NL2032126B1 - High-temperature oxidation device for high-salt dangerous waste - Google Patents

High-temperature oxidation device for high-salt dangerous waste Download PDF

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Publication number
NL2032126B1
NL2032126B1 NL2032126A NL2032126A NL2032126B1 NL 2032126 B1 NL2032126 B1 NL 2032126B1 NL 2032126 A NL2032126 A NL 2032126A NL 2032126 A NL2032126 A NL 2032126A NL 2032126 B1 NL2032126 B1 NL 2032126B1
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Netherlands
Prior art keywords
inlet
furnace body
hot air
oxidation furnace
solid
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NL2032126A
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Dutch (nl)
Inventor
Yuan Wenjiao
Fan Wenhao
Zhang Ke
Li Meitong
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Univ Tianjin Technology
Yi Keli Tianjin Environmental Protection Tech Development Co Ltd
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Priority to NL2032126A priority Critical patent/NL2032126B1/en
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Publication of NL2032126B1 publication Critical patent/NL2032126B1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/70Chemical treatment, e.g. pH adjustment or oxidation

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Cyclones (AREA)

Abstract

A high-temperature oxidation device for high-salt dangerous waste consists of an oxidation furnace body, a hot air inlet, an air distribution plate, a solid feeder, a material 5 distributor, a classifier, a cyclone separator, an energy-saving heat exchanger, a return feeder, a bag filter, a wet filter and a sealing discharger. The beneficial effects of the present disclosure is that the device can completely decompose the organic matter in the solid waste without melting. The device controls the oxidation time of the material by adjusting the wind speed, feed particle size, wind pressure and return material to ensure 10 the complete decomposition of the organic matter. The device has the advantages of high efficiency, simple process, controllable high-temperature oxidative decomposition of organic matter, high thermal energy utilization rate, low operating cost, and easy implementation, and has wide application prospects with significant economic and social benefits.

