NL7711007A - Olefin polymerisation catalysts comprising zirconium-modified carriers - with chromium chelates dispersed thereon - Google Patents

Olefin polymerisation catalysts comprising zirconium-modified carriers - with chromium chelates dispersed thereon

Info

Publication number
NL7711007A
NL7711007A NL7711007A NL7711007A NL7711007A NL 7711007 A NL7711007 A NL 7711007A NL 7711007 A NL7711007 A NL 7711007A NL 7711007 A NL7711007 A NL 7711007A NL 7711007 A NL7711007 A NL 7711007A
Authority
NL
Netherlands
Prior art keywords
atoms
oxide
whole
olefin polymerisation
zirconium
Prior art date
Application number
NL7711007A
Other languages
Dutch (nl)
Original Assignee
Chemplex Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemplex Co filed Critical Chemplex Co
Priority to NL7711007A priority Critical patent/NL7711007A/en
Publication of NL7711007A publication Critical patent/NL7711007A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • C08F4/025Metal oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/78Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from chromium, molybdenum or tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Novel (olefin polymerisation) catalysts are prepd. by (1) dispersing a Zr cpd. onto a finely divided, inorganic difficulty reducible carrier composed of SiO2, Al oxide, thoeium oxide, Ti dioxide, Mg oxide or mixts. of them, (2) dispersing onto the Zr-modified carrier, a Cr chelate of a beta-dicarbonyl cpd. of formula (I), (II) or (III) R-CO-CH-CO-R mCrXn (I); (CO-CH-CO-R1)mCrXn (II) or (R-CO-C-CO-R')mCr Xn (III) (where R=H, alkenyl, aryl (cyclo)alkyl or cycloalkenyl or a combination of them, each R gp. contg. 0-20C atoms and a no. of H atoms corresp. to the valency; each R' is alkylene, alkenylene, arylene, cycloalkylene or cycloalkenylene or a combination of these divalent gps., each R' contg. 1-20C atoms and a no. of H atoms corresp. to the valency; m is a whole no. 1-3; n is a whole no. 0-2; m+n=a whole no. 2-3; X is a negative mixt. by heating in a non-oxidising atmos. at 427-1093 degrees C. USed for polymerising 2-8C 1-olefins to obtain solid polymers or copolymerising 2-20C olefins, in liq. soln., suspension or vapour phase.
NL7711007A 1977-10-07 1977-10-07 Olefin polymerisation catalysts comprising zirconium-modified carriers - with chromium chelates dispersed thereon NL7711007A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL7711007A NL7711007A (en) 1977-10-07 1977-10-07 Olefin polymerisation catalysts comprising zirconium-modified carriers - with chromium chelates dispersed thereon

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7711007A NL7711007A (en) 1977-10-07 1977-10-07 Olefin polymerisation catalysts comprising zirconium-modified carriers - with chromium chelates dispersed thereon

Publications (1)

Publication Number Publication Date
NL7711007A true NL7711007A (en) 1979-04-10

Family

ID=19829306

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7711007A NL7711007A (en) 1977-10-07 1977-10-07 Olefin polymerisation catalysts comprising zirconium-modified carriers - with chromium chelates dispersed thereon

Country Status (1)

Country Link
NL (1) NL7711007A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015078885A2 (en) 2013-11-28 2015-06-04 Saudi Basic Industries Corporation Chromium-based catalyst component comprising a modified inorganic oxide support

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015078885A2 (en) 2013-11-28 2015-06-04 Saudi Basic Industries Corporation Chromium-based catalyst component comprising a modified inorganic oxide support
WO2015078885A3 (en) * 2013-11-28 2016-03-10 Saudi Basic Industries Corporation Chromium-based catalyst component comprising a metal-halide modified inorganic oxide support

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Legal Events

Date Code Title Description
A1B A search report has been drawn up
BC A request for examination has been filed
BN A decision not to publish the application has become irrevocable