NL7812100A - Sulphuric acid refining of hydrocarbon(s) - using additives to prevent formation or effect sepn. of acid resins - Google Patents

Sulphuric acid refining of hydrocarbon(s) - using additives to prevent formation or effect sepn. of acid resins

Info

Publication number
NL7812100A
NL7812100A NL7812100A NL7812100A NL7812100A NL 7812100 A NL7812100 A NL 7812100A NL 7812100 A NL7812100 A NL 7812100A NL 7812100 A NL7812100 A NL 7812100A NL 7812100 A NL7812100 A NL 7812100A
Authority
NL
Netherlands
Prior art keywords
acid
pref
phase
degrees
solvent
Prior art date
Application number
NL7812100A
Other languages
Dutch (nl)
Original Assignee
Petrolchemisches Kombinat
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DD20260477A external-priority patent/DD138020A3/en
Priority claimed from DD77202605A external-priority patent/DD138475A3/en
Priority claimed from DD20260377A external-priority patent/DD138019A3/en
Application filed by Petrolchemisches Kombinat filed Critical Petrolchemisches Kombinat
Publication of NL7812100A publication Critical patent/NL7812100A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/69—Sulfur trioxide; Sulfuric acid
    • C01B17/90—Separation; Purification
    • C01B17/92—Recovery from acid tar or the like, e.g. alkylation acids
    • C01B17/925—Recovery from acid tar or the like, e.g. alkylation acids by processes involving a liquid-liquid extraction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G99/00—Subject matter not provided for in other groups of this subclass
    • C07G99/002—Compounds of unknown constitution containing sulfur
    • C07G99/0022—Compounds of unknown constitution containing sulfur derived from hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
    • C10G17/02—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acids or acid-containing liquids, e.g. acid sludge
    • C10G17/04—Liquid-liquid treatment forming two immiscible phases
    • C10G17/06—Liquid-liquid treatment forming two immiscible phases using acids derived from sulfur or acid sludge thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M175/00—Working-up used lubricants to recover useful products ; Cleaning

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

Sulphuric acid refining (esp. for regenerating used oils or producing speciality oils or pure hydrocarbons) is carried out using additives which prevent the formation of acid resins or separate such acid resins into a resin phase and an acid phase. The acid resin (50-60 pts.wt.) is agitated at ambient temp. with 25-40 pts. wt. of a phenolic tar (I) and 10-25 pts. wt. H2O, and the mixt. is settled at 50-90 (pref. 65-70) degrees C to form an organic resin phase. Specifically, (I) is obtained during the extn. or distn. of phenol, boils in the 230-350 degrees C range, and has a solidification point of approx. 20 degrees C and a density of 1.10-1.25 g/cc at 20 degrees C. Alternatively the reaction mixt. formed during refining is agitated at 20-60 (pref. 20-40) degrees C with a solvent and/or H2O, and is then sepd. (pref. by agitation and/or heating at 40-100 degrees C) into a refined oil phase, a resin phase and an aq. H2SO4 phase. When a solvent and H2O are used, the solvent is pref. (I) or an acid resin and the H2SO4: solvent: H2O ratio is between 1:0.01-0.03 and 1:3.0:1.k (pref. between 1:0.02:0.5 and 1:2.5:1.2) when the solvent is an acid resin or between 1:0.01:0.3 and 1:2.0-1.5 (pref. between 1:0.02:0.05 and 1:1.5:1.2) when the solvent is (I) when H2O is used alone, the H2SO4:H2O ratio is 1:0.2-1.5 (pref. 1:0.4:1.2). Stated advantages include: use of cheap solvents which do not have to be recovered; possibility of continuous operation with total recycle of by-products; up to 50% redn. in oil losses; 2- to 3-fold increase in settling rates; the recovered acid phase can be used in superphosphate mfr.; resin by-products can be used for road making and/or as fuels.
NL7812100A 1977-12-14 1978-12-12 Sulphuric acid refining of hydrocarbon(s) - using additives to prevent formation or effect sepn. of acid resins NL7812100A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DD20260477A DD138020A3 (en) 1977-12-14 1977-12-14 PROCESS OF CONTROLLED SULFUR ACIDS REFINATION-1
DD77202605A DD138475A3 (en) 1977-12-14 1977-12-14 METHOD FOR PROCESSING ACID RESINS
DD20260377A DD138019A3 (en) 1977-12-14 1977-12-14 PROCESS OF CONTROLLED SULFUR ACIDS REFINATION-2

Publications (1)

Publication Number Publication Date
NL7812100A true NL7812100A (en) 1979-06-18

Family

ID=27179824

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7812100A NL7812100A (en) 1977-12-14 1978-12-12 Sulphuric acid refining of hydrocarbon(s) - using additives to prevent formation or effect sepn. of acid resins

Country Status (1)

Country Link
NL (1) NL7812100A (en)

Similar Documents

Publication Publication Date Title
US2433396A (en) Process for production of sulfonic acids
US2168315A (en) Method for the purification of petroleum mahogany sulphonates
NL7812100A (en) Sulphuric acid refining of hydrocarbon(s) - using additives to prevent formation or effect sepn. of acid resins
US2263041A (en) Preparation of sulphonic acids
US2368452A (en) Separation and purification of green or water-soluble sulphonic acids
US3096192A (en) Asphalt compositions having reduced stripping tendencies
US2218174A (en) Preparation of sulphonic acids
US2446159A (en) Distillation of alcohol from hydrolyzed mixtures of alkyl sulfates and sulfuric acid
US2383057A (en) Extraction of hydrocarbons
JPS5583723A (en) Recovery of resorcinol
US3168585A (en) Separation of a dispersed liquid hydrocarbon phase from an immiscible liquid phase
US2426082A (en) Method for eliminating foaming in the recovery of sulfuric acid from an olefin recovery operation
DE1543548A1 (en) Process for the preparation of substituted 4,6-dinitrophenols
ES477879A1 (en) Binder compositions containing phenolic resins and organic phosphate and/or carbonate solvents
US4032581A (en) Method for separation of m- or p-cresol
ZA839284B (en) Process for purifying wet-processed phosphoric acid
US1092629A (en) Process for refining and decolorizing mineral wax.
DE1745319C3 (en) Process for the preparation of linear or crosslinked organopolysiloxanes
US2418210A (en) Process for treating alkylation sulfuric acid sludge
US2697122A (en) Process for isolating phenolic compounds from mixtures thereof
US2228788A (en) Purification of valuable hydro-
US2885453A (en) Process for separating polycyclic aromatic compounds from organic mixtures
US2466889A (en) Alcohol-soluble phenol-modified coumarone-indene resin
US2768169A (en) Purification of polymerizable heterocyclic nitrogen compounds at low temperatures
ES8603158A1 (en) Process for the preparation of a solution of an alkali metal phosphate.

Legal Events

Date Code Title Description
A85 Still pending on 85-01-01
BV The patent application has lapsed