Description

HIGH-TEMPERATURE OXIDATION DEVICE FOR HIGH-SALT
DANGEROUS WASTE
TECHNICAL FIELD
[0001] The present disclosure relates to a high-temperature oxidation device for high- salt dangerous waste, which belongs to resource environmental protection equipment.
BACKGROUND ART
[0002] China produces about 50 million tons of dangerous solid waste every year, of which more than 20% are inorganic salts containing organic substances. Since the existing dangerous waste incinerators are not suitable for dangerous waste containing inorganic salts, of the inorganic salts can melt or decompose at high temperatures, leaving the existing dangerous waste incinerators are not suitable for dangerous waste containing inorganic salts. A large amount of waste salt at home and abroad cannot be approperly treated, which has caused many environmental protection accidents and severe ecological and environmental burdens, and has seriously restricted the healthy development of the economy.
[0003] The existing treatment of dangerous solid waste salt is mainly landfill, which occupies a large amount of land, has high cost, has potential risks, and leaves pollution to future generations.
[0004] Inorganic salts in dangerous solid waste salts are valuable mineral resources and have a high value. The development of a device that can recycle dangerous waste salts at low cost has substantial economic value and social benefits.
SUMMARY
[0005] The present disclosure aims to provide a high-salt dangerous waste high- temperature oxidation device for the existing problems in the disposal of dangerous solid waste salts. The device effectively decomposes organic matter in inorganic salts by controlling the oxidation time below the melting temperature of inorganic salts, and turns dangerous waste into usable resources. The device is low cost, is efficient and is suitable for resource processing of various high-salt dangerous solid or liquid wastes.
[0006] Technical solution of the present disclosure.
[0007] A high-temperature oxidation device for high-salt dangerous waste, consisting of an oxidation furnace body, a hot air inlet, an air distribution plate, a solid feeder, a material distributor, a classifier, a cyclone separator, an energy-saving heat exchanger, a return feeder, a bag filter, a wet filter and a sealing discharger, wherein the oxidation furnace body is a vertical cylinder structure, the diameter of the cylinder structure is of any size, and is a straight cylinder or a cylinder of unequal width, the height-diameter ratios 1: (0.1-1), and an outer wall and lining material of the furnace body are made of high temperature resistant materials; the oxidation furnace body has a solid discharge port and is connected with a sealing discharger, and the sealing discharger is a spiral sealing structure to prevent the system from leaking; the oxidation furnace body has a hot air inlet at the bottom, a material inlet in the middle, and a hot air outlet at the top; the hot air inlet is provided with an adjustable valve to adjust the hot air temperature, and the inlet air temperature is 400-1400 °C; the air distribution plate is a spiral structure or a absorbent structure to distribute the hot air and increase the wind speed to prevent the solid objects from falling, the hole diameter of the absorbent structure is 2-300mm, and the hole spacing is 0.5-15mm; the solid feeder is a screw conveyor; the material distributor is an orifice plate, a pipe or a nozzle structure to allow solid or liquid materials to be fed. The material dispersion diameter is 0.001-10mm. The material distributor 1s set at any position in the cylinder, and the material and the hot air are co-current or counter-current; the classifier is an orifice plate structure or a mesh structure to block the passage of particles, and the hole diameter is 0.5-200mm; the cyclone separators are one or more in parallel or in series to capture particulate matter; the energy-saving heat exchanger is a device using the heat of the exhaust gas, and uses cold air to cool the exhaust gas, and the exchanged hot air is used for the combustion of the hot blast stove or for heating in other suitable environments; the return feeder 9 is a spiral or straight cylinder structure to return the material to the oxidation furnace to continue heating; the bag filter and wet filter are used to exhaust gas treatment; the hot gas outlet of the oxidation furnace body is connected to the inlet and outlet of the cyclone separator, the inlet and outlet of the energy-saving heat exchanger, the inlet and outlet of the bag filter, and the inlet and outlet of the wet filter through the pipeline in turn, and finally the exhaust gas is emptied; the solids separated by the cyclone separator are collected into the solid feeder through the return feeder and enter the oxidation furnace body through the material inlet.
[0008] The beneficial effects of the present disclosure are as follows.
[0009] The device can completely decompose the organic matter in the solid waste without melting. The device controls the oxidation time of the material by adjusting the wind speed, feed particle size, wind pressure and return material to ensure the complete decomposition of the organic matter. The device has a high efficiency, a simple process, a controllable high-temperature oxidative decomposition of organic matter, a high thermal energy utilization rate, a low operating cost, and an easy implementation, and has broad application prospects with significant economic and social benefits.
BRIEF DESCRIPTION OF THE DRAWINGS
[0010] FIG. 1 is a schematic structural diagram of a device according to the present disclosure.
[0011] The reference numbers in the drawings are as follows: 1. oxidation furnace body, 2. hot air inlet, 3. air distribution plate, 4. solid feeder, 5. material distributor, 6. classifier, 7. cyclone separator, 8. energy-saving heat exchanger, 9. return feeder, 10. bag filter, 11. wet filter, 12. sealing discharger.
