NL7803707A - Gasoline prodn. from natural gas - by conversion to synthesis gas, hydrocarbon synthesis, fractionation and isobutane alkylation - Google Patents

Gasoline prodn. from natural gas - by conversion to synthesis gas, hydrocarbon synthesis, fractionation and isobutane alkylation

Info

Publication number
NL7803707A
NL7803707A NL7803707A NL7803707A NL7803707A NL 7803707 A NL7803707 A NL 7803707A NL 7803707 A NL7803707 A NL 7803707A NL 7803707 A NL7803707 A NL 7803707A NL 7803707 A NL7803707 A NL 7803707A
Authority
NL
Netherlands
Prior art keywords
gasoline
fraction
synthesis
gas
natural gas
Prior art date
Application number
NL7803707A
Other languages
Dutch (nl)
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Priority to NL7803707A priority Critical patent/NL7803707A/en
Priority to CA319,382A priority patent/CA1122620A/en
Priority to NZ190105A priority patent/NZ190105A/en
Priority to AU45768/79A priority patent/AU527900B2/en
Publication of NL7803707A publication Critical patent/NL7803707A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/88—Ferrosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0485—Set-up of reactors or accessories; Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/88—Ferrosilicates; Ferroaluminosilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Prodn. of aromatic gasoline from natural gas is carried out by (a) converting the natural gas to synthesis gas, (b) converting the synthesis gas to a hydrocarbon mixt. using a catalyst contg. a crystalline silicate (I), (c) sepg. the hydrocarbon mixt. into a C2-fraction, an isobutane-contg. gaseous fraction and a gasoline-range aromatic fraction, (d) recycling the C2-fraction to step (a), (e) alkylating the isobutane-contg. fraction and sepg. a gasoline-range fraction from the prod. and (f) combining the gasoline-range fractions from steps (c) and (e). (I) is thermally stable at >600 degrees C, is capable of adsorbing 3 wt % H2O at 25 degrees C and 100% RH after dehydration at 400 degrees C in vacuo, and has the following molar compsn. in dehydrated form: (1.0 plus-or-minus 0.3)Rn/2O: aFe2O3.bAl2O3.-cGa2O3 :y (dSiO2.eGeO2) (where R is one or more mono-or divalent cations, a >=0.1, b >=0, c >=0, a+b+c = 1,y = 10, 10, d >=0.1, e >=0, d+e = 1, n is the valence of R). High synthesis gas conversions (e.g. 95-100%) can be obtd. with high (e.g. 60-80%) selectivity for C5+ gasoline. The blended gasoline produced in step (f) has a high octane no. (e.g. RON clear = 90-92).
NL7803707A 1978-04-07 1978-04-07 Gasoline prodn. from natural gas - by conversion to synthesis gas, hydrocarbon synthesis, fractionation and isobutane alkylation NL7803707A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
NL7803707A NL7803707A (en) 1978-04-07 1978-04-07 Gasoline prodn. from natural gas - by conversion to synthesis gas, hydrocarbon synthesis, fractionation and isobutane alkylation
CA319,382A CA1122620A (en) 1978-04-07 1979-01-10 Process for the preparation of an aromatic hydrocarbon mixture
NZ190105A NZ190105A (en) 1978-04-07 1979-04-05 Preparation of aromatic hydrocarbon mixture including alkylation of isobutane fraction
AU45768/79A AU527900B2 (en) 1978-04-07 1979-04-05 Production of gasoline from natural gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7803707A NL7803707A (en) 1978-04-07 1978-04-07 Gasoline prodn. from natural gas - by conversion to synthesis gas, hydrocarbon synthesis, fractionation and isobutane alkylation

Publications (1)

Publication Number Publication Date
NL7803707A true NL7803707A (en) 1979-10-09

Family

ID=19830613

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7803707A NL7803707A (en) 1978-04-07 1978-04-07 Gasoline prodn. from natural gas - by conversion to synthesis gas, hydrocarbon synthesis, fractionation and isobutane alkylation

Country Status (4)

Country Link
AU (1) AU527900B2 (en)
CA (1) CA1122620A (en)
NL (1) NL7803707A (en)
NZ (1) NZ190105A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018683A1 (en) * 1979-04-25 1980-11-12 Shell Internationale Researchmaatschappij B.V. Process for the preparation of hydrocarbons, and hydrocarbons so prepared
EP0039964A1 (en) * 1980-05-06 1981-11-18 Shell Internationale Researchmaatschappij B.V. A process for the preparation of an aromatic hydrocarbon mixture
FR2519563A1 (en) * 1982-01-14 1983-07-18 Azote & Prod Chim Catalyst for converting synthesis gas to hydrocarbon(s) - comprises transition metals and de:aluminated mordenite
EP0084469A1 (en) * 1982-01-14 1983-07-27 Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques Synthesis gas conversion catalysts

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2529099B2 (en) * 1982-06-25 1986-03-21 Azote & Prod Chim SYNTHESIS GAS CONVERSION CATALYSTS
EP0192289B1 (en) * 1985-02-22 1989-12-13 Shell Internationale Researchmaatschappij B.V. Process for the preparation of an aromatic hydrocarbons-containing mixture
GB8626532D0 (en) * 1986-11-06 1986-12-10 British Petroleum Co Plc Chemical process
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018683A1 (en) * 1979-04-25 1980-11-12 Shell Internationale Researchmaatschappij B.V. Process for the preparation of hydrocarbons, and hydrocarbons so prepared
EP0039964A1 (en) * 1980-05-06 1981-11-18 Shell Internationale Researchmaatschappij B.V. A process for the preparation of an aromatic hydrocarbon mixture
FR2519563A1 (en) * 1982-01-14 1983-07-18 Azote & Prod Chim Catalyst for converting synthesis gas to hydrocarbon(s) - comprises transition metals and de:aluminated mordenite
EP0084469A1 (en) * 1982-01-14 1983-07-27 Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques Synthesis gas conversion catalysts
US4500646A (en) * 1982-01-14 1985-02-19 Societe Chimique De La Grande Paroisse, Azote Et Producits Chimiques Conversion catalysts for synthesis gas

Also Published As

Publication number Publication date
CA1122620A (en) 1982-04-27
NZ190105A (en) 1981-07-13
AU4576879A (en) 1979-10-11
AU527900B2 (en) 1983-03-31

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