse med underbladet B. As already shown in examples 6-9, the use of letter receiving sheet B is not limited to the combination with a letter transfer sheet A from the same example, but the lower sheets from one example can also be combined with the upper sheets from the other examples. The color of the obtained registration thereby essentially corresponds to that mentioned in connection with subsheet B.
I foranstående eksempler ble bare overblad og underblad beskrevet, og registreringsmaterialet ble dannet av respektive to blad. Det er imidlertid også mulig å fremstille såkalte midtblad, som på sin ovre side i likhet med underblad B er påfbrt et sjikt og som på sin underside har et overfbrings-sjikt i likhet med overblad A. Med slike midtblad kan de i foranstående eksempler beskrevne overblad og underblad forenes til registreringsmaterialer, hvilke oppviser tolv og flere blad. Man anvender med spesiell for del for fremstilling av overfbrings-sjiktet til midtbladene de i eksemplene 8 og 9 under A angitte resepter eller lignende av smelt påfbrbare vokshoIdige blandinger. In the preceding examples, only the upper leaf and lower leaf were described, and the registration material was formed from the respective two leaves. However, it is also possible to produce so-called center leaves, which, like lower leaf B, have a layer applied on their upper side and which, on their underside, have a transfer layer similar to upper leaf A. With such middle leaves, the upper leaves described in the preceding examples can and lower leaves are combined into registration materials, which show twelve or more leaves. The recipes given in examples 8 and 9 under A or similar of melt-appliable waxy mixtures are used in particular for the production of the transfer layer for the middle leaves.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT813272A AT331825B (en) | 1972-09-21 | 1972-09-21 | COPY MATERIAL |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO138720B true NO138720B (en) | 1978-07-24 |
| NO138720C NO138720C (en) | 1978-11-01 |
Family
ID=3602847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO3708/73A NO138720C (en) | 1972-09-21 | 1973-09-20 | PRESSURE SENSITIVE, TOUR, TWO-LAYER TYPE REGISTRATION MATERIAL WITH ACID TRANSMISSION LAYER |
Country Status (23)
| Country | Link |
|---|---|
| JP (1) | JPS4970708A (en) |
| AR (1) | AR200279A1 (en) |
| AT (1) | AT331825B (en) |
| BE (1) | BE804091A (en) |
| BR (1) | BR7307082D0 (en) |
| CA (1) | CA993656A (en) |
| CH (1) | CH573314A5 (en) |
| DD (1) | DD106800A5 (en) |
| DE (1) | DE2342596A1 (en) |
| DK (1) | DK137221B (en) |
| ES (1) | ES418963A1 (en) |
| FI (1) | FI59220C (en) |
| FR (1) | FR2200787A5 (en) |
| GB (1) | GB1416755A (en) |
| IE (1) | IE38259B1 (en) |
| IL (1) | IL43232A (en) |
| IT (1) | IT995414B (en) |
| NL (1) | NL7313030A (en) |
| NO (1) | NO138720C (en) |
| SE (1) | SE414739B (en) |
| SU (1) | SU576905A3 (en) |
| TR (1) | TR17704A (en) |
| ZA (1) | ZA737195B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5835479B2 (en) * | 1978-12-18 | 1983-08-02 | 三島製紙株式会社 | pressure sensitive recording material |
| US4347282A (en) * | 1979-04-27 | 1982-08-31 | Frye Copysystems, Inc. | Chemical carbonless copy paper and transfer medium therefor |
| US4363664A (en) | 1980-01-25 | 1982-12-14 | Sterling Drug Inc. | Novel compositions and processes |
| EP0036117B1 (en) | 1980-03-14 | 1986-02-05 | Spezial-Papiermaschinenfabrik August Alfred Krupp GmbH & Co | Pressure-sensitive recording material |
| US4343494A (en) * | 1980-06-16 | 1982-08-10 | Frye Copysystems, Inc. | Carbonless copy paper system |
| US4339143A (en) * | 1980-08-18 | 1982-07-13 | Mishima Paper Co., Ltd. | Pressure-sensitive recording material |
| CN112268903B (en) * | 2020-10-15 | 2023-05-05 | 华能国际电力股份有限公司 | On-site metallographic tectorial membrane test paper and preparation and use methods thereof |
-
1972
- 1972-09-21 AT AT813272A patent/AT331825B/en not_active IP Right Cessation
-
1973
- 1973-08-23 DE DE19732342596 patent/DE2342596A1/en active Pending
- 1973-08-28 BE BE134997A patent/BE804091A/en unknown
- 1973-08-29 AR AR249820A patent/AR200279A1/en active
- 1973-08-29 FI FI2685/73A patent/FI59220C/en active
- 1973-08-29 CH CH1237473A patent/CH573314A5/xx not_active IP Right Cessation
- 1973-09-05 SE SE7312099A patent/SE414739B/en unknown
- 1973-09-06 TR TR17704A patent/TR17704A/en unknown
- 1973-09-10 ZA ZA737195*A patent/ZA737195B/en unknown
- 1973-09-12 BR BR7082/73A patent/BR7307082D0/en unknown
- 1973-09-13 DD DD173459A patent/DD106800A5/xx unknown
- 1973-09-14 IL IL43232A patent/IL43232A/en unknown
- 1973-09-17 CA CA181,179A patent/CA993656A/en not_active Expired
- 1973-09-18 IE IE1663/73A patent/IE38259B1/en unknown
- 1973-09-18 IT IT28991/73A patent/IT995414B/en active
- 1973-09-18 GB GB4369873A patent/GB1416755A/en not_active Expired
- 1973-09-18 FR FR7333346A patent/FR2200787A5/fr not_active Expired
- 1973-09-19 SU SU7301965102A patent/SU576905A3/en active
- 1973-09-20 JP JP48106457A patent/JPS4970708A/ja active Pending
- 1973-09-20 DK DK514273AA patent/DK137221B/en not_active IP Right Cessation
- 1973-09-20 NO NO3708/73A patent/NO138720C/en unknown
- 1973-09-21 ES ES418963A patent/ES418963A1/en not_active Expired
- 1973-09-21 NL NL7313030A patent/NL7313030A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| FI59220B (en) | 1981-03-31 |
| BR7307082D0 (en) | 1974-07-25 |
| JPS4970708A (en) | 1974-07-09 |
| SU576905A3 (en) | 1977-10-15 |
| IT995414B (en) | 1975-11-10 |
| FI59220C (en) | 1981-07-10 |
| DD106800A5 (en) | 1974-07-05 |
| AT331825B (en) | 1976-08-25 |
| GB1416755A (en) | 1975-12-03 |
| ZA737195B (en) | 1974-08-28 |
| DK137221B (en) | 1978-02-06 |
| IE38259B1 (en) | 1978-02-01 |
| IL43232A (en) | 1976-10-31 |
| ES418963A1 (en) | 1976-07-01 |
| NL7313030A (en) | 1974-03-25 |
| AR200279A1 (en) | 1974-10-31 |
| CH573314A5 (en) | 1976-03-15 |
| BE804091A (en) | 1973-12-17 |
| FR2200787A5 (en) | 1974-04-19 |
| SE414739B (en) | 1980-08-18 |
| DK137221C (en) | 1978-07-10 |
| IL43232A0 (en) | 1973-11-28 |
| NO138720C (en) | 1978-11-01 |
| IE38259L (en) | 1974-03-21 |
| DE2342596A1 (en) | 1974-04-11 |
| ATA813272A (en) | 1975-11-15 |
| CA993656A (en) | 1976-07-27 |
| TR17704A (en) | 1975-07-23 |
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