DETAILED DESCRIPTION OF THE EMBODIMENTS
[0012] The following non-limiting embodiments are used to illustrate the present disclosure.
[0013] Embodiment
[0014] A high-temperature oxidation device for high-salt dangerous waste, as shown in
FIG. 1, consists of an oxidation furnace body 1, a hot air inlet 2, an air distribution plate 3, a solid feeder 4, a material distributor 5, a classifier 6, a cyclone separator 7, an energy- saving heat exchanger 8, a return feeder 9, a bag filter 10, a wet filter 11 and a sealing discharger 12.
[0015] The oxidation furnace body 1 is a vertical cylinder structure. The diameter of the cylinder structure is of any size, and is a straight cylinder or a cylinder of unequal width, the height-diameter ratio is 1: (0.1-1), and an outer wall and the lining material of the furnace body are made of high temperature resistant materials. The oxidation furnace body 1 has a solid discharge port and is connected with a sealing discharger 12, and the sealing discharger 12 is a spiral sealing structure to prevent the system from leaking. The oxidation furnace body 1 has a hot air inlet at the bottom, a material inlet in the middle, and a hot air outlet at the top.
[0016] The hot air inlet 2 is provided with an adjustable valve to adjust the hot air temperature, and the inlet air temperature is 400-1400 °C.
[0017] The air distribution plate 3 is a spiral structure or a absorbent structure to distribute the hot air and increase the wind speed to prevent the solid objects from falling.
The hole diameter of the absorbent structure is 20mm, and the hole spacing is 2mm.
[0018] The solid feeder 4 is a screw conveyor.
[0019] The material distributor 5 is an orifice plate, a pipe or a nozzle structure to allow solid or liquid materials to enter. The material dispersion diameter is 0.001-10mm. The material distributor 5 is set at any position in the cylinder, and the material and the hot air are co-current or counter-current.
[0020] The classifier 6 is an orifice plate structure or a mesh structure to block the passage of particles, and the hole diameter is 0.5-200mm.
[0021] The cyclone separators 7 are two in parallel for capturing particulate matter.
[0022] The energy-saving heat exchanger 8 is a device using the heat of the exhaust gas, and uses cold air to cool the exhaust gas, and the exchanged hot air is used for the combustion of the hot blast stove or heating in other suitable environments.
[0023] The return feeder 9 is a spiral or straight cylinder structure to return the material to the oxidation furnace to continue heating.
[0024] The bag filter 10 and wet filter 11 are used to exhaust gas treatment.
[0025] The hot gas outlet of the oxidation furnace body is connected to the inlet and outlet of the cyclone separator 7, the inlet and outlet of the energy-saving heat exchanger 8, the inlet and outlet of the bag filter 10 and the inlet and outlet of the wet filter 11 through the pipeline in turn, and finally the exhaust gas is emptied.
[0026] The solids separated by the cyclone separator 7 are collected into the solid feeder 4 through the return feeder 9 and enter the oxidation furnace body 1 through the material inlet.
[0027] In this embodiment, the oxidation furnace body 1 is made of 310s heat-resistant stainless steel, and the structure is an unequal diameter cylinder. The maximum diameter of an upper portion is 1000mm, and the minimum diameter of a lower portion is 200mm, and a middle portion is designed with the sealing discharger 12, and the sealing discharger is of screw conveying structure. The lower portion of the cylinder has an air inlet 2, and the air inlet temperature 1s 800°C. An upper portion of the air inlet 2 is the air distribution plate 3, and the air distribution plate 3 is a spiral guide plate, and the rotation angle is 15° in a clockwise direction. The hole diameter of the material distributor 5 on the upper portion of the air distribution board is 2mm, and the upper portion of the material distributor 5 is fixed with the solid feeder 4. The solid feeder 4 is the screw conveyor. The top of the material distributor 5 is the classifier 6, and the hole diameter of the classifier is 2mm; the back of the classifier 6 is connected to the cyclone separator 7. The discharge port under the cyclone separator 7 is used to connect the return feeder 9, and the tail gas of the air outlet is connected to the inlet of the energy- saving heat exchanger 8. The outlet of the energy-saving heat exchanger 8 is connected tothe inlet of the bag filter 10; the gas outlet of the bag filter 10 is connected to the inlet of the wet filter 11, and the dedusted gas is discharged up to the standard by the damp filter.
[0028] The material is transported to the top of the material distributor 5 by the solid feeder 4, and the solid with a particle size larger than 2mm is transported out of the oxidation furnace through the sealing discharger as a finished product. Solid particles with a particle size less than 2mm are collected from the cyclone separator 7 and the bag filter 8 through the classifier 6, as the finished product or returned to the oxidation furnace 1.
[0029] In summary, due to the use of the technical solutions mentioned above, the organic matter in the high-salt and high-organic waste can be fully decomposed. A reliable device for the disposal of high-salt waste is provided. The device makes full use of energy consumption, is simple to operate, cost low operating cost, and is suitable for the disposal of various high-salt wastes. The present embodiment should not constitute a limitation to the present disclosure. According to the technical essence of the present disclosure, any simple modifications, equivalent changes and modifications made to the embodiments fall within the technical protection scope of the present disclosure.

