NL7403749A - Two-component catalyst system for trimerisation of - Google Patents

Two-component catalyst system for trimerisation of

Info

Publication number
NL7403749A
NL7403749A NL7403749A NL7403749A NL7403749A NL 7403749 A NL7403749 A NL 7403749A NL 7403749 A NL7403749 A NL 7403749A NL 7403749 A NL7403749 A NL 7403749A NL 7403749 A NL7403749 A NL 7403749A
Authority
NL
Netherlands
Prior art keywords
trimerisation
catalyst system
component catalyst
trimers
oxime
Prior art date
Application number
NL7403749A
Other versions
NL153538B (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to NL747403749A priority Critical patent/NL153538B/en
Publication of NL7403749A publication Critical patent/NL7403749A/en
Publication of NL153538B publication Critical patent/NL153538B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

A catalyst system for the trimerisation of isocyanates contains (1) a quaternary ammonium hydroxide (I) (where R1, R2, R3, R4 are alkyl or hydroxyalkyl of 1 to 6C, cycloalkyl of 5 or 6C, benzyl, phenyl or may be pyridine), and (2) compound (III) from (a) methanol, (b) a C2-6 oxime and (c) a phenol where R is halogen, methyl or amino; n is 0, 1, 2 or 3; m is 0 or 1, and when m is 1 the 2 OH groups are in the meta or para position. The catalyst system is more effective than present systems. Smaller concentrations and shorter reaction times are required and trimerisation on an industrial scale is possible. The trimers are used in paints, coating compositions, adhesives, -rubbers.
NL747403749A 1968-06-10 1974-03-20 METHOD FOR PREPARING ISOCYANATE TRIMERS NL153538B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL747403749A NL153538B (en) 1968-06-10 1974-03-20 METHOD FOR PREPARING ISOCYANATE TRIMERS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL6808140A NL6808140A (en) 1968-06-10 1968-06-10
NL747403749A NL153538B (en) 1968-06-10 1974-03-20 METHOD FOR PREPARING ISOCYANATE TRIMERS

Publications (2)

Publication Number Publication Date
NL7403749A true NL7403749A (en) 1974-06-25
NL153538B NL153538B (en) 1977-06-15

Family

ID=19803861

Family Applications (3)

Application Number Title Priority Date Filing Date
NL6808140A NL6808140A (en) 1968-06-10 1968-06-10
NL747403749A NL153538B (en) 1968-06-10 1974-03-20 METHOD FOR PREPARING ISOCYANATE TRIMERS
NL747403748A NL152258B (en) 1968-06-10 1974-03-20 METHOD FOR PREPARING ISOCYANATE TRIMERS

Family Applications Before (1)

Application Number Title Priority Date Filing Date
NL6808140A NL6808140A (en) 1968-06-10 1968-06-10

Family Applications After (1)

Application Number Title Priority Date Filing Date
NL747403748A NL152258B (en) 1968-06-10 1974-03-20 METHOD FOR PREPARING ISOCYANATE TRIMERS

Country Status (1)

Country Link
NL (3) NL6808140A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2732662A1 (en) * 1977-07-20 1979-02-01 Veba Chemie Ag ISOCYANURATE GROUPS AND TERMINALLY BLOCKED ISOCYANATE GROUP COMPOUNDS

Also Published As

Publication number Publication date
NL6808140A (en) 1969-12-12
NL153538B (en) 1977-06-15
NL7403748A (en) 1974-06-25
NL152258B (en) 1977-02-15

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Legal Events

Date Code Title Description
V1 Lapsed because of non-payment of the annual fee
NL80 Abbreviated name of patent owner mentioned of already nullified patent

Owner name: TAKEDA