Claims (1)

ConclusiesConclusions 1. Oxidatie-inrichting bij een hoge temperatuur voor gevaarlijk afval met een hoog zoutgehalte, die bestaat uit een oxidatieovenlichaam, een warmeluchtinlaat, een luchtverdelingsplaat, een vaste toevoerinrichting, een materiaalverdeler, een classificatiemiddel, een cycloonafscheider, een energiebesparende warmtewisselaar, een terugkeertoevoerinrichting, een zakkenfilter, een nat filter en een afdichtende afvoerinrichting, waarbij het oxidatieovenlichaam een verticale cilinderstructuur is, waarbij de diameter van de cilinder een rechte cilinder of een cilinder van ongelijke breedte van elke grootte is, waarbij de hoogte-diameterverhouding 1:(0,1-1) is en waarbij een buitenwand en voeringmateriaal van het ovenlichaam gemaakt zijn van materialen die resistent zijn tegen hoge temperaturen, waarbij het oxidatieovenlichaam een vastestofafvoerpoort heeft en verbonden is met een afdichtende afvoerinrichting en waarbij afdichtende afvoerinrichting een spiraal-afdichtende structuur is om te voorkomen dat het systeem lekt; waarbij het oxidatieovenlichaam een warmeluchtinlaat op de onderkant, een materiaalinlaat in het midden en een warmeluchtuitlaat op de bovenkant heeft, waarbij de warmeluchtinlaat voorzien is van een aanpasbare klep om de warmeluchttemperatuur aan te passen en waarbij de inlaatluchttemperatuur 400- 1400°C is; waarbij de luchtverdelingsplaat een spiraalstructuur of een absorberende structuur is om de warmte lucht te verdelen en de windsnelheid te verhogen om te voorkomen dat vaste voorwerpen vallen, waarbij de holtediameter van de absorberende structuur 2-300mm is en waarbij de holtetussenruimte 0,5-15mm is; waarbij de vastestoftoevoerinrichting een schroeftransportmiddel is; waarbij de materiaalverdeler een openingsplaat, een leiding of een mondstukstructuur is om vaste of vloeibare materialen toegevoerd te laten worden, waarbij de materiaalspreidingsdiameter 0,001- 10mm is, waarbij de materiaalverdeler ingesteld is op enige positie in de cilinder en het materiaal en de warme lucht met de stroom mee of tegen de stroom in zijn; waarbij het classificatiemiddel een openingsplaatstructuur of een maasstructuur is om de doorgang van deeltjes te blokkeren en waarbij de holtediameter 0,5-200mm is; waarbij de cycloonafscheiders één of meer parallel of in serie zijn om fijnstof af te vangen; waarbij de energiebesparende warmtewisselaar een inrichting is die gebruik maakt van warmte van het uitlaatgas en koude lucht gebruikt om het uitlaatgas af te koelen en waarbij de verwisselde warme lucht gebruikt wordt voor de verbranding van de heteluchtkachel of voor het verwarmen in andere geschikte omgevingen; waarbij de terugkeertoevoerinrichting een spiraal- of rechte cilinderstructuur is om het materiaal terug te voeren naar de oxidatieoven om door te gaan met het verwarmen; waarbij het zakkenfilter en natte filter gebruikt worden om gasbehandeling uit te stoten; waarbij de warmegasuitlaat van het oxidatieovenlichaam verbonden is met de inlaat en uitlaat van de cycloonafscheider, de inlaat en uitlaat van de energiebesparende warmtewisselaar, de inlaat en uitlaat van het zakkenfilter en de inlaat en uitlaat van het natte filter door de pijpleiding in bocht en waarbij uiteindelijk het uitlaatgas geloosd wordt; waarbij de vaste stoffen die gescheiden zijn door de cycloonafscheider verzameld zijn in de vastestoftoevoerinrichting door de terugkeertoevoerinrichting en het oxidatieovenlichaam betreden door de materiaalinlaat.1. High temperature oxidation device for high salinity hazardous waste, which consists of an oxidation furnace body, a hot air inlet, an air distribution plate, a fixed feeding device, a material distributor, a classification means, a cyclone separator, an energy saving heat exchanger, a return feeding device, a bag filter, a wet filter and a sealing discharge device, wherein the oxidation furnace body is a vertical cylinder structure, wherein the diameter of the cylinder is a straight cylinder or a cylinder of unequal width of any size, wherein the height-to-diameter ratio is 1:(0.1- 1) and wherein an outer wall and lining material of the furnace body are made of materials resistant to high temperatures, wherein the oxidation furnace body has a solid discharge port and is connected to a sealing discharge device and wherein sealing discharge device is a spiral sealing structure to prevent the system is leaking; wherein the oxidation furnace body has a hot air inlet on the bottom, a material inlet in the middle and a hot air outlet on the top, wherein the hot air inlet is provided with an adjustable valve to adjust the hot air temperature and wherein the inlet air temperature is 400-1400°C; wherein the air distribution plate is a spiral structure or an absorbent structure to distribute the heat air and increase the wind speed to prevent solid objects from falling, wherein the cavity diameter of the absorbent structure is 2-300mm and the cavity spacing is 0.5-15mm ; wherein the solid material supply device is a screw conveyor means; wherein the material distributor is an orifice plate, a conduit or a nozzle structure for feeding solid or liquid materials, wherein the material distribution diameter is 0.001-10mm, wherein the material distributor is set at any position in the cylinder and the material and hot air are conveyed with the to be with or against the current; wherein the classification means is an orifice plate structure or a mesh structure to block the passage of particles and wherein the cavity diameter is 0.5-200mm; wherein the cyclone separators are one or more in parallel or in series to capture particulate matter; wherein the energy-saving heat exchanger is a device that uses heat from the exhaust gas and uses cold air to cool the exhaust gas and wherein the exchanged warm air is used for the combustion of the hot air heater or for heating in other suitable environments; wherein the return feed device is a spiral or straight cylinder structure for returning the material to the oxidation furnace to continue heating; wherein the bag filter and wet filter are used to emit gas treatment; wherein the hot gas outlet of the oxidation furnace body is connected to the inlet and outlet of the cyclone separator, the inlet and outlet of the energy saving heat exchanger, the inlet and outlet of the bag filter and the inlet and outlet of the wet filter through the pipeline in bend and finally the exhaust gas is discharged; wherein the solids separated by the cyclone separator are collected in the solid feeding device through the return feeding device and enter the oxidation furnace body through the material inlet.
NL2032126A 2022-06-10 2022-06-10 High-temperature oxidation device for high-salt dangerous waste NL2032126B1 (en)

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NL2032126A NL2032126B1 (en) 2022-06-10 2022-06-10 High-temperature oxidation device for high-salt dangerous waste

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NL2032126B1 true NL2032126B1 (en) 2023-12-18

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